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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Trimethylphosphine

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Trimethylphosphine

Cas:594-09-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 594-09-2 with best quality

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

High Purity Trimethylphosphine Cas No: 594-09-2 CAS NO.594-09-2

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $2.0 / 6.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Trimethylphosphine

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $2.5 / 5.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

TrimethylphosphineCAS NO.:594-09-2

Cas:594-09-2

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Trimethylphosphine

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phosphine, trimethyl-(6CI,8CI,9CI)

Cas:594-09-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediates, Trimethylphosphine CAS:594-09-2

Cas:594-09-2

Min.Order:1 Kilogram

FOB Price: $90.5 / 94.6

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Trimethylphosphine CAS:594-09-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Trimethylphosphine CAS:594-09-2

Cas:594-09-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphine, trimethyl-(6CI,8CI,9CI)

Cas:594-09-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trimethylphosphine

Cas:594-09-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Trimethylphosphine/High quality/Best price

Cas:594-09-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Trimethylphosphine

Cas:594-09-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Trimethylphosphine Chemical Properties Melting point -86 °C (lit.) Boiling point 38-40 °C (lit.) density 0.738 g/mL at 20 °C (lit.) vapor pressure 7.24 psi ( 20 °C) refractive index n20/D 1.428(lit.) Fp −

Trimethylphosphine

Cas:594-09-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

594-09-2 Application:594-09-2

Trimethylphosphine /594-09-2

Cas:594-09-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Trimethylphosphine

Cas:594-09-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Phosphine, trimethyl-(6CI,8CI,9CI)

Cas:594-09-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Other

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

trimethylphosphane CAS No.594-09-2

Cas:594-09-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Trimethylphosphine cas 594-09-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Trimethylphosphine cas 594-09-2

Cas:594-09-2

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Trimethylphosphine

Cas:594-09-2

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

594-09-2

Cas:594-09-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Trimethylphosphine 594-09-2

Cas:594-09-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

Re(C5H5)(CO)(NO)(CH3)(P(CH3)3)2

Re(C5H5)(CO)(NO)(CH3)(P(CH3)3)2

A

(η5-C5H5)(CO)(NO)ReCH3

(η5-C5H5)(CO)(NO)ReCH3

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In acetone for 1 h; evapd. slowly under vacuo;A 98%
B n/a
In [(2)H6]acetone at room temp. for 1 day;
In tetrahydrofuran Kinetics; monitored by UV;
methyl isocyanate
593-75-9, 685498-28-6

methyl isocyanate

(η(5)-C5Me5)Co(PMe3)2

(η(5)-C5Me5)Co(PMe3)2

A

{(C5(CH3)5)Co(CNCH3)(P(CH3)3)}

{(C5(CH3)5)Co(CNCH3)(P(CH3)3)}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether under Ar, reaction temp.: -78°C, warmed to room temp.; removal of solvent, extn. (pentane), brought to dryness in vac., stored at -78°C for 2 days;A 95%
B n/a
methylene chloride
74-87-3

methylene chloride

phosphan
7803-51-2

phosphan

A

methylphosphine
593-54-4

methylphosphine

B

dimethylphosphane
676-59-5

dimethylphosphane

C

chloro-tetramethyl-phosphorane
880343-42-0

chloro-tetramethyl-phosphorane

D

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With potassium hydroxide; PTK In toluene at 15℃; for 18h;A 4%
B 92%
C 4 g
D 2%
methylenetriphenylphosphorane-(4,5-diethyl-2,5-dihydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborole)
114130-53-9

methylenetriphenylphosphorane-(4,5-diethyl-2,5-dihydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborole)

A

dimeric (P-B)(2)-4,5-diethyl-1,2,5,6-tetrahydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborine * toluene
114182-21-7

dimeric (P-B)(2)-4,5-diethyl-1,2,5,6-tetrahydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborine * toluene

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With toluene In toluene Ar atmosphere, refluxing (3 h); sublimation of PMe3, recrystn. of B-complex (hot toluene), washing (toluene), drying (0.001 Torr); elem. anal.;A 84%
B 92%
(η5-C5Me5)(PMe3)2Ru(CH2SiMe3)
87640-52-6

(η5-C5Me5)(PMe3)2Ru(CH2SiMe3)

Triethoxysilane
998-30-1

Triethoxysilane

A

tetramethylsilane
75-76-3

tetramethylsilane

B

(η5-C5Me5)(PMe3)ruthenium{Si(OEt)3}2H

(η5-C5Me5)(PMe3)ruthenium{Si(OEt)3}2H

C

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In inert atmosphere, heating of Ru-complex with HSi(OEt)3 (80°C, 12 h, closed vessel), briefly pumping to remove PMe3, continued heating (80°C, 6 h).; Evapn. in vac. gives a waxy solid, recrystn. (acetone), elem. anal.;A n/a
B 92%
C n/a
(bis(diisopropylamino)phosphanyl)diazomethane, lithium salt
113533-26-9

(bis(diisopropylamino)phosphanyl)diazomethane, lithium salt

rhodium(trimethylphosphine)4Cl
70525-09-6, 92670-96-7

rhodium(trimethylphosphine)4Cl

5-bis(trimethylphosphine)rhoda-4-bis(diisopropylamino)phospha-1-n-butyl-Δ2-pyrazoline
116405-38-0

5-bis(trimethylphosphine)rhoda-4-bis(diisopropylamino)phospha-1-n-butyl-Δ2-pyrazoline

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With n-C4H9Li byproducts: LiCl; Excess of n-Buli.;A 90%
B n/a
cis-HRh(COCH3)(P(CH3)3)3Cl
82555-25-7

cis-HRh(COCH3)(P(CH3)3)3Cl

[Rh(trimethylphosphine)3]Cl
36103-64-7

[Rh(trimethylphosphine)3]Cl

C

methane
34557-54-5

methane

D

acetaldehyde
75-07-0

acetaldehyde

E

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
Rh complex heated at 90°C for 2 h; collection of the volatile products under high vaccum;A 13%
B 80%
C 13%
D 87%
E 19%
In benzene-d6 soln. of Rh complex in benzene-d6 heated at 70°C for 2 h;A 54%
B 15%
C 51%
D 14%
E 50%
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

dimethylfumarate
624-49-7

dimethylfumarate

A

{cyclopentadienyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

{cyclopentadienyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether addn. of fumaric acid dimethylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), chromy. on Al2O3, elution with ether-pentane, concn. (vac.), filtn., washing with pentane and drying (vac.); elem. anal.;A 85%
B n/a
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

{cyclopentadienyl(trimethylphosphane)(acrylic acid methylester)cobalt}

{cyclopentadienyl(trimethylphosphane)(acrylic acid methylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In hexane addn. of acrylic acid methylester to the Co compd. in hexane under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 85%
B n/a
In diethyl ether addn. of acrylic acid methylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 85%
B n/a
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

Benzyl isocyanide
88333-03-3, 10340-91-7

Benzyl isocyanide

A

(η(5)-C5H5)Co(PMe3)(CNCH2Ph)

(η(5)-C5H5)Co(PMe3)(CNCH2Ph)

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In benzene under Ar, stirred for a few minutes at room temp.; removal of solvent in vac., extn. (pentane), cooling to -78°C; elem. anal.;A 85%
B n/a
(η2-1,2-diphenyl-1-cyclopropene)(trimethylphosphane)zirconocene
133911-64-5

(η2-1,2-diphenyl-1-cyclopropene)(trimethylphosphane)zirconocene

A

1,1-bis(η5-cyclopentadienyl)-2,3-diphenyl-1-(trimethylphosphane)-1-zirconacyclobut-2-ene
133911-65-6

1,1-bis(η5-cyclopentadienyl)-2,3-diphenyl-1-(trimethylphosphane)-1-zirconacyclobut-2-ene

B

1,1-bis(η5-cyclopentadienyl)-2,3-diphenyl-1-zirconacyclobut-2-ene
133911-66-7

1,1-bis(η5-cyclopentadienyl)-2,3-diphenyl-1-zirconacyclobut-2-ene

C

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In tetrahydrofuran-d8 (Ar), -100°C; (31)P-NMR;A 84%
B 0%
C 16%
bis(trimethylphosphine)(eta.5-indenyl)cobalt

bis(trimethylphosphine)(eta.5-indenyl)cobalt

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

{indenyl(trimethylphosphane)(acrylic acid methylester)cobalt}

{indenyl(trimethylphosphane)(acrylic acid methylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In hexane addn. of acrylic acid methylester to the Co compd. in hexane under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 83%
B n/a
In diethyl ether addn. of acrylic acid methylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 83%
B n/a
tetrakis(trimethylphosphine)platinum(0)
33937-27-8

tetrakis(trimethylphosphine)platinum(0)

Benzo[b]thiophene
95-15-8

Benzo[b]thiophene

[(CH3)3P]2PtC8SH6
202662-81-5

[(CH3)3P]2PtC8SH6

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In toluene reflux; elem. anal.;A 83%
B n/a
carbon disulfide
75-15-0

carbon disulfide

tetrakis(trimethylphosphine)nickel(0)
28069-69-4

tetrakis(trimethylphosphine)nickel(0)

A

[nickel(0)(trimethylphosphine)3(η2-SCS)]

[nickel(0)(trimethylphosphine)3(η2-SCS)]

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃; for 24h; Inert atmosphere; Schlenk technique;A 81%
B n/a
trans-(2,4,6-trimethylphenyl)chlorobis(trimethylphosphine)nickel(II)

trans-(2,4,6-trimethylphenyl)chlorobis(trimethylphosphine)nickel(II)

sodium cyclopentadienide

sodium cyclopentadienide

A

{(η5-C5H5)Ni(2,4,6-C6H2Me3)(PMe3)}

{(η5-C5H5)Ni(2,4,6-C6H2Me3)(PMe3)}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In not given byproducts: NaCl; N2 atmosphere; react. of Ni-complex with excess of NaCp (1.5 equiv) at 20°C for 12 h; elem. anal.;A 80%
B n/a
trans-{Ni(2,4,6-C6H2Me3)Br(PMe3)2}

trans-{Ni(2,4,6-C6H2Me3)Br(PMe3)2}

sodium cyclopentadienide

sodium cyclopentadienide

A

{(η5-C5H5)Ni(2,4,6-C6H2Me3)(PMe3)}

{(η5-C5H5)Ni(2,4,6-C6H2Me3)(PMe3)}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In not given byproducts: NaBr; N2 atmosphere; react. of Ni-complex with excess of NaCp (1.5 equiv) at 20°C for 12 h; elem. anal.;A 80%
B n/a
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

dimethylfumarate
624-49-7

dimethylfumarate

A

{indenyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

{indenyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether addn. of fumaric acid dimethylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), chromy. on Al2O3, elution with ether-pentane, concn. (vac.), filtn., washing with pentane and drying (vac.); elem. anal.;A 80%
B n/a
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

dimethylfumarate
624-49-7

dimethylfumarate

A

{trifluoromethylcyclopentadienyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

{trifluoromethylcyclopentadienyl(trimethylphosphane)2(fumaric acid dimethylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether addn. of fumaric acid dimethylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), chromy. on Al2O3, elution with ether-pentane, concn. (vac.), filtn., washing with pentane and drying (vac.); elem. anal.;A 78%
B n/a
(η5-C5Me5)(PMe3)2Ru(CH2SiMe3)
87640-52-6

(η5-C5Me5)(PMe3)2Ru(CH2SiMe3)

diphenylsilyl chloride
1631-83-0

diphenylsilyl chloride

A

tetramethylsilane
75-76-3

tetramethylsilane

B

(η5-C5Me5)(PMe3)ruthenium{Si(phenyl)2Cl}2H

(η5-C5Me5)(PMe3)ruthenium{Si(phenyl)2Cl}2H

C

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In inert atmosphere, heating of Ru-complex with HSi(Ph2Cl)3 (110°C, 16 h, closed vessel, stirring), periodic pumping to remove PMe3.; Cooling to room temp., addn. of pentane, cooling (-78°C, 6 h), filtn. of pale yellow crystals, washing (pentane, -78°C), drying in vac, elem. anal.;A n/a
B 78%
C n/a
chlorodimethyloxobis(trimethylphosphine)rhenium(V)

chlorodimethyloxobis(trimethylphosphine)rhenium(V)

1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In toluene N2 or Ar atmosphere of vac.; stirring (1 h); filtn., concn. (vac.), cooling (-20°C); elem. anal.;A 76%
B n/a
allylmagnesium bromide
1730-25-2

allylmagnesium bromide

(η5-pentamethylcyclopentadienyl)(PMe3)Fe(C3H5)

(η5-pentamethylcyclopentadienyl)(PMe3)Fe(C3H5)

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether inert atmosphere; -78°C, then room temp., stirring 15 min.; evapn. (vac.), drying, extn. (petroleum ether), partial evapn. of filtrate, crystn. (-78°C), collection (filtration), drying (vac.); elem. anal.;A 76%
B n/a
trans-MoCl(NO)(PMe3)4
119998-04-8

trans-MoCl(NO)(PMe3)4

MoCl(η3-S2CPMe3)(NO)(PMe3)2
119998-14-0

MoCl(η3-S2CPMe3)(NO)(PMe3)2

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With CS2 In tetrahydrofuran Ar or N2 atmosphere; addn. of 1.4 equiv of CS2 to a soln. of Mo-complex, stirring (24 h at room temp.), pptn.; collection (filtration), washing (Et2O), crystn. (CHCl3), -30°C;A 75%
B n/a
{AgNO3(trimethylphosphine)}

{AgNO3(trimethylphosphine)}

thiourea
17356-08-0

thiourea

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In water heating an aq. soln. of the Ag compound with a concd. soln. of thiourea with N2 bubbling through the soln.;75%
bis(trimethylphosphine)(η5-trifluoromethylcyclopentadienyl)cobalt

bis(trimethylphosphine)(η5-trifluoromethylcyclopentadienyl)cobalt

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

{trifluoromethylcyclopentadienyl(trimethylphosphane)(acrylic acid methylester)cobalt}

{trifluoromethylcyclopentadienyl(trimethylphosphane)(acrylic acid methylester)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In hexane addn. of acrylic acid methylester to the Co compd. in hexane under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 73%
B n/a
In diethyl ether addn. of acrylic acid methylester to the Co compd. in ether under Ar and stirring at room temp. for 30 min; evapn. (vac.), dissolving in ether, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with cold pentane and drying (vac.); elem. anal.;A 73%
B n/a
bis(trimethylphosphine)(eta.5-indenyl)cobalt

bis(trimethylphosphine)(eta.5-indenyl)cobalt

acrylonitrile
107-13-1

acrylonitrile

A

{indenyl(trimethylphosphane)2(acrylonitrile)cobalt}

{indenyl(trimethylphosphane)2(acrylonitrile)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether addn. of acrylonitrile to the Co compd. in ether under Ar and stirring at room temp. for 1 h; evapn. (vac.), dissolving in ether-hexane, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with pentane and drying (vac.); elem. anal.; exo-endo-mixture, identified by (1)H-NMR;A 73%
B n/a
(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

acrylonitrile
107-13-1

acrylonitrile

A

{cyclopentadienyl(trimethylphosphane)2(acrylonitrile)cobalt}

{cyclopentadienyl(trimethylphosphane)2(acrylonitrile)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether addn. of acrylonitrile to the Co compd. in ether under Ar and stirring at room temp. for 1 h; evapn. (vac.), dissolving in ether-hexane, chromy. on Al2O3, elution with ether-hexane, concn., cooling to -78°C, filtn., washing with pentane and drying (vac.); elem. anal.; exo-endo-mixture, identified by (1)H- and (13)C-NMR;A 72%
B n/a
tetrakis(trimethylphosphine)nickel(0)
28069-69-4

tetrakis(trimethylphosphine)nickel(0)

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

A

[nickel(trimethylphosphine)3(η2-SCNPh)]

[nickel(trimethylphosphine)3(η2-SCNPh)]

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃; for 24h; Inert atmosphere; Schlenk technique;A 72%
B n/a
MoCl2(CO)2{P(CH3)3}3
83828-53-9

MoCl2(CO)2{P(CH3)3}3

potassium isopropylxanthate
140-92-1

potassium isopropylxanthate

A

Mo(η3-(S,S',C)S2CO-i-Pr)2(CO)(trimethylphosphine)2
125841-34-1

Mo(η3-(S,S',C)S2CO-i-Pr)2(CO)(trimethylphosphine)2

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: CO, KCl; N2 or Ar atmosphere; stirring (2 h, room temp.); evapn. (vac.), extn. (petroleum ether/Et2O 1:1), centrifugation and cooling (-35°C); elem. anal.;A 70%
B n/a
maleic anhydride
108-31-6

maleic anhydride

(cyclopentadienyl)bis(trimethylphosphine)cobalt

(cyclopentadienyl)bis(trimethylphosphine)cobalt

A

{cyclopentadienyl(trimethylphosphane)2(maleic anhydride)cobalt}

{cyclopentadienyl(trimethylphosphane)2(maleic anhydride)cobalt}

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
In benzene addn. of maleic anhydride to the Co compd. in benzene under Ar and stirring at room temp. for 30 min; evapn. (vac.), washing with hexane, recrystn. from acetone-hexane, filtn., washing with ether and pentane and drying (vac.); elem. anal.;A 70%
B n/a
trans-{W(ethylene)2(P(CH3)3)4}
84879-23-2

trans-{W(ethylene)2(P(CH3)3)4}

A

{WH(OOCCHCH2)(C2H4)(P(CH3)3)2}2*0.5(C2H5)2O
122214-24-8

{WH(OOCCHCH2)(C2H4)(P(CH3)3)2}2*0.5(C2H5)2O

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With CO2 In diethyl ether under N2; reacting ethene complex with CO2, 20°C, 1 atm, 30 min; filtering off ppt., 2nd crop from mother liquor by cooling to -20°C overnight; elem. anal.;A 65%
B n/a
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

trimethylphosphane
594-09-2

trimethylphosphane

(6-Bromhexyl)trimethylphosphoniumbromid
72385-53-6

(6-Bromhexyl)trimethylphosphoniumbromid

Conditions
ConditionsYield
In toluene for 72h; Ambient temperature;100%
allyl bromide
106-95-6

allyl bromide

trimethylphosphane
594-09-2

trimethylphosphane

trimethyl-2-propen-1-ylphosphonium bromide
41301-43-3

trimethyl-2-propen-1-ylphosphonium bromide

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 0 - 20℃; for 2.5h; Inert atmosphere;100%
In diethyl ether Ambient temperature;
In toluene at 20℃; Inert atmosphere;
In dichloromethane for 12h; Inert atmosphere;
(bromomethyl)pentafluorobenzene
1765-40-8

(bromomethyl)pentafluorobenzene

trimethylphosphane
594-09-2

trimethylphosphane

Trimethyl<(pentafluorphenyl)methyl>phosphoniumbromid
80431-31-8

Trimethyl<(pentafluorphenyl)methyl>phosphoniumbromid

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1h;100%
1,10-diiododecane
16355-92-3

1,10-diiododecane

trimethylphosphane
594-09-2

trimethylphosphane

(10-Iodo-decyl)-trimethyl-phosphonium; iodide
138730-46-8

(10-Iodo-decyl)-trimethyl-phosphonium; iodide

Conditions
ConditionsYield
In toluene for 72h; Ambient temperature;100%
(2-chloroethyl)diphenylphosphane
5055-11-8

(2-chloroethyl)diphenylphosphane

trimethylphosphane
594-09-2

trimethylphosphane

(2-Diphenylphosphanyl-ethyl)-trimethyl-phosphonium; chloride
138710-61-9

(2-Diphenylphosphanyl-ethyl)-trimethyl-phosphonium; chloride

Conditions
ConditionsYield
In toluene for 72h; Heating;100%
3-(diphenylphosphino)propyl chloride
57137-55-0

3-(diphenylphosphino)propyl chloride

trimethylphosphane
594-09-2

trimethylphosphane

(3-Diphenylphosphanyl-propyl)-trimethyl-phosphonium; chloride
170125-48-1

(3-Diphenylphosphanyl-propyl)-trimethyl-phosphonium; chloride

Conditions
ConditionsYield
In toluene for 72h; Heating;100%
Phosphoric acid (E)-2-chloro-1-chloromethyl-vinyl ester diethyl ester
89094-99-5

Phosphoric acid (E)-2-chloro-1-chloromethyl-vinyl ester diethyl ester

trimethylphosphane
594-09-2

trimethylphosphane

O,O-diethyl α-(trimethylphosphoniummethyl)-β-chlorovinyl phosphate chloride
120115-73-3

O,O-diethyl α-(trimethylphosphoniummethyl)-β-chlorovinyl phosphate chloride

Conditions
ConditionsYield
at 0℃; for 2h;100%
In diethyl ether for 12h; Ambient temperature; Yield given;
C16H31PSi

C16H31PSi

trimethylphosphane
594-09-2

trimethylphosphane

C19H40P2Si

C19H40P2Si

Conditions
ConditionsYield
In pentane at 0℃; Addition;100%
(η5-C5H5){P(OMe)3}2MoCPh

(η5-C5H5){P(OMe)3}2MoCPh

trimethylphosphane
594-09-2

trimethylphosphane

{(η5-C5H5)(PMe3)2(Cl)MoCPh}Cl

{(η5-C5H5)(PMe3)2(Cl)MoCPh}Cl

Conditions
ConditionsYield
In dichloromethane Irradiation (UV/VIS);100%
In chloroform Irradiation (UV/VIS);100%
In chloroform Irradiation (UV/VIS); addn. of PMe3 to the Mo compd. in CHCl3 and irradiation (Hanovia medium pressure mercury vapor lamp) for 30 min at room temp.; evapn. (vac.), dissolving in CH2Cl2 and pptn. with hexane; elem. anal.;60%
Ir(C4(COOCH3)4)(C(CH2)3O){P(C6H5)3}2(CO)(1+)*BF4(1-)=Ir(C4(COOCH3)4)(C(CH2)3O){P(C6H5)3}2(CO)BF4

Ir(C4(COOCH3)4)(C(CH2)3O){P(C6H5)3}2(CO)(1+)*BF4(1-)=Ir(C4(COOCH3)4)(C(CH2)3O){P(C6H5)3}2(CO)BF4

trimethylphosphane
594-09-2

trimethylphosphane

Ir(C3H3O2)4{P(C6H5)3}2(CO)(CCHCH2CH2O)

Ir(C3H3O2)4{P(C6H5)3}2(CO)(CCHCH2CH2O)

Conditions
ConditionsYield
In acetone cooled to -76°C, stirred at 23°C for 3h; filtered; NMR, IR, elem. anal.;100%
(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)
12146-37-1, 124717-04-0

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)

trimethylphosphane
594-09-2

trimethylphosphane

cis-bis(trimethylphosphine)tetracarbonylmolybdenum
16027-45-5

cis-bis(trimethylphosphine)tetracarbonylmolybdenum

B

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

Conditions
ConditionsYield
In tetrahydrofuran reaction in a calorimeter under argon;A 100%
B n/a
bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

trimethylphosphane
594-09-2

trimethylphosphane

bis(cyclopentadienyl)bis(trimethylphosphane)titanium(II)

bis(cyclopentadienyl)bis(trimethylphosphane)titanium(II)

Conditions
ConditionsYield
With Mg In tetrahydrofuran addn. of Mg (177 mmol) and P(CH3)3 (200 mmol) to soln. of ((C5H5)2TiCl2) (40.2 mmol) in THF under Ar; stirring for 20 h;; evapg. solvent at 1E-2 bar; extg. residue with pentane; crystn. at -78°C; elem. anal.;;100%
With n-C4H9Li In tetrahydrofuran byproducts: LiCl, C4H8, C4H10; (Ar); to soln. of Ti complex was dropped hexane soln. of BuLi at -78°C within 0,5 h and stirred for 0,5 h, then was added PMe3, soln. was allowed to warm up to room temp. within 8 h and volatiles were removed at 0,1 Torr; pentane soln. of residue was filtered and filtrate cooled to -20°C, black crystals pptd., which were filtered off and dried at 0,01 Torr; elem. anal.;90%
With Na#Hg In diethyl ether byproducts: NaCl; (Ar); a suspn. of Ti complex in a soln. of ligand added slowly to Na amalgam, stirred for 12 h; filtered, evapd. (Ar);66%
cis-bis{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II)
36223-69-5

cis-bis{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II)

trimethylphosphane
594-09-2

trimethylphosphane

cis-bis(trimethylsilylmethyl)bis(trimethylphosphine)platinum(II)

cis-bis(trimethylsilylmethyl)bis(trimethylphosphine)platinum(II)

Conditions
ConditionsYield
In toluene under Ar, heated to 60°C for 14 days; removal of solvent in vacuo, addn. of n-hexane, cooled to -25°C; elem. anal.;100%
bis(ethenyldimethylsilylmethyl)(cod)Pt(II)

bis(ethenyldimethylsilylmethyl)(cod)Pt(II)

trimethylphosphane
594-09-2

trimethylphosphane

cis-bis(sila-neohexenyl)-bis-(trimethylphosphine)platinum(II)

cis-bis(sila-neohexenyl)-bis-(trimethylphosphine)platinum(II)

Conditions
ConditionsYield
In benzene (under N2 or Ar) addn. of P-compd. to Pt-complex in benzene at room temp., standing overnight (ambient temp.); solvent removal (vac.); elem. anal.;100%
{(Rh(η5-pentamethylcyclopentadienyl)Br2)2}

{(Rh(η5-pentamethylcyclopentadienyl)Br2)2}

trimethylphosphane
594-09-2

trimethylphosphane

(η5-C5Me5)Rh{PMe3}Br2

(η5-C5Me5)Rh{PMe3}Br2

Conditions
ConditionsYield
In dichloromethane PMe3 was condensed into a flask with complex and CH2Cl2 at -196°C, the mixt. was warmed to 25°C and stirred for 10 min;; recrystd. from CH2Cl2-hexane;;100%
{(η4-2-methyl-1,3-pentadiene)cobalt(carbonyl)3} tetrafluoroborate
128205-88-9

{(η4-2-methyl-1,3-pentadiene)cobalt(carbonyl)3} tetrafluoroborate

trimethylphosphane
594-09-2

trimethylphosphane

anti-{(η3-1-trimethylphosphonium-2-methyl-2-pentenyl)cobalt(carbonyl)3} tetrafluoroborate

anti-{(η3-1-trimethylphosphonium-2-methyl-2-pentenyl)cobalt(carbonyl)3} tetrafluoroborate

Conditions
ConditionsYield
In nitromethane addn. of the Co complex to CH3NO2 at 0°C, stirring to complete dissoln., dropwise addn. of PMe3 in CH3NO2 and react. for 10-15 min; addn. of Et2O, removing the solvent using cannula and drying (vac.);100%
(C5H5)MoCl2(P(C6H5)3)2

(C5H5)MoCl2(P(C6H5)3)2

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

Conditions
ConditionsYield
In dichloromethane byproducts: P(C6H5)3; mixing of the Mo compd. with the free phosphine (molar ratio 2.6:1) in CH2Cl2;;100%
C5H5V(CO)2(HCCH)

C5H5V(CO)2(HCCH)

trimethylphosphane
594-09-2

trimethylphosphane

C5H5V(CO)(P(CH3)3)(HCCH)

C5H5V(CO)(P(CH3)3)(HCCH)

Conditions
ConditionsYield
In pentane a solution of the alkyne-complex was cooled to -78°C; Me3P was added; standing over dry ice overnight; evaporation to dryness; dried in high vacuum;100%
cyclopentadienylmolybdenum(III)(bis(diphenylphosphino)ethane)Cl2

cyclopentadienylmolybdenum(III)(bis(diphenylphosphino)ethane)Cl2

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

Conditions
ConditionsYield
In dichloromethane mixing of the Mo compd. with the free phosphine (molar ratio 2.3:1) in CH2Cl2;;A 100%
B n/a
C5H5V(CO)2(CH3CCCH3)

C5H5V(CO)2(CH3CCCH3)

trimethylphosphane
594-09-2

trimethylphosphane

C5H5V(CO)(P(CH3)3)(CH3CCCH3)

C5H5V(CO)(P(CH3)3)(CH3CCCH3)

Conditions
ConditionsYield
In pentane a solution of the alkyne-complex was cooled to -78°C; Me3P was added; standing over dry ice overnight; evaporation to dryness; dried in high vacuum;100%
C5H5V(CO)2((CH3)3SiCCSi(CH3)3)

C5H5V(CO)2((CH3)3SiCCSi(CH3)3)

trimethylphosphane
594-09-2

trimethylphosphane

C5H5V(CO)(P(CH3)3)((CH3)3SiCCSi(CH3)3)

C5H5V(CO)(P(CH3)3)((CH3)3SiCCSi(CH3)3)

Conditions
ConditionsYield
In pentane a solution of the alkyne-complex was cooled to -78°C; Me3P was added; standing over dry ice overnight; evaporation to dryness; dried in high vacuum;100%
C5H5V(CO)2(HCCC6H5)

C5H5V(CO)2(HCCC6H5)

trimethylphosphane
594-09-2

trimethylphosphane

C5H5V(CO)(P(CH3)3)(HCCC6H5)

C5H5V(CO)(P(CH3)3)(HCCC6H5)

Conditions
ConditionsYield
In pentane a solution of the alkyne-complex was cooled to -78°C; Me3P was added; standing over dry ice overnight; evaporation to dryness; dried in high vacuum;100%
C5H5V(CO)2(C6H5CCC6H5)

C5H5V(CO)2(C6H5CCC6H5)

trimethylphosphane
594-09-2

trimethylphosphane

C5H5V(CO)(P(CH3)3)(H5C6CCC6H5)

C5H5V(CO)(P(CH3)3)(H5C6CCC6H5)

Conditions
ConditionsYield
In pentane a solution of the alkyne-complex was cooled to -78°C; Me3P was added; standing over dry ice overnight; evaporation to dryness; dried in high vacuum;100%
(η5-C5H5)(CO)(NO)ReCH3

(η5-C5H5)(CO)(NO)ReCH3

trimethylphosphane
594-09-2

trimethylphosphane

Re(C5H5)(CO)(NO)(CH3)(P(CH3)3)2

Re(C5H5)(CO)(NO)(CH3)(P(CH3)3)2

Conditions
ConditionsYield
In hexane evapd.;100%
In benzene-d6 under N2, soln. of educts in C6D6 heated at 51°C for 30 min; not isolated; detected by NMR;
In [(2)H6]acetone in NMR tube at room temp.;
3-(NNN'N'-tetramethylethylenediamine)-1,2-dicarba-3-palladadodecaborane
67538-15-2

3-(NNN'N'-tetramethylethylenediamine)-1,2-dicarba-3-palladadodecaborane

trimethylphosphane
594-09-2

trimethylphosphane

3,3-bis(trimethylphosphine)-1,2-dicarba-3-palladadodecaborane
67538-14-1

3,3-bis(trimethylphosphine)-1,2-dicarba-3-palladadodecaborane

Conditions
ConditionsYield
In dichloromethane PMe3 passed into soln. of Pd complex in CH2Cl2; added hexane, filtered, washed with Et2O/acetone, dried in vac.; elem. anal.;100%
(cyclopentadienyl)(carbonyl)(C8H6(C6H5))ruthenium

(cyclopentadienyl)(carbonyl)(C8H6(C6H5))ruthenium

trimethylphosphane
594-09-2

trimethylphosphane

(cyclopentadienyl)(carbonyl)(C8H6(C6H5)(PMe3))ruthenium

(cyclopentadienyl)(carbonyl)(C8H6(C6H5)(PMe3))ruthenium

Conditions
ConditionsYield
In benzene-d6 under N2; to Ru compd. in C6D6 addn. of PMe3 at room temp.; monitored by NMR; evapn. of solvent; elem. anal.;100%
{Cp(PEt3)2molybdenum(III) dichloride}

{Cp(PEt3)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

triethylphosphine
554-70-1

triethylphosphine

Conditions
ConditionsYield
In dichloromethane mixing of the Mo compd. with the free phosphine (molar ratio 4.5:1) in CH2Cl2;;A 100%
B n/a
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.1:1) in toluene;;A 100%
B n/a
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.1:1) in toluene;;A 100%
B n/a
{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.2:1) in toluene;;A 100%
B n/a
t-butylaminotetraisopropoxy(phenylimido)tungsten(VI)

t-butylaminotetraisopropoxy(phenylimido)tungsten(VI)

trimethylphosphane
594-09-2

trimethylphosphane

tetra-iso-propoxy(phenylimido)trimethylphosphinetungsten(VI)
97225-94-0

tetra-iso-propoxy(phenylimido)trimethylphosphinetungsten(VI)

Conditions
ConditionsYield
In petroleum ether PMe3 is added to soln. of W(NPh)(NH2CMe3)(OCHMe2)4 in petroleum ether and mixt. is stirred for 3 h; soln. is filtered, solvent removed;100%

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