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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

trans-Anethole Manufacturer/High quality/Best price/In stock

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Trans-Anethole supplier in China

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Colorless or light yellow liquid Storage:cool dry place Package:25kg/drum;200kg/drum Application:pharmaceutical i

Manufacturer high quality trans-Anethole Cas 4180-23-8 with good price

Cas:4180-23-8

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

High Quality Trans-Anethole

Cas:4180-23-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Trans-Anethole HACCP manufacturer

Cas:4180-23-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

trans-Anethole

Cas:4180-23-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc.

trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $0.9 / 1.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti

4180-23-8

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 4180-23-8 with best quality

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 4180-23-8

Cas:4180-23-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

trans-Anethole 4180-23-8

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Faithful Pure 99% trans-Anethole / Anethole liquid / Anistearoptene100% safe customs clearance

Cas:4180-23-8

Min.Order:10 Gram

FOB Price: $3.5

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

About us Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad.

Hot selling high quality trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $60.0 / 90.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

trans-Anethole CAS:4180-23-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

trans-Anethole CAS:4180-23-8

Cas:4180-23-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 4180-23-8 trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

trans-Anethole

Cas:4180-23-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:clear colorless to pale yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Applic

Benzene,1-methoxy-4-(1E)-1-propen-1-yl-

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

trans-Anethole

Cas:4180-23-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Miheng Trading Co., Ltd.

trans-Anethole CAS 4180-23-8 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly. 2

trans-Anethole CAS 4180-23-8

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

trans-Anethole

Cas:4180-23-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

trans-Anethole

Cas:4180-23-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shaanxi New nine Material Technology Co., Ltd.

Our Advantage: 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good quali

trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Trading Company

inquiry

Hefei Zhaobo Technology Co., Ltd.

trans-Anethole CAS 4180-23-8 Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality control sy

trans-Anethole CAS 4180-23-8

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Trans-Anethole

Cas:4180-23-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

trans-Anethol/trans-Anethole

Cas:4180-23-8

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

trans-Anethole Chemical Properties Melting point 20-21 °C(lit.) Boiling point 234-237 °C(lit.) density 0.988 g/mL at 25 °C(lit.) vapor pressure 1.33 hPa (63 °C) FEMA 2086 | TRANS-ANETHOLE refractive index n20/D

trans-Anethole

Cas:4180-23-8

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

trans-Anethole

Cas:4180-23-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Synthetic route

Estragole
140-67-0

Estragole

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With Polystyrene-supported 4-tert-butyl-2-(diisopropylphosphino)-1H-imidazole and ruthenium complex In [(2)H6]acetone at 25℃; for 0.166667h; Reagent/catalyst; Inert atmosphere; Glovebox; stereoselective reaction;99%
With PdClMe(2,9-dimethyl-1,10-phenanthroline); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In chloroform-d1 at 0℃; for 16h; Sealed tube;99%
With nickel(II) iodide; 6,6'-dimethyl-2,2'-bipyridine; phosphonic acid diethyl ester; zinc In N,N-dimethyl acetamide at 35℃; for 24h;97%
cis-Anethole
25679-28-1

cis-Anethole

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: cis-Anethole With cobalt(II) chloride; 2,2'-bis(diphenylphosphino)diphenylamine In toluene at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: With sodium triethylborohydride In toluene at 20℃; for 1h; Catalytic behavior; Reagent/catalyst; Schlenk technique; Inert atmosphere; diastereoselective reaction;
99%
With sodium hydrogen sulfate at 100 - 155℃; for 1h; Temperature;95.4%
cadmium(II) sulphide In dichloromethane Product distribution; Irradiation;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

potassium trifluoro(prop-1-en-2-yl)borate

potassium trifluoro(prop-1-en-2-yl)borate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With potassium carbonate; dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) In water; isopropyl alcohol at 120℃; for 0.5h; Inert atmosphere; Microwave irradiation;97%
para-iodoanisole
696-62-8

para-iodoanisole

(E)-phenyl(prop-1-en-1-yl)silane

(E)-phenyl(prop-1-en-1-yl)silane

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: (E)-phenyl(prop-1-en-1-yl)silane With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.05h; Glovebox; Inert atmosphere; Schlenk technique;
Stage #2: para-iodoanisole With tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran for 10h; Hiyama Coupling; Glovebox; Inert atmosphere; Schlenk technique;
97%
ethyltriphenylphosphonium bromide
1530-32-1

ethyltriphenylphosphonium bromide

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: ethyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at -78 - 0℃; Inert atmosphere;
Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran at -78 - 25℃; for 3.83333h; Wittig reaction; Inert atmosphere;
Stage #3: With dichloro bis(acetonitrile) palladium(II) In chloroform at 25℃; for 72h;
94%
1-phenyl-2-(2-pyridyl)-1,2-disodiumethane

1-phenyl-2-(2-pyridyl)-1,2-disodiumethane

1-(1,2-dibromopropyl)-4-methoxybenzene
1201-60-1

1-(1,2-dibromopropyl)-4-methoxybenzene

A

2-(1,2,2-triphenylvinyl)pyridine

2-(1,2,2-triphenylvinyl)pyridine

B

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 0.166667h;A n/a
B 91%
anethole
104-46-1

anethole

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II) In dichloromethane at 20℃; for 14h;90%
1-(1,2-dibromopropyl)-4-methoxybenzene
1201-60-1

1-(1,2-dibromopropyl)-4-methoxybenzene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane In tetrahydrofuran at 0℃; for 10h;90%
methylmagnesium chloride
676-58-4

methylmagnesium chloride

1-(2-fluorovinyl)-4-methoxybenzene
15197-86-1

1-(2-fluorovinyl)-4-methoxybenzene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;89%
1-(4-methoxyphenyl)-1-propanol
5349-60-0

1-(4-methoxyphenyl)-1-propanol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With 1-hexyl-3-methyl-1-imidazolium bromide at 140℃; for 0.116667h; Reactivity; Reagent/catalyst; Time; Microwave irradiation; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction;87%
With silica gel In 1,4-dioxane for 0.05h; microwave irradiation;67%
With trichlorophosphate In pyridine for 2h; Heating;
(E)-p-methoxy-cinnamyl alcohol
53484-50-7

(E)-p-methoxy-cinnamyl alcohol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With bis(tricyclohexylphosphine)nickel(II) dichloride; n-hexylmagnesium chloride; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 100℃; for 12h; Inert atmosphere; Schlenk technique;86%
1-(4-methoxyphenyl)prop-1-yl acetate
16031-55-3

1-(4-methoxyphenyl)prop-1-yl acetate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With 1-hexyl-3-methyl-1-imidazolium bromide at 140℃; for 0.166667h; Microwave irradiation; chemoselective reaction;82%
para-iodoanisole
696-62-8

para-iodoanisole

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With orotic acid; caesium carbonate In acetone at 100℃; for 24h; Suzuki coupling; Inert atmosphere;82%
(1RS,2RS)-1-(4'-methoxyphenyl)-2-(diphenylphosphinoyl)propan-1-ol
88533-70-4, 88533-77-1, 103785-85-9, 103785-86-0

(1RS,2RS)-1-(4'-methoxyphenyl)-2-(diphenylphosphinoyl)propan-1-ol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide81.3%
2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-propan-1-ol
88533-70-4, 88533-77-1, 103785-85-9, 103785-86-0

2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-propan-1-ol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide81%
C17H18O3
1106676-03-2

C17H18O3

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With 1-hexyl-3-methyl-1-imidazolium bromide at 140℃; for 0.166667h; Microwave irradiation; chemoselective reaction;80%
1,1-bis(4-methoxyphenyl)propane
4792-39-6

1,1-bis(4-methoxyphenyl)propane

A

methoxybenzene
100-66-3

methoxybenzene

B

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With silica gel In water at 400℃; Inert atmosphere;A 77.3%
B 45.1%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

propionaldehyde
123-38-6

propionaldehyde

malononitrile
109-77-3

malononitrile

A

3-amino-4'-methoxy-6-methyl-[1,1'-biphenyl]-2,4-dicarbonitrile
1338442-76-4

3-amino-4'-methoxy-6-methyl-[1,1'-biphenyl]-2,4-dicarbonitrile

B

2-amino-4-ethyl-5-methylbenzene-1,3-dicarbonitrile
55525-92-3

2-amino-4-ethyl-5-methylbenzene-1,3-dicarbonitrile

C

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With morpholine In N,N-dimethyl-formamide at 80℃;A 77%
B 8%
C 10%
(1R*,2S*)-2-Diphenylphosphinoyl-1-(4-methoxyphenyl)propan-1-ol
88533-70-4, 88533-77-1, 103785-85-9, 103785-86-0

(1R*,2S*)-2-Diphenylphosphinoyl-1-(4-methoxyphenyl)propan-1-ol

A

cis-Anethole
25679-28-1

cis-Anethole

B

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxideA 75%
B 6%
1-(4-methoxylphenyl)-2-propen-1-ol
51410-44-7

1-(4-methoxylphenyl)-2-propen-1-ol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With bis(tricyclohexylphosphine)nickel(II) dichloride; n-hexylmagnesium chloride; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 100℃; for 12h; Inert atmosphere; Schlenk technique;75%
ethyl phenyl sulfone
599-70-2

ethyl phenyl sulfone

4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With C24H20ClN2OPRu; potassium tert-butylate In 1,4-dioxane at 125℃; for 5h; Inert atmosphere; Schlenk technique; Glovebox;71%
4-Methoxypropiophenone
121-97-1

4-Methoxypropiophenone

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; potassium carbonate; bis(pinacol)diborane; bis[2-(diphenylphosphino)phenyl] ether In hexane at 70℃; for 10h; Glovebox; Sealed tube; Inert atmosphere; stereoselective reaction;68%
Estragole
140-67-0

Estragole

carbon monoxide
201230-82-2

carbon monoxide

A

4-n-propylanisole
104-45-0

4-n-propylanisole

B

3-(p-methoxyphenyl)-2-methylpropionaldehyde
5462-06-6

3-(p-methoxyphenyl)-2-methylpropionaldehyde

C

4-(4-methoxyphenyl)butyraldehyde
56047-51-9

4-(4-methoxyphenyl)butyraldehyde

D

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine In water; butan-1-ol at 80℃; under 10350.8 Torr; for 6h; microemulsion/sol-gel; Further byproducts given;A 1.4%
B 27.4%
C 63.8%
D 6.7%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

(E)-propenyl-tri-n-butylstannane
105494-65-3, 66680-85-1, 66680-84-0

(E)-propenyl-tri-n-butylstannane

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With palladium diacetate; orotic acid; cesium fluoride In 1,4-dioxane at 100℃; for 18h; Stille Cross Coupling; Sealed tube; Inert atmosphere; Schlenk technique;62%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

allyltributylstanane
24850-33-7

allyltributylstanane

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; lithium chloride In diethylene glycol dimethyl ether at 130℃; Stille Cross Coupling; Inert atmosphere; regioselective reaction;62%
trans-1-methoxy-4-(2-methylsulfanylvinyl)benzene
14846-66-3

trans-1-methoxy-4-(2-methylsulfanylvinyl)benzene

methylmagnesium bromide
75-16-1

methylmagnesium bromide

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
bis(triphenylphosphine)nickel(II) chloride In diethyl ether; benzene Heating;60%
2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

acetone
67-64-1

acetone

B

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With iron(III) chloride; silver tetrafluoroborate In dichloromethane at 25℃; for 3h; Inert atmosphere;A n/a
B 60%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

3-(4-methoxyphenyl)-1-iodopropane
113379-13-8

3-(4-methoxyphenyl)-1-iodopropane

A

1-(3-cyclopropylpropyl)-4-methoxybenzene

1-(3-cyclopropylpropyl)-4-methoxybenzene

B

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide With iodine; magnesium In 2-methyltetrahydrofuran for 1.5h; Inert atmosphere; Reflux;
Stage #2: 3-(4-methoxyphenyl)-1-iodopropane With N,N,N,N,-tetramethylethylenediamine; cobalt(II) chloride In tetrahydrofuran; 2-methyltetrahydrofuran at 0℃; for 1h; Catalytic behavior; Temperature; Inert atmosphere; chemoselective reaction;
A 56%
B 17%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

2-Bromo-1-(4-methoxy-phenyl)-propan-1-ol
82947-15-7, 82947-17-9

2-Bromo-1-(4-methoxy-phenyl)-propan-1-ol

Conditions
ConditionsYield
With hypobromous acid In 1,4-dioxane at 20℃; for 0.5h;100%
acetic acid
64-19-7

acetic acid

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

C12H15BrO3

C12H15BrO3

Conditions
ConditionsYield
With N-Bromosuccinimide; benzamidin for 3h;100%
pyridin-2-yl sulfenyl chloride
59089-57-5

pyridin-2-yl sulfenyl chloride

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

trans-3-(4-methoxyphenyl)-2-methyl-2H,3H-thiazolo[3,2-]pyridin-4-ium chloride

trans-3-(4-methoxyphenyl)-2-methyl-2H,3H-thiazolo[3,2-]pyridin-4-ium chloride

Conditions
ConditionsYield
Stage #1: pyridin-2-yl sulfenyl chloride With sulfuryl dichloride In dichloromethane at 20℃; for 0.166667h;
Stage #2: E-1-(4'-methoxyphenyl)prop-1-ene In dichloromethane at 20℃; for 20h; regioselective reaction;
100%
2,2'-dipyridyldiselenide
59957-75-4

2,2'-dipyridyldiselenide

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

trans-3-(4-methoxyphenyl)-2-methyl-2H,3H-selenazolo[3,2-]pyridin-4-ium chloride

trans-3-(4-methoxyphenyl)-2-methyl-2H,3H-selenazolo[3,2-]pyridin-4-ium chloride

Conditions
ConditionsYield
Stage #1: 2,2'-dipyridyldiselenide With sulfuryl dichloride In chloroform at 20℃; for 0.333333h;
Stage #2: E-1-(4'-methoxyphenyl)prop-1-ene In chloroform at 20℃; for 5h; Reflux; regioselective reaction;
100%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

4-n-propylanisole
104-45-0

4-n-propylanisole

Conditions
ConditionsYield
With magnesium; nickel dichloride In water at 20℃; for 12h; Sealed tube; Photolysis; Inert atmosphere;99%
With oxygen; hydrazine hydrate In propan-1-ol at 120℃; under 15001.5 Torr; for 0.5h;91%
With oxygen; hydrazine hydrate In propan-1-ol at 120℃; under 15001.5 Torr; for 0.166667h; Flow reactor;91%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; acrylic acid methyl ester In dichloromethane for 2h; Reflux; Inert atmosphere;99%
With C33H43Cl2N3O3RuS In toluene at 110℃; for 2h; Inert atmosphere;90%
With silica-supported Hoveyda-Grubbs II catalyst In hexane at 70℃; for 14h; Inert atmosphere; Glovebox;74%
(1,3-dimesitylimidazolin-2-ylidene)(C2H4)RuCl2; (p-cymene)RuCl2 In toluene at 85℃; for 2h;90 % Turnov.
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

trans-2-(p-methoxyphenyl)-3-methyloxirane

trans-2-(p-methoxyphenyl)-3-methyloxirane

Conditions
ConditionsYield
With dihydrogen peroxide; Ru(2,2':6',2''-terpyridine)(2,6-pyridinedicarboxylate) In tert-Amyl alcohol at 20℃; for 12h; Conversion of starting material;99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

ethyl benzenesulfenate
54815-45-1

ethyl benzenesulfenate

sodium thiocyanide
540-72-7

sodium thiocyanide

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(1R*,2R*)-1-isothiocyanato-1-(4-methoxyphenyl)-2-phenylthiopropane

(1R*,2R*)-1-isothiocyanato-1-(4-methoxyphenyl)-2-phenylthiopropane

Conditions
ConditionsYield
Stage #1: chloro-trimethyl-silane; sodium thiocyanide In chloroform at 20℃; for 1h;
Stage #2: ethyl benzenesulfenate; E-1-(4'-methoxyphenyl)prop-1-ene In chloroform
99%
styrene
292638-84-7

styrene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

1-methoxy-4-((1S*,2R*,4S*)-2-methyl-4-phenylcyclobutyl)benzene

1-methoxy-4-((1S*,2R*,4S*)-2-methyl-4-phenylcyclobutyl)benzene

Conditions
ConditionsYield
With 9-(2-methylphenyl)-1,3,6,8-tetramethoxythioxanthylium trifluoromethanesulfonate In nitromethane at 20℃; for 2h; Catalytic behavior; Solvent; Reagent/catalyst; Irradiation; regioselective reaction;99%
With iron perchlorate hexahydrate In ethyl acetate at 40℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; diastereoselective reaction;88%
With iron perchlorate hexahydrate In ethyl acetate at 40℃; under 760.051 Torr; for 24h; Solvent; Reagent/catalyst;88%
With Fe(3,4,7,8-tetramethyl-1,10-phenanthroline)3(PF6)3 In 2,2,2-trifluoroethanol; 1,2-dichloro-ethane at 20℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent;86%
t-butyl 2-diazobut-3-enoate
132524-91-5

t-butyl 2-diazobut-3-enoate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

tert-butyl 5-(4-methoxyphenyl)-4-methylcyclopent-1-enecarboxylate

tert-butyl 5-(4-methoxyphenyl)-4-methylcyclopent-1-enecarboxylate

Conditions
ConditionsYield
With tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In nitromethane; dichloromethane at 35℃; for 1h; Reagent/catalyst; Irradiation; diastereoselective reaction;99%
2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Conditions
ConditionsYield
With cross-linked copolymer based on polymethyl methacrylate and 4,7-diphenylbenzothiadiazole; air In nitromethane at 20℃; for 8h; Diels-Alder Cycloaddition; UV-irradiation;99%
With 9-fluorenone In nitromethane at 20℃; for 6h; Catalytic behavior; Mechanism; Reagent/catalyst; Concentration; Solvent; Diels-Alder Cycloaddition; Irradiation;74%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

isoprene
78-79-5

isoprene

(1S,2S)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

(1S,2S)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Conditions
ConditionsYield
With cross-linked copolymer based on polymethyl methacrylate and 4,7-diphenylbenzothiadiazole; air In nitromethane at 20℃; for 4h; Solvent; Reagent/catalyst; Diels-Alder Cycloaddition; UV-irradiation;99%
With 9-fluorenone In nitromethane at 20℃; for 23h; Diels-Alder Cycloaddition; Irradiation;88%
2,4-Dimethyl-1,3-pentadiene
1000-86-8

2,4-Dimethyl-1,3-pentadiene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

C17H24O

C17H24O

Conditions
ConditionsYield
With cross-linked copolymer based on polymethyl methacrylate and 4,7-diphenylbenzothiadiazole; air In nitromethane at 20℃; for 48h; Diels-Alder Cycloaddition; UV-irradiation;99%
2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl
112150-19-3

(±)-(1S,2S)-4'-methoxy-2,4,5-trimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Conditions
ConditionsYield
With tris(2,2’--bipyrazyl)ruthenium(II) bis(tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) In dichloromethane at 20℃; for 1h; Diels-Alder Cycloaddition; Irradiation; regioselective reaction;98%
With iron perchlorate hexahydrate In acetonitrile at 20℃; for 24h; Diels-Alder Cycloaddition; regioselective reaction;98%
With iron(III) chloride In acetonitrile at 20℃; for 1h; Time; Reagent/catalyst; Solvent;98%
4-methoxynaphth-1-ol
84-85-5

4-methoxynaphth-1-ol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(+/-)-trans-2-(4-methoxyphenyl)-2,3-dihydro-5-methoxy-3-methylnaphtho<1,2-b>furan
139016-16-3

(+/-)-trans-2-(4-methoxyphenyl)-2,3-dihydro-5-methoxy-3-methylnaphtho<1,2-b>furan

Conditions
ConditionsYield
With ammonium peroxydisulfate In nitromethane for 12h; Irradiation; Inert atmosphere;98%
With tetrabutylammonium tetrafluoroborate In acetonitrile Electrolysis;96%
With tetrabutylammonium tetrafluoroborate In acetonitrile Electrolysis;96%
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile for 12h; Irradiation; Schlenk technique;92%
With lithium perchlorate; acetic acid In acetonitrile for 3h; Ambient temperature; electrolysis, platinum electrodes;64%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

isoprene
78-79-5

isoprene

(1SR,2SR)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl
112150-17-1

(1SR,2SR)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Conditions
ConditionsYield
With tris(2,2’--bipyrazyl)ruthenium(II) bis(tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) In dichloromethane at 20℃; for 1h; Diels-Alder Cycloaddition; Irradiation; regioselective reaction;98%
With lithium perchlorate In nitromethane at 20℃; Concentration; Diels-Alder Cycloaddition; Electrolysis;98%
With iron perchlorate hexahydrate In acetonitrile at 20℃; for 24h; Reagent/catalyst; Diels-Alder Cycloaddition; regioselective reaction;98%
2-carbonyl-3-butenenitrile
60556-87-8

2-carbonyl-3-butenenitrile

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

trans-3,4-dihydro-2-(4-methoxyphenyl)-3-methyl-2H-pyran-6-carbonitrile

trans-3,4-dihydro-2-(4-methoxyphenyl)-3-methyl-2H-pyran-6-carbonitrile

Conditions
ConditionsYield
In acetonitrile at 20℃; for 168h; hetero-Diels-Alder cycloaddition;98%
benzaldehyde
100-52-7

benzaldehyde

4-nitro-aniline
100-01-6

4-nitro-aniline

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

cis-4-(4-methoxyphenyl)-3-methyl-6-nitro-2-phenyl-1,2,3,4-tetrahydroquinoline

cis-4-(4-methoxyphenyl)-3-methyl-6-nitro-2-phenyl-1,2,3,4-tetrahydroquinoline

Conditions
ConditionsYield
Stage #1: benzaldehyde; 4-nitro-aniline In acetonitrile at 20℃; for 1h; Povarov reaction;
Stage #2: E-1-(4'-methoxyphenyl)prop-1-ene With copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 24h; Povarov reaction; diastereoselective reaction;
98%
With boron trifluoride diethyl etherate In acetonitrile at 70℃; for 10h; imino Diels-Alder reaction;95%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

bromocatecholborane
51901-85-0

bromocatecholborane

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(Z)-2-(1-(4-methoxyphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1217435-96-5

(Z)-2-(1-(4-methoxyphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
Stage #1: bromocatecholborane With N-Methyldicyclohexylamine; [(bis(3,5-di-tert-butylphenyl)(tert-butyl)phosphine)PdI2]2 In toluene at 70℃; for 0.0833333h; Heck Reaction; Schlenk technique; Inert atmosphere; Sealed tube;
Stage #2: E-1-(4'-methoxyphenyl)prop-1-ene In toluene at 70℃; for 4h; Heck Reaction; Schlenk technique; Sealed tube; Inert atmosphere;
Stage #3: 2,3-dimethyl-2,3-butane diol In toluene at 20℃; for 0.5h; stereoselective reaction;
98%
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(±)-(5R,6S)-5-(4-methoxyphenyl)-6-methylbicyclo[2.2.1]hept-2-ene

(±)-(5R,6S)-5-(4-methoxyphenyl)-6-methylbicyclo[2.2.1]hept-2-ene

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 20℃; for 2h;98%
para-fluorostyrene
405-99-2

para-fluorostyrene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

1-fluoro-4-((1S*,2S*,3R*)-2-(4-methoxyphenyl)-3-methylcyclobutyl)benzene

1-fluoro-4-((1S*,2S*,3R*)-2-(4-methoxyphenyl)-3-methylcyclobutyl)benzene

Conditions
ConditionsYield
With 9-(2-methylphenyl)-1,3,6,8-tetramethoxythioxanthylium trifluoromethanesulfonate In nitromethane at 20℃; for 2h; Irradiation; regioselective reaction;98%
xanth-9-one
90-47-1

xanth-9-one

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(E)-9-(3-(4-methoxyphenyl)allylidene)-9H-xanthene

(E)-9-(3-(4-methoxyphenyl)allylidene)-9H-xanthene

Conditions
ConditionsYield
With tris(trimethylsilyl)amine; tetramethylammonium fluoride at 60℃; for 5h; Inert atmosphere; Sealed tube; Glovebox;98%
4-methoxy-phenol
150-76-5

4-methoxy-phenol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(+/-)-trans-2-(4-methoxyphenyl)-2,3-dihydro-5-methoxy-3-methylbenzofuran
139016-13-0

(+/-)-trans-2-(4-methoxyphenyl)-2,3-dihydro-5-methoxy-3-methylbenzofuran

Conditions
ConditionsYield
With ammonium peroxydisulfate In nitromethane for 22h; Catalytic behavior; Solvent; Reagent/catalyst; Irradiation; Inert atmosphere;97%
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile for 27h; Irradiation; Schlenk technique;88%
With lithium perchlorate; acetic acid In acetonitrile for 2h; Ambient temperature; electrolysis, platinum electrodes;80%
formaldehyd
50-00-0

formaldehyd

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

4-p-methoxyphenyl-5-methyl-1,3-dioxane
5689-72-5

4-p-methoxyphenyl-5-methyl-1,3-dioxane

Conditions
ConditionsYield
resine C35O; hydrogen cation In benzene at 60℃; for 12h;97%
5-(benzyloxy)-[1,1'-biphenyl]-2-ol
1416734-90-1

5-(benzyloxy)-[1,1'-biphenyl]-2-ol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

C29H26O3

C29H26O3

Conditions
ConditionsYield
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile for 30h; Irradiation; Schlenk technique;97%
4-(benzyloxy)-2-(tert-butyl)phenol
3421-95-2

4-(benzyloxy)-2-(tert-butyl)phenol

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

C27H30O3

C27H30O3

Conditions
ConditionsYield
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile for 30h; Irradiation; Schlenk technique;97%
7-methyl-3-methene-1,6-octadiene
123-35-3

7-methyl-3-methene-1,6-octadiene

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

(±)-(1S,2S)-4'-methoxy-2-methyl-4-(4-methylpent-3-en-1-yl)-1,2,3,6-tetrahydro-1,1'-biphenyl

(±)-(1S,2S)-4'-methoxy-2-methyl-4-(4-methylpent-3-en-1-yl)-1,2,3,6-tetrahydro-1,1'-biphenyl

Conditions
ConditionsYield
With iron perchlorate hexahydrate In acetonitrile at 20℃; for 24h; Diels-Alder Cycloaddition; regioselective reaction;97%
With C26H18N10Ru(2+)*2C32H12BF24(1-) In dichloromethane for 1.5h; Diels-Alder Cycloaddition; Irradiation;88%
With 9-(2-trifluoromethylphenyl)-1,3,6,8-tetramethoxythioxanthylium trifluoromethanesulfonate In nitromethane at 20℃; for 1h; Diels-Alder Cycloaddition; UV-irradiation;84%
With iron(III) chloride In dichloromethane; acetonitrile at 0℃; for 3h;76%
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