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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyldiphenylphosphine Manufacturer/High quality/Best price/In stock

Cas:1486-28-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant production

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Diphenylmethylphosphine

Cas:1486-28-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM METHYLDIPHENYLPHOSPHINE

Cas:1486-28-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1486-28-8 with best quality

Cas:1486-28-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: METHYLDIPHENYLPHOSPHINE Synonyms: METHYLDIPHENYLPHOSPHINE;DIPHENYLMETHYLPHOSPHINE;Methyldiphenylphsphine;Methyldiphenylphosphine,99%;Diphenylphosphinomethane;Methyldiphenylphosphine, 99% 25GR;Methyldiphenylphosphine, 99% 5GR;98% (

METHYLDIPHENYLPHOSPHINE

Cas:1486-28-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

METHYLDIPHENYLPHOSPHINECAS: 1486-28-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

METHYLDIPHENYLPHOSPHINECAS: 1486-28-8

Cas:1486-28-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Methyldiphenylphsphine

Cas:1486-28-8

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality moderate price & quick delivery Appearance: Colorless to light yellow liquiD Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:

Phosphine,methyldiphenyl-

Cas:1486-28-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Other

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Methyldiphenylphsphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Diphenylmethylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyldiphenylphosphine cas no. 1486-28-8 98%

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

METHYLDIPHENYLPHOSPHINE

Cas:1486-28-8

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Diphenylmethylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Methyldiphenylphosphine 100g

Cas:1486-28-8

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

MethyldiphenylphosphineAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals a

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

Methyldiphenylphsphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Methyldiphenylphosphine cas 1486-28-8Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methyldiphenylphosphine cas 1486-28-8

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:1g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

METHYLDIPHENYLPHOSPHINE

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Methyldiphenylphosphine

Cas:1486-28-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.1:1) in toluene;;A 100%
B n/a
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

triethylphosphine
554-70-1

triethylphosphine

{Cp(PEt3)2molybdenum(III) dichloride}

{Cp(PEt3)2molybdenum(III) dichloride}

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;;A 100%
B n/a
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;;A 100%
B n/a
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

cyclopentadienylmolybdenum(III)(bis(diphenylphosphino)ethane)Cl2

cyclopentadienylmolybdenum(III)(bis(diphenylphosphino)ethane)Cl2

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In dichloromethane mixing of the Mo compd. with the free phosphine (molar ratio 1.1:1) inCH2Cl2;;A 100%
B n/a
diphenyl(methyl)phosphine oxide
2129-89-7

diphenyl(methyl)phosphine oxide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride; cerium(III) chloride In tetrahydrofuran at 40℃; for 0.5h;98%
With aluminium hydride*tetrahydrofuran In tetrahydrofuran for 0.5h; Heating;96%
Stage #1: diphenyl(methyl)phosphine oxide With trityl tetrakis(pentafluorophenyl)borate In (2)H8-toluene at 20℃; Glovebox; Inert atmosphere;
Stage #2: With phenylsilane In (2)H8-toluene at 80℃; for 1.5h; Glovebox; Inert atmosphere; Sealed tube;
93%
Diphenylphosphonigsaeure-trimethylsilylester
13683-01-7

Diphenylphosphonigsaeure-trimethylsilylester

methyllithium
917-54-4

methyllithium

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 25℃; for 2h;96%
Ph2PCH2NHPh

Ph2PCH2NHPh

methyl iodide
74-88-4

methyl iodide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
Stage #1: Ph2PCH2NHPh With methyllithium In toluene at -78 - 20℃; Inert atmosphere;
Stage #2: methyl iodide In toluene at -78℃; Inert atmosphere;
95%
n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

methylmagnesium bromide
75-16-1

methylmagnesium bromide

cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole
119841-34-8, 127780-84-1

cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole

phenylmagnesium bromide

phenylmagnesium bromide

A

dibutyl-methyl-phosphine
33374-48-0

dibutyl-methyl-phosphine

B

n-Butyl-methyl-phenyl-phosphin
36050-91-6, 36850-51-8, 36850-52-9

n-Butyl-methyl-phenyl-phosphin

C

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

D

4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol
736137-64-7

4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol

Conditions
ConditionsYield
Stage #1: n-butyl magnesium bromide; cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole; phenylmagnesium bromide In tetrahydrofuran for 0.0833333h;
Stage #2: methylmagnesium bromide In tetrahydrofuran Title compound not separated from byproducts;
A n/a
B n/a
C n/a
D 90%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole
119841-34-8, 127780-84-1

cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole

phenylmagnesium bromide

phenylmagnesium bromide

A

diethylmethylphosphine
1605-58-9

diethylmethylphosphine

B

ethylmethylphenylphosphine
15849-84-0, 52119-19-4, 72974-35-7

ethylmethylphenylphosphine

C

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

D

4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol
736137-64-7

4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol

Conditions
ConditionsYield
Stage #1: ethylmagnesium bromide; cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole; phenylmagnesium bromide In tetrahydrofuran for 0.0833333h;
Stage #2: methylmagnesium bromide In tetrahydrofuran Title compound not separated from byproducts;
A n/a
B n/a
C n/a
D 90%
Ph2PCH2NH(t-Bu)
126140-10-1

Ph2PCH2NH(t-Bu)

methyl iodide
74-88-4

methyl iodide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
Stage #1: Ph2PCH2NH(t-Bu) With methyllithium In toluene at -78 - 20℃; Inert atmosphere;
Stage #2: methyl iodide In toluene at -78℃; Inert atmosphere;
89%
trimethylsulphonium iodide
2181-42-2

trimethylsulphonium iodide

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
Stage #1: trimethylsulphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -70℃; for 0.166667h;
Stage #2: (trimethylsilyl)diphenylphosphine In tetrahydrofuran; hexane at -70 - 20℃; for 0.5h;
88%
phenylsilane
694-53-1

phenylsilane

Methylenetriphenylphosphorane
19493-09-5

Methylenetriphenylphosphorane

A

triphenyl<(phenylsilyl)methylene>phosphorane

triphenyl<(phenylsilyl)methylene>phosphorane

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With bis(trimethylsilyl)amide yttrium(III) In benzene-d6 at 25℃; for 0.5h; Catalytic behavior; Reagent/catalyst;A 88%
B n/a
Na(1+)*P(CH3)C6H5(1-)=NaP(CH3)C6H5

Na(1+)*P(CH3)C6H5(1-)=NaP(CH3)C6H5

chlorobenzene
108-90-7

chlorobenzene

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With 15-crown-5 In tetrahydrofuran at 25℃; for 6h; Inert atmosphere;88%
1-methoxy-2-trimethylsilylethyne
24082-05-1

1-methoxy-2-trimethylsilylethyne

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

A

bis(trimethylsilyl)ketene
19061-00-8

bis(trimethylsilyl)ketene

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In acetonitrile for 48h; Ambient temperature;A 65%
B 82%
methyl-triphenylphosphonium iodide
2065-66-9

methyl-triphenylphosphonium iodide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride; water In 1,4-dioxane for 0.25h; Heating;79%
With tetrakis(triphenylphosphine) palladium(0); hydrogen; triethylamine In 1,4-dioxane at 130℃; under 76000 Torr; Product distribution; other quaternary phosphonium salts;
6,6'-dimethyl fulvene
2175-91-9

6,6'-dimethyl fulvene

(lithiomethyl)diphenylphosphane
62263-69-8

(lithiomethyl)diphenylphosphane

A

lithium (1-methylethenyl)cyclopentadiene
77060-52-7

lithium (1-methylethenyl)cyclopentadiene

B

dilithium salt of 2,4-bis(1,3-cyclopentadienyl)-4-methyl-1-pentene
77060-51-6

dilithium salt of 2,4-bis(1,3-cyclopentadienyl)-4-methyl-1-pentene

C

dilithium salt of 6-(1,3-cyclopentadienyl)-6,8,8-trimethylbicyclo<3.3.0>octa-1,3-diene
77060-48-1

dilithium salt of 6-(1,3-cyclopentadienyl)-6,8,8-trimethylbicyclo<3.3.0>octa-1,3-diene

D

lithium <1,1-dimethyl-2-(diphenylphosphino)ethyl>cyclopentadienide
77061-27-9

lithium <1,1-dimethyl-2-(diphenylphosphino)ethyl>cyclopentadienide

E

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In Petroleum ether at 27℃; for 168h; Product distribution;A 5%
B 30%
C 25%
D 12%
E 78%
6,6'-dimethyl fulvene
2175-91-9

6,6'-dimethyl fulvene

(lithiomethyl)diphenylphosphane
62263-69-8

(lithiomethyl)diphenylphosphane

A

dilithium salt of 2,4-bis(1,3-cyclopentadienyl)-4-methyl-1-pentene
77060-51-6

dilithium salt of 2,4-bis(1,3-cyclopentadienyl)-4-methyl-1-pentene

B

dilithium salt of 6-(1,3-cyclopentadienyl)-6,8,8-trimethylbicyclo<3.3.0>octa-1,3-diene
77060-48-1

dilithium salt of 6-(1,3-cyclopentadienyl)-6,8,8-trimethylbicyclo<3.3.0>octa-1,3-diene

C

lithium <1,1-dimethyl-2-(diphenylphosphino)ethyl>cyclopentadienide
77061-27-9

lithium <1,1-dimethyl-2-(diphenylphosphino)ethyl>cyclopentadienide

D

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In Petroleum ether at 27℃; for 168h;A n/a
B n/a
C 12%
D 78%
N-phenyl methyldiphenyl-λ5-phosphazene
57901-20-9

N-phenyl methyldiphenyl-λ5-phosphazene

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 6h; Ambient temperature;78%
phenylsilane
694-53-1

phenylsilane

Methylenetriphenylphosphorane
19493-09-5

Methylenetriphenylphosphorane

A

Diphenyl-phenylsilanylmethyl-phosphane
86934-57-8

Diphenyl-phenylsilanylmethyl-phosphane

B

triphenyl<(phenylsilyl)methylene>phosphorane

triphenyl<(phenylsilyl)methylene>phosphorane

C

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With C31H52N2PSi4Y In benzene-d6 at 25℃; for 3.5h;A n/a
B 77%
C n/a
[Li(THF)1.5][(CO)4W(μ-PPh2)2Os(CO)2(CHO)(PMePh2)]
88904-52-3

[Li(THF)1.5][(CO)4W(μ-PPh2)2Os(CO)2(CHO)(PMePh2)]

Li[(CO)4W(μ-PPh2)2Os(H)(CO)2(PMePh2)]
91740-00-0

Li[(CO)4W(μ-PPh2)2Os(H)(CO)2(PMePh2)]

Li[(CO)4W(μ-PPh2)2Os(H)(CO)3]
91739-99-0

Li[(CO)4W(μ-PPh2)2Os(H)(CO)3]

C

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In dimethylsulfoxide-d6 under N2, soln. of educt in (CD3)2SO heated at 100°C for 11 h; identified by NMR;A 25%
B 75%
C n/a
triphenylphosphine
603-35-0

triphenylphosphine

methyl iodide
74-88-4

methyl iodide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
Stage #1: triphenylphosphine In tetrahydrofuran at 20℃; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran for 0.166667h; Inert atmosphere;
75%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In diethyl ether at -35℃; Inert atmosphere;74%
methyl(phenyl)(trimethylsilyl)phosphine
59877-21-3

methyl(phenyl)(trimethylsilyl)phosphine

chlorobenzene
108-90-7

chlorobenzene

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) chloride; potassium tert-butylate In 1,4-dioxane at 90℃; for 12h; Inert atmosphere;69%
Lithiumdiphenylphosphinoformiat

Lithiumdiphenylphosphinoformiat

methyl iodide
74-88-4

methyl iodide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In pentane at -30 - 20℃; for 16h;60%
Cp2Zr(Cl)CH2PPh2

Cp2Zr(Cl)CH2PPh2

A

((η5-cyclopentadienyl)2ZrCl)2(OCC(H)PPh2)

((η5-cyclopentadienyl)2ZrCl)2(OCC(H)PPh2)

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
With CO In tetrahydrofuran treatment with CO; addn. of pentane;A 60%
B n/a
borane-THF
14044-65-6

borane-THF

diphenyl(methyl)phosphine oxide
2129-89-7

diphenyl(methyl)phosphine oxide

A

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

B

diphenylmethylphosphine-borane complex
54067-17-3

diphenylmethylphosphine-borane complex

Conditions
ConditionsYield
With titanium(IV) isopropylate In tetrahydrofuran; toluene at 80℃; for 24h; Schlenk technique; Inert atmosphere;A 57%
B 20%
With titanium(IV) isopropylate In tetrahydrofuran; toluene at 80℃; for 24h; Schlenk technique; Inert atmosphere;A 40%
B 45%
5-lithiomethyl-5H-dibenzophosphole
98753-65-2

5-lithiomethyl-5H-dibenzophosphole

A

5-methyl-5H-dibenzophosphole
16546-79-5

5-methyl-5H-dibenzophosphole

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
by hydrolysis;A 43%
B 10%
C n/a
cis-{PdMe2(PMePh2)2}

cis-{PdMe2(PMePh2)2}

2-dimethylsilyl-1-diphenylphosphinoethane
86934-58-9

2-dimethylsilyl-1-diphenylphosphinoethane

(Si(CH3)2C2H4P(C6H5)2)2Pd

(Si(CH3)2C2H4P(C6H5)2)2Pd

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In diethyl ether byproducts: CH4; (N2), dried solvents, -40°C, dropwise addn. of educts, 4 h, evapn. in vac. (same temp.), addn. of petroleum ether yield yellow pptn., cooled down to -78°C; filtration ppt., washing (pentane), dried (high vac.), elem. anal.;A 42%
B n/a
[{((2,6-dimethylphenyl)NC(methyl))2CH}AlH2]
1357931-84-0

[{((2,6-dimethylphenyl)NC(methyl))2CH}AlH2]

Methylenetriphenylphosphorane
19493-09-5

Methylenetriphenylphosphorane

A

C27H31AlN2

C27H31AlN2

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In benzene at 60℃; for 2h; Glovebox; Heating;A 21%
B n/a
diethyl ether
60-29-7

diethyl ether

sodium methylate
124-41-4

sodium methylate

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

A

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

B

diphenyl(methyl)phosphine oxide
2129-89-7

diphenyl(methyl)phosphine oxide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

diphenyl(methyl)phosphine oxide
2129-89-7

diphenyl(methyl)phosphine oxide

Conditions
ConditionsYield
With polymeric complex of oxodiperoxochromium(VI) compound and pyrazine (Pyz-CrO5)n In dichloromethane for 0.1h; Ambient temperature;100%
With dihydrogen peroxide In dichloromethane; water at 20℃; for 3h; Glovebox; Inert atmosphere;100%
With α-azohydroperoxides In benzene-d6 at 32℃;95%
Phenyl azide
622-37-7

Phenyl azide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

N-phenyl methyldiphenyl-λ5-phosphazene
57901-20-9

N-phenyl methyldiphenyl-λ5-phosphazene

Conditions
ConditionsYield
In dichloromethane at 25℃; for 4h; Staudinger reaction;100%
diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

methyldiphenylphosphine borane complex

methyldiphenylphosphine borane complex

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran at -78 - 20℃;100%
With dimethylsulfide borane complex In tetrahydrofuran at 25℃; for 1h;91%
With dimethylsulfide borane complex complexation;
diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

C13H13IP(1+)*I3(1-)

C13H13IP(1+)*I3(1-)

Conditions
ConditionsYield
With iodine In diethyl ether at 20℃; for 48h; Addition;100%
diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

C16H31PSi

C16H31PSi

C29H44P2Si

C29H44P2Si

Conditions
ConditionsYield
In pentane at 0℃; Addition;100%
(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)
12146-37-1, 124717-04-0

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

cis-{molybdenum(0)(carbonyl)4(P(phenyl)2(methyl))2}
37438-49-6, 81938-99-0

cis-{molybdenum(0)(carbonyl)4(P(phenyl)2(methyl))2}

B

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

Conditions
ConditionsYield
In tetrahydrofuran reaction in a calorimeter under argon;A 100%
B n/a
PPh4{PtW(μ-CC6H3Me2-2,6)(CO)2(cod)(η5-C2B9H9Me2)}

PPh4{PtW(μ-CC6H3Me2-2,6)(CO)2(cod)(η5-C2B9H9Me2)}

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

PPh4{PtW(μ-CC6H3Me2-2,6)(CO)2(PMePh2)2(η5-C2B9H9Me2)}

PPh4{PtW(μ-CC6H3Me2-2,6)(CO)2(PMePh2)2(η5-C2B9H9Me2)}

Conditions
ConditionsYield
With PMePh2 In dichloromethane; dichloromethane-d2 shaken for 1 min; evapn., not isolated, identified by NMR-spectroscopy;;100%
{(Rh(η5-pentamethylcyclopentadienyl)Br2)2}

{(Rh(η5-pentamethylcyclopentadienyl)Br2)2}

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

(η5-C5Me5)Rh{PMePh2}Br2

(η5-C5Me5)Rh{PMePh2}Br2

Conditions
ConditionsYield
In dichloromethane N2 atmosphere; addn. of phosphine to Rh complex, stirring (30 min., room temp.); evapn. (vac.), recrystn. (CH2Cl2/hexane); elem. anal.;100%
[Rh(η(5)-pentamethylcyclopentadienyl)(μ-I)I]2

[Rh(η(5)-pentamethylcyclopentadienyl)(μ-I)I]2

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

(η5-C5Me5)Rh{PMePh2}I2

(η5-C5Me5)Rh{PMePh2}I2

Conditions
ConditionsYield
In dichloromethane N2 atmosphere; addn. of phosphine to Rh complex, stirring (30 min., room temp.); evapn. (vac.), recrystn. (CH2Cl2/hexane);100%
HRh{(P(OCH3)2O)2H}2(CO)

HRh{(P(OCH3)2O)2H}2(CO)

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

HRh{(P(OCH3)2O)2H}2(P(C6H5)2CH3)

HRh{(P(OCH3)2O)2H}2(P(C6H5)2CH3)

Conditions
ConditionsYield
In chloroform-d1 byproducts: CO; (N2); stirring at ambiente temp.; react. followed by (1)H NMR; completed after 20 h; evapn. to dryness; recrystn. from pure hexane; elem. anal.; (31)P-, (1)H-, (13)C-NMR; IR;100%
exo-nido-[Rh(PhS(CH3)C2B9H10)(PPh3)2]

exo-nido-[Rh(PhS(CH3)C2B9H10)(PPh3)2]

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Rh(P(C6H5)2CH3)4(1+)*CH3(SC6H5)C2B9H10(1-)=[Rh(P(C6H5)2CH3)4][CH3(SC6H5)C2B9H10]

Rh(P(C6H5)2CH3)4(1+)*CH3(SC6H5)C2B9H10(1-)=[Rh(P(C6H5)2CH3)4][CH3(SC6H5)C2B9H10]

Conditions
ConditionsYield
In not given100%
(Z)-methyl 2-azido-3-phenylacrylate
81777-11-9

(Z)-methyl 2-azido-3-phenylacrylate

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

3-methoxycarbonyl-1-methyl-1,1,4-triphenyl-2-aza-1λ5-phosphabuta-1,3-diene
129990-86-9

3-methoxycarbonyl-1-methyl-1,1,4-triphenyl-2-aza-1λ5-phosphabuta-1,3-diene

Conditions
ConditionsYield
In diethyl ether Ambient temperature;99%
[ReOCl3(PPh3)2]

[ReOCl3(PPh3)2]

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Re(PMe2Ph)3Cl3
15613-32-8

Re(PMe2Ph)3Cl3

Conditions
ConditionsYield
In not given Re-complex reacted with ligand according to Chatt, J; Leigh, G. J; Mingos, D. M. P.; Paske, R. J. J. Chem. Soc. A 1968, 2636;99%
borane tetrahydrofuran

borane tetrahydrofuran

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

diphenylmethylphosphine-borane complex
54067-17-3

diphenylmethylphosphine-borane complex

Conditions
ConditionsYield
In tetrahydrofuran under N2, Schlenk techniques; soln. of P compd. (1.35 mmol) added to soln. of B compd. (1.30 mmol) at -78°C with stirring, warmed to roomtemp. overnight; evapd.;99%
[((triphenylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

[((triphenylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

[((diphenylmethylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)
174092-69-4

[((diphenylmethylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

Conditions
ConditionsYield
In dichloromethane 4 equivs. of phosphine, stirring for 30 min at room temp.; evapn., washing (MePh, ether); NMR spectroscopy;99%
fac-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Rh(H)(Cl)(PPh3)]

fac-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Rh(H)(Cl)(PPh3)]

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

fac-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Rh(H)(Cl)(PPh2Me)]

fac-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Rh(H)(Cl)(PPh2Me)]

Conditions
ConditionsYield
In toluene (Ar); std. Schlenk technique; soln. of P ligand in toluene was added dropwise to stirred soln. of Rh complex in toluene; soln. was stirred at room temp. for 20 h; solvent removed (vac.);99%
chlorobis(cyclooctene)-iridium(I) dimer

chlorobis(cyclooctene)-iridium(I) dimer

o-Ph2PC6H4CH2OCH2C5H4N-2
146583-33-7

o-Ph2PC6H4CH2OCH2C5H4N-2

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

mer-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Ir(H)(Cl)(PMePh2)]
921195-66-6, 920742-68-3

mer-[(Ph2PC6H4CHOCH2C5H4N-κ(3)P,C,N)Ir(H)(Cl)(PMePh2)]

Conditions
ConditionsYield
In toluene (Ar); std. Schlenk technique; soln. of P ligand in toluene was added dropwise to stirred soln. of Ir complex (0.5 equiv.) and P-N ligand (1 equiv.) in toluene; soln. was stirred at room temp. for 12 h; solvent removed (vac.);99%
dichloromethane
75-09-2

dichloromethane

water
7732-18-5

water

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

ZnCl4(2-)*2(C6H5)2(CH3)2P(1+)=[(C6H5)2(CH3)2P]2[ZnCl4]

ZnCl4(2-)*2(C6H5)2(CH3)2P(1+)=[(C6H5)2(CH3)2P]2[ZnCl4]

B

cobalt
7440-48-4

cobalt

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In dichloromethaneA n/a
B 99%
C n/a
D n/a
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

bis(methyldiphenylphosphine)nickel(II) chloride
28665-20-5, 15683-37-1

bis(methyldiphenylphosphine)nickel(II) chloride

Conditions
ConditionsYield
In ethanol at 80℃; for 0.5h; Sealed tube; Inert atmosphere;99%
1-ferrocenylphenylmethanol

1-ferrocenylphenylmethanol

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

[phenyl(ferrocenyl)methyl]methyldiphenylphosphonium triflate

[phenyl(ferrocenyl)methyl]methyldiphenylphosphonium triflate

Conditions
ConditionsYield
In chloroform Inert atmosphere;99%
diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

azidoformiate de methyle
1516-56-9

azidoformiate de methyle

P,P-diphenyl-P-(methyl)(N-methoxycabonyl)phosphazene
127802-81-7

P,P-diphenyl-P-(methyl)(N-methoxycabonyl)phosphazene

Conditions
ConditionsYield
In diethyl ether Staudinger reaction;98%
N-[5-(bromomethyl)-4-(4-fluorophenyl)-6-(propan-2-yl)pyrimidin-2-yl]-N-methylmethanesulfonamide
799842-07-2

N-[5-(bromomethyl)-4-(4-fluorophenyl)-6-(propan-2-yl)pyrimidin-2-yl]-N-methylmethanesulfonamide

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

({4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]-5-pyrimidinyl}methyl)-methyldiphenylphosphonium bromide

({4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]-5-pyrimidinyl}methyl)-methyldiphenylphosphonium bromide

Conditions
ConditionsYield
In tetrahydrofuran at 50℃; for 0.25h;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.75 h; evapd. in vac., chromd., recrystd.;98%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;98%
cobalt(II) chloride dihydrate In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;98%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;96%
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;78%
(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

cis-{PdMe2(PMePh2)2}

cis-{PdMe2(PMePh2)2}

Conditions
ConditionsYield
In pentane; benzene react. of Pd complex with phosphine in benzene and addn. of pentane;98%
In benzene addn. of pentane; cooling to -30°C; decanting;90%
thallium(I) tetrafluoroborate
28625-02-7

thallium(I) tetrafluoroborate

{bis(2,6-diisopropylphenylimido)pyridine(chloro)(methyldiphenylphosphine)tungsten}

{bis(2,6-diisopropylphenylimido)pyridine(chloro)(methyldiphenylphosphine)tungsten}

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

{bis(2,6-diisopropylphenylimido)bis(methyldiphenylphosphine)tungsten} tetrafluoroborate

{bis(2,6-diisopropylphenylimido)bis(methyldiphenylphosphine)tungsten} tetrafluoroborate

Conditions
ConditionsYield
In tetrahydrofuran TlBF4 is added to a soln. of the starting complex and the phosphine in THF, stirred overnight; cooled to -40°C, filtered, the filtrate is evapd. to dryness, elem. anal.;98%

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