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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Dimethylphenylphosphine

Cas:672-66-2

Min.Order:1 Kilogram

FOB Price: $3.0

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Dimethylphenylphosphine

Cas:672-66-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

672-66-2 DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 672-66-2 with best quality

Cas:672-66-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

DIMETHYLPHENYLPHOSPHINE CAS672-66-2

Cas:672-66-2

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phosphine,dimethylphenyl-

Cas:672-66-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

DIMETHYLPHENYLPHOSPHINE CAS:672-66-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

DIMETHYLPHENYLPHOSPHINE CAS:672-66-2

Cas:672-66-2

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphine,dimethylphenyl-

Cas:672-66-2

Min.Order:1 Kilogram

Negotiable

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phosphine,dimethylphenyl-

Cas:672-66-2

Min.Order:0

Negotiable

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply dimethylphenylphosphine

Cas:672-66-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Dimethyl(phenyl)phosphane

Cas:672-66-2

Min.Order:10 Gram

FOB Price: $100.0

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Dimethylphenylphosphine

Cas:672-66-2

Min.Order:0

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Type:Other

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Dimethylphenylphosphine 250mg

Cas:672-66-2

Min.Order:1 bottle

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Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-[2-(Morpholin-4-yl)ethoxy]benzaldehyde 97%

Cas:672-66-2

Min.Order:0

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

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Henan Tianfu Chemical Co., Ltd.

Good quantity Storage:R.T. Package:as per buyers Application:Reagent Transportation:by air/sea

Dimethylphenylphosphine, 99%

Cas:672-66-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Phosphine,dimethylphenyl-

Cas:672-66-2

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DB BIOTECH CO., LTD

best seller Application:API

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

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Hangzhou Fandachem Co.,Ltd

Dimethylphenylphosphine cas 672-66-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Dimethylphenylphosphine cas 672-66-2

Cas:672-66-2

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

Negotiable

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

672-66-2

Cas:672-66-2

Min.Order:0

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Hebei Muhuang Technology Co., Ltd

best seller Application:API

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

Dimethylphenylphosphine manufacturer

Cas:672-66-2

Min.Order:0

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

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HWRK Chem

in store Package:100g Application:Organic Chemicals

Dimethylphenylphosphine

Cas:672-66-2

Min.Order:0

Negotiable

Type:Trading Company

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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

National Research Platform ISO 9001 CAS No. 672-66-2

Cas:672-66-2

Min.Order:0

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Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Dimethylphenylphosphine CAS NO.672-66-2

Cas:672-66-2

Min.Order:0

Negotiable

Type:Trading Company

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Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

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Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

DIMETHYLPHENYLPHOSPHINE

Cas:672-66-2

Min.Order:0

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Type:Other

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Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

DiMethylphenylphosphine

Cas:672-66-2

Min.Order:1 Gram

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Type:Other

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Synthetic route

dimethylphenylphosphine-borane complex

dimethylphenylphosphine-borane complex

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With methanol; 4 A molecular sieve In tetrahydrofuran at 100℃; for 22h;100%
With piperazinomethyl polystyrene resin In toluene at 115℃; for 17h;
{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.2:1) in toluene;;A 100%
B n/a
dimethyl(phenyl)phosphine oxide
10311-08-7

dimethyl(phenyl)phosphine oxide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With polymethylhydrosiloxane In neat (no solvent) at 150℃; for 10h; Reagent/catalyst; Temperature; Inert atmosphere; Green chemistry;95%
With phenylsilane In neat (no solvent) at 110℃; for 1.75h; Reagent/catalyst; Temperature; Time; Inert atmosphere; Green chemistry;95%
With [AlH3(triethylamine)] In hexane at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;98 %Chromat.
With hexylsilane; trifluorormethanesulfonic acid In toluene at 70℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction;94 %Spectr.
With methanesulfonic acid; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 4.5h; Inert atmosphere; Schlenk technique;
(η-C5H5)2W(CH3)(CH2P(CH3)2C6H5)PF6

(η-C5H5)2W(CH3)(CH2P(CH3)2C6H5)PF6

A

(tungsten(η-cyclopentadienyl)2(ethylene)H)(PF6)

(tungsten(η-cyclopentadienyl)2(ethylene)H)(PF6)

B

(C5H5)2W(CH2P(CH3)2C6H5)(C2H5)(1+)*PF6(1-)
82917-98-4

(C5H5)2W(CH2P(CH3)2C6H5)(C2H5)(1+)*PF6(1-)

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
heated in sealed tube for 12 d at 75°C; elem. anal.;A n/a
B 86%
C n/a
[(C5H5)(C5H4)Zr(P(CH3)2C6H5)]2
71844-81-0

[(C5H5)(C5H4)Zr(P(CH3)2C6H5)]2

A

zirconocene dichloride
1291-32-3

zirconocene dichloride

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With hydrogenchloride In benzene-d6 (N2); HCl gas added to complex soln. at 0°C, shaken at room temp.; not isolated, detected by NMR;A 60%
B 80%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
75%
With diethyl ether
chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene byproducts: pyridine; N2 or Ar atmosphere of vac.; stirring (1 h); filtn., concn. (vac.), cooling (-20°C); elem. anal.;A 62%
B n/a
chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

trimethyloxo(dimethylphenylphosphine)rhenium(V)

trimethyloxo(dimethylphenylphosphine)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C

methylzinc chloride
5158-46-3

methylzinc chloride

Conditions
ConditionsYield
In toluene N2 or Ar atmosphere of vac.; 0°C; removal of solvent (0°C, vac.), extn. (pentane), removal of pentane (vac.);A 51%
B n/a
C n/a
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

trimethyloxo(bipyridine)rhenium(V)

trimethyloxo(bipyridine)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene N2 or Ar atmosphere of vac.; addn. of soln. of ZnMe2 to soln. of Re-compd. in toluene (0°C), removal of solvent (0°C, vac.), extn. (pentane), addn. of bipy; removal of solvent and excess of bipy (vac.), crystn. (pentane, -50°C);A 35%
B n/a
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With benzene
Dimethyl-phenyl-phosphonium
24151-41-5

Dimethyl-phenyl-phosphonium

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With methane; trimethylphosphane at 47℃; under 0.01 Torr; Equilibrium constant; Thermodynamic data; irradiation with short electron pulse; ΔG;
dimethyldiphenylphosphonium bromide
2129-85-3

dimethyldiphenylphosphonium bromide

A

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In methanol; acetonitrile at 20℃; Product distribution; cathodic reduction, influence of potential on the product ratio;
trimethylphosphane
594-09-2

trimethylphosphane

A

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

B

Mo2Cl4(PMe2Ph)3(PMe3)

Mo2Cl4(PMe2Ph)3(PMe3)

Conditions
ConditionsYield
With Mo2Cl4(PMe2Ph)4 In (2)H8-toluene Thermodynamic data; ΔH(excit.); ΔS(excit.);
water
7732-18-5

water

dichloro-phenyl-phosphine; compound with dimethylphenylphosphine

dichloro-phenyl-phosphine; compound with dimethylphenylphosphine

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

fluorobenzene
462-06-6

fluorobenzene

dimethyl(trimethylsilyl)phosphine
26464-99-3

dimethyl(trimethylsilyl)phosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 at 180℃; for 90h;60 % Spectr.
C8H11P*H(1+)*BF4(1-)

C8H11P*H(1+)*BF4(1-)

(dibutyl)(phenyl)phosphine
6372-44-7

(dibutyl)(phenyl)phosphine

A

C14H23P*BF4(1-)*H(1+)

C14H23P*BF4(1-)*H(1+)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; Equilibrium constant;
C8H11P*H(1+)*BF4(1-)

C8H11P*H(1+)*BF4(1-)

cyclohexyldiphenylphosphine
6372-42-5

cyclohexyldiphenylphosphine

A

C18H21P*H(1+)*BF4(1-)

C18H21P*H(1+)*BF4(1-)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; Equilibrium constant;
triphenylphosphine
603-35-0

triphenylphosphine

thiocyanato

thiocyanato

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) Na / 1.) liquid NH3, 1 h, 2.) 2.5 h
2: 1.) Na; NH4Cl / liquid NH3, 1.) 1 h, 2.) 2.5 h
View Scheme
Conditions
ConditionsYield
With H2 In toluene Copper-complex is hydrogenated under 3 atm of H2 in toluene, the color of the soln. changes quickly from yellow to orange (under exclusion of air).; investigation by (1)H NMR;
cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 Cis-isomer is dissolved in C6D6 in a NMR-tube.; monitored by (31)P NMR for 19 days;
trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 Trans-isomer is dissolved in C6D6 in a NMR-tube.; monitored by (31)P NMR for 19 days;
Cp2Ti(CH2CO).PMe2Ph
118458-17-6

Cp2Ti(CH2CO).PMe2Ph

acetylene
74-86-2

acetylene

A

(C5H5)2TiOCCH2CHCH
82808-18-2

(C5H5)2TiOCCH2CHCH

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given
Cp2TiCH2.PMe2Ph
108969-89-7

Cp2TiCH2.PMe2Ph

triethylphosphine
554-70-1

triethylphosphine

A

Cp2TiCH2.PEt3
84254-01-3

Cp2TiCH2.PEt3

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given Kinetics; equil. react.; (31)P-NMR;
(dimethylphenylphosphine)bis(2,4-dimethylpentadienyl)titanium

(dimethylphenylphosphine)bis(2,4-dimethylpentadienyl)titanium

A

bis(2,4-dimethylpentadienyl)titanium

bis(2,4-dimethylpentadienyl)titanium

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In tetrahydrofuran under N2, dissociation in soln.; detn. by (31)P-NMR;
mer-trichlorotris(dimethylphenylphosphine)tungsten(III)
135745-75-4, 150653-03-5

mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

A

tetrachlorotris(dimethylphenylphosphine)tungsten(IV)
47690-18-6

tetrachlorotris(dimethylphenylphosphine)tungsten(IV)

B

WCl4(PMe2Ph)2
30411-60-0

WCl4(PMe2Ph)2

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given decomposition of the mer-isomer above 90°C (Ar);
{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

triethylphosphine
554-70-1

triethylphosphine

{Cp(PEt3)2molybdenum(III) dichloride}

{Cp(PEt3)2molybdenum(III) dichloride}

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;; equilibrium;
ethyl iodide
75-03-6

ethyl iodide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

dimethylethylphenylphosphonium iodide
72153-49-2

dimethylethylphenylphosphonium iodide

Conditions
ConditionsYield
In benzene at 20℃; for 12h; Inert atmosphere; Schlenk technique;100%
Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C16H31PSi

C16H31PSi

[(dicyclohexylphosphanyl-trimethylsilanyl-methylene)-dimethyl-λ5-phosphanyl]-benzene

[(dicyclohexylphosphanyl-trimethylsilanyl-methylene)-dimethyl-λ5-phosphanyl]-benzene

Conditions
ConditionsYield
In pentane at 0℃; Addition;100%
[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)](1+)*[BF4](1-)=[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)][BF4]

[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)](1+)*[BF4](1-)=[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)][BF4]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)](1+)*[BF4](1-)=[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)][BF4]

[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)](1+)*[BF4](1-)=[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)][BF4]

Conditions
ConditionsYield
In dichloromethane excess of ligand in light petroleum added to stirred soln. of complex in CH2Cl2, reacted for 10 min; evapd. (vac.), washed (Et2O), dried (vac.); elem. anal.;100%
(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)
12146-37-1, 124717-04-0

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

bis(phenyldimethylphosphine)molybdenum tetracarbonyl
24554-47-0

bis(phenyldimethylphosphine)molybdenum tetracarbonyl

B

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

Conditions
ConditionsYield
In tetrahydrofuran reaction in a calorimeter;A 100%
B n/a
{Pt2Cl2(PMe2Ph)4}{BF4}2

{Pt2Cl2(PMe2Ph)4}{BF4}2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{PtCl(PMe2Ph)3}{BF4}
56954-49-5

{PtCl(PMe2Ph)3}{BF4}

Conditions
ConditionsYield
In acetone dissolved in acetone, PMe2Ph was added; solution was evaporated, dried in vacuo, elem. anal., NMR;100%
(C5H5)MoCl2(P(C6H5)3)2

(C5H5)MoCl2(P(C6H5)3)2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

Conditions
ConditionsYield
In dichloromethane byproducts: P(C6H5)3; mixing of the Mo compd. with the free phosphine (molar ratio 2.8:1) in CH2Cl2;;100%
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;;A 100%
B n/a
cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]
33542-07-3

cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)
80700-08-9, 80736-08-9

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)

Conditions
ConditionsYield
In methanol at -30°C;100%
[NEt4N][Re3(μ-H)4(CO)9(C3H4N2)]
511550-07-5, 210559-10-7

[NEt4N][Re3(μ-H)4(CO)9(C3H4N2)]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[Et4N][Re3(μ-H)4(CO)9(PMe2PH)]
210559-25-4

[Et4N][Re3(μ-H)4(CO)9(PMe2PH)]

Conditions
ConditionsYield
In [(2)H6]acetone N2-atmosphere; 193 to 298 K; detd. by NMR spectroscopy;100%
((CH3)5C5)Ir(C2H(CH3)O2NSO2C6H4CH3)

((CH3)5C5)Ir(C2H(CH3)O2NSO2C6H4CH3)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

((CH3)5C5)Ir(P(CH3)2C6H5)(C2H(CH3)O2NSO2C6H4CH3)

((CH3)5C5)Ir(P(CH3)2C6H5)(C2H(CH3)O2NSO2C6H4CH3)

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; elem. anal.;100%
(butane-1,4-diyl)iodo(methyl)platinum(IV)

(butane-1,4-diyl)iodo(methyl)platinum(IV)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(butane-1,4-diyl)bis(dimethylphenylphosphine)iodo(methyl)platinum(IV)
59991-54-7

(butane-1,4-diyl)bis(dimethylphenylphosphine)iodo(methyl)platinum(IV)

Conditions
ConditionsYield
In dichloromethane room temp., stirring (30 h); filtration, volume reduction, pptn. on MeOH addn.;100%
C62H80Hf2N2O2(2+)*2C24BF20(1-)

C62H80Hf2N2O2(2+)*2C24BF20(1-)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

2C24BF20(1-)*C78H102Hf2N2O2P2(2+)

2C24BF20(1-)*C78H102Hf2N2O2P2(2+)

Conditions
ConditionsYield
at 20℃; for 24h; Inert atmosphere;100%
sodium hexaflorophosphate

sodium hexaflorophosphate

[W(hydrotris(3,5-dimethylpyrazolyl)borate)(CO)2(η(1)-CBr)]

[W(hydrotris(3,5-dimethylpyrazolyl)borate)(CO)2(η(1)-CBr)]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{HB(3,5-Me2C3HN2)3(CO)2WCPMe2Ph}PF6

{HB(3,5-Me2C3HN2)3(CO)2WCPMe2Ph}PF6

Conditions
ConditionsYield
In acetonitrile Inert atmosphere; Schlenk technique;100%
4-bromobutylphosphonium bromide
7333-63-3

4-bromobutylphosphonium bromide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C30H34P2(2+)*2Br(1-)
89807-18-1

C30H34P2(2+)*2Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 4h; Heating;99%
Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Trifluoro-methanesulfonatetriphenyl-trifluoromethanesulfonyloxymethyl-arsonium;

Trifluoro-methanesulfonatetriphenyl-trifluoromethanesulfonyloxymethyl-arsonium;

(Dimethylphenylphosphonio)(triphenylarsonio)methan-bis(trifluormethansulfonat)

(Dimethylphenylphosphonio)(triphenylarsonio)methan-bis(trifluormethansulfonat)

Conditions
ConditionsYield
In acetonitrile for 24h; Ambient temperature;99%
dinitrosylbis(triphenylphosphine)cobalt hexafluorophosphate

dinitrosylbis(triphenylphosphine)cobalt hexafluorophosphate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Co(NO)2(P(C6H5)(CH3)2)2(1+)*PF6(1-)=[Co(NO)2(P(C6H5)(CH3)2)2]PF6

Co(NO)2(P(C6H5)(CH3)2)2(1+)*PF6(1-)=[Co(NO)2(P(C6H5)(CH3)2)2]PF6

Conditions
ConditionsYield
In dichloromethane byproducts: PPh3; N2-atmosphere; excess of incoming phosphine, 20°C;99%
[(4-MePy)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

[(4-MePy)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(P(CH3)2Ph)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

[(P(CH3)2Ph)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

Conditions
ConditionsYield
In chloroform byproducts: 4-methylpyridine; excess of ligand added to Ru-Fe complex in CHCl3 at room temp.; pptn. with hexane;99%
[(η(5)-heptamethylindenyl)RhCl(μ-Cl)]2
171193-96-7

[(η(5)-heptamethylindenyl)RhCl(μ-Cl)]2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(η(5)-heptamethylindenyl)Rh(PMe2Ph)Cl2]
171193-98-9

[(η(5)-heptamethylindenyl)Rh(PMe2Ph)Cl2]

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; 24 h; solvent removal (vac.), recrystn. (THF/hexane, -40°C); elem. anal.;99%
[Ni(C6Cl4(PPh2)-2)2]

[Ni(C6Cl4(PPh2)-2)2]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[Ni(C6Cl4(PPh2)-2)2(PMe2Ph)]

[Ni(C6Cl4(PPh2)-2)2(PMe2Ph)]

Conditions
ConditionsYield
In toluene N2-atmosphere; equimolar amts., stirring (dissoln.); sepn. on EtOH addn.; elem. anal.;99%
technetium tetrachloride

technetium tetrachloride

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

trans-[(99)TcCl4(PMe2Ph)2]
53749-04-5

trans-[(99)TcCl4(PMe2Ph)2]

Conditions
ConditionsYield
In benzene Schlenk technique, radiation precautions; PMe2Ph added to suspn. of TcCl4, mixt. stirred at room temp.;99%
dichloromethane
75-09-2

dichloromethane

water
7732-18-5

water

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

B

cobalt
7440-48-4

cobalt

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In dichloromethaneA n/a
B 99%
C n/a
D n/a
ethyl 2-methylbuta-2,3-dienoate
5717-41-9

ethyl 2-methylbuta-2,3-dienoate

trifluoroacetic acid
76-05-1

trifluoroacetic acid

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

dimethylphenyl(4-ethoxy-3-methyl-4-oxobut-1-en-2-yl)phosphonium trifluoroacetate
1332456-48-0

dimethylphenyl(4-ethoxy-3-methyl-4-oxobut-1-en-2-yl)phosphonium trifluoroacetate

Conditions
ConditionsYield
In chloroform at 20℃; for 12h;99%
Methyl 3-bromopropionate
3395-91-3

Methyl 3-bromopropionate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(3-methoxy-3-oxopropyl)dimethyl(phenyl)phosphonium bromide

(3-methoxy-3-oxopropyl)dimethyl(phenyl)phosphonium bromide

Conditions
ConditionsYield
In acetonitrile at 20℃;99%
methyl (E)-3-[(phenylcarbamoyl)diazenyl]but-2-enoate
146000-78-4

methyl (E)-3-[(phenylcarbamoyl)diazenyl]but-2-enoate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C20H24N3O3P

C20H24N3O3P

Conditions
ConditionsYield
In diethyl ether at 0 - 5℃; for 0.2h;98%
μ-oxo-bis[(nitrosotrimethylsilylmethane)nitrosyloxomolybdenum]
79829-64-4

μ-oxo-bis[(nitrosotrimethylsilylmethane)nitrosyloxomolybdenum]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Mo2O3(NO)2(ONCH2Si(CH3)3)2(P(CH3)2C6H5)2
79846-11-0

Mo2O3(NO)2(ONCH2Si(CH3)3)2(P(CH3)2C6H5)2

Conditions
ConditionsYield
In toluene ppt. washed with toluene, THF and diethyl ether, dried in vac.; elem. anal.;98%
Re(CO)4(OC(OCH3)CHCCH2COOCH3)
182137-83-3

Re(CO)4(OC(OCH3)CHCCH2COOCH3)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

fac-Re(CO)3(PMe2Ph)[C(CH2CO2Me)=C(H)CO2Me]

fac-Re(CO)3(PMe2Ph)[C(CH2CO2Me)=C(H)CO2Me]

Conditions
ConditionsYield
In hexane N2-atmosphere; refluxing (30 min); evapn. (vac.), chromy. (SiO2, hexane / CH2Cl2 = 2 : 1);98%
(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)
184682-63-1

(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Co(P(CH3)2C6H5)I((CH3)4C5CH2C6F4CF2)
184682-69-7

Co(P(CH3)2C6H5)I((CH3)4C5CH2C6F4CF2)

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; stirring (room temp., 19 h); evapn. (vac.);98%
(pentamethylcyclopentadienyl)iridium(II) hydride
226922-36-7

(pentamethylcyclopentadienyl)iridium(II) hydride

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(Cp(*)IrH)2(μ-H)(μ-Me2PC6H4)]

[(Cp(*)IrH)2(μ-H)(μ-Me2PC6H4)]

Conditions
ConditionsYield
In benzene (Ar or N2); ligand added to Ir complex in C6H6, stirred at room temp. for 16 h; evapd. (vac.), extd. (C6H6), evapd.; elem. anal.;98%
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