DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:535-15-9
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryNow we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti
[Product name]: Ethyl dichloroacetate [Molecular formula]: C4H6Cl2O2 [Molecular weight]: 157 [CAS number]: 535-15-9 [RTECS number]: AG6125000 [UN Code]: 2810 [Appearance and properties]: colorless liquid, with pungent odor. [Main Uses]
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:535-15-9
Min.Order:0 Metric Ton
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Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Cas:535-15-9
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryHunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:535-15-9
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical
1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:535-15-9
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiry(1)High quality from own laboratory (2)Competitive price in China market. (3)mature Technical support (4)Fast delivery and shipping.(5)We can help our regular clients to suggest some vials factories which produce different size vials(2ml, 5ml, 7
Cas:535-15-9
Min.Order:100 Gram
FOB Price: $700.0 / 800.0
Type:Trading Company
inquiry1.Introduction of 535-15-9 Acetic acid,2,2-dichloro-, ethyl ester has the CAS registry number of 535-15-9. It is a kind of colorless liquid, Storage:Store in a cool, dry place. Store in a tightly closed container Packa
Cas:535-15-9
Min.Order:10 Gram
Negotiable
Type:Lab/Research institutions
inquiryWe did before and have a mature technology.If you need NMR/HPLC,please contact with us Package:As your requrement Application:Intermediate Transportation:By Express
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High Purity, Supplement, Prompt shipment Application:intermediate of liquid crystal
Acetic acid,2,2-dichloro-, ethyl ester Application:99
Cas:535-15-9
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryEthyl dichloroacetate is an ester and its base catalyzed hydrolysis has been reported. Package:100 mL in glass bottle Application:Ethyl dichloroacetate may be used in the synthesis of -halo-carboxylic acid ester.
Conditions | Yield |
---|---|
at 0℃; | 96% |
1,1,1-triethoxy-2,2-dichloroethane
A
ethanol
B
ethyl acetate
C
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With acetic acid Heating; | A n/a B n/a C 95% |
ethanol
pentachloroacetone
A
chloroform
B
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With pyridine for 2h; Heating; | A 9.2 g B 82.2% |
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 1h; chemoselective reaction; | 79% |
With 10% Pt/activated carbon; hydrogen In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 1h; chemoselective reaction; | 79% |
With N-ethyl-N,N-diisopropylamine In acetonitrile at 28℃; for 72h; Irradiation; Inert atmosphere; | 70% |
ethanol
pentachloro-2-(trimethylsiloxy)propene
A
chloroform
B
ethyl trimethylsilyl ether
C
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With triethylamine for 8h; Heating; Yields of byproduct given; | A n/a B n/a C 71% |
With triethylamine for 8h; Heating; Yield given; | A n/a B n/a C 71% |
2,2-dichloro-3-oxo-propionic acid ethyl ester
A
ethyl 1,1-dichloroacetate
B
Formanilid
Conditions | Yield |
---|---|
With aniline In tetrachloromethane for 12h; Ambient temperature; | A 50% B 66% |
2,2-dichloro-3-oxo-propionic acid ethyl ester
aniline
A
ethyl 1,1-dichloroacetate
B
Formanilid
Conditions | Yield |
---|---|
In tetrachloromethane for 12h; Ambient temperature; | A 50% B 66% |
ethanol
Trichloroethylene
ethyl acetate
A
freon-121
B
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With chlorine monofluoride 1.) Freon 113; 2.) 20 - 25 deg C, 30 min.; Yield given. Multistep reaction; | A 65% B n/a |
dichloro-acetic acid
ethyl N-tert-butyl-4-nitrobenzenesulfonimidate
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
In dichloromethane Heating; | 58% |
Conditions | Yield |
---|---|
With phosphorus pentoxide; copper(II) sulfate; sodium sulfate for 2h; Heating; | 40% |
With hydrogenchloride | |
With sulfuric acid unter wiederholtem Abdestillieren des entstandenen Wassers mit Benzol; |
Conditions | Yield |
---|---|
at 100 - 120℃; |
Conditions | Yield |
---|---|
at 25℃; unter Lichtausschluss; |
ethanol
pentachloroacetone
aluminum ethoxide
A
chloroform
B
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With aluminum ethoxide |
Conditions | Yield |
---|---|
at 150℃; |
ethanol
2,2-diacetoxy-1,1,1-trichloro-ethane
potassium cyanide
A
ethyl acetate
B
ethyl 1,1-dichloroacetate
ethanol
2,2-diacetoxy-1,1,1-trichloro-ethane
potassium cyanide
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With sulfuric acid; potassium chloride |
Conditions | Yield |
---|---|
beim Chlorieren; |
(E)-1,2-dichloro-1-ethoxy-ethene
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With chlorine at 25℃; dann Behandeln mit Wasser; |
ethanol
ammonium acetate
2-acetoxy-3,3,3-trichloro-propionitrile
A
dichloroacetamide
B
ethyl 1,1-dichloroacetate
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With water In tetrahydrofuran |
Conditions | Yield |
---|---|
at 18 - 25℃; Yield given; |
1,1-dichloro-2,2-diethoxy-ethene
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With hydrogenchloride; water In [D3]acetonitrile |
Ethyl trichloroacetate
A
methylene chloride
B
dichloromethane
C
chloroacetic acid ethyl ester
D
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With hydrogen cation; tetranormalbutyl ammonium fluoride for 0.166667h; Product distribution; Ambient temperature; equilibrium; products determined by GC-MS; |
Ethyl trichloroacetate
A
tetrachloro-succinic acid diethyl ester
B
diethyl (Z)-2,3-dichlorobutenedioate
C
diethyl 2,3-dichlorofumarate
D
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With iron(II) chloride In acetonitrile at 25 - 82℃; Rate constant; Thermodynamic data; Product distribution; ΔH(excit.), ΔS(excit.), var. reagent conc., var. reaction time; |
N-nitrosoacetanilide
ethyl dichlorothionoacetate
A
ethyl (phenylhydrazono)chloroacetate
B
4-Chloro-2-phenyl-2H-[1,2,3]thiadiazol-5-one
C
diphenyldisulfane
D
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
In acetone at 20℃; for 20h; Yield given. Yields of byproduct given; |
ethyl dichlorothionoacetate
A
ethyl (phenylhydrazono)chloroacetate
B
4-Chloro-2-phenyl-2H-[1,2,3]thiadiazol-5-one
C
diphenyldisulfane
D
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With N-nitrosoacetanilide In acetone at 20℃; for 20h; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With bis(tri-n-butyltin)oxide In benzene at 80℃; for 10h; other esters, other solvents, other temperatures and reaction times; | 100% |
With bis(tri-n-butyltin)oxide In benzene at 80℃; for 10h; | 100% |
With 2,2'-azobis(isobutyronitrile); bis(tri-n-butyltin)oxide In benzene at 80℃; for 1.5h; | 100 % Spectr. |
Conditions | Yield |
---|---|
In tetrahydrofuran | 100% |
hexanal
ethyl 1,1-dichloroacetate
2-Chloro-3-pentyl-oxirane-2-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With sodium ethanolate In diethyl ether 0-5 deg C, 1 h; reflux, 3 h; | 98% |
With sodium ethanolate 1.) ether, 30 min, 2.) ether, reflux, 3 h; Multistep reaction; | |
With base In diethyl ether Darzens condensation; |
ethanethiol
ethyl 1,1-dichloroacetate
Bis(ethylthio)essigsaeure-ethylester
Conditions | Yield |
---|---|
With potassium carbonate; Aliquat 336 In toluene for 8h; Ambient temperature; | 98% |
isovaleraldehyde
ethyl 1,1-dichloroacetate
2-Chloro-3-isobutyl-oxirane-2-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With sodium ethanolate In diethyl ether 0-5 deg C, 1 h; reflux, 3 h; | 98% |
With base In diethyl ether Darzens condensation; |
Conditions | Yield |
---|---|
With hydrogenchloride In N,N-dimethyl-formamide | 97% |
(2R,3R)-2-benzylamino-3-(4-methylsulfonylphenyl)-propane-1,3-diol
ethyl 1,1-dichloroacetate
thiamphenicol
Conditions | Yield |
---|---|
Stage #1: (2R,3R)-2-benzylamino-3-(4-methylsulfonylphenyl)-propane-1,3-diol With hydrogenchloride; hydrogen; palladium on activated charcoal In ethanol at 20℃; for 2h; Stage #2: ethyl 1,1-dichloroacetate With triethylamine In methanol at 30℃; for 6h; Further stages.; | 96% |
(1R,2S)-1-(4-methylsulfonylphenyl)-2-benzylamino-3-fluoro-1-propanol
ethyl 1,1-dichloroacetate
Florfenicol
Conditions | Yield |
---|---|
Stage #1: (1R,2S)-1-(4-methylsulfonylphenyl)-2-benzylamino-3-fluoro-1-propanol With sulfuric acid; hydrogen; palladium on activated charcoal In ethanol at 20℃; for 2h; Stage #2: ethyl 1,1-dichloroacetate With triethylamine In methanol at 30℃; for 6h; Further stages.; | 96% |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; potassium carbonate In acetonitrile Reagent/catalyst; Solvent; Reflux; | 93.98% |
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With triethylamine In methanol at 20℃; for 12h; | 93% |
(2-Benzylamino-ethyl)-phosphinic acid ethyl ester
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
for 12h; Heating; | 92% |
2-Methylbutyraldehyde
ethyl 1,1-dichloroacetate
(E)-ethyl 4-methylhex-2-enoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 92% |
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 92% |
4-methoxy-benzaldehyde
ethyl 1,1-dichloroacetate
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 92% |
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 92% |
ethyl 1,1-dichloroacetate
2,3-isopropylidene-glyceraldehyde
ethyl (E)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate
Conditions | Yield |
---|---|
With chromium dichloride In tetrahydrofuran at 75℃; for 3h; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 91% |
acetophenone
ethyl 1,1-dichloroacetate
2-chloro-3-hydroxy-3-phenyl-butyric acid ethyl ester
Conditions | Yield |
---|---|
bronze-coloured C8K; silver(I) acetate; zinc(II) chloride In tetrahydrofuran at -20℃; for 0.666667h; | 90% |
With amalgamated magnesium; diethyl ether |
isobutyraldehyde
ethyl 1,1-dichloroacetate
ethyl 2-chloro-3-isopropyloxirane-2-carboxylate
Conditions | Yield |
---|---|
With sodium ethanolate In diethyl ether 0-5 deg C, 1 h; reflux, 3 h; | 90% |
With base In diethyl ether Darzens condensation; | |
With sodium ethanolate In diethyl ether; ethanol at 0℃; for 1h; |
3-phenyl-propenal
ethyl 1,1-dichloroacetate
(2E)-ethyl 5-phenylpenta-2,4-dienoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 90% |
ethyl 1,1-dichloroacetate
2,3,4,5-di-O-isopropylidenealdehydo-L-xylose
ethyl (E)-2,3-dideoxy-4,5:6,7-di-O-isopropylidene-L-xylo-hept-2-enonate
Conditions | Yield |
---|---|
With chromium dichloride In tetrahydrofuran at 75℃; for 3h; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 90% |
Conditions | Yield |
---|---|
With potassium carbonate; Aliquat 336 In toluene for 8h; Ambient temperature; | 89% |
isovaleraldehyde
ethyl 1,1-dichloroacetate
ethyl (E)-5-methylhex-2-enoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 89% |
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 89% |
cyclopentanone
ethyl 1,1-dichloroacetate
chloro-(1-hydroxy-cyclohexyl)-acetic acid ethyl ester
Conditions | Yield |
---|---|
bronze-coloured C8K; silver(I) acetate; zinc(II) chloride In tetrahydrofuran at 0℃; for 1h; | 88% |
10-Undecenal
ethyl 1,1-dichloroacetate
ethyl (E)-trideca-2,12-dienoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 88% |
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 88% |
4-chlorobenzaldehyde
ethyl 1,1-dichloroacetate
ethyl (E)-3-(4-chlorophenyl)prop-2-enoate
Conditions | Yield |
---|---|
With manganese In tetrahydrofuran for 3h; Heating; | 88% |
With manganese In tetrahydrofuran for 3h; Reflux; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 88% |
3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose
ethyl 1,1-dichloroacetate
ethyl (E)-[3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-gluco]-heptofuran-5-en-uronate
Conditions | Yield |
---|---|
With chromium dichloride In tetrahydrofuran at 75℃; for 3h; Inert atmosphere; optical yield given as %de; stereoselective reaction; | 87% |
Conditions | Yield |
---|---|
With sodium ethanolate In diethyl ether 0-5 deg C, 1 h; reflux, 3 h; | 86% |
With sodium ethanolate 1.) ether, 30 min, 2.) ether, reflux, 3 h; Multistep reaction; | |
With base In diethyl ether Darzens condensation; |
ethyl 1,1-dichloroacetate
ethyl 2-chloro-2-deuterioacetate
Conditions | Yield |
---|---|
With tributyltin deuteride for 24h; Ambient temperature; | 86% |
2-acetyl-2-cyclohexen-1-one
ethyl 1,1-dichloroacetate
Conditions | Yield |
---|---|
With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 3h; | 86% |
phenylacetylene
ethyl 1,1-dichloroacetate
1,1-dichloro-4-phenylbut-3-yn-2-one
Conditions | Yield |
---|---|
Stage #1: phenylacetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: ethyl 1,1-dichloroacetate With boron trifluoride diethyl etherate In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.; | 85% |
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