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4-Methoxystyrene Chemical Properties Melting point 2°C Boiling point 41-42 °C/0.5 mmHg (lit.) density 1.009 g/mL at 25 °C (lit.) refractive index n20/D 1.562 Fp 170 °F storage temp. 2-8°C solubility Sli
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Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 0.0833333h; | 100% |
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 5h; further catalysts; | 73% |
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc(II) chloride 1.) THF, RT, 20 min, 2.) RT, 1 h; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With cesium fluoride; palladium diacetate In 1,4-dioxane at 100℃; for 3h; Stille cross-coupling; | 99% |
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole In toluene at 60℃; for 10h; Stille coupling; Inert atmosphere; | 88% |
With cesium fluoride In 1,4-dioxane at 100 - 110℃; for 22h; Stille Cross Coupling; | 80% |
Conditions | Yield |
---|---|
With hydrogen; 3-azapentane-1,5-diamine In methanol at 25℃; for 6h; | 99% |
With pyridine; hydrogen at 25℃; under 760.051 Torr; for 6h; Reagent/catalyst; Solvent; Green chemistry; chemoselective reaction; | 96% |
With hydrogen In methanol at 20℃; for 40h; chemoselective reaction; | 95% |
Conditions | Yield |
---|---|
With [CuCl(ClIPr)]; sodium t-butanolate; tert-butyl alcohol In tetrahydrofuran; hexane at 40℃; for 20h; Inert atmosphere; chemoselective reaction; | 99% |
Conditions | Yield |
---|---|
With 1-butyl-3-methyl-3H-imidazol-1-ium fluoride In acetonitrile at 70℃; Hiyama Coupling; Inert atmosphere; | 98% |
With sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle In water at 120℃; for 0.166667h; Hiyama reaction; microwave irradiation; | 82% |
With trans-[1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene]PdCl2(NC5H5); sodium hydroxide In 1,4-dioxane; water at 80℃; for 7h; Hiyama cross-coupling; | 41 %Chromat. |
Conditions | Yield |
---|---|
With sodium hydroxide; tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt at 160℃; for 5h; | 97.5% |
With 1,10-Phenanthroline; copper hydroxide In 1-methyl-pyrrolidin-2-one at 210℃; for 1h; Inert atmosphere; Green chemistry; | 68% |
With copper(I) sulfate; copper(II) sulfate; hydroquinone In quinoline for 0.5h; Heating; | 29.1% |
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 100℃; for 5h; Reagent/catalyst; Solvent; Temperature; Hiyama Coupling; Sealed tube; | 97% |
With sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle In water at 120℃; for 0.166667h; Hiyama reaction; microwave irradiation; | 84% |
With tetrabutyl ammonium fluoride; palladium dichloride In tetrahydrofuran at 65℃; for 9h; Hiyama coupling; | 78% |
Conditions | Yield |
---|---|
With potassium hydrogensulfate at 190℃; under 22 Torr; Pressure; Temperature; Large scale; | 96.3% |
With phosphotungstic acid In dimethyl sulfoxide at 100℃; for 1h; Inert atmosphere; | 91% |
With 1,1,1-trichloro-3,3,3-trifluoro-propan-2-one; toluene-4-sulfonic acid; hydroquinone In benzene for 10h; Heating; | 88% |
Conditions | Yield |
---|---|
With hydrogen In hexane at 50℃; under 760.051 Torr; for 10h; | A 96% B 4% |
With hydrogen In methanol at 20℃; under 760.051 Torr; for 24h; | |
With hydrogen In methanol at 25℃; for 2h; | A 89 %Chromat. B 11 %Chromat. |
Conditions | Yield |
---|---|
Stage #1: 4-Methoxybenzyl alcohol With triethylphosphine hydrobromide at 100℃; for 0.166667h; Microwave irradiation; Stage #2: formaldehyd With potassium carbonate In water at 100℃; for 0.0833333h; Microwave irradiation; | 96% |
Conditions | Yield |
---|---|
With potassium hydroxide In water; acetone at 20℃; for 124h; | 96% |
tert-butyl (3R,αR)-3-[N-benzyl-N-(α-methyl-p-methoxybenzyl)amino]-7-iodoheptanoate
A
4-Methoxystyrene
B
tert-butyl (R)-2-[N(1)-benzylpiperidin-2-yl]acetate
Conditions | Yield |
---|---|
In acetonitrile at 80℃; for 16h; | A 65% B 94% |
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether 1) -70 deg C, 1-2 h, 2) -70 - 20 deg C, 15 h; | 93% |
In tetrahydrofuran | 91% |
In tetrahydrofuran; ethanol at -70℃; for 12h; Product distribution; use of var. solvents (H2O and H2O/EtOH), var. temp. and other reagent (Cl3Mo=CH2); | 92 % Chromat. |
In tetrahydrofuran; ethanol for 12h; -70 degC to room temp.; | 92 % Chromat. |
Conditions | Yield |
---|---|
With palladium(II) acetylacetonate; potassium fluoride In N,N-dimethyl-formamide at 130℃; under 1500.15 Torr; for 3h; Reagent/catalyst; Time; Hiyama Coupling; Inert atmosphere; | 93% |
Methyltriphenylphosphonium bromide
4-methoxy-benzaldehyde
4-Methoxystyrene
Conditions | Yield |
---|---|
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at -78℃; for 0.25h; Inert atmosphere; Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran Inert atmosphere; | 91% |
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran at 20℃; | 88.9% |
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran for 0.25h; Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran Wittig olefination; Further stages.; | 82% |
4-methoxy-trans-cinnamaldehyde
4-Methoxystyrene
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; oxygen; sodium carbonate In isopropyl alcohol at 120℃; for 24h; regioselective reaction; | 91% |
With pyridine; palladium diacetate; triphenylphosphine In water at 100℃; for 24h; Inert atmosphere; | 72% |
With palladium 10% on activated carbon; sodium carbonate In isopropyl alcohol at 120℃; for 6h; Inert atmosphere; |
Conditions | Yield |
---|---|
With methoxy(cyclooctadiene)rhodium(I) dimer; N,N-Dimethylacrylamide; 3-Methoxybenzoic acid; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 90℃; for 24h; Inert atmosphere; Glovebox; Sealed tube; chemoselective reaction; | 91% |
Conditions | Yield |
---|---|
With Methyltriphenylphosphonium bromide; potassium carbonate In 1,4-dioxane at 100℃; for 16h; Microwave irradiation; Sealed tube; Inert atmosphere; | 90% |
With aluminium silicate; acetic anhydride at 400℃; | |
Multi-step reaction with 3 steps 1: 85 percent / tetrahydrofuran 2: 96 percent / H2O2, (NH4)6MoO7*4H2O / ethanol / 65 h / Ambient temperature 3: 63 percent / LDA / tetrahydrofuran / 1) -78 deg C, 1 h, 2) r.t., 1 h View Scheme |
Conditions | Yield |
---|---|
With palladium diacetate; C22H27P; triethylamine In 1,4-dioxane; Hexadecane at 120℃; for 20h; Reagent/catalyst; Heck Reaction; Schlenk technique; Inert atmosphere; Autoclave; | 90% |
With tributyl-amine; potassium carbonate; palladium In N,N-dimethyl-formamide at 150℃; under 7757.43 Torr; for 1h; Heck reaction; microwave irradiation; | 67% |
With dichloro bis(acetonitrile) palladium(II); C9H13N3O; triethylamine In N,N-dimethyl-formamide at 160℃; under 4500.45 Torr; for 2h; Catalytic behavior; Heck Reaction; regioselective reaction; | 26% |
With lithium perchlorate; triethylamine; triphenylphosphine In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide electrolysis; | 70 % Chromat. |
With dichlorobis(tri-O-tolylphosphine)palladium; triethylamine In acetonitrile at 70℃; under 3345.86 Torr; Temperature; Reagent/catalyst; Heck Reaction; |
Conditions | Yield |
---|---|
With Wilkinson's catalyst; isopropyl alcohol; 4-diphenylphosphanyl-benzoic acid 2-trimethylsilanyl-ethyl ester In tetrahydrofuran at 25℃; for 0.5h; | 90% |
With (IMes)CuCl; triphenylphosphine; isopropyl alcohol In 1,4-dioxane; diethyl ether at 60℃; for 16h; | 82% |
With tris(triphenylphosphine)rhodium(l) chloride; triphenylphosphine; isopropyl alcohol In tetrahydrofuran at 25℃; for 2h; Reagent/catalyst; chemoselective reaction; | 73% |
With RhCl(PPh3)3; triphenylphosphine In 1,4-dioxane; isopropyl alcohol; toluene at 50℃; | 40 mg |
para-iodoanisole
4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane
4-Methoxystyrene
Conditions | Yield |
---|---|
With silver(l) oxide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 67℃; for 24h; Suzuki-Miyaura reaction; | 90% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 66℃; for 1.5h; | 89% |
Conditions | Yield |
---|---|
With P(i-BuNCH2CH2)2(BnNCH2CH2)N; dimethyl-N-fluoroamine; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 100 - 110℃; Stille reaction; | 89% |
With Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); cesium fluoride In tetrahydrofuran at 50℃; for 6h; Stille Cross Coupling; | 85% |
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; cesium fluoride In 1,4-dioxane at 100℃; for 48h; Stille cross-coupling; | 83% |
Conditions | Yield |
---|---|
With Hoveyda-Grubbs catalyst second generation; di-μ-bromobis-(tritert-butylphosphine)dipalladium(I) In tetrahydrofuran at 60℃; under 7500.75 Torr; for 16h; Autoclave; | 89% |
Conditions | Yield |
---|---|
With 1-methyl-pyrrolidin-2-one; copper(l) iodide; sodium chloride at 90℃; for 6h; other reagent: MnBr2, NaCl, N-methylpyrrolidone; | 88% |
With palladium; N,N-dimethyl-formamide In 1-methyl-pyrrolidin-2-one at 120℃; for 15h; | 44% |
With 9-phosphatriptycene deriv; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 50℃; for 2h; Stille coupling; | 64 % Spectr. |
(R,S)-NN-dimethyl-N-phenacyl-1-p-methoxyphenylethylammonium bromide
A
4-Methoxystyrene
B
4,4'-(butane-2,3-diyl)bis(methoxybenzene)
C
rac-1-(4-methoxyphenyl)-ethanol
D
2-dimethylamino-3-p-methoxyphenyl-1-phenylbutan-1-one
Conditions | Yield |
---|---|
With sodium hydroxide In water at 0℃; for 14h; Further byproducts given; | A 0.4% B 4% C 1.1% D 87% |
With sodium hydroxide In water at 0℃; for 14h; Further byproducts given; | A 0.4% B 4% C 1.1% D 87% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-) In decane; acetonitrile at 45℃; for 4h; Wacker Oxidation; | 100% |
With water; oxygen In methanol; dimethyl sulfoxide at 80℃; under 1520.1 Torr; for 20h; Wacker Oxidation; Autoclave; | 99% |
With palladium diacetate; 9-tert-butyl-10-methylanthracene ozonide In acetonitrile for 72h; Ambient temperature; | 93% |
Conditions | Yield |
---|---|
With hydrogen; 1,5-hexadienerhodium(I)-chloride dimer In hexane for 7h; Ambient temperature; pH=7.6; | 100% |
With C28H18Fe(1-)*K(1+)*C12H24O6*C4H8O; hydrogen In toluene at 60℃; under 1500.15 Torr; for 24h; Reagent/catalyst; Temperature; Pressure; Time; chemoselective reaction; | 100% |
With hydrogen In d(4)-methanol at 20℃; under 760.051 Torr; for 6h; | 100% |
4-Methoxystyrene
2-bromo-1-(4-methoxyphenyl)ethanol
Conditions | Yield |
---|---|
With N-Bromosuccinimide; water In acetonitrile at 20℃; | 100% |
With N,N'-dibromo-N,N'-(1,2-ethanediyl)bis(p-toluenesulfonamide); ammonium acetate; water In acetone at 20℃; for 0.0333333h; | 95% |
With hydrogen bromide; dimethyl sulfoxide In water at 60℃; for 12h; | 93% |
4-Methoxystyrene
diisopropoxyphosphorylsulfenyl chloride
Thiophosphoric acid S-[2-chloro-2-(4-methoxy-phenyl)-ethyl] ester O,O'-diisopropyl ester
Conditions | Yield |
---|---|
In tetrachloromethane at 25℃; for 2h; Rate constant; | 100% |
In tetrachloromethane at 25℃; for 2h; | 98% |
Conditions | Yield |
---|---|
With 1H-imidazole; [MnIII(TPP)(OAc)]; tetra-n-butylammonium hydrogen monopersulfate In dichloromethane at 20℃; for 0.5h; | 100% |
With dihydrogen peroxide In ethanol; water at 50℃; for 1h; Catalytic behavior; Green chemistry; | 99% |
With dihydrogen peroxide; cobalt(II) acetate In water at 20℃; for 3h; Ionic liquid; Green chemistry; | 98% |
Conditions | Yield |
---|---|
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique; | 100% |
With ruthenium trichloride; [bis(acetoxy)iodo]benzene In dichloromethane; water at 30℃; for 2.5h; Solvent; | 92.1% |
With dihydrogen peroxide In acetonitrile at 65℃; for 6h; | 92% |
4-Methoxystyrene
Conditions | Yield |
---|---|
In benzene-d6 reaction in NMR tube, soln. was kept at room temp. for 2 h; solvent was removed in vac.; NMR; | 100% |
4-Methoxystyrene
N-(4-hydroxyphenyl)-4-methylbenzenesulfonamide
N-(2-(4-methoxyphenyl)-2,3-dihydrobenzofuran-5-yl)-4-methylbenzenesulfonamide
Conditions | Yield |
---|---|
With bis-[(trifluoroacetoxy)iodo]benzene | 100% |
4-Methoxystyrene
2-hydroxy-2-methylpropanenitrile
2-(4-methoxyphenyl)propionitrile
Conditions | Yield |
---|---|
With 3-[bis-(4-methoxy-phenyl)-phosphanyl]-2H-isoquinolin-1-one; N-{6-[bis-(4-methoxy-phenyl)-phosphanyl]-pyridin-2-yl}-2,2-dimethyl-propionamide; bis(1,5-cyclooctadiene)nickel (0) In toluene at 35℃; for 25h; Inert atmosphere; regioselective reaction; | 100% |
4-Methoxystyrene
Conditions | Yield |
---|---|
With 1-chloro-1λ3-benzo[d][1,2]iodaoxol-3(1H)-one; trimethylsilylazide; cesium fluoride In dichloromethane at 0℃; for 12h; Mechanism; Reagent/catalyst; Temperature; Solvent; | 100% |
Conditions | Yield |
---|---|
With C28H24FN2O3PPd; tetrabutylammomium bromide; sodium acetate at 140℃; for 12h; Catalytic behavior; Inert atmosphere; Schlenk technique; regioselective reaction; | 100% |
methanol
4-Methoxystyrene
2-(4-methoxyphenyl)acetaldehyde dimethyl acetal
Conditions | Yield |
---|---|
With Pyridine-2,6-dicarboxylic acid; iron(II) tetrafluoroborate hexahydrate; [bis(acetoxy)iodo]benzene at 20℃; for 20h; Molecular sieve; Inert atmosphere; regioselective reaction; | 99% |
With ammonium iodide; Oxone at 30℃; for 3h; Green chemistry; regioselective reaction; | 78% |
With thallium(III) nitrate | |
Stage #1: methanol; 4-Methoxystyrene With ammonium iodide for 0.0166667h; Inert atmosphere; Stage #2: With Oxone at 30℃; |
4-Methoxystyrene
[N-(p-tolylsulfonyl)imino]phenyliodinane
2-(4-methoxyphenyl)-1-tosylaziridine
Conditions | Yield |
---|---|
With [CuI(tris[(tetramethylguanidino)-phenyl]amine)][PF6] In acetonitrile for 2h; Inert atmosphere; Molecular sieve; | 99% |
With C12H18CuN6(2+)*2C16AlF36O4(1-) In acetonitrile at 25℃; for 0.0166667h; Inert atmosphere; | 93% |
With iodine In water at 20℃; for 12h; Green chemistry; | 87% |
Conditions | Yield |
---|---|
With 2-benzyloxymethylphenyldiphenylphosphine; bi(allylnickel bromide); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 0 - 23℃; under 760.051 Torr; for 72h; Schlenk technique; | 99% |
With hexakis(acetonitrile)nickel(II) tetrafluoroborate; diethylaluminium chloride; triphenylphosphine In dichloromethane; toluene at 20℃; under 7500.6 Torr; for 1h; hydrovinylation; | 76% |
With 2; diethylaluminium chloride; triphenylphosphine In dichloromethane; toluene under 7500.6 Torr; for 0.5h; Yield given; |
4-Methoxystyrene
1-(4-methoxyphenyl) ethane-1,2-diol
Conditions | Yield |
---|---|
With dmap; osmium(VIII) oxide; 4-methylmorpholine N-oxide In water; acetone at 20℃; | 99% |
Stage #1: 4-Methoxystyrene With formic acid; 2,6-dichloropyridine N-oxide; dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin In chloroform at 20℃; Darkness; Stage #2: With potassium carbonate In methanol | 95% |
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In tetrahydrofuran; water; tert-butyl alcohol at 20℃; for 12h; Sealed tube; | 94% |
4-Methoxystyrene
2-bromo-4-nitroaniline
2-amino-5-nitro-4'-methoxystilbene
Conditions | Yield |
---|---|
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 120℃; for 72h; | 99% |
4-Methoxystyrene
2-carbonyl-3-butenenitrile
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 22h; hetero-Diels-Alder cycloaddition; | 99% |
4-Methoxystyrene
para-nitrophenyl bromide
A
(E)-1-methoxy-4-(4-nitrostyryl)benzene
B
1-(4-methoxyphenyl)-1-(4-nitrophenyl)ethylene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; potassium carbonate; bis-<(4-Cl-2-PdCl-Ph)-(4-Cl-Ph)-methanone oxime> In N,N-dimethyl-formamide at 130℃; for 4h; Product distribution; Further Variations:; Reaction partners; Reagents; Temperatures; Heck-Mizoroki-Jeffery reaction; | A 99% B n/a |
Conditions | Yield |
---|---|
With N-iodo-succinimide In dichloromethane at -78 - 0℃; | 99% |
Stage #1: 4-Methoxystyrene; 3-methyl-2-buten-1-ol In dichloromethane at 20℃; for 0.0833333h; Stage #2: With N-iodo-succinimide In dichloromethane at -78 - 0℃; Further stages.; | 99% |
4-Methoxystyrene
Conditions | Yield |
---|---|
With bromodichloromethane; sodium iodide In acetonitrile at 90℃; for 12h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere; Sealed tube; | 99% |
With bis(acetylacetonato)palladium(II); trifluoroacetic acid In dichloromethane at 20℃; for 0.0833333h; stereoselective reaction; | 92% |
With ethanol; triphenylphosphine; zinc; bis(triphenylphosphine)dichlorocobalt(II) In acetonitrile at 80℃; for 18h; | 82% |
With ruthenium trichloride In tetrahydrofuran | 81% |
4-Methoxystyrene
1-phenylmethylpiperazine
N-benzyl-N'-[2-(4-methoxyphenyl)ethyl]piperazine
Conditions | Yield |
---|---|
Stage #1: 1-phenylmethylpiperazine With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 0.166667h; Stage #2: 4-Methoxystyrene In tetrahydrofuran; hexane at 20℃; for 24h; Further stages.; | 99% |
4-Methoxystyrene
t-butyl diazoacetate
Conditions | Yield |
---|---|
With C67H51IrN2O2 In tetrahydrofuran at -50℃; for 24.1667h; optical yield given as %ee; enantioselective reaction; | 99% |
chiral phenyliridium(III)-salen complex In tetrahydrofuran at -50 - 20℃; | 99 % Spectr. |
Conditions | Yield |
---|---|
With CO In tetrahydrofuran | 99% |
Conditions | Yield |
---|---|
With bi(allylnickel bromide); C43H34NO2P; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at -78℃; under 760.051 Torr; for 1h; Reagent/catalyst; | 99% |
With bi(allylnickel bromide); {benzyl[(S)-1-(1-naphthyl)ethyl]amino}[(R)-1,1'-binaphthyl-2,2'-diyldioxy]phosphine; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at -78℃; for 1h; Inert atmosphere; enantioselective reaction; |
4-Methoxystyrene
4-fluoro-1-iodobenzene
1-(4-methoxystyryl)-4-fluorobenzene
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; triethylamine In N,N-dimethyl-formamide at 200℃; for 0.166667h; Heck reaction; Microwave irradiation; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; triethylamine In N,N-dimethyl-formamide at 200℃; for 0.166667h; Mizoroki-Heck reaction; Microwave irradiation; | 99% |
4-Methoxystyrene
1-Bromo-4-fluorobenzene
1-(4-methoxystyryl)-4-fluorobenzene
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; tetrabutylammomium bromide; sodium acetate In 1-methyl-pyrrolidin-2-one at 200℃; for 0.5h; Heck reaction; Microwave irradiation; | 99% |
With 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; tetrabutylammomium bromide; sodium acetate; bis(dibenzylideneacetone)-palladium(0) In 1-methyl-pyrrolidin-2-one at 200℃; for 0.5h; Mizoroki-Heck reaction; Microwave irradiation; | 99% |
With dichloro bis(acetonitrile) palladium(II); 10F6P(1-)*C235H200N20O10(10+); potassium hydroxide In 1-methyl-pyrrolidin-2-one at 160℃; for 5h; Heck Reaction; Inert atmosphere; | 95% |
With potassium phosphate; C34H46Br4N8Pd2 In N,N-dimethyl-formamide at 110℃; for 4h; Heck Reaction; | 73% |
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