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Cas:121-69-7
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
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inquiryUnique advantages for N,N-Dimethylaniline CAS 121-69-7 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Liquid Storage:0-6°C Package:180kg/drum Application:Intermediate Transpo
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Cas:121-69-7
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inquiryN,N-Dimethylaniline Basic information Product Name: N,N-Dimethylaniline Synonyms: Aniline, N,N-dimethyl-;Benzenamine,N,N-dimethyl-;Dimethylanilin;Dimethylaniline,N-N-dimethylphenylamine;
Cas:121-69-7
Min.Order:1 Kilogram
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inquiryProduct Description Product name N,N-Dimethylaniline CAS 121-69-7 Assay 99% Appearance Light Yellow Liq
Cas:121-69-7
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Cas:121-69-7
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Cas:121-69-7
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inquiryFactory supply N,N-Dimethylaniline CAS 121-69-7 with favorable priceAppearance:Yellow oily liquid Storage:0-6°C Package:according to customers' requirements Application:Pharmaceutical Intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect
Cas:121-69-7
Min.Order:1 Gram
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inquiryProduct name: N,N-Dimethyl Aniline CAS No.:121-69-7 Molecule Formula:C8H12N Molecule Weight:122.19 Purity: 99.0% Package: 190kg/drum Description:Colorless to light yellow oily liquid Manufacture Standards:Enterprise Standard
Cas:121-69-7
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inquiryProName: N,N-Dimethylaniline CasNo: 121-69-7 Molecular Formula: C8H11N Appearance: colorless to light yellow oily liquid Application: It is an important raw material and in... DeliveryTime: prompt PackAge: according to th
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Min.Order:100 Gram
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inquiryR & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
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Conditions | Yield |
---|---|
With 4-methyl-morpholine; tetrahydroxydiboron; 5%-palladium/activated carbon In 1,2-dichloro-ethane at 50℃; for 3h; | 100% |
With lithium aluminium tetrahydride; di-tert-butyl peroxide In tetrahydrofuran for 3h; Irradiation; | 93% |
With isopropyl alcohol at 20℃; for 24h; UV-irradiation; chemoselective reaction; | 82% |
Conditions | Yield |
---|---|
With 9-borabicyclo[3.3.1]nonane dimer; proazaphosphatrane In tetrahydrofuran-d8 at 90℃; under 750.075 Torr; for 0.166667h; Catalytic behavior; Time; Inert atmosphere; Schlenk technique; Sealed tube; chemoselective reaction; | 100% |
With [Ru(Triphos)(TMM)]; hydrogen; bis(trifluoromethanesulfonyl)amide In tetrahydrofuran at 150℃; under 60006 Torr; for 10h; Temperature; Time; Reagent/catalyst; Pressure; Inert atmosphere; | 99% |
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Autoclave; Green chemistry; | 99% |
(4-(N,N-dimethylamino)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With water In dimethylsulfoxide-d6 at 100℃; for 96h; | 100% |
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With water In dimethylsulfoxide-d6 at 100℃; for 168h; | 100% |
carbon dioxide
N,N’-dimethyl-N,N’-diphenylmethanediamine
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With potassium tungstate; phenylsilane In acetonitrile at 70℃; for 12h; | 100% |
Conditions | Yield |
---|---|
With ferric(III) bromide; 1,2,3,4,5-pentamethylcyclopentadiene; Pyroglutamic acid In 1,2,4-Trimethylbenzene at 200℃; for 36h; Inert atmosphere; | 99% |
With tetrachloromethane; copper(ll) bromide at 180℃; for 6h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; | 99% |
With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,2,4-Trimethylbenzene at 200℃; for 36h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate In dibutyl ether at 100℃; for 8h; Inert atmosphere; Schlenk technique; | 99% |
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; 1,3-bis-(diphenylphosphino)propane; phenylsilane In dibutyl ether at 20℃; for 18h; Schlenk technique; Inert atmosphere; | 98% |
With tetrabutyl ammonium fluoride; HSiPh3 In acetonitrile at 50℃; | 95% |
phenyltrimethylammonium iodide
(4-(dimethylamino)phenyl)zinc(II) chloride
A
N,N-dimethyl-4-biphenylamine
B
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 90℃; for 8h; Negishi coupling reaction; Inert atmosphere; | A 99% B n/a |
Conditions | Yield |
---|---|
With NHC-Pd(II)-Im; potassium tert-butylate at 20℃; for 6h; Inert atmosphere; | 99% |
With bis(1,5-cyclooctadiene)nickel (0); 7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium chloride; potassium tert-butylate In water; toluene at 35℃; for 24h; Catalytic behavior; Reagent/catalyst; Glovebox; Sealed tube; Inert atmosphere; | 99 %Chromat. |
Conditions | Yield |
---|---|
With C27H36Cl2N2Zn at 100℃; for 20h; | 99% |
Conditions | Yield |
---|---|
With phenylsilane In dibutyl ether at 100℃; for 8h; Catalytic behavior; Solvent; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 99% |
With phenylsilane; copper diacetate In dibutyl ether at 80℃; for 8h; Catalytic behavior; Reagent/catalyst; Schlenk technique; Green chemistry; | 97% |
With copper (II) carbonate hydroxide; phenylsilane; 1,4-di(diphenylphosphino)-butane In acetonitrile at 60℃; for 12h; | 74% |
Conditions | Yield |
---|---|
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry; | 99% |
carbon dioxide
N,N’-dimethyl-N,N’-diphenylmethanediamine
A
N,N-dimethyl-aniline
B
N-methylaniline
Conditions | Yield |
---|---|
With diphenylsilane; cesium formate In acetonitrile at 50℃; under 750.075 Torr; Green chemistry; | A 99% B n/a |
Conditions | Yield |
---|---|
With phenylboronic acid In dichloromethane at 20℃; for 0.0833333h; | 98% |
With AFA In dichloromethane at 0 - 21℃; | 97% |
With Amberlite IRA-400; borohydride form; copper(II) sulfate In methanol at 20℃; for 1h; Reduction; | 94% |
Conditions | Yield |
---|---|
palladium at 120℃; for 20h; | A 98% B 98% |
Conditions | Yield |
---|---|
With Raney-Ni at 169.84℃; under 22502.3 Torr; for 5h; Inert atmosphere; Autoclave; | 98% |
With aluminum (III) chloride; water In acetonitrile at 20℃; Reagent/catalyst; Irradiation; | 88% |
With TiO2 supported nano-Pd(0.8) catalyst In water at 20℃; for 15h; Inert atmosphere; Irradiation; Green chemistry; | 76 %Chromat. |
With palladium 10% on activated carbon; potassium tert-butylate at 150℃; for 36h; |
Conditions | Yield |
---|---|
With sodium carbonate In water; dimethyl sulfoxide at 130℃; for 15h; Schlenk technique; Sealed tube; Green chemistry; | 98% |
With methanol; hydrogen at 79.84℃; under 9750.98 Torr; for 1.41667h; Autoclave; |
Conditions | Yield |
---|---|
With disodium telluride In ethanol Heating; | 97% |
With hydrogenchloride bei der Destillation; | |
With potassium hydroxide | |
Multi-step reaction with 2 steps 1: silver oxide 2: Erhitzen View Scheme |
benzyl<2-(N,N-dimethylamino)phenyl>diphenylphosphonium bromide
A
benzyldiphenylphosphine oxide
B
N,N-dimethyl-aniline
C
benzene
Conditions | Yield |
---|---|
With potassium hydroxide In 1,4-dioxane; water at 37.7℃; relative rate constant; other o- and p-substituted phenyl phosphomium salts; other temperature; | A 96% B 96.5% C 3.5% |
Conditions | Yield |
---|---|
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 85℃; for 24h; Inert atmosphere; | 95% |
With potassium hydroxide In N,N-dimethyl-formamide at 110℃; for 18h; Buchwald-Hartwig Coupling; | 73% |
at 250 - 260℃; |
Conditions | Yield |
---|---|
With potassium tert-butylate; N,N-dimethyl-formamide at 35℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; | 95% |
With allyl-trimethyl-silane In cyclohexane Quantum yield; Further Variations:; Solvents; UV-irradiation; | |
With [hmim][ClO4] for 16h; Irradiation; | 78 % Chromat. |
In isopropyl alcohol for 4h; Irradiation; Inert atmosphere; | 99 %Chromat. |
With triethanolamine; water In ethanol for 24h; Irradiation; Glovebox; | 90 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In toluene at 140℃; under 30003 Torr; for 3h; chemoselective reaction; | 95% |
With tetrakis(triphenylphosphine)platinum; phenylsilane; C30H51Cl3Mo3N6PPtS4(1+)*BF4(1-) In tetrahydrofuran at 70℃; under 760.051 Torr; Inert atmosphere; Schlenk technique; chemoselective reaction; | 91% |
Conditions | Yield |
---|---|
With N-methylpyrrolidine zinc borohydride; sulfuric acid In tetrahydrofuran; water at 0 - 10℃; | 94% |
With sodium cyanoborohydride for 2h; | 92% |
With acetic acid; zinc In 1,4-dioxane at 30℃; for 0.5h; | 92% |
(benzyl)di(methyl)(phenyl)ammonium bromide
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With sodium hydrogen telluride In N,N-dimethyl-formamide at 40℃; for 4h; | 94% |
With sodium hydrogen telluride In N,N-dimethyl-formamide at 40℃; for 4h; Mechanism; other phase transfer catalysts; |
A
thallium(III) iodide
B
lithium trifluoroacetate
C
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
In acetone -70°C, several hours, warming to room temp.; redn. of vol. (distn., vac., room temp.), pptn. on addn. of water, crystn. (overnight), dissolving (acetone), pptn. on pentane addn., crystn. (several days); | A 94% B n/a C n/a |
Conditions | Yield |
---|---|
With [Ru(Triphos)(TMM)]; hydrogen; bis(trifluoromethanesulfonyl)amide In tetrahydrofuran at 150℃; under 60006 Torr; for 15h; Inert atmosphere; | 94% |
With [RhCl{κ3-P,C,P′=C(NCH2PCy2)2C10H6}]; phenylsilane In toluene at 90℃; for 16h; Schlenk technique; | 93% |
With hydrogen In hexane at 140℃; under 15001.5 - 60006 Torr; for 7h; Inert atmosphere; Autoclave; | 92% |
carbon dioxide
N-methylaniline
A
N,N-dimethyl-aniline
B
N-methyl-N-phenylformamide
Conditions | Yield |
---|---|
With phenylsilane In N,N-dimethyl acetamide at 60℃; for 4h; Time; Sealed tube; | A 94% B 8% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 110℃; under 760.051 Torr; for 48h; Mechanism; Solvent; Reagent/catalyst; Schlenk technique; | A 92% B 8% |
With phenylsilane; C23H23O2P In acetonitrile at 100℃; under 15001.5 Torr; for 24h; | A 8% B 91% |
4-(dimethylamino)benzene-boronic acid
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
With water In dimethyl sulfoxide at 100℃; for 2h; Reagent/catalyst; Solvent; Enzymatic reaction; | 94% |
Multi-step reaction with 2 steps 1: dimethyl sulfoxide / toluene / 0.5 h / 120 °C / Dean-Stark 2: water / dimethylsulfoxide-d6 / 168 h / 100 °C View Scheme | |
Multi-step reaction with 2 steps 1: N,N-dimethyl-formamide / 1 h / 120 °C / Molecular sieve; Inert atmosphere 2: water / dimethylsulfoxide-d6 / 168 h / 100 °C View Scheme | |
Multi-step reaction with 2 steps 1: toluene / 1 h / 20 °C / Inert atmosphere 2: water / dimethylsulfoxide-d6 / 96 h / 100 °C View Scheme |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In 2,2,2-trifluoroethanol for 1.1h; Reflux; | 93% |
Stage #1: formaldehyd; N-methylaniline With hydrogenchloride In methanol at 20℃; Stage #2: With N-methylpiperidine zinc borohydride In methanol at 20℃; for 0.25h; | 88% |
With N-methylpyrrolidine zinc borohydride; sulfuric acid In tetrahydrofuran; water at 0 - 10℃; for 0.333333h; | 88% |
Conditions | Yield |
---|---|
With 4a-FlEt-OOH In 1,4-dioxane at 30℃; Rate constant; | 100% |
With oxygen; ruthenium trichloride In 1,2-dichloro-ethane at 20℃; under 760 Torr; for 8h; | 98% |
With dihydrogen peroxide In acetonitrile at 80℃; under 760.051 Torr; for 4h; | 98% |
Conditions | Yield |
---|---|
With bis(trimethylsilyl)sulphate at 170℃; for 5h; | 100% |
Stage #1: N,N-dimethyl-aniline With bis(trimethylsilyl)sulphate at 170℃; for 4h; Stage #2: With water | 96% |
With bis(trimethylsilyl)sulphate at 170℃; for 4h; | 85% |
Conditions | Yield |
---|---|
With bismuth(III) nitrate; sulfuric acid; silica gel at 25℃; for 0.0333333h; | 100% |
With sodium nitrate In neat (no solvent) at 20℃; for 0.05h; Green chemistry; | 98% |
With 2-chloro-1-methyl-pyridinium iodide; water; silica gel; sodium nitrite In hexane at 20℃; for 0.75h; regioselective reaction; | 85% |
Conditions | Yield |
---|---|
In methanol for 2h; Ambient temperature; | 100% |
(4-Benzotriazol-1-ylmethyl-phenyl)-diethyl-amine
N,N-dimethyl-aniline
C19H26N2
Conditions | Yield |
---|---|
In acetic acid for 3h; Heating; | 100% |
benzoyl chloride
N,N-dimethyl-aniline
methyl 5-oxopyrrolidine-2-carboxylate
N-methyl-N-phenyl-benzamide
Conditions | Yield |
---|---|
Product distribution; | 100% |
N,N-dimethyl-aniline
bis(2-amino-4-nitrophenyl) ether
Conditions | Yield |
---|---|
Stage #1: bis(2-amino-4-nitrophenyl) ether With hydrogenchloride; sodium nitrite at 0 - 5℃; for 1h; Stage #2: N,N-dimethyl-aniline With hydrogenchloride In acetate buffer pH=5; | 100% |
Conditions | Yield |
---|---|
In benzene at 23℃; for 48h; | 100% |
Conditions | Yield |
---|---|
In toluene Product distribution / selectivity; | 100% |
In neat (no solvent) addn. of diborane to amine at liquid N2 temp., keeping at -111°C, -78°C and 0°C consecutively, stirring at 0°C for 4-6 h (vacuum line); cooling to -78°C, removal of B2H6 by distn.; | |
In neat (no solvent) at 0°C;; | |
In neat (no solvent) at room temp.;; |
[Cp*Ru(CH3CN)3]OTf
N,N-dimethyl-aniline
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: CH3CN; under N2; addn. of Ru-complex to N,N-dimethylaniline and THF (benzene-free), mixt. stirred (30°C); addn. of hexane, solid filtered, washed twice (hexane), dried (vac.), elem. anal.; | 100% |
[((CH3)3CC(NC(CH3)3)2)GaCH3](1+)*[B(C6F5)4](1-)=[((CH3)3CC(NC(CH3)3)2)GaCH3][B(C6F5)4]
N,N-dimethyl-aniline
[((CH3)3CC(NC(CH3)3)2)Ga(CH3)(N(CH3)2C6H5)](1+)*[B(C6F5)4](1-)=[((CH3)3CC(NC(CH3)3)2)Ga(CH3)(N(CH3)2C6H5)][B(C6F5)4]
Conditions | Yield |
---|---|
In further solvent(s) under N2; in C6D5Cl, 23°C, 10 min; not isolated; NMR; | 100% |
Conditions | Yield |
---|---|
With C47H45Cl2N5Ru2(2+)*2F6P(1-); dihydrogen peroxide; acetic acid In methanol at 60℃; for 8h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; | 100% |
With dihydrogen peroxide; acetic acid In water at 20℃; for 0.416667h; Reagent/catalyst; Solvent; | 98% |
With C22H26N2O5U; dihydrogen peroxide; acetic acid In methanol at 20℃; for 8h; Catalytic behavior; Reagent/catalyst; Solvent; Irradiation; | 97% |
trifluorormethanesulfonic acid
N,N-dimethyl-aniline
N,N-dimethylphenylammonium trifluoromethanesulfonate
Conditions | Yield |
---|---|
In hexane at 20℃; for 1h; | 100% |
N,N-dimethyl-aniline
3-iodo-N,N-dimethylaniline
Conditions | Yield |
---|---|
Stage #1: N,N-dimethyl-aniline With (TMEDA)Na(TMP)(t-Bu)Zn(t-Bu) In hexane at 20℃; Inert atmosphere; Stage #2: With iodine Inert atmosphere; | 100% |
N,N-dimethyl-aniline
chromium(0) hexacarbonyl
(N,N-dimethylaniline)tricarbonylchromium
Conditions | Yield |
---|---|
In decalin byproducts: CO; 3.5:1 mixture of arene and Cr(CO)6 in solvent purged for 20 min with Ar, evacuated for 20 min, mixture refluxed, cooled to 20°C, cooled to -18°C under argon, reaction time 5.5 h; filtered off, dissolved in benzene, filtered through Kieselguhr, concentrated, light petroleum added, crystn. at -18°C, complexes eluted with benzene/ethyl acetate, elem. anal., NMR; | 99.5% |
In neat (no solvent) boiling;; | 91% |
In neat (no solvent) boiling;; | 91% |
Conditions | Yield |
---|---|
With aluminum (III) chloride; sodium pyrophosphate; hydrazine hydrate; pyrographite; ammonium hydroxide; 1-butyl-3-methylimidazolium chloride; sodium hydroxide at 130℃; for 0.0222222h; Reagent/catalyst; Temperature; | 99.4% |
With acetic acid; β-naphthol In ethanol at 20℃; for 12h; Mannich type Friedel-Crafts reaction; | 90% |
With acetic acid In water | 82% |
N,N-dimethyl-aniline
A
2-dimethylamino-benzenesulfonic acid
B
p-N,N-dimethylaminobenzenesulfonic acid
Conditions | Yield |
---|---|
With chlorosulfonic acid In 1,2-dichloro-benzene at 50℃; for 1h; Product distribution; Kinetics; Mechanism; E(activ), oth. temperatures; | A 0.6% B 99.4% |
With sulfur trioxide In 1,2-dichloro-ethane at 5℃; Rate constant; Thermodynamic data; Product distribution; oth. temperature, E(activ.), var. ratios of reactants; | |
With sulfuric acid In 1,2-dichloro-benzene at 180℃; Kinetics; Thermodynamic data; Equilibrium constant; variation of molar ratio and temperature, Ea, ΔGo, ΔHo, ΔSo; | |
With sulfuric acid In 1,2-dichloro-benzene at 24.9℃; Thermodynamic data; Mechanism; Activation Free Energy, Enthalpy, Entropy of sulfonation and desulfonation; |
N,N-dimethyl-aniline
4-amino-3-nitrobenzoic acid
4'-dimethylamino-2-nitroazobenzene-4-carboxylic acid
Conditions | Yield |
---|---|
Stage #1: 4-amino-3-nitrobenzoic acid With hydrogenchloride; sodium nitrite In water; acetic acid at 15 - 20℃; for 0.25h; Stage #2: N,N-dimethyl-aniline In water; acetic acid at 0 - 5℃; | 99.4% |
ethenetetracarbonitrile
N,N-dimethyl-aniline
2-(4-dimethylaminophenyl)ethylene-1,1,2-tricarbonitrile
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20 - 25℃; for 0.0833333h; Sonication; | 99% |
In N,N-dimethyl-formamide at 50 - 60℃; for 0.5h; | 95% |
With choline chloride; urea at 35℃; for 0.0833333h; Reagent/catalyst; Solvent; Green chemistry; | 89% |
With N,N-dimethyl-formamide | |
In N,N-dimethyl-formamide |
allyl iodid
N,N-dimethyl-aniline
N-allyl-N,N-dimethylbenzenaminium iodide
Conditions | Yield |
---|---|
at 30℃; | 99% |
Conditions | Yield |
---|---|
With methanol; tetraethylammonium chloride; bromine In dichloromethane at 35℃; other substituted anilines: regioselectivity of bromination; | 99% |
With methanol; tetraethylammonium chloride; bromine In dichloromethane at 35℃; | 99% |
With hexabromocyclopenta-1,3-diene; triethylamine In acetonitrile for 24h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With iodine at 30℃; for 12h; Green chemistry; | 99% |
With tetrafluoroboric acid; [bis(pyridine)iodine]+ tetrafluoroborate In diethyl ether; dichloromethane for 0.1h; Ambient temperature; | 98% |
With iodine In 1,4-dioxane; pyridine at 0 - 20℃; | 98% |
N,N-dimethyl-aniline
N,N-Dimethylaniline hydroiodide
Conditions | Yield |
---|---|
With hydrogen iodide In 1,4-dioxane; water at 0 - 20℃; for 12h; | 99% |
With hydrogen iodide |
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