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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromo-N,N-Dimethylaniline supplier in China

Cas:586-77-6

Min.Order:0 Metric Ton

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 4-Bromo-N,N-dimethylaniline CAS No. 586-77-6 Appearance White sheet crystal

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:10 Gram

FOB Price: $20.0 / 30.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 586-77-6 4-Bromo-N,N-dimethylaniline Manufacturer

Cas:586-77-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 4-Bromo-N,N-dimethylaniline 98% TOP1 supplier in China

Cas:586-77-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

4-Bromo-N,N-dimethylaniline CAS 586-77-6 P-BROMO-N,N-DIMETHYLANILINE CAS no 586-77-6 4-bromo-dimethylaniline 4-Bromo-N,N-dimethylaniline Manufacturer High quality Best price In stock factory CAS 586-77-6 4-Bromo-N,N-dimethylaniline COA TDS pric

4-Bromo-N,N-dimethylaniline CAS 586-77-6 P-BROMO-N,N-DIMETHYLANILINE CAS no 586-77-6 4-bromo-dimethylaniline

Cas:586-77-6

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Bromo-N,N-dimethylaniline Basic information Product Name: 4-Bromo-N,N-dimethylaniline Synonyms: P-BROMO-N,N-DIMETHYLANILINE;N,N-DIMETHYL-P-BROMOANILINE;N-(4-BROMOPHENYL)-N,N-DIMETH

TIANFU-CHEM CAS:586-77-6 4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

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Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 586-77-6 with best price

Cas:586-77-6

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 4-Bromo-N,N-dimethylaniline Synonym: 4-N,N-dimethylaminobromobenzene; 4-Dimethylaminobromobenzene;Intermediate of Mifepristone Cas No.: 586-77-6 Formula: C8H10BrN MW: 200.08 EINECS No.:209-582-2 Density: 1.4±0.1 g/cm3 Boiling p

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

P-BROMO-N,N-DIMETHYLANILINECAS NO.:586-77-6

Cas:586-77-6

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Bromo-N,N-dimethylaniline 586-77-6

Cas:586-77-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

4-Bromo-N,N-dimethylaniline CAS:586-77-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

4-Bromo-N,N-dimethylaniline CAS:586-77-6

Cas:586-77-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Bromo-N,N-dimethylaniline 586-77-6

Cas:586-77-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

586-77-6 factory Buy 4-Bromo-N,N-dimethylaniline Molecular Formula C8H10BrN Molar Mass 200.08 Density 1.3220 Melting Point 52-54 °C (lit.) Boling Point 264 °C (lit.) Flash

586-77-6 factory Buy 4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

Negotiable

Type:Other

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Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity 4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 4-Bromo-N,N-Dimethylaniline CAS No.:586-77-6 Molecule Formula:C8H10BrN Molecule Weight:200.08 Purity: 98.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 4-Bromo-N,N-Dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

4-Bromo-N,N-dimethylaniline Chemical Properties Melting point 52-54 °C (lit.) Boiling point 264 °C (lit.) density 1.3220 refractive index 1.5748 (estimate) Fp >230 °F storage temp. 2-8°C pka 4.23(at 25℃)

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Chinese supplier of 4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Chinese supplier of 4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:0

Negotiable

Type:Other

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Bromo-N,N-dimethylaniline

Cas:586-77-6

Min.Order:0

Negotiable

Type:Manufacturers

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Synthetic route

4-(dimethylamino)benzene-boronic acid
28611-39-4

4-(dimethylamino)benzene-boronic acid

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane at 20℃; for 0.166667h;100%
With 2-bromopentane; sodium hydride In dimethyl sulfoxide at 80℃;
Multi-step reaction with 2 steps
1: toluene / 1 h / 20 °C / Inert atmosphere
2: N-Bromosuccinimide / dichloromethane / 0.17 h / 20 °C
View Scheme
(4-(N,N-dimethylamino)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
171364-78-6

(4-(N,N-dimethylamino)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane at 20℃; for 0.166667h;100%
N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With methanol; tetraethylammonium chloride; bromine In dichloromethane at 35℃; other substituted anilines: regioselectivity of bromination;99%
With methanol; tetraethylammonium chloride; bromine In dichloromethane at 35℃;99%
With hexabromocyclopenta-1,3-diene; triethylamine In acetonitrile for 24h; Ambient temperature;99%
formaldehyd
50-00-0

formaldehyd

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With sodium cyanoborohydride; acetic acid at 0 - 65℃; for 3.42h;99%
With Zr(BH4)2Cl2(dabco)2; zirconium(IV) chloride In methanol; water at 20℃; for 0.1h;95%
With sodium tetrahydroborate In 2,2,2-trifluoroethanol for 4.3h; Reflux;94%
carbon dioxide
124-38-9

carbon dioxide

4-bromo-N-methylaniline
6911-87-1

4-bromo-N-methylaniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry;99%
With sodium tetrahydroborate In 1,4-dioxane at 100℃; under 7500.75 Torr; for 24h; Autoclave;93%
With diphenylsilane; [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene In N,N-dimethyl-formamide at 50℃; under 760.051 Torr; chemoselective reaction;91%
dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With formic acid; triethylamine at 150℃; for 12h; Inert atmosphere; Green chemistry;97%
carbon dioxide
124-38-9

carbon dioxide

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With diphenylsilane; C21H41N3NiP2 In acetonitrile at 120℃; under 2052.14 Torr; for 24h; Autoclave;87%
With dimanganese decacarbonyl; phenylsilane; C29H33N2P In acetonitrile at 100℃; under 750.075 Torr; for 15h;79%
With methanesulfonic acid; hydrogen; tris(acetylacetonato)ruthenium(III); [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In tetrahydrofuran at 140℃; for 24h; Autoclave; Inert atmosphere;89 %Chromat.
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With 0.72 KNaX-BS zeolite at 150℃; for 1h; Reagent/catalyst;85%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

4-bromo-aniline
106-40-1

4-bromo-aniline

A

4-bromo-N-methylaniline
6911-87-1

4-bromo-N-methylaniline

B

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With 0.94 HY-BS zeolite at 150℃; for 1h;A 81%
B 16%
methanol
67-56-1

methanol

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With Cu1-Mo1/TiO2 In neat liquid at 20℃; for 21h; Catalytic behavior; Inert atmosphere; UV-irradiation;80%
With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; for 0.5h; chemoselective reaction;60%
With TiO2 supported nano-Pd(0.3) catalyst In water at 20℃; for 5h; Inert atmosphere; Irradiation; Green chemistry;8 %Chromat.
With zinc oxide-supported iridium catalyst at 150℃; under 3750.38 Torr; for 8h; Inert atmosphere;38 %Chromat.
N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

A

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

B

2,4-dibromo-N,N-dimethylaniline
64230-27-9

2,4-dibromo-N,N-dimethylaniline

Conditions
ConditionsYield
With dihydrogen peroxide; vanadia; potassium bromide In chloroform; water at 24.84℃; under 760.051 Torr;A 75%
B 12%
With [bis(acetoxy)iodo]benzene; lithium bromide In tetrahydrofuran at 20℃; for 0.5h;A 73%
B 18%
With bromine; acetic acid In tetrachloromethane for 0.0833333h; Ambient temperature; other reagents: bromine, bromodimethylsulfonium bromide, bromodimethylsulfonium bromide/acetic acid;A 68%
B 29%
(4-dimethylamino-phenyl)-phosphonous acid dichloride
29972-74-5

(4-dimethylamino-phenyl)-phosphonous acid dichloride

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With pyridine; bromine In dichloromethane at 20℃; for 12h;67%
N,N-dimethylaniline N-oxide
874-52-2

N,N-dimethylaniline N-oxide

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
Stage #1: N,N-dimethylaniline N-oxide With dibromo sulfoxide In tetrahydrofuran at -78℃; for 4h; Inert atmosphere;
Stage #2: With triethylamine In tetrahydrofuran at -78 - 23℃; for 0.75h; Solvent; Temperature; Inert atmosphere; regioselective reaction;
55%
methanol
67-56-1

methanol

4-bromo-N-methylaniline
6911-87-1

4-bromo-N-methylaniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With rhodium(III) chloride hydrate; potassium tert-butylate at 130℃; for 24h; Sealed tube; High pressure;44%
4-bromo-aniline
106-40-1

4-bromo-aniline

methyl iodide
74-88-4

methyl iodide

A

4-bromo-N-methylaniline
6911-87-1

4-bromo-N-methylaniline

B

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 20℃;A 26%
B 20%
With potassium carbonate In tetrahydrofuran at 20℃;A 26%
B 20%
With potassium carbonate In tetrahydrofuranA 26%
B 20%
formaldehyd
50-00-0

formaldehyd

2,4,6-tribromoaniline
147-82-0

2,4,6-tribromoaniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With hydrogenchloride; amalgamated zinc; acetic acid
5,5-dibromobarbituric acid
511-67-1

5,5-dibromobarbituric acid

ethanol
64-17-5

ethanol

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

5,5-dibromobarbituric acid
511-67-1

5,5-dibromobarbituric acid

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With ethanol
4-(dimethylamino)phenyl(phenyl)methanol
7494-77-1

4-(dimethylamino)phenyl(phenyl)methanol

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With chloroform; bromine
With diethyl ether; bromine
2-[(4-bromophenyl)(methyl)amino]acetonitrile
157671-45-9

2-[(4-bromophenyl)(methyl)amino]acetonitrile

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
With sulfuric acid
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

Conditions
ConditionsYield
With 4-methyl-morpholine; tetrahydroxydiboron; 5%-palladium/activated carbon In 1,2-dichloro-ethane at 50℃; for 3h;100%
With lithium aluminium tetrahydride; di-tert-butyl peroxide In tetrahydrofuran for 3h; Irradiation;93%
With isopropyl alcohol at 20℃; for 24h; UV-irradiation; chemoselective reaction;82%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

phenylboronic acid
98-80-6

phenylboronic acid

N,N-dimethyl-4-biphenylamine
1137-79-7

N,N-dimethyl-4-biphenylamine

Conditions
ConditionsYield
With potassium phosphate; naphthidine di(radical cation)s-stabilized Pd nanoparticles In 1,4-dioxane at 80℃; for 8h; Suzuki-Miyaura cross-coupling reaction;100%
With tetrabutylammomium bromide; potassium carbonate; cyclopalladated N-dodecylferrocenylimine In methanol; water at 20℃; for 18h; Suzuki-Miyaura cross-coupling reaction;99%
With potassium carbonate In ethanol; water at 50℃; for 4h; Suzuki-Miyaura Coupling;99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

(E)-3-(4-dimethylaminophenyl)-2-methyl acrylic acid methyl ester
50704-04-6

(E)-3-(4-dimethylaminophenyl)-2-methyl acrylic acid methyl ester

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; Cy2NMe2 In 1,4-dioxane at 20℃; for 24h; Heck coupling;100%
With [(C6H5)PdBr2]2[HPtBu3]2 In 1,4-dioxane at 20℃; for 18h; Heck reaction; Inert atmosphere;97%
With N-Methyldicyclohexylamine; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butylphosphonium tetraphenylborate In tetrahydrofuran at 30℃; for 25h; Product distribution / selectivity;87%
sodium cyanide
773837-37-9

sodium cyanide

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

2-[(4-bromophenyl)(methyl)amino]acetonitrile
157671-45-9

2-[(4-bromophenyl)(methyl)amino]acetonitrile

Conditions
ConditionsYield
With C47H45Cl2N5Ru2(2+)*2F6P(1-); dihydrogen peroxide; acetic acid In methanol at 60℃; for 10h; Inert atmosphere;100%
With dihydrogen peroxide; acetic acid In water at 20℃; for 0.583333h;95%
With oxygen; vanadia; acetic acid In methanol at 60℃; for 2h;92%
Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

(chloromethyl)[4-(dimethylamino)phenyl]dimethylsilane
60457-97-8

(chloromethyl)[4-(dimethylamino)phenyl]dimethylsilane

Conditions
ConditionsYield
Stage #1: 4-bromo-N,N-dimethylaniline With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: Chloro(chloromethyl)dimethylsilane
99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

4-chlorobenzophenone
134-85-0

4-chlorobenzophenone

(4'-(dimethylamino)-[1,1'-biphenyl]-4-yl)(phenyl)methanone
94869-73-5

(4'-(dimethylamino)-[1,1'-biphenyl]-4-yl)(phenyl)methanone

Conditions
ConditionsYield
Stage #1: 4-bromo-N,N-dimethylaniline With lithium
Stage #2: With zinc(II) chloride
Stage #3: 4-chlorobenzophenone; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 8h; Negishi cross-coupling; Further stages.;
99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

chlorobenzene
108-90-7

chlorobenzene

N,N-dimethyl-4-biphenylamine
1137-79-7

N,N-dimethyl-4-biphenylamine

Conditions
ConditionsYield
Stage #1: 4-bromo-N,N-dimethylaniline With lithium
Stage #2: With zinc(II) chloride
Stage #3: chlorobenzene; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Negishi cross-coupling; Further stages.;
99%
2,2,2-trifluoroacetamide
354-38-1

2,2,2-trifluoroacetamide

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

2,2,2-trifluoro-(4-N,N-dimethyphenyl)acetamide
41116-22-7

2,2,2-trifluoro-(4-N,N-dimethyphenyl)acetamide

Conditions
ConditionsYield
With potassium carbonate; N,N`-dimethylethylenediamine; copper(l) iodide In 1,4-dioxane at 75℃;99%
sodium cyanide
773837-37-9

sodium cyanide

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

4-cyano-N,N-dimethylaniline
1197-19-9

4-cyano-N,N-dimethylaniline

Conditions
ConditionsYield
With tri-tert-butyl phosphine; [Pd2(dba)5]; zinc In tetrahydrofuran; acetonitrile at 70℃; for 2h;99%
Diphenylmethane
101-81-5

Diphenylmethane

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

4-benzhydryl-N,N-dimethylaniline
13865-57-1

4-benzhydryl-N,N-dimethylaniline

Conditions
ConditionsYield
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere;99%
With 15-crown-5; NiXantphos; palladium diacetate; sodium hexamethyldisilazane at 23℃; for 12h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube;99%
4-fluorodiphenylmethane
587-79-1

4-fluorodiphenylmethane

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

{4-[(4-Fluoro-phenyl)-phenyl-methyl]-phenyl}-dimethyl-amine
39768-73-5

{4-[(4-Fluoro-phenyl)-phenyl-methyl]-phenyl}-dimethyl-amine

Conditions
ConditionsYield
With 15-crown-5; NiXantphos; palladium diacetate; sodium hexamethyldisilazane at 23℃; for 12h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube;99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

N-(quinolin-8-yl)-3-(trifluoromethyl)benzamide
331627-96-4

N-(quinolin-8-yl)-3-(trifluoromethyl)benzamide

C25H20F3N3O
1436849-50-1

C25H20F3N3O

Conditions
ConditionsYield
With Ru(OAc)2(p-cymene); sodium carbonate; triphenylphosphine In toluene at 130℃; for 15h;99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

p-tolylboronic pinacol ester
195062-57-8

p-tolylboronic pinacol ester

4-dimethylamino-4'-methylbiphenyl
141082-00-0

4-dimethylamino-4'-methylbiphenyl

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium hydroxide In neat (no solvent) at 110℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

4-tolylmagnesium chloride
696-61-7

4-tolylmagnesium chloride

4-dimethylamino-4'-methylbiphenyl
141082-00-0

4-dimethylamino-4'-methylbiphenyl

Conditions
ConditionsYield
With C36H52Br2N4NiSi In tetrahydrofuran at 70℃; for 24h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique;99%
benzo[c]-[1,2,5]thiadiazole-5,6-dicarbonitrile
54512-79-7

benzo[c]-[1,2,5]thiadiazole-5,6-dicarbonitrile

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

4,7-bis(4-(dimethylamino)phenyl)benzo[c][1,2,5]thiadiazole-5,6-dicarbonitrile

4,7-bis(4-(dimethylamino)phenyl)benzo[c][1,2,5]thiadiazole-5,6-dicarbonitrile

Conditions
ConditionsYield
With di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; palladium diacetate; potassium carbonate; Trimethylacetic acid In toluene at 120℃; Inert atmosphere; Sealed tube;99%
With di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; palladium diacetate; potassium carbonate; Trimethylacetic acid In toluene at 120℃; Inert atmosphere; Sealed tube;
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