CAS No.13463-40-6,Ironpentacarbonyl Suppliers,MSDS download

Synthetic route

: 15321-51-4
diiron nonacarbonyl

: 103932-33-8
Os{PCO(CF3)}(CO)2(P(C6H5)3)2

: 13463-40-6
iron pentacarbonyl

: Os{P{Fe(CO)4}CO(CF3)}(CO)2(P(C6H5)3)2

Conditions

Conditions	Yield
In tetrahydrofuran educts suspended in THF; after 1 h solvent removed in vacuo;; residue left under vacuum for 1 h; dissolved in CH2Cl2; addn. of ethanol; concentration; filtration; washed with ethanol and n-hexane; elem. anal.;	A n/a B 100%

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: 17685-52-8
triiron dodecarbonyl

: 13463-40-6
iron pentacarbonyl

Conditions

Conditions	Yield
With carbon monoxide In n-heptane Irradiation (UV/VIS); soln. of Fe3(CO)12 in n-heptane is irradiated for 30 min in slow streamof CO;	98%
In n-heptane Irradiation (UV/VIS); soln. of Fe3(CO)12 in n-heptane is irradiated at 293 K for 75 min in slow stream N2;	96%
With carbon monoxide In N,N-dimethyl-formamide decompn. in presence of CO (1 atm) betwwen 0 and 25°C; intermediates observed;; not isolated; detn. by ESR;

: 15321-51-4
diiron nonacarbonyl

: 124686-70-0
((t-Bu)4(Me)2azasilagermane)

: 13463-40-6
iron pentacarbonyl

B: 124686-68-6
((t-Bu)4(Me)2azasilagermane)iron tetracarbonyl

Conditions

Conditions	Yield
In benzene To a soln. of Ge compd. in benzene is added the carbonyl compd., suspn. is stirred for 12 h.; Recrystn. from toluene, NMR.;	A n/a B 97%

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: 15321-51-4
diiron nonacarbonyl

: 38611-86-8
1,3-bis(diphenylstibino)propane

: 13463-40-6
iron pentacarbonyl

: [(Fe(CO)4)2((C6H5)2Sb(CH2)3Sb(C6H5)2)]

Conditions

Conditions	Yield
In tetrahydrofuran (N2); soln. of Fe complex (2 equiv.) and Sb ligand in THF was stirred atroom temp. for 2 d; filtered; volatiles removed (vac.);	A n/a B 97%

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: 15321-51-4
diiron nonacarbonyl

: 33446-84-3
1,1-dimethoxy-1-silacyclobutane

: 13463-40-6
iron pentacarbonyl

B: 68046-55-9
2,2,2,2-tetracarbonyl-1,1-dimethoxy-1-sila-2-ferracyclopentane

Conditions

Conditions	Yield
In benzene addn. of 2 equiv. of Si-compd. to Fe-complex suspn. (held above freezingpoint), warming to 21°C, stirring (12 h); removal of Fe(CO)5 and solvent (vac.), distn. (1E-2 Torr, 30°C); elem. anal.;	A n/a B 96%
With carbon monoxide In not given N2-atmosphere;

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: disodium tetracarbonylferrate

: 124-38-9
carbon dioxide

: 13463-40-6
iron pentacarbonyl

B: 497-19-8
sodium carbonate

Conditions

Conditions	Yield
In tetrahydrofuran reductive disproportionation, mechanism discussed;; IR; iron carbonyl not isolated;;	A 82% B 94%

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: 15321-51-4
diiron nonacarbonyl

: Fe(CO)4CCC(C4H9)2

: 13463-40-6
iron pentacarbonyl

B: μ-(Di-tert-butylallenyliden)-bis(tetracarbonyleisen)(Fe-Fe)

Conditions

Conditions	Yield
In petroleum ether addn. of Fe2(CO)9 to soln. of Fe org. complex, stirring for 30 min at 40°C; filtering, chromy., recrystn. from petroleum ether;	A n/a B 92%

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: 122190-26-5
N(C6H4OCH3)C(O)(C(COOCH3))2C(CH3)C(CH3)N(C6H4OCH3)Fe(CO)3

: 13463-40-6
iron pentacarbonyl

B: 1-(4-methoxyphenyl)-3,4-dicarbomethoxy-5-methyl-5(1-{N-(4-methoxyphenyl)imino}ethyl)-1,5-dihydropyrrol-2-one

Conditions

Conditions	Yield
In acetone in a steel autoclave with glass insert, keeping at 75-90 °C, 4 d, under 180 bar of CO pressure; evapn. of the solvent and Fe(CO)5;	A n/a B 90%

: 15321-51-4
diiron nonacarbonyl

: Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

: 13463-40-6
iron pentacarbonyl

B: 17685-52-8
triiron dodecarbonyl

C: CrFe(μ-C(C6H4Me2-2,6))(CO)5(η-C5H5)

Conditions

Conditions	Yield
In tetrahydrofuran N2, stirring for 6 h at room temp.;; evapd., dissolved in CH2Cl2/light petroleum 1/1, chromd. (alumina, CH2Cl2/light petroleum 1/1), evapd., elem. anal.;	A n/a B n/a C 88%

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: 2295-12-7
1,1-dimethylsilacyclobutane

: 15321-51-4
diiron nonacarbonyl

: 13463-40-6
iron pentacarbonyl

B: 17685-52-8
triiron dodecarbonyl

C: 39114-08-4
2,2,2,2-tetracarbonyl-1,1-dimethyl-1-sila-2-ferracyclopentane

Conditions

Conditions	Yield
In benzene addn. of 2 equiv. of Si-compd. to Fe-complex suspn. (held above freezingpoint), warming to 21°C, stirring (24 h); removal of Fe(CO)5 and solvent (vac.), dissoln. in hexane, crystn. (-30°C, several days), filtration off of Fe3(CO)12, evapn. of filtrate(vac., low temp.), sublimation (1E-3 Torr, 0°C); elem. anal.;	A n/a B n/a C 86%

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: 15321-51-4
diiron nonacarbonyl

: Mo(C(C6H4NMe2-4))(CO)2(η-C5H5)

: 13463-40-6
iron pentacarbonyl

B: MoFe(μ-CC6H4NMe2-4)(CO)6(η-C5H5)

C: Mo2Fe(μ-C2(C6H4NMe2-4))2(CO)6(η-C5H5)2

Conditions

Conditions	Yield
In diethyl ether N2, stirring for 5 h at ambient temp.; evapd., dissolved in CH2Cl2/light petroleum 1/2, separation by chromy. (Kieselgel, water-cooled, CH2Cl2/light petroleum 1/2, then CH2Cl2/thf 1/1), evapd., elem. anal.;	A n/a B 85% C n/a

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: cis-(methyloxalyl)(methoxycarbonyl)tetracarbonyliron

A: 553-90-2
Dimethyl oxalate

: 13463-40-6
iron pentacarbonyl

C: bis(methoxycarbonyl)tetracarbonyliron

Conditions

Conditions	Yield
In dichloromethane-d2 byproducts: CO; introducing a soln. of Fe-complex in CD2Cl2 into NMR tube, maintaining temp. at 28°C under N2; monitoring by (13)C-NMR and gas chromatography;	A 15% B n/a C 85%
With carbon monoxide In dichloromethane-d2 introducing a soln. of Fe-complex in CH2Cl2 into an autoclave thermostated at 34°C, stirring for 2.5 h under CO pressure; monitoring by (13)C-NMR and gas chromatography, cooling, removal of solvent under vacuum, redissolution in CD2Cl2, monitoring by (13)C-NMR;

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: dicarbonyl{O-4-η-((E)-4-phenylbut-3-en-2-one)}(triphenylphosphine)iron

: 13463-40-6
iron pentacarbonyl

B: 35679-07-3, 14649-69-5
tetracarbonyl(triphenylphosphine)iron

: tricarbonyl(benzylideneacetone)iron

Conditions

Conditions	Yield
With carbon monoxide In Petroleum ether thermal decompn. in petroleum ether at 70°C under 1 atm of CO; analyzed by IR;	A 0% B 0% C 80%

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: 15321-51-4
diiron nonacarbonyl

: hexaborane(10)

: 13463-40-6
iron pentacarbonyl

B: -.u.-Fe(CO)B6H10

Conditions

Conditions	Yield
	A n/a B 77%

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: 15321-51-4
diiron nonacarbonyl

: Mo(CC6H4OCH3-2)(CO)2(η5-C5H5)

: 13463-40-6
iron pentacarbonyl

B: 17685-52-8
triiron dodecarbonyl

C: MoFe(μ-CC6H4OMe-2)(CO)6(η-C5H5)

Conditions

Conditions	Yield
In diethyl ether N2, stirring for 4 h at ambient temp.; evapd., dissolved in CH2Cl2/light petroleum 1/5, chromd. (Kieselgel, water-cooled, CH2Cl2/light petroleum 1/5, then 1/1), evapd., recrystd. from light petroleum at -78°C, elem. anal.;	A n/a B n/a C 76%

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: 15321-51-4
diiron nonacarbonyl

: selenium

: Mo(C(C6H3Me2-2,6))(CO)2(η-C5H5)

: 13463-40-6
iron pentacarbonyl

B: MoFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions

Conditions	Yield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C); elem. anal.;	A n/a B 76%

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: 15321-51-4
diiron nonacarbonyl

: 93923-00-3
μ3-arsenic-hexacarbonyltris(η5-cyclopentadienyl)trimolybdenum (3 Mo-Mo)

: 13463-40-6
iron pentacarbonyl

B: cyclopentadienylmolybdenum tricarbonyl dimer

C: 111769-94-9
μ4-arsenic-μ-carbonyl-diμ(Fe, Mo)-carbonyl-dicarbonylbis(η5-cyclopentadienyl)(dicarbonyliron){tricarbonyl(η5-cyclopentadienyl)molybdenum}dimolybdenum (2 Fe-Mo, Mo-Mo)

Conditions

Conditions	Yield
In toluene refluxing for 1.5 h; solvent and Fe(CO)5 removed in vac., residue dissolved in toluene; chromy. (silica gel) with hexane/toluene (1:1) yields Cp2Mo2(CO)6, then with toluene PhMe(MoCp(CO)2)2(AsMoCp(CO)3)Fe(CO)5 which is crystd. from CH2Cl2/hexane at -18°C; elem. anal.;	A n/a B n/a C 75%

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: 15321-51-4
diiron nonacarbonyl

: selenium

: Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

: 13463-40-6
iron pentacarbonyl

B: CrFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions

Conditions	Yield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C);	A n/a B 75%

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: 15321-51-4
diiron nonacarbonyl

: selenium

: {W(CC6H3Me2-2,6)(CO)2(η5-C5H5)

: 13463-40-6
iron pentacarbonyl

B: WFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions

Conditions	Yield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C); elem. anal.;	A n/a B 74%

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: bis(μ,η2-decanoyl)hexacarbonyldiiron

: 13463-40-6
iron pentacarbonyl

B: 504-57-4
10-Nonadecanon

Conditions

Conditions	Yield
With methyl iodide In cyclohexane byproducts: n-nonyl iodide, n-decane, CH3COC9H19; (N2); added n-tridecane, methyl iodide and cyclohexane to Fe-complex; stirred at room temp. for 3 h; cooled to -78°C; IR, GLPC, HPLC;	A 46% B 73%

: 15321-51-4
diiron nonacarbonyl

: (trifluoroethenyl)ferrocene

: 13463-40-6
iron pentacarbonyl

B: [Fe(CO)4(η2-trifluorovinylferrocene)]

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 8h; Inert atmosphere; Schlenk technique;	A n/a B 72%

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: 15321-51-4
diiron nonacarbonyl

: 30681-90-4
1,1,2-Trimethyl-1-silacyclobutane

: 13463-40-6
iron pentacarbonyl

B: 17685-52-8
triiron dodecarbonyl

C: 60104-88-3
2,2,2,2-tetracarbonyl-1,1,5-trimethyl-1-sila-2-ferracyclopentane

Conditions

Conditions	Yield
In benzene N2-atmosphere; slight excess of Si-compd., stirring (21°C, 24 h); evapn. (vac., cooling to just above freezing), dissoln. in hexane, standing at -30°C for several d, filtration off of Fe3(CO)12 (-30°C), evapn. of filtrate (low temp., vac.), distn. (0.001 Torr, probe at 0°C); elem. anal.;	A n/a B n/a C 71%

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: 644-97-3
Dichlorophenylphosphine

: diiron nonacarbonyl

: 13463-40-6
iron pentacarbonyl

B: 85539-24-8
[Fe(CO)4(PPhCl2)]

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 16h; Schlenk technique; Darkness; Inert atmosphere;	A n/a B 71%

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: cis-(ethyloxalyl)(ethoxycarbonyl)tetracarbonyliron

: 13463-40-6
iron pentacarbonyl

B: bis(ethoxycarbonyl)tetracarbonyliron

C: 95-92-1
oxalic acid diethyl ester

Conditions

Conditions	Yield
In dichloromethane-d2 byproducts: CO; introducing a soln. of Fe-complex in CD2Cl2 into NMR tube, maintaining temp. at 28°C under N2; monitoring by (13)C-NMR and gas chromatography;	A n/a B 70% C 30%

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: 15321-51-4
diiron nonacarbonyl

: 50964-61-9
Methyl-bis-dimethylarsino-amin

: 13463-40-6
iron pentacarbonyl

B: 101482-34-2
bis(dimethylarsino)methylaminoirontetracarbonyl

Conditions

Conditions	Yield
In diethyl ether (N2); arsenic-compd. in 40% excess; react. at 25°C for 16 h;; filtn., solvent is removed, destillation, elem. anal.;;	A n/a B 69%

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: 122501-48-8
3,4-bis(2',2,'6',6'-tetramethylpiperidino)-1,2-diphospha-3,4-dibora[1.1.0]bicyclobutane

: 15321-51-4
diiron nonacarbonyl

: 13463-40-6
iron pentacarbonyl

B: 122575-20-6
2,4-bis(2',2',6',6'-tetramethylpiperidino)-1,3,2,4-diphosphadiborabicyclo{1.1.0}-butan-bis(tetracarbonyleisen)

Conditions

Conditions	Yield
In toluene stirring at room temp. under N2 for 1 day; evapn. (vac.) and recrystn. from Et2O; elem. anal.;	A n/a B 68%

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: 15321-51-4
diiron nonacarbonyl

: 23800-57-9
1,3,5-triphenylpent-2-en-1,5-dione

: 13463-40-6
iron pentacarbonyl

: C6H5COCH2C(C6H5)CHC(C6H5)OFe(CO)3

Conditions

Conditions	Yield
In benzene at 15-25 °C,for 4-20 h;	A n/a B 65%
In toluene at 15-25 °C,for 4-20 h;	A n/a B 65%

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: 13463-40-6
iron pentacarbonyl

: di(rhodium)tetracarbonyl dichloride

: 56-34-8
tetraethylammonium chloride

: Fe5RhC(CO)16(1-)*(C2H5)4N(1+)={Fe5RhC(CO)16}((C2H5)4N)

Conditions

Conditions	Yield
With sodium amalgam In diethylene glycol Ar, soln. of Fe(CO)5 treated with Na#Hg, Fe(CO)5 added, stirred and heated to 150-160°C, continued for 3-4 h at 130-140°C, cooledto about 20°C, Rh-compound added, stirred for 30-40 min, filtered, 3-fold excess hexane added; decanted; ppt. washed (hexane); extd. (water); Et4NCl in H2O added; pptfiltered; washed (water); dried (vac., 20°C); recrystd. (CH2Cl2); elem. anal.;	100%

Yield

With sodium amalgam In diethylene glycol Ar, soln. of Fe(CO)5 treated with Na#Hg, Fe(CO)5 added, stirred and heated to 150-160°C, continued for 3-4 h at 130-140°C, cooledto about 20°C, Rh-compound added, stirred for 30-40 min, filtered, 3-fold excess hexane added; decanted; ppt. washed (hexane); extd. (water); Et4NCl in H2O added; pptfiltered; washed (water); dried (vac., 20°C); recrystd. (CH2Cl2); elem. anal.;

100%

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: 13463-40-6
iron pentacarbonyl

: 10028-15-6
ozone

: iron(III) oxide

Conditions

Conditions	Yield
In water Kinetics; Irradiation (UV/VIS); React. occurs at room temp.;	99%
In water; acetone Kinetics; Irradiation (UV/VIS); React. occurs at room temp.;	99%
In further solvent(s) Kinetics; Irradiation (UV/VIS); React. occurs at room temp. in perfluorodecaline or perfluoropolyether.;	99%

: 13463-40-6
iron pentacarbonyl

: 603-32-7
triphenyl-arsane

: 14375-84-9, 35644-25-8
Fe(CO)4(As(C6H5)3)

Conditions

Conditions	Yield
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 0.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	99%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	94%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 3 h; evapd. in vac., chromd., recrystd.;	88%

: 13463-40-6
iron pentacarbonyl

: 603-35-0
triphenylphosphine

: 35679-07-3, 14649-69-5
tetracarbonyl(triphenylphosphine)iron

Conditions

Conditions	Yield
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 0.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	99%
CoBr2*3H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1.25 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	98%
cobalt(II) chloride dihydrate In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 2 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	83%
With trimethylamine-N-oxide In ethanol; hexane Kinetics; byproducts: CO2, (CH3)3N; mixing of a soln. of (CH3)3NO in C2H5OH and a soln. of PPh3 in n-C6H14 (at least 10 fold excess) with a soln. of Ru(CO)5 in n-C6H14 (compn. of mixed solvent: 1/2(v/v) C2H5OH/n-hexane) at different temp. in the range 11.3-33.9°C, vigorous shaking; detn. by IR;

: 13463-40-6
iron pentacarbonyl

: 1165952-91-9
cyclohexa-1,3-diene

: 12152-72-6
(cyclohexa-1,3-diene)iron tricarbonyl

Conditions

Conditions	Yield
With catalyst: PhCH=CH-CH=N-C6H4(OMe-4) In 1,4-dioxane Ar-atmosphere; refluxing soln. of Fe-complex, catalyst and cyclohexadiene (excess) for 45 h; evapn., chromy. (SiO2, pentane);	99%
With catalyst: PhCH=CH-CH=N-C6H4(OMe-4) In 1,4-dioxane Ar-atmosphere; refluxing soln. of Fe-complex, catalyst and cyclohexadiene (excess) for 45 h, addn. of new portion of catalyst and diene, refluxing for 24 h; evapn., dissoln. (pentane), filtration (Celite), evapn.;	89%
In hexane Irradiation (UV/VIS); Ar atmosphere;	77%

: 13463-40-6
iron pentacarbonyl

: 2,7,12,17-tetra-n-propylporphycene

: μ-oxodi[iron(III)(2,7,12,17-tetra-n-propylporphycenato)]

Conditions

Conditions	Yield
With iodine In toluene Fe(CO)5 soln. added to ligand soln., I2 added, refluxed for 5 h; cooled, filtered, evapd.; solid residue after filtration extd. (CHCl3) mixed with previously obtained solid, soln. stirred with aq. NaOH for 4 h, org. layer evapd., dissolved in CH2Cl2, chromd. (Al2O3, hexane/CH2Cl2, CH2Cl2);	99%

: 13463-40-6
iron pentacarbonyl

: 344310-48-1
(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2

: 84180-96-1
(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2[Fe(CO)4]2

Conditions

Conditions	Yield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 150°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;	99%

: 13463-40-6
iron pentacarbonyl

: 345652-78-0
((CH3)2PCH2CH2)(C6H5)SiCH2CH2Si(C6H5)(CH2CH2P(CH3)2)

A: 84180-98-3
(CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2[Fe(CO)4]2

B: Fe*2(CH3)2PC2H4(C6H5)SiC2H4Si(C6H5)C2H4P(CH3)2*3CO = ((CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2)2Fe(CO)3

Conditions

Conditions	Yield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 150°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;	A 99% B n/a

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: 13463-40-6
iron pentacarbonyl

: 2,7,12,17-tetra-n-propylporphycene-d4

: (μ-oxo)diiron(III) 2,7,12,17-tetra-n-propylporphycene-d4

Conditions

Conditions	Yield
With iodine In toluene Fe(CO)5 soln. added to ligand soln., I2 added, refluxed for 5 h; cooled, filtered, evapd.; solid residue after filtration extd. (CHCl3) mixed with previously obtained solid, soln. stirred with aq. NaOH for 4 h, org. layer evapd., dissolved in CH2Cl2, chromd. (Al2O3, hexane/CH2Cl2, CH2Cl2);	99%

: 13463-40-6
iron pentacarbonyl

: 852716-21-3
(SeSi(C(CH3)3)3)2

: [Fe(CO)3(μ-SeSi(t-Bu)3)]2

Conditions

Conditions	Yield
In benzene-d6 Irradiation (UV/VIS); dry N2 or Ar; soln. of disulfide and Fe compd. (1:2 molar ratio) irradiated for 14 d, NMR control; crystd. on slow evapn., elem. anal.;	99%

: 13463-40-6
iron pentacarbonyl

: 1,8-bis(3,4,5-trimethoxybenzene)octa-1,7-diyne

: C30H30FeO10

Conditions

Conditions	Yield
In toluene at 130℃; Sonogashira Cross-Coupling; Sealed tube;	98.2%

: 13463-40-6
iron pentacarbonyl

: 35679-07-3, 14649-69-5
tetracarbonyl(triphenylphosphine)iron

Conditions

Conditions	Yield
With triphenylphosphine; tetrakis(triphenylphosphine)platinum In benzene byproducts: CO; under N2, refluxing soln. of metal carbonyl, org. compd. and Pt(PPh3)4 in benzene (molar ratio metal carbonyl/org. compd./Pt(PPh3)4 1:2:0.1, 5 h), cooling (room temp.); removal of solvent (vac.), dissoln. (CH2Cl2), chromy. (silica gel, CH2Cl2/hexane 1:1), recrystn. (CH2Cl2/hexane);	98%
With triphenylphosphine; pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	97%
With triphenylphosphine; palladium(II) oxide In toluene byproducts: CO; 10 h, toluene under reflux, PdO catalyst;; not sepd., detected by IR-spectra;;	96%

: 13463-40-6
iron pentacarbonyl

: 998-40-3
tributylphosphine

: 18474-82-3
Fe(CO)4PBu3

Conditions

Conditions	Yield
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.0 h; evapd. in vac., chromd., recrystd.;	98%
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.0 h; evapd. in vac., chromd., recrystd.;	98%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	93%

: 13463-40-6
iron pentacarbonyl

: 1486-28-8
diphenyl(methyl)phosphine

: 37410-36-9, 41206-81-9
Fe(CO)4PPh2Me

Conditions

Conditions	Yield
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.75 h; evapd. in vac., chromd., recrystd.;	98%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	98%
cobalt(II) chloride dihydrate In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	98%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	96%
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	78%

: 13463-40-6
iron pentacarbonyl

: 13246-32-7
ortho-phenylenebis(dimethylarsine)

A: 56760-75-9
C6H4(As(CH3)2)2Fe(CO)4

B: 15308-59-5, 56760-75-9
(CO)3Fe{(CH3)2AsC6H4As(CH3)2}

Conditions

Conditions	Yield
In neat (no solvent) tube was charged with ligand and Fe(CO)5, degassed and sealed under vac. (0.1 mmHg), tube was wrapped in foil and heated in an oil bath at 180°C for 7 h under N2, allowed to stand overnight at room temp., tube was frozen in liq. N2; solid residue was crushed, washed with ether under N2, taken up in CH2Cl2, soln. was filtered under N2, solvent was removed, chromd. under N2 on Florisil, eluted with benzene/hexane;	A n/a B 98%

Yield

In neat (no solvent) tube was charged with ligand and Fe(CO)5, degassed and sealed under vac. (0.1 mmHg), tube was wrapped in foil and heated in an oil bath at 180°C for 7 h under N2, allowed to stand overnight at room temp., tube was frozen in liq. N2; solid residue was crushed, washed with ether under N2, taken up in CH2Cl2, soln. was filtered under N2, solvent was removed, chromd. under N2 on Florisil, eluted with benzene/hexane;

A n/a
B 98%

...Expand

: 13463-40-6
iron pentacarbonyl

: tris(1,2-naphthoquinone-1-oximato)iron(III)

: bis(1,2-naphthoquinone-2-oximato)iron(II)

Conditions

Conditions	Yield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated under reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;	98%

: 13463-40-6
iron pentacarbonyl

: tris(5-methoxybenzo-1-quinone-2-oximato)iron(III)

: bis(5-metoxy-1,2-quinone-2-oximato)iron(II)

Conditions

Conditions	Yield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated under reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;	98%

: 13463-40-6
iron pentacarbonyl

: 1,2,3-trimethylbicyclo<10.3.0>pentadecadiene

: {(C12H20C3(CH3)3)Fe(CO)2}2

Conditions

Conditions	Yield
In toluene (N2); reflux of mixt. for 3 days (125°C); filtn., residue is washed with toluene and cooled down to -30°C, soln. is decanted, crystals are washed with hexane, elem. anal.;	98%

: 13463-40-6
iron pentacarbonyl

: 696-26-4
dimethylphenylarsine

: 83653-44-5
Fe(CO)4(As(C6H5)(CH3)2)

Conditions

Conditions	Yield
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	98%
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.5 h; evapd. in vac., chromd., recrystd.;	97%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.25 h; evapd. in vac., chromd., recrystd.;	95%

: 13463-40-6
iron pentacarbonyl

: 84114-40-9
((CH3)2PCH2CH2)2SiCH2CH2CH2

: 84206-91-7
[Fe(CO)4]2((CH3)2PCH2CH2)2SiCH2CH2CH2

Conditions

Conditions	Yield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 140°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;	98%

: 13463-40-6
iron pentacarbonyl

: Ga(AmIm)

: Fe(CO)4{Ga(AmIm)}

Conditions

Conditions	Yield
In toluene at 25℃; for 18h; Inert atmosphere;	98%

: 13463-40-6
iron pentacarbonyl

: C58H72FeN4O4Si2

: C61H72Fe2N4O7Si2

Conditions

Conditions	Yield
Stage #1: C58H72FeN4O4Si2 In toluene at 20℃; for 0.166667h; Schlenk technique; Inert atmosphere; Stage #2: iron pentacarbonyl In toluene at 20 - 100℃; Schlenk technique; Inert atmosphere;	97.1%

: 13463-40-6
iron pentacarbonyl

: 603-36-1
triphenylantimony

: 20516-78-3, 35917-16-9
Fe(CO)4(Sb(C6H5)3)

Conditions

Conditions	Yield
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;	97%
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;	97%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.0 h; evapd. in vac., chromd., recrystd.;	96%

: 13463-40-6
iron pentacarbonyl

: 431-94-7
N-chlorobistrifluoromethylamine

: 371-71-1
Perfluoro-2-azapropen

Conditions

Conditions	Yield
0°C;	97%
0°C;	97%

: 13463-40-6
iron pentacarbonyl

: 758-43-0
N-bromobis(trifluoromethyl)amine

: 371-71-1
Perfluoro-2-azapropen

Conditions

Conditions	Yield
0°C;	97%
0°C;	97%

: 13463-40-6
iron pentacarbonyl

: 118734-49-9
4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole

A: 118772-37-5
tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)iron

B: 201230-82-2
carbon monoxide

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); Ar atmosphere, photolysis (125-W medium-pressure Hg lamp, 4.5 h); solvent removal (12 Torr), dissoln. (pentane), filtn., evapn., sublimation (70-80°C, 0.001 Torr); elem. anal.;	A 73% B 97%

...Expand

: 13463-40-6
iron pentacarbonyl

: tris(1,2-naphthoquinone-2-oximato)iron(III)

: bis(1,2-naphthoquinone-1-oximato)iron(II)

Conditions

Conditions	Yield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated ander reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;	97%

: 13463-40-6
iron pentacarbonyl

: 7487-94-7
mercury (II) chloride

: (CO)5Fe*3HgCl2

Conditions

Conditions	Yield
In pentane under dry nitrogen; stirred 6 h at 0°C; washed with cold pentane, dried in a steam of N2; elem. anal.;	97%

Related products

13463-41-7

Zinc pyrithione

13463-43-9

Sulfuric acid, iron(2+)salt (1:1), hydrate (8CI,9CI)

13463-67-7

Titanium dioxide

13463-71-3

2-Propenoic acid,2-methyl-, 3-hydroxy-2,2-dimethylpropyl ester

134637-67-5

Benzene,1,5-dinitro-2,4-bis(phenylmethoxy)-

13464-19-2

Carbonochloridothioicacid, S-phenyl ester

13464-24-9

Phenol,4,4'-(1,1-dimethyl-3-methylene-1,3-propanediyl)bis-

13464-35-2

Arsenenous acid, potassium salt (1:1)

13464-43-2

Arsenenic acid,lead(2+) salt (9CI)

13464-44-3

Arsenicacid (H3AsO4), zinc salt (2:3) (8CI,9CI)

Raw Materials

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CAS No.:13463-40-6
Name:Ironpentacarbonyl
Article Data:264
Molecular Structure:
Formula:C5Fe O5
Molecular Weight:195.899
Synonyms:Ironcarbonyl (Fe(CO)5) (8CI); Iron pentacarbonyl; Iron pentacarbonyl (Fe(CO)5);Pentacarbonyl iron; R 20
EINECS:236-670-8
Density:1.49 g/mL at 25 °C(lit.)
Melting Point:-20 °C
Boiling Point:103 °C(lit.)
Flash Point:5 °F
Solubility:Solubility in organic solvents
Appearance:straw-yellow liquid
Hazard Symbols:Flammable, dangerous fire risk. Toxic by ingestion, inhalation, and skin absorption. TLV: TWA 0.1 ppm (Fe); STEL 0.2 ppm.
Risk Codes11-24-26/28
Safety: A poison by inhalation, skin contact, ingestion, subcutaneous, and intravenous routes. Inhalation causes dizziness, nausea, and vomiting. If continued, unconsciousness follows. Often there is a delayed reaction of chest pain, cough, and difficult breathing. There may be cyanosis and circulatory collapse. In fatal cases, death occurs from the fourth to eleventh day with pneumonitis and injury to kidneys, liver, and brain. Iron carbonyl is less toxic than nickel carbonyl.
A very dangerous fire and moderate explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Warning: pyrophoric in air. Mixtures with nitrogen oxide explode above 50°C. Violent reaction with zinc + transition metal halides (e.g., cobalt halides, rhodium halides, ruthenium halides). Mixtures with acetic acid + water produce a pyrophoric powder. To fight fire, use water, foam, CO₂, dry chemical. See also CARBONYLS and IRON COMPOUNDS.
Transport Information:UN 1994 6
PSA:0.00000
LogP:-1.04250

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