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Shandong Zhimao New Materials Co., Ltd.

Appearance:black powder Package:Packing Transportation:By sea Port:Tianjin/Qingdao

Manganese dioxide

Cas:1313-13-9

Min.Order:25 Metric Ton

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Manganese dioxide Manufacturer/High quality/Best price/In stock

Cas:1313-13-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Whole sell 90% purity of lowest price of Manganese(IV) oxide powder 1313-13-9 Manganese(IV) oxide powder 1313-13-9 Appearance Black to brown powder Conforms Assa

Whole sell 90% purity of lowest price of Manganese(IV) oxide powder 1313-13-9

Cas:1313-13-9

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Manganese Dioxide supplier in China

Cas:1313-13-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

1 Factory price 2 High quality 3 Good service chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw m

China Factory Electrolytic Manganese Metal Powder 1313-13-9

Cas:1313-13-9

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Manganese dioxide

Cas:1313-13-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic MANGANESE DIOXIDE 1313-13-9 Manufacturer

Cas:1313-13-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Shanxi Zorui Biotechnology Co.Ltd.

Zorui combines R&D, production and sales into its operations, While continuously providing high-quality raw materials, we also provide and optimize technical solutions for customers to achieve mutual benefit. We adhere to the "quality, integ

Manganese Dioxide Black Powder MnO2 Industrial Grade Chemicals CAS 1313-13-9

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Manganese dioxide,1313-13-9

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

products, pharmaceutical intermediates, veterinary drug intermediates, dye intermediates, pigments, cosmetic raw materials and chemical reagents. Our company has a group of sales team, service and information feedback vertical integration of perfect

Manganese dioxide CAS:1313-13-9。

Cas:1313-13-9

Min.Order:1 Metric Ton

FOB Price: $1200.0 / 1888.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 1313-13-9 with best price

Cas:1313-13-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: Manganese(IV) oxide Synonyms: Manganese dioxide CAS:1313-13-9 MF: MnO2 Appearance:black powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application: It is used for the preparation of manganese salt, ox

Manganese(IV) oxide

Cas:1313-13-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Manganese dioxide 1313-13-9

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Manganese dioxide

Cas:1313-13-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Manganese dioxide CAS:1313-13-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Manganese dioxide CAS:1313-13-9

Cas:1313-13-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Manganese dioxide

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: Manganese dioxide Synonyms: manganese dioxide, ore of Chapter 26;manganese dioxide, other than natural;Manganese(IV)oxide pn activated carbon;Manganeseoxideactivatedtechngr;Manganeseoxideblackpowder;Manganeseoxideonactivatedcarbon;

Manganese dioxide big supplier with lower price

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Manganese dioxide CAS: 1313-13-9 Specification Item Standard Test Results Identification A.H-NMR:Comply with the structure Complies B.LC-MS:Comply with the s

Factory supply Manganese dioxide

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Manganese dioxide

Cas:1313-13-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Manganese dioxide, MnO2 Manganese (IV) oxide CAS NO.1313-13-9

Cas:1313-13-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Triumph International Development Limilted

Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Air/Courie

Manganese(IV) oxide

Cas:1313-13-9

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Manganese dioxide CAS.1313-13-9

Cas:1313-13-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Manganese dioxide

Cas:1313-13-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Manganese Dioxide

Cas:1313-13-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:beige crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Inte

Manganese dioxide

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: Manganese Dioxide CAS No.:1313-13-9 Molecule Formula:MnO2 Molecule Weight:86.94 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS SPECI

Best Quality Manganese Dioxide with good supplier

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Manganese dioxide

Cas:1313-13-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity Manganese dioxide

Cas:1313-13-9

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Manganese dioxide.99%

Cas:1313-13-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in

Manganese (IV) oxide

Cas:1313-13-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

manganese(II) nitrate

manganese(II) nitrate

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
at 430℃; for 4h;95.5%
In neat (no solvent) Kinetics; byproducts: nitrous gases; investigation of thermal decompn. at 163-196 °C;;
With chlorine In water Irradiation (UV/VIS);
manganese(II) nitrate
172332-99-9

manganese(II) nitrate

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
at 430℃; for 4h;95.5%
manganese(II) perchlorate

manganese(II) perchlorate

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

manganese(ll) chloride

manganese(ll) chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: Cl2, O2; thermal decompn., 190-240°C;A 95%
B 5%
manganese(II)

manganese(II)

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
With fluorine In nitric acid oxidn. of weakly H2SO4-acidic ice-cooled Mn(II)-salt-soln. with F2;;91.5%
With hypochloric acid In not given
With bromine In ammonia oxidn. of ammoniacal Mn(II)-salt-soln. at 50 °C with Br2;;
Mn(N,N'-bis(salicylaldehyde)meso-2,3-butanediimine)

Mn(N,N'-bis(salicylaldehyde)meso-2,3-butanediimine)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)meso-2,3-butanediimine)OH

Mn(N,N'-bis(salicylaldehyde)meso-2,3-butanediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 7%
B 90%
Mn(N,N'-bis(salicylaldehyde)-1,1,2,2-tetramethylethylenediimine)
64593-36-8

Mn(N,N'-bis(salicylaldehyde)-1,1,2,2-tetramethylethylenediimine)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)-1,1,2,2-tetramethylethylenediimine)OH

Mn(N,N'-bis(salicylaldehyde)-1,1,2,2-tetramethylethylenediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 10%
B 90%
2,2′-((1E,1′E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenolmanganese(II)

2,2′-((1E,1′E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenolmanganese(II)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)ethylenediimine)OH

Mn(N,N'-bis(salicylaldehyde)ethylenediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 9%
B 90%
Mn(N,N'-bis(salicylaldehyde)meso-1,2-diphenylethylenediimine)

Mn(N,N'-bis(salicylaldehyde)meso-1,2-diphenylethylenediimine)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)meso-1,2-diphenylethylenediimine)OH

Mn(N,N'-bis(salicylaldehyde)meso-1,2-diphenylethylenediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 9%
B 89%
Mn(N,N'-bis(salicylaldehyde)-1,3-propanediimine) * H2O
58770-12-0

Mn(N,N'-bis(salicylaldehyde)-1,3-propanediimine) * H2O

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)-1,3-propanediimine)OH

Mn(N,N'-bis(salicylaldehyde)-1,3-propanediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 9%
B 88%
Mn(N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine)

Mn(N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Mn(N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine)OH

Mn(N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 10%
B 87%
Mn(N,N'-bis(salicylaldehyde)o-phenylenediimine) * H2O
852529-28-3

Mn(N,N'-bis(salicylaldehyde)o-phenylenediimine) * H2O

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(N,N'-bis(salicylaldehyde)o-phenylenediimine)OH

Mn(N,N'-bis(salicylaldehyde)o-phenylenediimine)OH

Conditions
ConditionsYield
With O2 In pyridine 1 atm O2, refluxing for 10 h (pptn.); collection (filtration); second crop and MnO2 on evapn. of filtrate; elem. anal.;A 14%
B 83%
manganese
7439-96-5

manganese

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

permanganate(VII) ion

permanganate(VII) ion

Conditions
ConditionsYield
In further solvent(s) Electrolysis; in K2CO3 soln., current density 11.4-18.2 A/dm2 at 19°C;A 3.9%
B 81%
In further solvent(s) Electrolysis; in K2CO3 soln., current density 11.4-18.2 A/dm2 at 25-32°C;A 11%
B 67.6%
In further solvent(s) Electrolysis; in K2CO3 soln., current density 11.4-18.2 A/dm2 at 37°C;A 15.1%
B 58.5%
manganese(II) sulfate

manganese(II) sulfate

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
In sulfuric acid aq. H2SO4; Electrolysis; electrolytic deposition from soln. of MnSO4 in aq. H2SO4 at 30 °C (graphite-anode coated with PbO2, c.d. 5 A/dm*dm);; product contains PbO2 (88% MnO2);;75%
With potassium permanganate In water at 80℃; for 16h;
With sodium hydroxide; potassium permanganate In water at 70℃; for 13.5h;
oxygen
80937-33-3

oxygen

manganese(II)

manganese(II)

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
potassium hydroxide; sodium hydroxide In water oxidn. of Mn(2+) in alkaline soln. with oxygen;;70%
iron(III) oxide; lead(II) oxide; tin(IV) oxide In water oxidn. of Mn(2+) in alkaline soln. with oxygen;;
calcium oxide In water oxidn. of Mn(2+) in alkaline soln. with oxygen;;
cobalt(II) chloride; copper dichloride In water oxidn. of Mn(2+) in alkaline soln. with oxygen;;
Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)=Mn(NC5H4NNCHC(CH3)NNC5H4N)

Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)=Mn(NC5H4NNCHC(CH3)NNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*O2*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)(C5H5N)O2

Mn(2+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*O2*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)(C5H5N)O2

C

Mn(2+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)(C5H5N)O

D

Mn(3+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*OH(1-)*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)OH(C5H5N)

Mn(3+)*NC5H4NNC(CH3)C(CH3)NNC5H4N(2-)*OH(1-)*C5H5N=Mn(NC5H4NNC(CH3)C(CH3)NNC5H4N)OH(C5H5N)

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 1 week); filtration (under O2), crystn. (-15°C, 1 week); O2(1-) and OH(1-)complexes by chromy. of filtrate (Al2O3); elem. anal.;A n/a
B 15%
C 40%
D 15%
Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)=Mn(NC5H4NNCHC(CH3)NNC5H4N)

Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)=Mn(NC5H4NNCHC(CH3)NNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHC(CH3)NNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NNCHC(CH3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHC(CH3)NNC5H4N)(C5H5N)O

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 38%
Mn(2+)*NC5H4NNC(C6H5)C(C6H5)NNC5H4N(2-)=Mn(NC5H4NNC(C6H5)C(C6H5)NNC5H4N)

Mn(2+)*NC5H4NNC(C6H5)C(C6H5)NNC5H4N(2-)=Mn(NC5H4NNC(C6H5)C(C6H5)NNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NNC(C6H5)C(C6H5)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNC(C6H5)C(C6H5)NNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NNC(C6H5)C(C6H5)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNC(C6H5)C(C6H5)NNC5H4N)(C5H5N)O

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 37%
Mn(2+)*NC5H4NNCHC(C(CH3)3)NNC5H4N(2-)=Mn(NC5H4NNCHC(C(CH3)3)NNC5H4N)

Mn(2+)*NC5H4NNCHC(C(CH3)3)NNC5H4N(2-)=Mn(NC5H4NNCHC(C(CH3)3)NNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NNCHC(C(CH3)3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHC(C(CH3)3)NNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NNCHC(C(CH3)3)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHC(C(CH3)3)NNC5H4N)(C5H5N)O

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 36%
Mn(2+)*NC5H3BrNNCHCHNNC5H3BrN(2-)=Mn(NC5H3BrNNCHCHNNC5H3BrN)

Mn(2+)*NC5H3BrNNCHCHNNC5H3BrN(2-)=Mn(NC5H3BrNNCHCHNNC5H3BrN)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3BrNNCHCHNNC5H3BrN(2-)*O2*C5H5N=Mn(NC5H3BrNNCHCHNNC5H3BrN)(C5H5N)O2

Mn(2+)*NC5H3BrNNCHCHNNC5H3BrN(2-)*O2*C5H5N=Mn(NC5H3BrNNCHCHNNC5H3BrN)(C5H5N)O2

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 36%
Mn(2+)*NC5H4NNCHCHNNC5H4N(2-)=Mn(NC5H4NNCHCHNNC5H4N)

Mn(2+)*NC5H4NNCHCHNNC5H4N(2-)=Mn(NC5H4NNCHCHNNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NNCHCHNNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHCHNNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NNCHCHNNC5H4N(2-)*O*C5H5N=Mn(NC5H4NNCHCHNNC5H4N)(C5H5N)O

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 35%
Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)

Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*O*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)(C5H5N)O

Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*O*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)(C5H5N)O

C

Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*O2*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)(C5H5N)O2

Mn(2+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*O2*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)(C5H5N)O2

D

Mn(3+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*OH(1-)*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)OH(C5H5N)

Mn(3+)*NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN(2-)*OH(1-)*C5H5N=Mn(NC5H3BrNNC(CH3)C(CH3)NNC5H3BrN)OH(C5H5N)

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 1 week); filtration (under O2), crystn. (-15°C, 1 week); O2(1-) and OH(1-)complexes by chromy. of filtrate (Al2O3); elem. anal.;A n/a
B 35%
C 14%
D 12%
Mn(2+)*NC5H3(CH3)NNCHCHNNC5H3(CH3)N(2-)=Mn(NC5H3(CH3)NNCHCHNNC5H3(CH3)N)

Mn(2+)*NC5H3(CH3)NNCHCHNNC5H3(CH3)N(2-)=Mn(NC5H3(CH3)NNCHCHNNC5H3(CH3)N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3(CH3)NNCHCHNNC5H3(CH3)N(2-)*O2*C5H5N=Mn(NC5H3(CH3)NNCHCHNNC5H3(CH3)N)(C5H5N)O2

Mn(2+)*NC5H3(CH3)NNCHCHNNC5H3(CH3)N(2-)*O2*C5H5N=Mn(NC5H3(CH3)NNCHCHNNC5H3(CH3)N)(C5H5N)O2

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 34%
Mn(2+)*NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N(2-)=Mn(NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N)

Mn(2+)*NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N(2-)=Mn(NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N(2-)*O2*C5H5N=Mn(NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N)(C5H5N)O2

Mn(2+)*NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N(2-)*O2*C5H5N=Mn(NC5H3(CH3)NNC(CH3)C(CH3)NNC5H3(CH3)N)(C5H5N)O2

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 32%
Mn(2+)*NC5H4NN(C6H8)NNC5H4N(2-)=Mn(NC5H4NN(C6H8)NNC5H4N)

Mn(2+)*NC5H4NN(C6H8)NNC5H4N(2-)=Mn(NC5H4NN(C6H8)NNC5H4N)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H4NN(C6H8)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NN(C6H8)NNC5H4N)(C5H5N)O

Mn(2+)*NC5H4NN(C6H8)NNC5H4N(2-)*O*C5H5N=Mn(NC5H4NN(C6H8)NNC5H4N)(C5H5N)O

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 30%
Mn(2+)*NC5H3ClNNCHCHNNC5H3ClN(2-)=Mn(NC5H3ClNNCHCHNNC5H3ClN)

Mn(2+)*NC5H3ClNNCHCHNNC5H3ClN(2-)=Mn(NC5H3ClNNCHCHNNC5H3ClN)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3ClNNCHCHNNC5H3ClN(2-)*O2*C5H5N=Mn(NC5H3ClNNCHCHNNC5H3ClN)(C5H5N)O2

Mn(2+)*NC5H3ClNNCHCHNNC5H3ClN(2-)*O2*C5H5N=Mn(NC5H3ClNNCHCHNNC5H3ClN)(C5H5N)O2

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 30%
manganese(II) chloride tetrahydrate

manganese(II) chloride tetrahydrate

Na16[Na2(water)2Mn2(As2W15O56)2]*50(water)

Na16[Na2(water)2Mn2(As2W15O56)2]*50(water)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Na15[Mn(water)Mn2(As2W15O56)2]*55(water)

Na15[Mn(water)Mn2(As2W15O56)2]*55(water)

Conditions
ConditionsYield
With Na2S2O8; NaCl In water mixing MnCl2*4H2O in aq. NaCl, As compd. at 65°C, mixing for 30 min, addn. of Na2S2O8, heating to 80°C for 2 h; hot filtration, storage at room temp. in air, filtration, washing with 1 M NaCl and EtOH, air drying;A n/a
B 30%
Mn(2+)*NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN(2-)=Mn(NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN)

Mn(2+)*NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN(2-)=Mn(NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN)

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

Mn(2+)*NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN(2-)*O2*C5H5N=Mn(NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN)(C5H5N)O2

Mn(2+)*NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN(2-)*O2*C5H5N=Mn(NC5H3ClNNC(CH3)C(CH3)NNC5H3ClN)(C5H5N)O2

Conditions
ConditionsYield
With O2; pyridine In pyridine dissoln. of Mn-complex (N2-atmosphere), exposing to 1 atm O2; manometricfollowing of O2 uptake (-15°C, 10 h); filtration (under O2), crystn. (-15°C, 1 week); elem. anal.;A n/a
B 28%
manganese(II) perchlorate hexahydrate

manganese(II) perchlorate hexahydrate

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
With air; (CH2N(i-Pr)CH2C9H6N)2; H2O2 In methanol mixt. of ligand and Mn salt (1 equiv.) in MeOH was stirred for 2 d in air at room temp.; filtered; H2O2 added to filtrate;27%
4C48H44O16(4-)*9Mn(2+)*22H2O*4C3H7NO*2CHO2(1-)

4C48H44O16(4-)*9Mn(2+)*22H2O*4C3H7NO*2CHO2(1-)

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
Stage #1: 4C48H44O16(4-)*9Mn(2+)*22H2O*4C3H7NO*2CHO2(1-) at 212℃;
Stage #2: at 302℃;
15.1%
manganese(ll) chloride

manganese(ll) chloride

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
With potassium permanganate In water at 30 - 70℃; for 16h;
With sodium hydroxide; potassium permanganate In water at 70℃; for 13h;
With chlorine In water Irradiation (UV/VIS);
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

C19H24O2
1234357-54-0

C19H24O2

4'-hexyloxybiphenyl-4-carbaldehyde
121118-78-3

4'-hexyloxybiphenyl-4-carbaldehyde

Conditions
ConditionsYield
In dichloromethane100%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium hydroxide
1310-73-2

sodium hydroxide

permanganate(VII) ion

permanganate(VII) ion

Conditions
ConditionsYield
copper(II) sulfate In not given 80-90°C, 20 min; not isolated; UV/VIS spectrometry;98.5%
cobalt(II) nitrate In not given 80-90°C, 20 min; not isolated;73%
silver nitrate In not given 80-90°C, 20 min; not isolated;72%
iron(III) sulfate In not given 80-90°C, 20 min; not isolated;65%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

copper(II) oxide

copper(II) oxide

CuMnO3

CuMnO3

Conditions
ConditionsYield
Stage #1: manganese(IV) oxide; copper(II) oxide In water at 110℃; Green chemistry;
Stage #2: at 180℃; for 3h; Green chemistry;
Stage #3: at 900℃; for 20h; Calcination; Green chemistry;
98%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

(η5-cyclopentadienyl)Co((MeO)C6H3(CH2CH2OH)C6H4N)C(O)CH2CH2

(η5-cyclopentadienyl)Co((MeO)C6H3(CH2CH2OH)C6H4N)C(O)CH2CH2

(η5-cyclopentadienyl)Co((MeO)C6H2(CH2CH2O)C6H4N)C(O)CH2CH2

(η5-cyclopentadienyl)Co((MeO)C6H2(CH2CH2O)C6H4N)C(O)CH2CH2

Conditions
ConditionsYield
In dichloromethane 23°C, 5-30 min; IR, (1)H- and (13)C-NMR spectroscopy, DEPT, MS;96%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

pentafluorobenzenesulfinamide
54556-76-2

pentafluorobenzenesulfinamide

2,3,4,5,6-pentafluorobenzenesulfonamide
778-36-9

2,3,4,5,6-pentafluorobenzenesulfonamide

Conditions
ConditionsYield
In benzene oxidn., in anhydr. C6H6 at 70°C, 16 h;96%
In benzene oxidn., in anhydr. C6H6 at 70°C, 16 h;96%
In benzene in dry benzene 70°C;
In benzene in dry benzene 70°C;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

lithium hydroxide monohydrate
1310-66-3

lithium hydroxide monohydrate

lithium nitrate

lithium nitrate

lithium manganate

lithium manganate

Conditions
ConditionsYield
In melt mixing of LiOH*H2O, LiNO3 and MnO2 by grinding in a mortar, heating at 280°C for 12 h in air, cooling to room temp.; washing with distd. water, centrifuging, drying at 80°C under vac.;95%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

phosphonic Acid
13598-36-2

phosphonic Acid

borax

borax

water
7732-18-5

water

Na(1+)*Mn(3+)*B(3+)*P2O7(4-)*3OH(1-)=NaMn[BP2O7(OH)3]

Na(1+)*Mn(3+)*B(3+)*P2O7(4-)*3OH(1-)=NaMn[BP2O7(OH)3]

Conditions
ConditionsYield
In water High Pressure; MnO2 (5 mmol), B compd. (10 mmol), and H3PO3 (45 mmol) in H2O, mixt. sealed, heated at 200°C for 4 d; washed hot water (80°C), elem. anal.;95%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

dicarbonyl[1-4-η-5-(2-hydroxyethyl)cyclohepta-1,3-diene](triphenyl phosphite)iron
103816-90-6

dicarbonyl[1-4-η-5-(2-hydroxyethyl)cyclohepta-1,3-diene](triphenyl phosphite)iron

Fe(CO)2(P(OC6H5)3)(C7H8(CH2CH2O))
103816-95-1

Fe(CO)2(P(OC6H5)3)(C7H8(CH2CH2O))

Conditions
ConditionsYield
In benzene refluxing MnO2 (overnight, water separator), cooling, addn. Fe-compd., refluxing (20 min); cooling, filtration (Celite), removal solvent;90%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

pyrite

pyrite

oxygen
80937-33-3

oxygen

manganese(II) sulfate

manganese(II) sulfate

Conditions
ConditionsYield
In neat (no solvent) byproducts: Fe2O3; on heating at 800°C for 0.5hours;;89%
In neat (no solvent) byproducts: Fe2O3; on heating at 800°C for 0.5hours;;89%
In neat (no solvent) temp. should not be higher then 700 up to 800°C (thermal decompn. of MnSO4);;
In neat (no solvent) temp. should not be higher then 700 up to 800°C (thermal decompn. of MnSO4);;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

pyrite

pyrite

manganese(II) sulfate

manganese(II) sulfate

Conditions
ConditionsYield
In neat (no solvent) MnO2:pyrite=1:1, 7h, 500°C;; MnSO4 as crust on MnO2;;88%
In neat (no solvent) MnO2:pyrite=1:1, 7h, 500°C;; MnSO4 as crust on MnO2;;88%
In neat (no solvent) best react. conditions: 500°C, 1h;;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Fe(C5H4CHMeCH2CH(NMe2)C5H3CHCHCH2OH)

Fe(C5H4CHMeCH2CH(NMe2)C5H3CHCHCH2OH)

Fe(C5H4CHMeCH2CH(NMe2)C5H3CHCHCHO)

Fe(C5H4CHMeCH2CH(NMe2)C5H3CHCHCHO)

Conditions
ConditionsYield
In dichloromethane (Ar); addn. of MnO2 to CH2Cl2 soln. of ferrocenophane deriv., stirring at room temp. for 12 h; filtration through celite, evapn., elem. anal.;88%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

[Cu(bis[2-(diphenylphosphino)phenyl]ether)2]tetrafluoroborate
947372-37-4

[Cu(bis[2-(diphenylphosphino)phenyl]ether)2]tetrafluoroborate

[Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,O-Ph2PC6H4OC6H4P(O)Ph2)][BF4]
947372-39-6

[Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,O-Ph2PC6H4OC6H4P(O)Ph2)][BF4]

Conditions
ConditionsYield
In dichloromethane under N2; mixt. of Cu complex and MnO2 in CH2Cl2 stirred at room temp. for 2 h; filtered; concd.; Et2O added; crystals collected; elem. anal.;87%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

2,2-bis(3,5-bis(2-isopropoxyphenyl)-1H-pyrazol-1-yl)acetic acid
1414813-59-4

2,2-bis(3,5-bis(2-isopropoxyphenyl)-1H-pyrazol-1-yl)acetic acid

potassium tert-butylate
865-47-4

potassium tert-butylate

bis(2,2-bis(3,5-bis(2-isopropoxyphenyl)-1H-pyrazol-1-yl)acetate)manganese(II)
1414813-66-3

bis(2,2-bis(3,5-bis(2-isopropoxyphenyl)-1H-pyrazol-1-yl)acetate)manganese(II)

Conditions
ConditionsYield
Stage #1: 2,2-bis(3,5-bis(2-isopropoxyphenyl)-1H-pyrazol-1-yl)acetic acid; potassium tert-butylate In tetrahydrofuran at 20℃; for 0.5h; Schlenk technique;
Stage #2: manganese(IV) oxide In tetrahydrofuran for 1h; Reflux;
Stage #3: In tetrahydrofuran at 20℃; for 24h; Schlenk technique;
87%
hydrogenchloride
7647-01-0

hydrogenchloride

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

cesium chloride

cesium chloride

water
7732-18-5

water

CsMnCl3(H2O)2

CsMnCl3(H2O)2

Conditions
ConditionsYield
at 150℃; for 65h;85%
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

pentafluorophenylmercaptoamine
31377-92-1

pentafluorophenylmercaptoamine

2,3,4,5,6-pentafluorobenzenesulfonamide
778-36-9

2,3,4,5,6-pentafluorobenzenesulfonamide

Conditions
ConditionsYield
In benzene oxidn., in anhydr. C6H6 at 70°C, 16 h;83%
In benzene oxidn., in anhydr. C6H6 at 70°C, 16 h;83%
70°C, 16 h;
70°C, 16 h;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

manganese(II) nitrate

manganese(II) nitrate

trans-1,2-Cyclohexanediaminetetraacetic acid
13291-61-7

trans-1,2-Cyclohexanediaminetetraacetic acid

K{Mn(cdta)}*2.5H2O

K{Mn(cdta)}*2.5H2O

Conditions
ConditionsYield
molar ratio of C14H22N2O8:Mn(NO3)2=2:1, 0°C, 0.5-1 h; filtrn. of excess MnO2, addn. of an equal vol. of cold ethanol, then standing for several hours at 0°C, washing with abs. ethanol, drying in vac. at room temp.;80%
molar ratio of C14H22N2O8:Mn(NO3)2=2:1, 0°C, 0.5-1 h; filtrn. of excess MnO2, addn. of an equal vol. of cold ethanol, then standing for several hours at 0°C, washing with abs. ethanol, drying in vac. at room temp.;80%
molar ratio of C14H22N2O8:Mn(NO3)2=2:1, 0°C, 0.5-1 h; filtrn. of excess MnO2, addn. of an equal vol. of cold ethanol, then standing for several hours at 0°C, washing with abs. ethanol;
molar ratio of C14H22N2O8:Mn(NO3)2=2:1, 0°C, 0.5-1 h; filtrn. of excess MnO2, addn. of an equal vol. of cold ethanol, then standing for several hours at 0°C, washing with abs. ethanol;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

isopropyl alcohol
67-63-0

isopropyl alcohol

A

manganese oxide

manganese oxide

manganese hydroxide

manganese hydroxide

kurnakite

kurnakite

Conditions
ConditionsYield
In isopropyl alcohol byproducts: acetone; by a react. of Yb2O3 with i-PrOH at 285°C for 20 h; according to Buslaeva et al. Zh. Neorg. Khim., 2001, vol. 46, no. 3, p. 380; Neorg. Mater., 2002, vol. 38, no. 6, p. 706; XRD studies;A n/a
B 80%
C n/a
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

manganese hydroxide

manganese hydroxide

kurnakite

kurnakite

Conditions
ConditionsYield
With isopropyl alcohol In isopropyl alcohol byproducts: (CH3)2CO, H2O; High Pressure; according to Buslaeva, E. Yu., et al., Zh. Neorg. Khim., 2001, vol. 46, p. 380; in glass ampule powdered oxide placed, i-PrOH added; placed intoautoclave; autoclave was pressurized; furnace temp. raised at 60-70 K/h ; heated at 300°C for 2-6 h; monitored by X-ray diffraction;A 80%
B 20%
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