Product Name

  • Name

    DIMETHYLPHENYLPHOSPHINE

  • EINECS 211-595-3
  • CAS No. 672-66-2
  • Article Data55
  • CAS DataBase
  • Density 0.971 g/mL at 25 °C(lit.)
  • Solubility Insoluble in water
  • Melting Point 126-127ºC
  • Formula C8H11 P
  • Boiling Point 74-75 °C12 mm Hg(lit.)
  • Molecular Weight 138.149
  • Flash Point 122 °F
  • Transport Information UN 1993 3
  • Appearance Colorless to light yellow liquid
  • Safety Explodes when heated above 55°C or on impact. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.
  • Risk Codes 10-36/37/38
  • Molecular Structure Molecular Structure of 672-66-2 (DIMETHYLPHENYLPHOSPHINE)
  • Hazard Symbols IrritantXi
  • Synonyms Dimethylphenylphosphine;NSC 158474; Phenyldimethylphosphine
  • PSA 13.59000
  • LogP 2.05340

Synthetic route

dimethylphenylphosphine-borane complex

dimethylphenylphosphine-borane complex

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With methanol; 4 A molecular sieve In tetrahydrofuran at 100℃; for 22h;100%
With piperazinomethyl polystyrene resin In toluene at 115℃; for 17h;
{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

trimethylphosphane
594-09-2

trimethylphosphane

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

cyclopentadienylmolybdenum(III)(PMe3)2Cl2

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.2:1) in toluene;;A 100%
B n/a
dimethyl(phenyl)phosphine oxide
10311-08-7

dimethyl(phenyl)phosphine oxide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With polymethylhydrosiloxane In neat (no solvent) at 150℃; for 10h; Reagent/catalyst; Temperature; Inert atmosphere; Green chemistry;95%
With phenylsilane In neat (no solvent) at 110℃; for 1.75h; Reagent/catalyst; Temperature; Time; Inert atmosphere; Green chemistry;95%
With [AlH3(triethylamine)] In hexane at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;98 %Chromat.
With hexylsilane; trifluorormethanesulfonic acid In toluene at 70℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction;94 %Spectr.
With methanesulfonic acid; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 4.5h; Inert atmosphere; Schlenk technique;
(η-C5H5)2W(CH3)(CH2P(CH3)2C6H5)PF6

(η-C5H5)2W(CH3)(CH2P(CH3)2C6H5)PF6

A

(tungsten(η-cyclopentadienyl)2(ethylene)H)(PF6)

(tungsten(η-cyclopentadienyl)2(ethylene)H)(PF6)

B

(C5H5)2W(CH2P(CH3)2C6H5)(C2H5)(1+)*PF6(1-)
82917-98-4

(C5H5)2W(CH2P(CH3)2C6H5)(C2H5)(1+)*PF6(1-)

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
heated in sealed tube for 12 d at 75°C; elem. anal.;A n/a
B 86%
C n/a
[(C5H5)(C5H4)Zr(P(CH3)2C6H5)]2
71844-81-0

[(C5H5)(C5H4)Zr(P(CH3)2C6H5)]2

A

zirconocene dichloride
1291-32-3

zirconocene dichloride

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With hydrogenchloride In benzene-d6 (N2); HCl gas added to complex soln. at 0°C, shaken at room temp.; not isolated, detected by NMR;A 60%
B 80%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
75%
With diethyl ether
chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

chlorodimethyloxo(bis(dimethylphosphino)ethane)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene byproducts: pyridine; N2 or Ar atmosphere of vac.; stirring (1 h); filtn., concn. (vac.), cooling (-20°C); elem. anal.;A 62%
B n/a
chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

trimethyloxo(dimethylphenylphosphine)rhenium(V)

trimethyloxo(dimethylphenylphosphine)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C

methylzinc chloride
5158-46-3

methylzinc chloride

Conditions
ConditionsYield
In toluene N2 or Ar atmosphere of vac.; 0°C; removal of solvent (0°C, vac.), extn. (pentane), removal of pentane (vac.);A 51%
B n/a
C n/a
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

chlorodimethyloxobis(dimethylphenylphosphine)rhenium(V)

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

trimethyloxo(bipyridine)rhenium(V)

trimethyloxo(bipyridine)rhenium(V)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene N2 or Ar atmosphere of vac.; addn. of soln. of ZnMe2 to soln. of Re-compd. in toluene (0°C), removal of solvent (0°C, vac.), extn. (pentane), addn. of bipy; removal of solvent and excess of bipy (vac.), crystn. (pentane, -50°C);A 35%
B n/a
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With benzene
Dimethyl-phenyl-phosphonium
24151-41-5

Dimethyl-phenyl-phosphonium

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
With methane; trimethylphosphane at 47℃; under 0.01 Torr; Equilibrium constant; Thermodynamic data; irradiation with short electron pulse; ΔG;
dimethyldiphenylphosphonium bromide
2129-85-3

dimethyldiphenylphosphonium bromide

A

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In methanol; acetonitrile at 20℃; Product distribution; cathodic reduction, influence of potential on the product ratio;
trimethylphosphane
594-09-2

trimethylphosphane

A

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

B

Mo2Cl4(PMe2Ph)3(PMe3)

Mo2Cl4(PMe2Ph)3(PMe3)

Conditions
ConditionsYield
With Mo2Cl4(PMe2Ph)4 In (2)H8-toluene Thermodynamic data; ΔH(excit.); ΔS(excit.);
water
7732-18-5

water

dichloro-phenyl-phosphine; compound with dimethylphenylphosphine

dichloro-phenyl-phosphine; compound with dimethylphenylphosphine

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

fluorobenzene
462-06-6

fluorobenzene

dimethyl(trimethylsilyl)phosphine
26464-99-3

dimethyl(trimethylsilyl)phosphine

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 at 180℃; for 90h;60 % Spectr.
C8H11P*H(1+)*BF4(1-)

C8H11P*H(1+)*BF4(1-)

(dibutyl)(phenyl)phosphine
6372-44-7

(dibutyl)(phenyl)phosphine

A

C14H23P*BF4(1-)*H(1+)

C14H23P*BF4(1-)*H(1+)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; Equilibrium constant;
C8H11P*H(1+)*BF4(1-)

C8H11P*H(1+)*BF4(1-)

cyclohexyldiphenylphosphine
6372-42-5

cyclohexyldiphenylphosphine

A

C18H21P*H(1+)*BF4(1-)

C18H21P*H(1+)*BF4(1-)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; Equilibrium constant;
triphenylphosphine
603-35-0

triphenylphosphine

thiocyanato

thiocyanato

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) Na / 1.) liquid NH3, 1 h, 2.) 2.5 h
2: 1.) Na; NH4Cl / liquid NH3, 1.) 1 h, 2.) 2.5 h
View Scheme
Conditions
ConditionsYield
With H2 In toluene Copper-complex is hydrogenated under 3 atm of H2 in toluene, the color of the soln. changes quickly from yellow to orange (under exclusion of air).; investigation by (1)H NMR;
cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 Cis-isomer is dissolved in C6D6 in a NMR-tube.; monitored by (31)P NMR for 19 days;
trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

trans-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

cis-(molybdenum-bis(dinitrogen)(PMe2Ph)4)

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In benzene-d6 Trans-isomer is dissolved in C6D6 in a NMR-tube.; monitored by (31)P NMR for 19 days;
Cp2Ti(CH2CO).PMe2Ph
118458-17-6

Cp2Ti(CH2CO).PMe2Ph

acetylene
74-86-2

acetylene

A

(C5H5)2TiOCCH2CHCH
82808-18-2

(C5H5)2TiOCCH2CHCH

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given
Cp2TiCH2.PMe2Ph
108969-89-7

Cp2TiCH2.PMe2Ph

triethylphosphine
554-70-1

triethylphosphine

A

Cp2TiCH2.PEt3
84254-01-3

Cp2TiCH2.PEt3

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given Kinetics; equil. react.; (31)P-NMR;
(dimethylphenylphosphine)bis(2,4-dimethylpentadienyl)titanium

(dimethylphenylphosphine)bis(2,4-dimethylpentadienyl)titanium

A

bis(2,4-dimethylpentadienyl)titanium

bis(2,4-dimethylpentadienyl)titanium

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In tetrahydrofuran under N2, dissociation in soln.; detn. by (31)P-NMR;
mer-trichlorotris(dimethylphenylphosphine)tungsten(III)
135745-75-4, 150653-03-5

mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

A

tetrachlorotris(dimethylphenylphosphine)tungsten(IV)
47690-18-6

tetrachlorotris(dimethylphenylphosphine)tungsten(IV)

B

WCl4(PMe2Ph)2
30411-60-0

WCl4(PMe2Ph)2

C

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given decomposition of the mer-isomer above 90°C (Ar);
{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

triethylphosphine
554-70-1

triethylphosphine

{Cp(PEt3)2molybdenum(III) dichloride}

{Cp(PEt3)2molybdenum(III) dichloride}

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;; equilibrium;
ethyl iodide
75-03-6

ethyl iodide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

dimethylethylphenylphosphonium iodide
72153-49-2

dimethylethylphenylphosphonium iodide

Conditions
ConditionsYield
In benzene at 20℃; for 12h; Inert atmosphere; Schlenk technique;100%
Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C16H31PSi

C16H31PSi

[(dicyclohexylphosphanyl-trimethylsilanyl-methylene)-dimethyl-λ5-phosphanyl]-benzene

[(dicyclohexylphosphanyl-trimethylsilanyl-methylene)-dimethyl-λ5-phosphanyl]-benzene

Conditions
ConditionsYield
In pentane at 0℃; Addition;100%
[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)](1+)*[BF4](1-)=[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)][BF4]

[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)](1+)*[BF4](1-)=[PtW(CH(C6H4CH3))(CO)2(P(CH3)2C6H5)2(C5H5)][BF4]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)](1+)*[BF4](1-)=[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)][BF4]

[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)](1+)*[BF4](1-)=[PtW(CHC6H4CH3)(CO)2(P(CH3)2C6H5)3(C5H5)][BF4]

Conditions
ConditionsYield
In dichloromethane excess of ligand in light petroleum added to stirred soln. of complex in CH2Cl2, reacted for 10 min; evapd. (vac.), washed (Et2O), dried (vac.); elem. anal.;100%
(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)
12146-37-1, 124717-04-0

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

bis(phenyldimethylphosphine)molybdenum tetracarbonyl
24554-47-0

bis(phenyldimethylphosphine)molybdenum tetracarbonyl

B

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

Conditions
ConditionsYield
In tetrahydrofuran reaction in a calorimeter;A 100%
B n/a
{Pt2Cl2(PMe2Ph)4}{BF4}2

{Pt2Cl2(PMe2Ph)4}{BF4}2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{PtCl(PMe2Ph)3}{BF4}
56954-49-5

{PtCl(PMe2Ph)3}{BF4}

Conditions
ConditionsYield
In acetone dissolved in acetone, PMe2Ph was added; solution was evaporated, dried in vacuo, elem. anal., NMR;100%
(C5H5)MoCl2(P(C6H5)3)2

(C5H5)MoCl2(P(C6H5)3)2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

Conditions
ConditionsYield
In dichloromethane byproducts: P(C6H5)3; mixing of the Mo compd. with the free phosphine (molar ratio 2.8:1) in CH2Cl2;;100%
{Cp(PMePh2)2molybdenum(III) dichloride}

{Cp(PMePh2)2molybdenum(III) dichloride}

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{Cp(PMe2Ph)2molybdenum(III) dichloride}

{Cp(PMe2Ph)2molybdenum(III) dichloride}

B

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.0:1) in toluene;;A 100%
B n/a
cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]
33542-07-3

cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)
80700-08-9, 80736-08-9

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)

Conditions
ConditionsYield
In methanol at -30°C;100%
[NEt4N][Re3(μ-H)4(CO)9(C3H4N2)]
511550-07-5, 210559-10-7

[NEt4N][Re3(μ-H)4(CO)9(C3H4N2)]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[Et4N][Re3(μ-H)4(CO)9(PMe2PH)]
210559-25-4

[Et4N][Re3(μ-H)4(CO)9(PMe2PH)]

Conditions
ConditionsYield
In [(2)H6]acetone N2-atmosphere; 193 to 298 K; detd. by NMR spectroscopy;100%
((CH3)5C5)Ir(C2H(CH3)O2NSO2C6H4CH3)

((CH3)5C5)Ir(C2H(CH3)O2NSO2C6H4CH3)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

((CH3)5C5)Ir(P(CH3)2C6H5)(C2H(CH3)O2NSO2C6H4CH3)

((CH3)5C5)Ir(P(CH3)2C6H5)(C2H(CH3)O2NSO2C6H4CH3)

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; elem. anal.;100%
(butane-1,4-diyl)iodo(methyl)platinum(IV)

(butane-1,4-diyl)iodo(methyl)platinum(IV)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(butane-1,4-diyl)bis(dimethylphenylphosphine)iodo(methyl)platinum(IV)
59991-54-7

(butane-1,4-diyl)bis(dimethylphenylphosphine)iodo(methyl)platinum(IV)

Conditions
ConditionsYield
In dichloromethane room temp., stirring (30 h); filtration, volume reduction, pptn. on MeOH addn.;100%
C62H80Hf2N2O2(2+)*2C24BF20(1-)

C62H80Hf2N2O2(2+)*2C24BF20(1-)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

2C24BF20(1-)*C78H102Hf2N2O2P2(2+)

2C24BF20(1-)*C78H102Hf2N2O2P2(2+)

Conditions
ConditionsYield
at 20℃; for 24h; Inert atmosphere;100%
sodium hexaflorophosphate

sodium hexaflorophosphate

[W(hydrotris(3,5-dimethylpyrazolyl)borate)(CO)2(η(1)-CBr)]

[W(hydrotris(3,5-dimethylpyrazolyl)borate)(CO)2(η(1)-CBr)]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

{HB(3,5-Me2C3HN2)3(CO)2WCPMe2Ph}PF6

{HB(3,5-Me2C3HN2)3(CO)2WCPMe2Ph}PF6

Conditions
ConditionsYield
In acetonitrile Inert atmosphere; Schlenk technique;100%
4-bromobutylphosphonium bromide
7333-63-3

4-bromobutylphosphonium bromide

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C30H34P2(2+)*2Br(1-)
89807-18-1

C30H34P2(2+)*2Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 4h; Heating;99%
Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Trifluoro-methanesulfonatetriphenyl-trifluoromethanesulfonyloxymethyl-arsonium;

Trifluoro-methanesulfonatetriphenyl-trifluoromethanesulfonyloxymethyl-arsonium;

(Dimethylphenylphosphonio)(triphenylarsonio)methan-bis(trifluormethansulfonat)

(Dimethylphenylphosphonio)(triphenylarsonio)methan-bis(trifluormethansulfonat)

Conditions
ConditionsYield
In acetonitrile for 24h; Ambient temperature;99%
dinitrosylbis(triphenylphosphine)cobalt hexafluorophosphate

dinitrosylbis(triphenylphosphine)cobalt hexafluorophosphate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Co(NO)2(P(C6H5)(CH3)2)2(1+)*PF6(1-)=[Co(NO)2(P(C6H5)(CH3)2)2]PF6

Co(NO)2(P(C6H5)(CH3)2)2(1+)*PF6(1-)=[Co(NO)2(P(C6H5)(CH3)2)2]PF6

Conditions
ConditionsYield
In dichloromethane byproducts: PPh3; N2-atmosphere; excess of incoming phosphine, 20°C;99%
[(4-MePy)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

[(4-MePy)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(P(CH3)2Ph)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

[(P(CH3)2Ph)Fe(phthalocyanate)O]2Ru(tetrakis(4-methoxyphenyl)porphyrinate)

Conditions
ConditionsYield
In chloroform byproducts: 4-methylpyridine; excess of ligand added to Ru-Fe complex in CHCl3 at room temp.; pptn. with hexane;99%
[(η(5)-heptamethylindenyl)RhCl(μ-Cl)]2
171193-96-7

[(η(5)-heptamethylindenyl)RhCl(μ-Cl)]2

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(η(5)-heptamethylindenyl)Rh(PMe2Ph)Cl2]
171193-98-9

[(η(5)-heptamethylindenyl)Rh(PMe2Ph)Cl2]

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; 24 h; solvent removal (vac.), recrystn. (THF/hexane, -40°C); elem. anal.;99%
[Ni(C6Cl4(PPh2)-2)2]

[Ni(C6Cl4(PPh2)-2)2]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[Ni(C6Cl4(PPh2)-2)2(PMe2Ph)]

[Ni(C6Cl4(PPh2)-2)2(PMe2Ph)]

Conditions
ConditionsYield
In toluene N2-atmosphere; equimolar amts., stirring (dissoln.); sepn. on EtOH addn.; elem. anal.;99%
technetium tetrachloride

technetium tetrachloride

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

trans-[(99)TcCl4(PMe2Ph)2]
53749-04-5

trans-[(99)TcCl4(PMe2Ph)2]

Conditions
ConditionsYield
In benzene Schlenk technique, radiation precautions; PMe2Ph added to suspn. of TcCl4, mixt. stirred at room temp.;99%
dichloromethane
75-09-2

dichloromethane

water
7732-18-5

water

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

B

cobalt
7440-48-4

cobalt

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In dichloromethaneA n/a
B 99%
C n/a
D n/a
ethyl 2-methylbuta-2,3-dienoate
5717-41-9

ethyl 2-methylbuta-2,3-dienoate

trifluoroacetic acid
76-05-1

trifluoroacetic acid

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

dimethylphenyl(4-ethoxy-3-methyl-4-oxobut-1-en-2-yl)phosphonium trifluoroacetate
1332456-48-0

dimethylphenyl(4-ethoxy-3-methyl-4-oxobut-1-en-2-yl)phosphonium trifluoroacetate

Conditions
ConditionsYield
In chloroform at 20℃; for 12h;99%
Methyl 3-bromopropionate
3395-91-3

Methyl 3-bromopropionate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(3-methoxy-3-oxopropyl)dimethyl(phenyl)phosphonium bromide

(3-methoxy-3-oxopropyl)dimethyl(phenyl)phosphonium bromide

Conditions
ConditionsYield
In acetonitrile at 20℃;99%
methyl (E)-3-[(phenylcarbamoyl)diazenyl]but-2-enoate
146000-78-4

methyl (E)-3-[(phenylcarbamoyl)diazenyl]but-2-enoate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

C20H24N3O3P

C20H24N3O3P

Conditions
ConditionsYield
In diethyl ether at 0 - 5℃; for 0.2h;98%
μ-oxo-bis[(nitrosotrimethylsilylmethane)nitrosyloxomolybdenum]
79829-64-4

μ-oxo-bis[(nitrosotrimethylsilylmethane)nitrosyloxomolybdenum]

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Mo2O3(NO)2(ONCH2Si(CH3)3)2(P(CH3)2C6H5)2
79846-11-0

Mo2O3(NO)2(ONCH2Si(CH3)3)2(P(CH3)2C6H5)2

Conditions
ConditionsYield
In toluene ppt. washed with toluene, THF and diethyl ether, dried in vac.; elem. anal.;98%
Re(CO)4(OC(OCH3)CHCCH2COOCH3)
182137-83-3

Re(CO)4(OC(OCH3)CHCCH2COOCH3)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

fac-Re(CO)3(PMe2Ph)[C(CH2CO2Me)=C(H)CO2Me]

fac-Re(CO)3(PMe2Ph)[C(CH2CO2Me)=C(H)CO2Me]

Conditions
ConditionsYield
In hexane N2-atmosphere; refluxing (30 min); evapn. (vac.), chromy. (SiO2, hexane / CH2Cl2 = 2 : 1);98%
(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)
184682-63-1

(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Co(P(CH3)2C6H5)I((CH3)4C5CH2C6F4CF2)
184682-69-7

Co(P(CH3)2C6H5)I((CH3)4C5CH2C6F4CF2)

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; stirring (room temp., 19 h); evapn. (vac.);98%
(pentamethylcyclopentadienyl)iridium(II) hydride
226922-36-7

(pentamethylcyclopentadienyl)iridium(II) hydride

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

[(Cp(*)IrH)2(μ-H)(μ-Me2PC6H4)]

[(Cp(*)IrH)2(μ-H)(μ-Me2PC6H4)]

Conditions
ConditionsYield
In benzene (Ar or N2); ligand added to Ir complex in C6H6, stirred at room temp. for 16 h; evapd. (vac.), extd. (C6H6), evapd.; elem. anal.;98%

DIMETHYLPHENYLPHOSPHINE Chemical Properties

Product Name: Dimethylphenylphosphine (CAS NO.672-66-2)


Molecular Formula: C8H11P
Molecular Weight: 138.15g/mol
Mol File: 672-66-2.mol
Einecs: 211-595-3
Appearance: Colorless to light yellow liqui
Boiling point: 193.3 °C at 760 mmHg
Storage Temperature: Flammables area
Flash Point: 50 °C
Density: 0.971 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.563(lit.)
Sensitive: Air Sensitive
Enthalpy of Vaporization: 41.19 kJ/mol
Vapour Pressure: 0.653 mmHg at 25°C
XLogP3-AA: 1.5
H-Bond Donor: 0
H-Bond Acceptor: 0
Product Categories: Ligand; Catalysis and Inorganic Chemistry; Phosphine Ligands; Phosphorus Compounds

DIMETHYLPHENYLPHOSPHINE Safety Profile

Safety Information of Dimethylphenylphosphine (CAS NO.672-66-2):
Hazard Codes: Xi
Risk Statements: 10-36/37/38 
10:  Flammable
36:  Irritating to the eyes 
37:  Irritating to the respiratory system 
38:  Irritating to the skin 
Safety Statements: 26-36-16
16:  Keep away from sources of ignition - No smoking
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing

DIMETHYLPHENYLPHOSPHINE Specification

 Dimethylphenylphosphine ,its CAS NO. is 672-66-2,the synonyms is Phosphorus dimethyl phenyl ; Dimethylphenylphosphine ; Phenyldimethylphosphine ; Phosphine, dimethylphenyl- ; d Dimethylphenylphosphine,c69.2%,h7.9% ; Dimethylphenylphosphine,99% .

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