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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply p-propylanisole

Cas:104-45-0

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Propylanisole

Cas:104-45-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

tianfu-chem_ 4-N-PROPYLANISOLE,104-45-0

Cas:104-45-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 104-45-0 with best price

Cas:104-45-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-methoxy-4-propyl- 104-45-0

Cas:104-45-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-N-PROPYLANISOLE 104-45-0

Cas:104-45-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda

1-methoxy-4-propylbenzene 104-45-0

Cas:104-45-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offer4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1-Methoxy-4-propylbenzene 100g

Cas:104-45-0

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

ZHEJIANG JIUZHOU CHEM CO., LTD is a market-oriented and innovation-driven biopharmaceutical company. The company is focusing on the R&D, manufacturing and sales of pharmaceutical products both for peptide and small molecule. Through technical inn

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Other

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Benzene,1-methoxy-4-propyl-Appearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

Benzene,1-methoxy-4-propyl-

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

4-N-PROPYLANISOLE

Cas:104-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our?company?has?been?in?existence?for?10?years?since?its?establishment.?We?have?our?own?unique?team.?The??company?integrates?independent?research?and?development,?production?and?sales.?We?have?established?famous??brands?at?home?and?abroad.?At?present

1-Methoxy-4-propylbenzene

Cas:104-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

Estragole
140-67-0

Estragole

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With hydrogen; sodium triethylborohydride In tetrahydrofuran at 23℃; under 30003 Torr; for 96h; Reagent/catalyst; Autoclave;100%
With hydrogen; sodium triethylborohydride In tetrahydrofuran at 23℃; under 30402 Torr; for 18h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere;100%
With borane-ammonia complex; Pd(SIPr)(PCy3) In isopropyl alcohol at 50℃; for 16h; Inert atmosphere; Glovebox;99%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With magnesium; nickel dichloride In water at 20℃; for 12h; Sealed tube; Photolysis; Inert atmosphere;99%
With oxygen; hydrazine hydrate In propan-1-ol at 120℃; under 15001.5 Torr; for 0.5h;91%
With oxygen; hydrazine hydrate In propan-1-ol at 120℃; under 15001.5 Torr; for 0.166667h; Flow reactor;91%
anethole
104-46-1

anethole

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With C28H18Co(1-)*K(1+)*2C4H10O2; hydrogen In toluene at 60℃; under 7500.75 Torr; for 24h; chemoselective reaction;99%
With sodium hydrogen telluride In ethanol Heating; overnight;94%
With formic acid; Pd(SIPr)(PCy3) In tetrahydrofuran at 60℃; for 24h; Inert atmosphere;94%
1-methanesulfonyloxy-3-(4-methoxyphenyl)propane
72456-64-5

1-methanesulfonyloxy-3-(4-methoxyphenyl)propane

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With samarium diiodide; tri-n-butyl-tin hydride; lithium iodide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at 20 - 35℃; for 21h; Elimination;95%
2-phenyl-1,3,2-benzodioxaborole
5747-23-9

2-phenyl-1,3,2-benzodioxaborole

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With oxygen; hydrazine hydrate In acetonitrile at 32℃; under 760.051 Torr; for 5h; Schlenk technique;A 95%
B 91%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

propyl bromide
106-94-5

propyl bromide

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
Stage #1: propyl bromide With chloro-trimethyl-silane; diisobutylaluminium hydride; magnesium; 1-Bromo-2-chloroethane In tetrahydrofuran at 40℃; Flow reactor;
Stage #2: With 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; Flow reactor;
Stage #3: 4-chloromethoxybenzene With iron(III)-acetylacetonate In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Flow reactor; Irradiation;
95%
1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonic acid 4-methoxyphenyl ester
93131-74-9

1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonic acid 4-methoxyphenyl ester

propyl bromide
106-94-5

propyl bromide

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 5-(dicyclohexylphosphaneyl)-1-(2,6-diisopropoxyphenyl)-1H-pyrazole; magnesium; lithium chloride; zinc(II) chloride In tetrahydrofuran at 25℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction;93%
4-n-Propylphenol
645-56-7

4-n-Propylphenol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With layered double hydroxide - supported L-methionine at 180℃; for 6h; Autoclave; chemoselective reaction;89%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

n-propylmagnesium bromide
927-77-5

n-propylmagnesium bromide

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With palladium diacetate; zinc dibromide; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 20 - 25℃; for 2.5h; Inert atmosphere;88%
Estragole
140-67-0

Estragole

A

(Z)-1-(4-tolyl)-1-propene
2077-29-4

(Z)-1-(4-tolyl)-1-propene

B

(E)-1-methyl-4-(prop-1-enyl)benzene
2077-30-7

(E)-1-methyl-4-(prop-1-enyl)benzene

C

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With iron(III) chloride; lithium aluminium tetrahydride; hydrogen In tetrahydrofuran at 18℃; under 750.075 Torr; for 24h; Inert atmosphere; Sealed tube;A n/a
B n/a
C 84%
4-(p-methoxyphenyl)but-1-ene
20574-98-5

4-(p-methoxyphenyl)but-1-ene

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With iron(III)-acetylacetonate; ethanol; phenylsilane; thiophenol In propan-1-ol at 23℃; for 108h; Inert atmosphere;83%
isopropyl chloride
75-29-6

isopropyl chloride

4-methoxyphenyl triflate
66107-29-7

4-methoxyphenyl triflate

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

1-methoxy-4-(1-methylethyl)benzene
4132-48-3

1-methoxy-4-(1-methylethyl)benzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dibutylphosphanyl)-1-phenylpyrrole; magnesium; lithium chloride; zinc(II) chloride In tetrahydrofuran at 60℃; for 16h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube;A 76%
B n/a
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

iso-propylmagnesium halide

iso-propylmagnesium halide

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With palladium diacetate; zinc dibromide; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 20 - 25℃; for 2.5h; Inert atmosphere;72%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

3-(4-methoxyphenyl)-1-iodopropane
113379-13-8

3-(4-methoxyphenyl)-1-iodopropane

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

1-(3-cyclopropylpropyl)-4-methoxybenzene

1-(3-cyclopropylpropyl)-4-methoxybenzene

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With N,N,N,N,-tetramethylethylenediamine; cobalt(II) chloride In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Inert atmosphere; chemoselective reaction;
A 6%
B 69%
4-methoxyphenylcyclopropane
4030-17-5

4-methoxyphenylcyclopropane

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With C9H24B11N2(1+)*C24BF20(1-); hydrogen In benzene at 80℃; for 24h; Autoclave;69%
4-methoxyphenyl triflate
66107-29-7

4-methoxyphenyl triflate

isopropyl bromide
75-26-3

isopropyl bromide

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

1-methoxy-4-(1-methylethyl)benzene
4132-48-3

1-methoxy-4-(1-methylethyl)benzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dibutylphosphanyl)-1-phenylpyrrole; magnesium; lithium chloride; zinc(II) chloride In tetrahydrofuran at 60℃; for 16h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube;A 68%
B n/a
4-methoxy-α-ethylbenzyl methyl ether
88932-42-7

4-methoxy-α-ethylbenzyl methyl ether

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With triethylsilane; iron(III) chloride In dichloromethane at 20℃; for 1.5h;66%
With triethylsilane; iron(III) chloride In dichloromethane at 20℃; for 1.5h;66%
Estragole
140-67-0

Estragole

carbon monoxide
201230-82-2

carbon monoxide

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

3-(p-methoxyphenyl)-2-methylpropionaldehyde
5462-06-6

3-(p-methoxyphenyl)-2-methylpropionaldehyde

C

4-(4-methoxyphenyl)butyraldehyde
56047-51-9

4-(4-methoxyphenyl)butyraldehyde

D

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine In water; butan-1-ol at 80℃; under 10350.8 Torr; for 6h; microemulsion/sol-gel; Further byproducts given;A 1.4%
B 27.4%
C 63.8%
D 6.7%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

1-propylmagnesium chloride
2234-82-4

1-propylmagnesium chloride

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With palladium diacetate; zinc dibromide; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 20 - 25℃; for 2.5h; Inert atmosphere;63%
4-n-Propylphenol
645-56-7

4-n-Propylphenol

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With potassium carbonate In 1,2-dimethoxyethane at 145℃; for 0.416667h; Microwave irradiation; Inert atmosphere; Sealed vessel;61%
O-[3-(4-meethoxyphenyl)propyl] O-phenyl thiocarbonate
1242438-12-5

O-[3-(4-meethoxyphenyl)propyl] O-phenyl thiocarbonate

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With di-tert-butyl peroxide; tris-(trimethylsilyl)silane In benzene at 135℃; for 2h; Barton-McCombie deoxygenation; Inert atmosphere;60%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

3-(4-methoxyphenyl)-1-iodopropane
113379-13-8

3-(4-methoxyphenyl)-1-iodopropane

A

Estragole
140-67-0

Estragole

B

4-n-propylanisole
104-45-0

4-n-propylanisole

C

1-(3-cyclopropylpropyl)-4-methoxybenzene

1-(3-cyclopropylpropyl)-4-methoxybenzene

D

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With N,N,N,N,-tetramethylethylenediamine; cobalt(II) aceylacetonate In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Inert atmosphere; chemoselective reaction;
A 15%
B 7%
C 45%
D 10%
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With cobalt(II) chloride In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Inert atmosphere; chemoselective reaction;
A 10%
B 13%
C 16%
D 7%
4-methoxy-trans-cinnamaldehyde
24680-50-0, 71277-11-7, 1963-36-6

4-methoxy-trans-cinnamaldehyde

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

3-(4-methoxyphenyl)propional
20401-88-1

3-(4-methoxyphenyl)propional

C

3-(p-methoxyphenyl)-1-propanol
5406-18-8

3-(p-methoxyphenyl)-1-propanol

Conditions
ConditionsYield
With methanol; formic acid; water; silica gel; palladium dichloride for 0.9h; Irradiation; microwave;A 36%
B 8%
C 44%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

3-(4-methoxyphenyl)-1-iodopropane
113379-13-8

3-(4-methoxyphenyl)-1-iodopropane

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

1-(3-cyclopropylpropyl)-4-methoxybenzene

1-(3-cyclopropylpropyl)-4-methoxybenzene

C

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With (1R,2R)-1,2,3,3-tetramethyl-1,2-cyclohexanediamine; cobalt(II) chloride In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Reagent/catalyst; Inert atmosphere; chemoselective reaction;
A 11%
B 42%
C 28%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

1-methoxy-4-(1-methylethyl)benzene
4132-48-3

1-methoxy-4-(1-methylethyl)benzene

Conditions
ConditionsYield
With N,N,N'N'-tetramethyl-1,3-propanediamine; 1,3-bis(mesityl)imidazolium chloride; cobalt(II) chloride In diethyl ether at 25℃; for 1h; Inert atmosphere;A 34%
B 9%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

3-(4-methoxyphenyl)-1-iodopropane
113379-13-8

3-(4-methoxyphenyl)-1-iodopropane

A

Estragole
140-67-0

Estragole

B

4-n-propylanisole
104-45-0

4-n-propylanisole

C

1-(3-cyclopropylpropyl)-4-methoxybenzene

1-(3-cyclopropylpropyl)-4-methoxybenzene

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With iron(III) chloride; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Inert atmosphere; chemoselective reaction;
A 19%
B 15%
C 32%
carbon monoxide
201230-82-2

carbon monoxide

anethole
104-46-1

anethole

A

4-(4-methoxyphenyl)butan-1-ol
52244-70-9

4-(4-methoxyphenyl)butan-1-ol

B

4-n-propylanisole
104-45-0

4-n-propylanisole

C

2-(4-Methoxy-phenyl)-butan-1-ol
55297-05-7

2-(4-Methoxy-phenyl)-butan-1-ol

Conditions
ConditionsYield
With 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II); dicarbonylacetylacetonatorhodium(I); tris[(R)-2’-(benzyloxy)-1,1’-binaphthyl-2-yl]phosphite; hydrogen In toluene at 120℃; under 30003 Torr; for 20h; Autoclave;A n/a
B 16%
C n/a
Estragole
140-67-0

Estragole

A

cis-Anethole
25679-28-1

cis-Anethole

B

4-n-propylanisole
104-45-0

4-n-propylanisole

C

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With borane-ammonia complex; [Fe(nacnac)dippCH2SiMe3] In benzene-d6 at 60℃; for 16h; Inert atmosphere; Glovebox; Overall yield = 62 percent; Overall yield = 45.9 mg; Optical yield = 80.769 percent de;A n/a
B 15%
C n/a
With carbonylhydrido[6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) In isopropyl alcohol at 20℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique; Sealed tube;
para-iodoanisole
696-62-8

para-iodoanisole

propyl zinc chloride
98398-49-3

propyl zinc chloride

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran; diethyl ether at 20℃; for 3h;A 94 % Spectr.
B 5%
4-n-butylanisole
18272-84-9

4-n-butylanisole

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
at 310 - 320℃; im Rohr;
at 310 - 320℃; im mit Stickstoff gefuellten Rohr;
4-n-propylanisole
104-45-0

4-n-propylanisole

acetyl chloride
75-36-5

acetyl chloride

1-(2-Methoxy-5-propylphenyl)ethanone
873314-99-9

1-(2-Methoxy-5-propylphenyl)ethanone

Conditions
ConditionsYield
Stage #1: 4-n-propylanisole; acetyl chloride With aluminum (III) chloride In dichloromethane at -10℃; for 0.5h;
Stage #2: With hydrogenchloride In dichloromethane; water
100%
Stage #1: 4-n-propylanisole; acetyl chloride With aluminum (III) chloride In dichloromethane at -10℃; for 0.5h; Friedel Crafts Acylation;
Stage #2: With hydrogenchloride; water In dichloromethane at 0℃;
4-n-propylanisole
104-45-0

4-n-propylanisole

4-Methoxystyrene
637-69-4

4-Methoxystyrene

Conditions
ConditionsYield
With [CuCl(ClIPr)]; sodium t-butanolate; tert-butyl alcohol In tetrahydrofuran; hexane at 40℃; for 20h; Inert atmosphere; chemoselective reaction;99%
4-n-propylanisole
104-45-0

4-n-propylanisole

4-Methoxypropiophenone
121-97-1

4-Methoxypropiophenone

Conditions
ConditionsYield
With dipotassium peroxodisulfate; copper(I) sulfate In water; acetonitrile at 65 - 70℃; for 3h;85%
With formic acid; water; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane at 110 - 120℃; for 0.266667h; microwave irradiation;66%
With Bromotrichloromethane; Ir[2-(2,4-difluorophenyl)-5-(trifluoromethyl)pyridine]2(4,4'-di-tert-butyl-2,2'-bipyridine)PF6; water; potassium carbonate In acetonitrile at 20℃; Irradiation; Inert atmosphere; regioselective reaction;60%
4-n-propylanisole
104-45-0

4-n-propylanisole

α-bromoethyl 3-bromo-4-methoxyphenyl ketone
4374-35-0

α-bromoethyl 3-bromo-4-methoxyphenyl ketone

Conditions
ConditionsYield
With N-Bromosuccinimide; water at 35 - 40℃; for 10h; Wohl-Ziegler Bromination; Irradiation;82%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

4-n-propylanisole
104-45-0

4-n-propylanisole

1-(1-(4-methoxyphenyl)propyl)-1H-benzo[d][1,2,3]triazole
156602-61-8

1-(1-(4-methoxyphenyl)propyl)-1H-benzo[d][1,2,3]triazole

Conditions
ConditionsYield
With Bromotrichloromethane; Ir[2-(2,4-difluorophenyl)-5-(trifluoromethyl)pyridine]2(4,4'-di-tert-butyl-2,2'-bipyridine)PF6; potassium carbonate In acetonitrile at 20℃; Irradiation; Inert atmosphere; regioselective reaction;80%
4-n-propylanisole
104-45-0

4-n-propylanisole

acetic acid
64-19-7

acetic acid

1-(4-methoxyphenyl)prop-1-yl acetate
16031-55-3

1-(4-methoxyphenyl)prop-1-yl acetate

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone for 1.16667h; sonication;74%
4-n-propylanisole
104-45-0

4-n-propylanisole

4-methoxy-trans-cinnamaldehyde
24680-50-0, 71277-11-7, 1963-36-6

4-methoxy-trans-cinnamaldehyde

Conditions
ConditionsYield
With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane for 2h;72%
4-n-propylanisole
104-45-0

4-n-propylanisole

4-methoxycinnamaldehyde
1963-36-6

4-methoxycinnamaldehyde

Conditions
ConditionsYield
With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane Microwave irradiation;70%
4-n-propylanisole
104-45-0

4-n-propylanisole

A

4-methoxycinnamaldehyde
1963-36-6

4-methoxycinnamaldehyde

B

4-methoxy-trans-cinnamaldehyde
24680-50-0, 71277-11-7, 1963-36-6

4-methoxy-trans-cinnamaldehyde

Conditions
ConditionsYield
With bunazosin In 1,4-dioxaneA 68%
B n/a
4-n-propylanisole
104-45-0

4-n-propylanisole

A

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

B

4-Methoxypropiophenone
121-97-1

4-Methoxypropiophenone

Conditions
ConditionsYield
With 2-Iodobenzoic acid; potassium peroxomonosulfate; water In acetonitrile for 8h;A 6%
B 64%
4-n-propylanisole
104-45-0

4-n-propylanisole

5-[(oxodiphenyl-λ6-sulfaneylidene)amino]-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate

5-[(oxodiphenyl-λ6-sulfaneylidene)amino]-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate

{[1-(4-methoxyphenyl)propyl]imino}diphenyl-λ6-sulfanone

{[1-(4-methoxyphenyl)propyl]imino}diphenyl-λ6-sulfanone

Conditions
ConditionsYield
With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; sodium hydrogencarbonate In acetonitrile at 20℃; Schlenk technique; Inert atmosphere; Molecular sieve; Irradiation;62%

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