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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Ethyl 4-methoxycinnamate Manufacturer/High quality/Best price/In stock

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Ethyl 4-Methoxycinnamate supplier in China

Cas:24393-56-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Ethyl 4-methoxycinnamate HACCP manufacturer

Cas:24393-56-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Isooctyl-p-methoxycinnamate

Cas:24393-56-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Ethyl 4-methoxycinnamate Synonyms: 4-METHOXYCINNAMIC ACID ETHYL ESTER;3-(4-METHOXYPHENYL)ACRYLIC ACID ETHYL ESTER;ETHYL P-METHOXYCINNAMATE;ETHYL 3-(4-METHOXYPHENYL)ACRYLATE;ETHYL 4-METHOXYCINNAMATE;RARECHEM AL BI 0241;Methoxyci

24393-56-4 Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

Ethyl 4-methoxycinnamate CAS 24393-56-4

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 24393-56-4 with best price

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethyl 4-methoxycinnamate 24393-56-4

Cas:24393-56-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Ethyl 4-methoxycinnamate,99%

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

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Leader Biochemical Group

PRODUCT DETAILS Ethyl 4-methoxycinnamate Basic information Product Name: Ethyl 4-methoxycinnamate Synonyms: 4-METHOXYCINNAMIC ACID ETHYL ESTER;3-(4-ME

The world Biggest Manufacturer factory sales Ethyl 4-methoxycinnamate CAS 24393-56-4

Cas:24393-56-4

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Ethyl 4-Methoxycinnamate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hefei Zhaobo Technology Co., Ltd.

Our Advantages Production: Advanced chemical equipment with years of experience Staffs for producing various extract products. Quality Control:A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Specif

Ethyl 4-methoxycinnamate CAS 24393-56-4

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $75.0 / 150.0

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methoxycinnamicacidethylester;98%

Cas:24393-56-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hubei CuiRan Biotechnology Co., Ltd

Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Ethyl 3-(4-methoxyphenyl)acrylate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

shanghai Tauto Biotech Co., Ltd

The quality is guaranteed. If you find the product is wrong compared with COA, we promise 100% refund or change product. COA and HPLC will be shipped out with goods. You can also inform your analysis method and we will follow your analysis me

Ethylp-methoxycinnamate

Cas:24393-56-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-methoxycinnamic acid ethyl ester

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

(E)-Ethyl 3-(4-Methoxyphenyl)acrylate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Ethyl 4-methoxycinnamate

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Sinoway Industrial Co., Ltd.

Why is SINOWAY:1) Specialized in pharmaceutical and healthcare industrial since 19872) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days.4) We have warehouse in USA with quickly shipment . Application:Herbal extr

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Ethyl 4-methoxycinnamate E84541 20mg

Cas:24393-56-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

PARAMETHOXYETHYLCINNAMATE

Cas:24393-56-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
In dichloromethane at 22℃; for 16h; Wittig reaction;100%
In dichloromethane at 20 - 25℃; Inert atmosphere;96%
In dichloromethane at 20℃; for 16h; Inert atmosphere;77%
ethyl potassium malonate
6148-64-7

ethyl potassium malonate

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With acetic acid; piperidine; dmap In N,N-dimethyl-formamide at 10 - 20℃; for 24h; Product distribution / selectivity;100%
With piperidine; dmap; acetic acid In N,N-dimethyl-formamide at 20℃; for 72h;98%
With piperidine; dmap; acetic acid In N,N-dimethyl-formamide at 10 - 25℃; Knoevenagel reaction;97%
With hydrogenchloride; piperidine; dmap In diethyl ether; N,N-dimethyl-formamide at 10 - 20℃; for 24h; Product distribution / selectivity;96%
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
65946-56-7

1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h;100%
With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; Peterson Olefination; stereoselective reaction;82%
ethanol
64-17-5

ethanol

(E)-3-(4-methoxyphenyl)acrylic acid
943-89-5

(E)-3-(4-methoxyphenyl)acrylic acid

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With sulfuric acid for 16h; Heating;99%
With sulfuric acid for 12h; Reflux; Inert atmosphere;99%
With sulfuric acid at 90℃; for 16h;96%
diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene at 25℃; for 24h; Horner-Wadsworth-Emmons reaction; Inert atmosphere; neat (no solvent); optical yield given as %de; stereoselective reaction;99%
With tetrabutyl ammonium fluoride In tetrahydrofuran at 30℃; for 4h; Glovebox;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃; for 2h; Horner-Wadsworth-Emmons olefination; Inert atmosphere; Neat (no solvent); stereoselective reaction;95%
para-iodoanisole
696-62-8

para-iodoanisole

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate at 130℃; for 16h; Heck olefination;99%
With potassium carbonate; Pd on 3-[(2-aminoethyl)amino]propyl-functionalized silica In N,N-dimethyl acetamide at 130℃; for 12h; Heck reaction;99%
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; palladium diacetate; triethylamine In N,N-dimethyl-formamide at 20℃; for 24h; Heck Reaction; Schlenk technique; Inert atmosphere; Cooling with liquid nitrogen; Irradiation;99%
hydrogen ethyl malonate
1071-46-1

hydrogen ethyl malonate

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With dmap In N,N-dimethyl-formamide at 25℃; Doebner-Knoevenagel reaction;99%
With dmap In N,N-dimethyl-formamide at 25℃; Knoevenagel reaction;99%
piperidine; dmap In N,N-dimethyl-formamide at 10 - 20℃; for 24h; Product distribution / selectivity;99%
With poly{styrene-co-[4-(N-methyl-N-vinylbenzyl-amino)pyridine]-co-[1-phenyl-3-(4-vinylbenzyl)piperazine]} In N,N-dimethyl-formamide at 50℃; decarboxylative Doebner-Knoevenagel condensation reaction; optical yield given as %de;97%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl bromoacetate
105-36-2

ethyl bromoacetate

A

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

B

(Z)-ethyl 3-(4-methoxyphenyl)acrylate
51507-22-3

(Z)-ethyl 3-(4-methoxyphenyl)acrylate

Conditions
ConditionsYield
With potassium carbonate In ethanol Wittig Olefination; Milling; diastereoselective reaction;A 98%
B n/a
With tributylphosphine; tetrakis(triphenylphosphine) palladium(0) at 110℃; for 24h; Yield given. Yields of byproduct given;
With sodium hydrogencarbonate; triphenylphosphine at 20℃; for 2h; Wittig reaction; Title compound not separated from byproducts.;
(carbethoxymethyl)triphenylphosphonium bromide
1530-45-6

(carbethoxymethyl)triphenylphosphonium bromide

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane; water at 25℃; Wittig reaction; Sonication; stereoselective reaction;98%
With triethylamine In dichloromethane at 20℃; for 16h; Inert atmosphere; Schlenk technique;
2Br(1-)*C26H32NO2P(2+)

2Br(1-)*C26H32NO2P(2+)

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 40℃; for 50h; Wittig reaction; Inert atmosphere; optical yield given as %de; diastereoselective reaction;98%
diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With Fe(TCP)Cl; polyethylene supported arsine; polymethylhydrosiloxane In toluene at 110℃; for 12h; Wittig type reaction; Inert atmosphere; optical yield given as %de; stereoselective reaction;97%
tris(triphenylphosphine)ruthenium(II) chloride In 1,2-dichloro-ethane at 50℃; for 12h;92%
With sodium disulfite; triphenyl-arsane; chloro[tetra(p-chlorophenyl)porphyrinato]iron(III) In water; toluene at 80℃; for 8h;81%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With PEG-OCOCH2CH2CO2CH2CH2-supported 3-methyl-imidazolium*Cl; potassium carbonate; palladium diacetate at 140℃; for 10h; Heck reaction;96%
With potassium phosphate; tetrabutylammomium bromide; [PdCl{[η5-C5H5)]Fe[(η5-C5H3)C(CH3)=NC12H25]}]2 In N,N-dimethyl-formamide at 140℃; for 12h; Heck coupling;95%
With C37H38BrClFeN3Pd; potassium acetate In N,N-dimethyl acetamide at 150℃; for 12h; Heck reaction; Inert atmosphere; regioselective reaction;93%
5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione
15795-54-7

5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

ethanol
64-17-5

ethanol

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
Stage #1: 5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione; ethanol With iron(III) chloride hexahydrate In nitromethane for 0.25h; Microwave irradiation;
Stage #2: With piperidine In nitromethane for 0.25h; Microwave irradiation; stereoselective reaction;
96%
diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

B

(Z)-ethyl 3-(4-methoxyphenyl)acrylate
51507-22-3

(Z)-ethyl 3-(4-methoxyphenyl)acrylate

Conditions
ConditionsYield
With triphenylphosphine In toluene at 80℃; for 6h; Inert atmosphere; optical yield given as %de; stereoselective reaction;A 95%
B n/a
With 5,10,15,20-tetraphenyl porphyrinato iron hydroxide; lithium bromide; phosphorous acid trimethyl ester In 1,4-dioxane at 85℃; for 18h; Wittig olefination;A 58%
B 1%
With triphenylphosphine; MoO2(S2CNEt2)2 In benzene at 80℃; for 5h; Yield given. Yields of byproduct given;
4-methoxybenzenediazonium tetrafluoroborate
459-64-3

4-methoxybenzenediazonium tetrafluoroborate

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With palladium diacetate In water at 20℃; for 16h; Heck Reaction;95%
With 3-benzyl-1-(2-hydroxy-2-phenylethyl)imidazolium chloride; palladium diacetate In ethanol at 36℃; for 3h; Heck-Matsuda reaction;92%
[(1,3-dimesitylimidazol-2-ylidene)(naphthoquinone)Pd(0)]2 In methanol at 50℃; for 1h; Heck reaction;91%
(IMes)Pd(NQ) In ethanol at 50℃; for 1h; Conversion of starting material; Heck Reaction;90%
With palladium(II) carboxymethylcellulose In water at 20℃; for 8h;81%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl bromoacetate
105-36-2

ethyl bromoacetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
Stage #1: ethyl bromoacetate With triphenyl phosphite; PEG-Te-Bu In toluene at 80℃; for 0.166667h;
Stage #2: With potassium carbonate In toluene for 0.0166667h;
Stage #3: 4-methoxy-benzaldehyde In toluene for 43h; Wittig-type olefination; Further stages.;
94%
With triphenyl phosphite; poly(ethylene glycol) di(2-(n-butyltelluro)ethyl) ether; potassium carbonate In toluene at 80℃;94%
With triphenyl phosphite; potassium carbonate; (BrBu2Te)2O In toluene at 80℃; for 72h; Wittig-type olefination;94%
ketene diethyl acetal
2678-54-8

ketene diethyl acetal

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With (2,4,5-trifluorophenyl)boronic acid In tert-butyl methyl ether at 50℃; for 14h;94%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl 1,1-dichloroacetate
535-15-9

ethyl 1,1-dichloroacetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With manganese In tetrahydrofuran for 3h; Heating;92%
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction;92%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 8h; Heck Reaction;91%
With C34H29BrCl2OP2Pd; potassium carbonate In water; N,N-dimethyl-formamide at 110℃; for 6h;66%
With C37H30Cl2OP2Pd; caesium carbonate In N,N-dimethyl acetamide; water at 110℃; for 4.5h; Heck Reaction; Green chemistry;61%
ethyl acrylate
140-88-5

ethyl acrylate

4-methoxybenzenediazonium o-benzenedisulfonimide

4-methoxybenzenediazonium o-benzenedisulfonimide

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With (triphenylphosphine)gold(I) chloride; calcium carbonate In acetonitrile at 35℃; for 5h; Inert atmosphere;91%
palladium diacetate In ethanol at 70℃; for 0.666667h; Heck arylation;84%
2Br(1-)*C28H34NO2P(2+)

2Br(1-)*C28H34NO2P(2+)

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 40℃; for 24h; Wittig reaction; Inert atmosphere; optical yield given as %de; diastereoselective reaction;91%
ethanol
64-17-5

ethanol

2-bromo-3-(4-methoxyphenyl)prop-2-enal
13532-16-6

2-bromo-3-(4-methoxyphenyl)prop-2-enal

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,3-bis(mesityl)imidazolium chloride In tetrahydrofuran at 20℃; Inert atmosphere; optical yield given as %de; stereoselective reaction;91%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl 4,4,4-trifluoroacetoacetate
372-31-6

ethyl 4,4,4-trifluoroacetoacetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With piperidine; aluminum oxide for 0.266667h; Microwave irradiation;89%
With piperidine In dichloromethane at 20℃; for 7h; stereoselective reaction;84%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

ethyl acetate
141-78-6

ethyl acetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With sodium hydride at 10 - 20℃; for 0.583333h;87%
With trimethylsilyl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine Mukaiyama Aldol Addition; Inert atmosphere;70%
With P(i-PrNCH2CH2)3N at 50℃; for 6h;60%
With sodium
With sodium
diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

A

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

B

(Z)-ethyl 3-(4-methoxyphenyl)acrylate
51507-22-3

(Z)-ethyl 3-(4-methoxyphenyl)acrylate

Conditions
ConditionsYield
Stage #1: 4-Methoxybenzyl alcohol With 1,10-Phenanthroline; potassium tert-butylate; copper(l) chloride In fluorobenzene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With 1-methyl-1H-imidazole; di-tert-butyl-diazodicarboxylate; oxygen In fluorobenzene Reflux;
Stage #3: diazoacetic acid ethyl ester With triphenylphosphine In fluorobenzene Inert atmosphere; optical yield given as %de; stereoselective reaction;
A 87%
B n/a
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With C48H40N4O4Pd2(4+); acetic acid; p-benzoquinone In water at 20℃; for 12h; Heck Reaction; Inert atmosphere;87%
With pyrrolidine; 5%-palladium/activated carbon; tetrabutylammomium bromide; oxygen In 1-methyl-pyrrolidin-2-one at 80℃; under 2587.76 Torr; for 12h; Heck Reaction;85%
With [2,2]bipyridinyl; oxygen; palladium diacetate In N,N-dimethyl-formamide at 20℃; Heck reaction;65 %Spectr.
diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

B

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

Conditions
ConditionsYield
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester; 4-methoxy-benzaldehyde With potassium carbonate for 6h; Horner-Wadsworth-Emmons olefination; Neat (no solvent); high-speed ball milling;
Stage #2: With Oxone for 12h; Neat (no solvent); high-speed ball milling; optical yield given as %de; diastereoselective reaction;
A 87%
B n/a
4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With C34H37N4O6Ru2(1+)*Cl(1-); potassium hydroxide In toluene at 70℃; for 6h; Wittig Olefination; Schlenk technique; Inert atmosphere;86%
With oxygen; caesium carbonate In toluene at 50℃; under 760.051 Torr; for 24h; Green chemistry;85%
With dipyridinium dichromate In dichloromethane at 20℃; for 24h; Wittig Olefination;81%
With hollandite In toluene at 110℃; for 4h; Catalytic behavior; Wittig Olefination; diastereoselective reaction;80%
With aluminum (III) chloride; Oxone In water at 20℃; for 3h; Wittig reaction; stereoselective reaction;55%
n-propyl acrylate
925-60-0

n-propyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 75℃; for 7h; Heck Reaction; Green chemistry;86%
E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst first generation In 1,2-dichloro-ethane at 70℃; Cross Metathesis; Schlenk technique; Inert atmosphere; Glovebox;85%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

ethyl trans-3-(4-methoxyphenyl)oxirane-2-carboxylate

ethyl trans-3-(4-methoxyphenyl)oxirane-2-carboxylate

Conditions
ConditionsYield
With Oxone; potassium carbonate; acetic acid; rac-2-F-2,5-(Me)2-5-(2-fluoroisopropyl)-cyclohexanone In 1,4-dioxane; water at 20℃; for 6h; pH=8.5 - 9;100%
With Oxone; sodium hydrogencarbonate In water; acetone at 20℃; for 24h;
With Oxone; sodium hydrogencarbonate In water; acetone; acetonitrile at 0℃; for 5h;
3,4-Dimethylphenol
95-65-8

3,4-Dimethylphenol

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

6,7-dimethyl-4-(4'-methoxyphenyl)-3,4-dihydrocoumarin
85903-43-1

6,7-dimethyl-4-(4'-methoxyphenyl)-3,4-dihydrocoumarin

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;100%
Sesamol
533-31-3

Sesamol

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

8-(4-methoxyphenyl)-7,8-dihydro-6H-[1,3]dioxolo[4,5-g]-chromen-6-one
267901-33-7

8-(4-methoxyphenyl)-7,8-dihydro-6H-[1,3]dioxolo[4,5-g]-chromen-6-one

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;100%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

β-naphthol
135-19-3

β-naphthol

1,2-dihydro-1-(4-methoxyphenyl)-3H-naphtho[2,1-b]pyran-3-one

1,2-dihydro-1-(4-methoxyphenyl)-3H-naphtho[2,1-b]pyran-3-one

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;100%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

ethyl 3-(4-methoxyphenyl)propanoate
22767-72-2

ethyl 3-(4-methoxyphenyl)propanoate

Conditions
ConditionsYield
With 0.42C23H20N4O4*2Cl(1-)*Zn(2+)*10.16H2O*0.58Pd(2+)*0.58C23H20N4O4(1-); hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 1h;99%
With hydrogen; platinum(IV) oxide In various solvent(s) at 25℃; for 2h;93%
With ethanol; nickel at 80 - 90℃; under 73550.8 Torr; Hydrogenation;
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

2,3-dibromo-3-(4-methoxyphenyl)propionic acid ethyl ester
157019-58-4

2,3-dibromo-3-(4-methoxyphenyl)propionic acid ethyl ester

Conditions
ConditionsYield
With bromine99%
With bromine In tetrachloromethane Heating;
With bromine In dichloromethane at 0℃;
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

(E)-p-methoxy-cinnamyl alcohol
53484-50-7

(E)-p-methoxy-cinnamyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 1h;98%
With diisobutylaluminium hydride In dichloromethane; toluene at -78℃; for 1.5h;94%
With diisobutylaluminium hydride In dichloromethane at -78 - 20℃; for 2h; Inert atmosphere;90%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

5,7-dimethyl-4-(4-methoxyphenyl)-3,4-dihydrobenzopyran-2-one
85903-47-5

5,7-dimethyl-4-(4-methoxyphenyl)-3,4-dihydrobenzopyran-2-one

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;98%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

ethyl 3-(4-methoxyphenyl)-3-(4,4,5,5,-tetramethyl-[1,3,2]dioxaborolan-2-yl)-propionate

ethyl 3-(4-methoxyphenyl)-3-(4,4,5,5,-tetramethyl-[1,3,2]dioxaborolan-2-yl)-propionate

Conditions
ConditionsYield
With methanol; sodium t-butanolate; bis[2-(diphenylphosphino)phenyl] ether; copper(l) chloride In tetrahydrofuran at 20℃; for 3h;98%
With NaOt-Bu; (+)-[Rh((S,S)-Phebox-i-Pr)OAc2(H2O)] In toluene under Ar; mixt. of MeOC6H4CHCHC(O)OEt (0.5 mmol), B2pin2 (0.6 mmol), NaOt-Bu (0.025-0.029 mmol) and Rh complex catalyst (1 mol%) stirred at 80°C for 0.5 h; chromd. (SiO2 column, hexane/ehtyl acetate eluent); 83% ee;91%
With NaOt-Bu; [rhodium(III)(bis(COCH2CH(s-Bu)N)phenyl)(OAc)2(H2O)] In toluene under Ar; mixt. of MeOC6H4CHCHC(O)OEt (0.5 mmol), B2pin2 (0.6 mmol), NaOt-Bu (0.025-0.029 mmol) and Rh complex catalyst (1 mol%) stirred at 80°C for 0.5 h; chromd. (SiO2 column, hexane/ehtyl acetate eluent); 94% ee;90%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

(E)-3-(4-methoxyphenyl)acrylic acid
943-89-5

(E)-3-(4-methoxyphenyl)acrylic acid

Conditions
ConditionsYield
With lithium hydroxide In tetrahydrofuran; water at 25℃; for 24h;97%
With sodium hydroxide In ethanol; water at 20℃; for 16h;80%
With lithium hydroxide monohydrate In methanol for 2h; Reflux;72%
ethylenebis(triphenylphosphine)platinum(0)
12120-15-9

ethylenebis(triphenylphosphine)platinum(0)

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

bis(triphenylphosphine)-(η2-ethyl 4-methoxycinnamate)platinum(0)

bis(triphenylphosphine)-(η2-ethyl 4-methoxycinnamate)platinum(0)

Conditions
ConditionsYield
In benzene for 1h; Inert atmosphere;97%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

isoprene
78-79-5

isoprene

(±)-ethyl (1S,2S)-4'-methoxy-4-methyl-1,2,3,6-tetrahydro-[1,1'-biphenyl]-2-carboxylate

(±)-ethyl (1S,2S)-4'-methoxy-4-methyl-1,2,3,6-tetrahydro-[1,1'-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With iron(III) chloride In acetonitrile at 0℃; for 24h; regioselective reaction;96%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

ethyl 2,3-dihydroxy-3-(4-methoxyphenyl)propionate
253350-07-1

ethyl 2,3-dihydroxy-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In various solvent(s) at 25℃; for 2h;95%
With chiral 3,6-bis(9-O-dihydroquinyl)pyridazine(thioethanol) immobilized on chloropropyl-silica gel; potassium carbonate; potassium hexacyanoferrate(III) In water; tert-butyl alcohol at 20℃; for 36h;69%
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

ethyl (2S,3R)-2,3-dihydroxy-3-(4-methoxyphenyl)propanoate
159848-77-8

ethyl (2S,3R)-2,3-dihydroxy-3-(4-methoxyphenyl)propanoate

Conditions
ConditionsYield
With osmium(VIII) oxide; 1,4-bis(9-O-dihydroquinidine)phthalazine In water; tert-butyl alcohol at 0℃; for 16h;94%
With (3a,9R,3'''a,4'"b,9'"R)-9,9'-[1,4-phthalazinediylbis(oxy)]bis[6'-(methyloxy)-10,11-dihydrocinchonan]; 4-methylmorpholine N-oxide; polyaniline-supported Os In water; acetone; acetonitrile at 20℃; for 12h; Sharpless asymmetric dihydroxylation;93%
With (3a,9R,3'''a,4'"b,9'"R)-9,9'-[1,4-phthalazinediylbis(oxy)]bis[6'-(methyloxy)-10,11-dihydrocinchonan]; 4-methylmorpholine N-oxide; Mg(1-x)Al(x)(OH)2(Cl)2*zH2O-OsO4 In water; tert-butyl alcohol at 20℃; for 12h;93%

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