PRODUCTS DETAILS 4'-Methoxyacetophenone Basic information Identification Description Regulatory Status Usage Natural occurrence Product Name: 4'-M
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryHebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryColorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day
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inquiryName: 4'-Methoxyacetophenone Synonyms: p-Acetanisole CAS:100-06-1 MF: C9H10O2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Pharmaceutical Intermediate Transportation:By sea
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inquiryAppearance:White crystals or crystalline powder Storage:R.T Package:25kg/drum Application:Formulated flavor Transportation:Express/Sea/Air Port:Any port in China
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inquiry4'-Methoxyacetophenone CAS: 100-06-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:100-06-1
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High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar
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Cas:100-06-1
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Cas:100-06-1
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Cas:100-06-1
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Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-) In decane; acetonitrile at 45℃; for 4h; Wacker Oxidation; | 100% |
With water; oxygen In methanol; dimethyl sulfoxide at 80℃; under 1520.1 Torr; for 20h; Wacker Oxidation; Autoclave; | 99% |
With palladium diacetate; 9-tert-butyl-10-methylanthracene ozonide In acetonitrile for 72h; Ambient temperature; | 93% |
Conditions | Yield |
---|---|
With 2.9-dimethyl-1,10-phenanthroline; oxygen; sodium hydrogencarbonate; gold(I) chloride In water at 100℃; under 38002.6 Torr; for 24h; | 100% |
With Cp*Ir(6,6'-dionato-2,2'-bipyridine)(H2O) In pentane for 5h; Reflux; | 100% |
With diisopropoxyaluminium trifluoroacetate; 4-nitrobenzaldehdye In benzene for 0.25h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With polystyrene-bound tetrafluorophenylbis(triflyl)methane In nitromethane at 50℃; for 2h; Friedel-Crafts acylation; | 100% |
With lithium perchlorate at 60℃; for 1h; | 100% |
With Sulfate; zirconium(IV) oxide at 110℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: acetic acid; methoxybenzene With trifluoroacetic anhydride In dichloromethane at 20℃; for 0.25h; Stage #2: With trifluorormethanesulfonic acid In dichloromethane at 20℃; for 1h; | 100% |
With methanesulfonic acid; pyrographite at 80℃; for 0.333333h; Friedel-Crafts acylation; | 98% |
With aluminum oxide; trifluoroacetic anhydride for 0.166667h; Ambient temperature; | 96% |
1-(1,1-Bis-ethylsulfanyl-ethyl)-4-methoxy-benzene
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With gallium(III) trichloride In dichloromethane; water for 0.25h; Ambient temperature; | 100% |
methoxybenzene
N,N-diacetyl-p-nitrophenylsulphenamide
A
4-(4-methoxyphenylsulfanyl)nitrobenzene
B
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With trifluoroacetic acid at 190 - 200℃; | A 100% B 21% |
Conditions | Yield |
---|---|
With gold(III) tribromide; water at 200℃; for 0.333333h; microwave irradiation; | 100% |
With Au nanoparticles covalently bonded to HS/SO3H functionalized periodic mesoporous organosilica (Et) at 70℃; for 1.5h; neat (no solvent); | 100% |
With hydrogenchloride; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 48℃; for 20h; Solvent; Schlenk technique; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With AcrH2 In acetonitrile at 298℃; for 19h; Irradiation; | 100% |
With AcrH2 In acetonitrile at 298℃; for 19h; Irradiation; | 100% |
With decaborane; palladium on activated charcoal In methanol at 20℃; for 2h; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone Heating; | 100% |
With potassium hydroxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 25℃; for 2h; Williamson synthesis; | 99% |
With potassium carbonate In acetone Heating; | 98% |
Conditions | Yield |
---|---|
With hydrogenchloride; Tonsil In ethyl acetate for 1.5h; Heating; | 100% |
With CuCl2*2H2O for 0.00277778h; microwave irradiation; | 95% |
With benzyltriphenylphosphonium dichromate; silica gel for 0.25h; | 95% |
Conditions | Yield |
---|---|
With aluminium trichloride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at -10℃; for 0.25h; | 99% |
With zinc at 80 - 82℃; for 0.00194444h; Friedel-Crafts acylation; microwave irradiation; | 99% |
With indium(III) tosylate In dodecane; nitromethane for 1h; Friedel-Crafts Acylation; Schlenk technique; Reflux; | 99% |
Conditions | Yield |
---|---|
Stage #1: 4-methoxyacetophenone oxime With hexachlorodisilane; silica gel In toluene at 110℃; for 0.5h; Stage #2: With water In toluene for 0.5h; | 99% |
With N,N'-dibromo-N,N'-(1,2-ethanediyl)bis(p-toluenesulfonamide) In tetrachloromethane at 20℃; for 2h; Product distribution; | 97% |
With formaldehyd; sodium dodecyl-sulfate In water at 50℃; for 2h; Ultrasound irradiation; | 97% |
Conditions | Yield |
---|---|
With oxygen In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 6h; Irradiation; | 99% |
With tert.-butylhydroperoxide In chlorobenzene at 99.84℃; for 10h; | 98% |
With dihydroxy-methyl-borane; bathophenanthroline; copper (I) acetate; lithium carbonate; N-fluorobis(benzenesulfon)imide In chlorobenzene at 45℃; for 16h; | 96% |
2-(4-methoxyphenyl)-2-methyI-1,3-dioxolane
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With cerium triflate In nitromethane; water at 20℃; for 6h; | 99% |
With water at 120℃; for 0.5h; microwave irradiation; | 99% |
With Montmorillonite K 10; water In acetone for 0.5h; Heating; | 97% |
1-(4-methoxy-phenyl)-2-phenoxy-ethanone
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With ammonium chloride; zinc In ethanol for 0.5h; Heating; | 99% |
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 3h; Schlenk technique; Inert atmosphere; | 92% |
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / tetrahydrofuran; water / 2 h / 20 °C 2: sodium salt of dibutyl phosphate; Methyl thioglycolate; [Ir(ppy)2(dtbpy)]PF6 / N,N-dimethyl acetamide / 24 h / 25 °C / Irradiation; Sealed tube; Inert atmosphere View Scheme |
2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one
A
2-methoxy-phenol
B
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With formic acid; N-ethyl-N,N-diisopropylamine; Lumogen F Orange 240 In acetonitrile at 25℃; for 8h; Reagent/catalyst; UV-irradiation; Inert atmosphere; | A 99% B 99% |
With formic acid; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; N-ethyl-N,N-diisopropylamine In ethanol at 20℃; Irradiation; chemoselective reaction; | A 95% B 72% |
With formic acid; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 12h; Reagent/catalyst; Irradiation; chemoselective reaction; | A 89% B 88% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; palladium on activated charcoal In water; ethyl acetate at 80℃; for 1h; | A 95% B 99% |
With 5%-palladium/activated carbon; ammonium formate In water at 80℃; for 1h; | A n/a B 98% |
With C32H25Cl2N6O2Rh2(1+)*Cl(1-); sodium hydroxide In water at 110℃; for 18h; Inert atmosphere; | A 89% B 86% |
2',3',4',5',6'-pentamethylacetophenone
methoxybenzene
A
2-Methoxyacetophenone
B
pentamethylbenzene,
C
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
trifluoroacetic acid for 20h; Heating; | A n/a B 98% C n/a |
With sodium 2,2,2-trifluoroacetate; trifluoroacetic acid for 0.5h; Product distribution; Rate constant; Heating; with various additives and additive amounts; | A n/a B 38% C n/a |
4-methoxyacetophenone phenylhydrazone
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With benzyltriphenylphosphonium dichromate; silica gel for 0.116667h; | 98% |
With 1-benzyl-1-aza-4-azoniabicyclo<2.2.2>octane periodate In acetonitrile for 0.75h; Oxidation; Heating; | 97% |
With Oxone; water; potassium hydrogencarbonate In acetone for 0.5h; Heating; | 97% |
Conditions | Yield |
---|---|
With 1-benzyl-4-aza-1-azoniabiyclo<2.2.2>octane peroxodisulfate In acetonitrile for 0.916667h; Heating; | 98% |
With Oxone; water; potassium hydrogencarbonate In acetonitrile for 0.5h; Heating; | 98% |
With benzyltriphenylphosphonium dichromate In acetonitrile for 0.583333h; Oxidation; Heating; | 98% |
acetic anhydride
methoxybenzene
A
acetic acid
B
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With lanthanum(lll) triflate In nitromethane at 50℃; for 24h; Kinetics; Product distribution; Further Variations:; Temperatures; Solvents; Reagents; Friedel-Crafts acylation; | A n/a B 98% |
Ce-Clay at 100℃; for 1 - 5h; | A n/a B 35% |
La-Clay at 100℃; for 1 - 5h; | A n/a B 15% |
1-(4-methoxyphenyl)-2-phenoxyethan-1-ol
A
1-(4-methoxyphenyl)ethanone
B
phenol
Conditions | Yield |
---|---|
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 135℃; for 4h; Inert atmosphere; | A 98% B n/a |
With sodium tetrahydroborate; palladium on activated charcoal In water; ethyl acetate at 80℃; for 1h; | A 98% B n/a |
With [Ir(ppy)2(dtbpy)]PF6; sodium salt of dibutyl phosphate; Methyl thioglycolate In N,N-dimethyl acetamide at 25℃; for 24h; Reagent/catalyst; Solvent; Irradiation; Sealed tube; Inert atmosphere; | A 86% B 71% |
2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; ammonium formate In ethanol; water at 80℃; for 1h; | 98% |
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 3h; Schlenk technique; Inert atmosphere; | 89% |
With formic acid; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; N-ethyl-N,N-diisopropylamine In ethanol at 20℃; for 12h; Irradiation; chemoselective reaction; |
1-(4-methoxyphenyl)-2-phenoxyethan-1-ol
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; ammonium formate In tert-butyl methyl ether; water at 80℃; for 3h; | 98% |
1-(4-methoxyphenyl)-2-(naphthalen-2-yloxy)ethan-1-one
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 3h; Schlenk technique; Inert atmosphere; | 98% |
4-Methoxystyrene
A
rac-1-(4-methoxyphenyl)-ethanol
B
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With 2.9-dimethyl-1,10-phenanthroline; phenylsilane; iron(II) chloride In ethanol at 20℃; for 4.5h; Reagent/catalyst; Wacker Oxidation; | A 2% B 97% |
With triethylsilane; (1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-Hexadecafluorophthalocyaninato)iron(II); oxygen In ethanol at 20℃; under 760.051 Torr; for 9.5h; Wacker Oxidation; Sealed tube; Green chemistry; chemoselective reaction; | A 12% B 85% |
With sodium hydroxide; sodium tetrahydroborate; oxygen; 5,10,15,20-tetrakis(1-methyl-4-pyridino)porphyrine tertachloride In water Ambient temperature; pH 12; | A 14% B 65% |
With triethylsilane; [5,10,15,20-tetra(2,6-dichlorophenyl)porphyrinato]cobalt(II); oxygen; phosphorous acid trimethyl ester 1.) 2-propanol, dichloromethane, 28 deg C, 1 atm, 30 min, 2.) 2-propanol, dichloromethane, RT, 2 h; Yield given. Multistep reaction. Yields of byproduct given; |
rac-1-(4-methoxyphenyl)-ethanol
3,3-dimethyldioxirane
A
p-methoxybenzoylmethanol
B
1-(4-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
In acetone at 25℃; for 3h; | A 3% B 97% |
In acetone at 25℃; for 3h; Thermodynamic data; Rate constant; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.); | A 3% B 97% |
Conditions | Yield |
---|---|
With potassium chloride; acetic anhydride In nitromethane; toluene | 97% |
Conditions | Yield |
---|---|
With 4-phenylnaphthalene-1,2-dione In acetonitrile at 80℃; for 36h; | 97% |
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccasefrom Trametes versicolor; oxygen In water at 30℃; pH=4.5; Enzymatic reaction; | 84% |
With caesium carbonate; dibenzoyl peroxide In N,N-dimethyl-formamide at 0 - 50℃; | 69% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 0.025h; Irradiation; | 100% |
With 4 A molecular sieve; NAP-MgO In toluene for 16h; Claisen-Schmidt condensation; Heating; | 98% |
With sodium hydroxide In ethanol at 20℃; Cooling with ice; | 95% |
4-methoxy-benzaldehyde
1-(4-methoxyphenyl)ethanone
(E)-1,3-bis(4-methoxyphenyl)-2-propene-1-one
Conditions | Yield |
---|---|
With sodium hydroxide In methanol at 20℃; for 20h; Aldol Condensation; | 100% |
With sodium hydroxide In ethanol at 20℃; for 48h; | 99% |
With sodium hydroxide In ethanol at 20℃; for 48h; Claisen-Schmidt Condensation; | 98% |
oxalic acid diethyl ester
1-(4-methoxyphenyl)ethanone
ethyl 3-(4-methoxybenzoyl)pyruvate
Conditions | Yield |
---|---|
Stage #1: 1-(4-methoxyphenyl)ethanone With sodium In ethanol at 20℃; for 0.5h; Stage #2: oxalic acid diethyl ester at 20 - 80℃; for 3h; | 100% |
With sodium hydride In N,N-dimethyl-formamide at 0 - 100℃; | 100% |
Stage #1: oxalic acid diethyl ester With sodium methylate In diethyl ether at 20℃; Inert atmosphere; Stage #2: 1-(4-methoxyphenyl)ethanone In diethyl ether at 20℃; for 12h; | 92% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 0℃; Inert atmosphere; | 100% |
Stage #1: 1-(4-methoxyphenyl)ethanone With C24H20Cl2F5NRuS; isopropyl alcohol at 82℃; for 0.166667h; Stage #2: With potassium hydroxide at 82℃; for 1h; | 100% |
With hydrogen; Ru(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl)(PPh3)2CO(H)2 In benzene at 70℃; under 3800 Torr; for 24h; | 99% |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃; | 100% |
With pyridine; hydroxylamine hydrochloride In ethanol at 75℃; for 22h; | 99% |
Conditions | Yield |
---|---|
With selenium (IV) oxide In 1,4-dioxane; water Heating; | 100% |
With tris(2,2'-bipyridyl)ruthenium dichloride; dioxane dibromide; sodium L-ascorbate In acetonitrile at 20℃; for 8h; Irradiation; Green chemistry; | 91% |
With selenium(IV) oxide In 1,4-dioxane for 3h; Reflux; | 88% |
Conditions | Yield |
---|---|
With bromine In 1,4-dioxane; diethyl ether for 0.5h; Ambient temperature; | 100% |
With N-Bromosuccinimide; toluene-4-sulfonic acid In chloroform at 20℃; for 12h; | 98.7% |
With bis(dimethylacetamide)hydrogen tribromide In methanol at 20 - 45℃; for 0.25h; | 96% |
Conditions | Yield |
---|---|
With hydrogen under 2250.23 Torr; for 4h; | 100% |
With palladium dichloride In methanol at 40℃; for 24h; Inert atmosphere; Green chemistry; chemoselective reaction; | 99% |
With hydrogen In 1,4-dioxane at 200℃; under 15001.5 Torr; | 98.9% |
Conditions | Yield |
---|---|
With perchloric acid for 0.666667h; | 100% |
carbonic acid dimethyl ester
1-(4-methoxyphenyl)ethanone
methyl 3-(4-methoxybenzoyl)acetate
Conditions | Yield |
---|---|
With sodium hydride In toluene at 110℃; | 100% |
Stage #1: carbonic acid dimethyl ester With sodium hydride In toluene at 110℃; Stage #2: 1-(4-methoxyphenyl)ethanone In toluene at 110℃; | 100% |
With sodium hydride In toluene for 4h; Inert atmosphere; Reflux; | 98% |
1-(4-methoxyphenyl)-3,3-bis(methylsulfanyl)propenone
1-(4-methoxyphenyl)ethanone
(E)-1,5-Bis-(4-methoxy-phenyl)-3-methylsulfanyl-pent-2-ene-1,5-dione
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran for 3h; Ambient temperature; | 100% |
1-(4-methoxyphenyl)-3,3-bis(methylsulfanyl)propenone
1-(4-methoxyphenyl)ethanone
(E)-1,5-Bis-(4-methoxy-phenyl)-3-methylsulfanyl-pent-2-ene-1,5-dione
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran Ambient temperature; | 100% |
1-(4-methoxyphenyl)ethanone
4-(4-methoxy-phenyl)-[1,2,3]thiadiazole
Conditions | Yield |
---|---|
Stage #1: 1-(4-methoxyphenyl)ethanone With polystyrene-sulfonylhydrazide resin; acetic acid In tetrahydrofuran at 50℃; for 4h; Solid phase reaction; Stage #2: With thionyl chloride In 1,2-dichloro-ethane at 60℃; for 5h; Solid phase reaction; Hurd-Mori cyclization; | 100% |
With iodine; potassium thioacyanate; toluene-4-sulfonic acid hydrazide; copper dichloride In dimethyl sulfoxide at 100℃; for 1h; Sealed tube; | 81% |
With iodine; potassium thioacyanate; toluene-4-sulfonic acid hydrazide; copper(l) chloride In dimethyl sulfoxide at 130℃; for 1h; | 81% |
Conditions | Yield |
---|---|
With Mg10Al2(OH)24CO3; oxygen; benzaldehyde In 1,2-dichloro-ethane at 40℃; for 24h; | 100% |
With bis-trimethylsilanyl peroxide; 4 A molecular sieve; tin(IV) chloride; rac-diaminocyclohexane In tetrahydrofuran; dichloromethane for 3h; Ambient temperature; | 97% |
With 3-chloro-benzenecarboperoxoic acid; scandium tris(trifluoromethanesulfonate) In dichloromethane for 1h; Ambient temperature; | 95% |
(S(S)R)-(+)-3-methyl-2-pivaloyl-2,3-dihydroisothiazole 1-oxide
1-(4-methoxyphenyl)ethanone
N-((R)-1-{2-[(S)-2-(4-Methoxy-phenyl)-2-oxo-ethanesulfinyl]-phenyl}-ethyl)-2,2-dimethyl-propionamide
Conditions | Yield |
---|---|
With sodium hexamethyldisilazane In tetrahydrofuran; toluene 1.) -78 deg C, 1 h, 2.) -78 deg C, 1 h; -78 deg C to r.t.; | 100% |
1-(4-methoxyphenyl)ethanone
(S)-1-(4-Methoxyphenyl)ethanol
Conditions | Yield |
---|---|
With dimethylsulfide borane complex; 4-chloro-2-(((1S,2R)-1-hydroxy-1-phenylpropan-2-ylamino)methyl)phenol In tetrahydrofuran for 2h; Inert atmosphere; Reflux; optical yield given as %ee; enantioselective reaction; | 100% |
diethylzinc; (+)-N,N'-Bis<(R)-1-phenylethyl>-1,2-ethylendiamin | 99% |
With (mer-[(S,S)-1,5-dimethyl-2,4-bis(4-phenyl-1,3-oxazolin-2-yl)benzene(1-)]Ru(CO)Cl)2(ZnCl2); hydrogen; sodium methylate; (-)-(S)-1-Anthracen-9-ylethanol In isopropyl alcohol at 40℃; under 22801.5 Torr; for 24h; Inert atmosphere; Autoclave; optical yield given as %ee; enantioselective reaction; | 99% |
Conditions | Yield |
---|---|
With (S,S)-RuCl2(2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl)(1,1-dianisyl-2-isopropyl-1,2-ethylenediamine); potassium tert-butylate; hydrogen In isopropyl alcohol at 26 - 30℃; under 7600 Torr; for 1h; | 100% |
With Trimethyl borate; (S)-diphenylprolinol; dimethylsulfide borane complex In tetrahydrofuran; toluene at 25℃; | 99% |
With potassium tert-butylate; hydrogen; [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); (R)-Ph-BINAN-H-Py In isopropyl alcohol at 25℃; under 38000 Torr; for 15h; | 99.3% |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In methanol Heating; | 100% |
With hydroxylamine hydrochloride; sodium acetate In methanol; water Reflux; | 100% |
With hydroxylamine hydrochloride; sodium acetate In methanol Reflux; | 100% |
N,N-dimethyl-formamide dimethyl acetal
1-(4-methoxyphenyl)ethanone
3-(dimethylamino)-1-(4-methoxyphenyl)prop-2-en-1-one
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 3.5h; Reflux; | 100% |
In N,N-dimethyl-formamide for 24h; Reflux; | 98% |
In neat (no solvent) at 160℃; for 0.25h; Microwave irradiation; | 95% |
formaldehyd
4-benzylpyperidine
1-(4-methoxyphenyl)ethanone
C35H44N2O2
Conditions | Yield |
---|---|
With hydrogenchloride In ethanol Mannich reaction; Heating; | 100% |
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