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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl acetate Manufacturer/High quality/Best price/In stock

Cas:79-20-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl Acetate supplier in China

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Methyl acetate Manufacturer/

Cas:79-20-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

Good products, good service. We have professional sales team working on sales service for 15 years. Good products can win good market but can not stand long without good service. We have strict sales regulation and service procedure to make sure yo

Methyl acetate

Cas:79-20-9

Min.Order:14 Metric Ton

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

Methyl acetate CAS No: 79-20-9 Molecular Structure£º Specifications Item Details

Methyl acetate

Cas:79-20-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--79-20-9--Methyl acetate factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relations

TIANFUCHEM--79-20-9--Methyl acetate factory price

Cas:79-20-9

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Ality Chemical Corporation

Product Name: Methyl acetate Synonyms: Acetic acid methyl ester

Factory Supply Methyl acetate

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Jinan Finer Chemical Co., Ltd

Product Description Product name Methyl acetate CAS 79-20-9 Assay 99% Appearance Colorless liquid

Methyl acetate

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product Name: Methyl acetate Synonyms: Acetic acid methyl ester CAS RN.: 79-20-9 EINECS: 201-185-2 Molecular Weight:

Methyl acetate

Cas:79-20-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 79-20-9 Methyl acetate with best price

Cas:79-20-9

Min.Order:10 Gram

Negotiable

Type:Other

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

Methyl acetate Aliphatic carboxylic acid esters

Cas:79-20-9

Min.Order:1 Kilogram

FOB Price: $60.0 / 80.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:79-20-9

Cas:79-20-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: Methyl acetate Synonyms: Metile (acetato di);metile(acetatodi);octanmetylu;octanmetylu(polish);Tereton;ACETIC ACID METHYL ESTER;METHYL ACETATE;LABOTEST-BB LT00785639 CAS: 79-20-9 MF: C3H6O2 MW: 74.08 EINECS: 201-185-2 Pro

Methyl acetate big supplier with lower price

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Methylacetate CAS:79-20-9 Specification Welcome to contact us to get complete COA. Shanghai Lonwin Chemical Co.,Ltd is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high qu

Factory supply Methylacetate

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Methyl Acetate CAS NO.79-20-9

Cas:79-20-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl acetate

Cas:79-20-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

METHYL ACETATE

Cas:79-20-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methyl Acetate

Cas:79-20-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:200kg/drum, or as per your request. Application:Used as Pharmaceutical Intermedia

Methyl acetate

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Siwei Development Group Ltd.

Product name: Methyl Acetate CAS No.: 79-20-9 Molecule Formula:C3H6O2 Molecule Weight:74.08 Purity: 99.0% Package: 190kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTI

Lower Price Methyl Acetate

Cas:79-20-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Wuhan Fortuna Chemical Co.,Ltd

CAS:79-20-9 EINECS:201-185-2 MW:74.08 MF:C3H6O2 Melting point:-98 °C Boiling point:57-58 °C(lit.) Appearance:colorless liquid Package:200kg/Steel drum Transportation:by sea Port:Shanghai

Methyl acetate

Cas:79-20-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Nanjing Yuance Industry&Trade Co., Ltd.

Product Name:Natural Methyl Acetate CAS: 79-20-9 MF: C3H6O2 MW: 74.08 EINECS: 201-185-2 Purity:99% FEMA:2676 mp -98 °C bp 57-58 …

Methyl acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Manufacturers

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Other

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Methyl Acetat

Cas:79-20-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

Methyl?acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methyl acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 79-20-9 with competitive price

Cas:79-20-9

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methyl acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Methyl Acetate

Cas:79-20-9

Min.Order:0

Negotiable

Type:Other

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Synthetic route

methanol
67-56-1

methanol

acetic acid
64-19-7

acetic acid

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
phosphotungstic acid at 65 - 70℃;100%
With 4-cyclopentyl-2,2,6,6-tetramethyl-[1,4,2,6]oxazadisilinan-4-ium tetrafluroborate for 0.333333h; Microwave irradiation;99%
With iodine In toluene for 6h; Ionic liquid; Reflux;92%
methanol
67-56-1

methanol

ethyl acetate
141-78-6

ethyl acetate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Temperature; Inert atmosphere;100%
K2CO3 + 5percent Carbowax 6000 at 170℃; Product distribution; various catalysts, various amounts of catalysts;54 % Chromat.
With trans-5,15-bis(2-hydroxy-1-naphthyl)octaethylporphyrine; silver perchlorate In benzene at 50℃; without AgClO4, other catalysts;
3-O-acetyl-1,2,5,6-di-isopropylidene-α-D-glucofuranose
29586-98-9

3-O-acetyl-1,2,5,6-di-isopropylidene-α-D-glucofuranose

B

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With n-butylstannoic acid In methanol at 65.4℃; for 2h;A 100%
B n/a
methanol
67-56-1

methanol

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With triethylamine at 20℃; under 8250660 Torr; for 2h; Product distribution;A 100%
B n/a
methanol
67-56-1

methanol

Isopropyl acetate
108-21-4

Isopropyl acetate

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With triethylamine at 20℃; under 8250660 Torr; for 2h; Product distribution;A 100%
B n/a
methanol
67-56-1

methanol

prednisolone 21-acetate
52-21-1

prednisolone 21-acetate

A

prednisolon
50-24-8

prednisolon

B

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With triethylamine at 20℃; under 8250660 Torr; for 2h; Product distribution;A n/a
B 100%
triacetylglycerol
102-76-1

triacetylglycerol

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With C16H25N3O2S In methanol at 23℃; for 24h;99%
methanol
67-56-1

methanol

N-acetyl-1,3-oxazol-2-one
60759-49-1

N-acetyl-1,3-oxazol-2-one

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
for 10h; Ambient temperature;98%
acetone
67-64-1

acetone

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With triethylamine at 160℃; for 5h; Autoclave; Green chemistry;98%
Acetyl bromide
506-96-7

Acetyl bromide

methoxytriphenylmethane
596-31-6

methoxytriphenylmethane

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

bromo-triphenyl-methane
596-43-0

bromo-triphenyl-methane

Conditions
ConditionsYield
at 70℃; for 13h;A 81%
B 97%
at 70℃; for 13h;A 0.65 g
B 3.39 g
sodium acetate
127-09-3

sodium acetate

dimethyl sulfate
77-78-1

dimethyl sulfate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
at 140℃; distillation throuh a vigreux column;95%
4-methylbenzenesulfenic acid methyl ester
67764-21-0

4-methylbenzenesulfenic acid methyl ester

cyclohexene
110-83-8

cyclohexene

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

p-Tolylchlorcyclohexensulfid
29903-51-3

p-Tolylchlorcyclohexensulfid

Conditions
ConditionsYield
With acetyl chloride at 0℃;A n/a
B 95%
methanol
67-56-1

methanol

sodium acetate
127-09-3

sodium acetate

A

ethane
74-84-0

ethane

B

acetic acid methyl ester
79-20-9

acetic acid methyl ester

C

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
In methanol byproducts: C2H4, CO2; Electrolysis; electrolysis of 3 % soln. of NaCH3CO2 in methanol using polished Pt sheet as anode, no formation of O, HCO2H or CH2O, yield of C2H6 does not depend on temperature;;A 95%
B n/a
C n/a
In methanol byproducts: C2H4, CO2; Electrolysis; electrolysis of 3 % soln. of NaCH3CO2 in methanol using polished Pt sheet as anode, no formation of O, HCO2H or CH2O, yield of C2H6 does not depend on temperature;;A 95%
B n/a
C n/a
3,4-dihydronaphthalen-1-yl acetate
19455-84-6

3,4-dihydronaphthalen-1-yl acetate

tributyltin methoxide
1067-52-3

tributyltin methoxide

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

4-tri(n-butyl)stannyloxy-1,2-dihydronaphthalene

4-tri(n-butyl)stannyloxy-1,2-dihydronaphthalene

Conditions
ConditionsYield
at 20℃; for 12h; Inert atmosphere;A n/a
B 95%
methyl chloroacetate
96-34-4

methyl chloroacetate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With sodium tetrahydroborate; tin(ll) chloride In tetrahydrofuran for 2h; Heating;94%
With sodium hydrogensulfide; tin(ll) chloride In tetrahydrofuran; water for 2h; other sulfur and aromatic compounds as hydro-dehalogenation agents; Yield given;
methanol
67-56-1

methanol

acetyl chloride
75-36-5

acetyl chloride

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With zinc(II) oxide at 20℃; for 0.166667h;94%
With 1,4-diaza-bicyclo[2.2.2]octane for 0.0333333h;92%
In acetonitrile at 0 - 25℃; Kinetics; Mechanism; also in the presence of NEt4Cl;
O-methyl selenoacetate
64713-88-8

O-methyl selenoacetate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With oxygen; methyl iodide; triethylphosphine In benzene at 50℃; for 5h;93%
With oxygen; methyl iodide; triethylphosphine In benzene at 50℃; for 5h; Mechanism; other O-alkyl selenoesters; the other products in the anaerobic conditions;93%
2-(1-ethoxy-ethylidene)-indan-1,3-dione
39560-91-3

2-(1-ethoxy-ethylidene)-indan-1,3-dione

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

Phthalonsaeure-anhydrid
6328-17-2

Phthalonsaeure-anhydrid

Conditions
ConditionsYield
With ozone In dichloromethane at -70℃;A n/a
B 92%
Isopropenyl acetate
108-22-5

Isopropenyl acetate

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

tributyltin methoxide, acetonyltributyltin

tributyltin methoxide, acetonyltributyltin

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

1-(2-methylphenyl)acetone
51052-00-7

1-(2-methylphenyl)acetone

Conditions
ConditionsYield
dichlorobis(tri-O-tolylphosphine)palladium In toluene at 100℃; for 5h;A n/a
B 91%
trans-MeOIr(CO)(PPh3)2
94070-38-9

trans-MeOIr(CO)(PPh3)2

A

HIrCl2(CO)(PPh3)2
17000-10-1

HIrCl2(CO)(PPh3)2

B

CH3C(O)IrCl2(CO){P(C6H5)3}2
33394-10-4

CH3C(O)IrCl2(CO){P(C6H5)3}2

C

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With acetyl chloride In benzene soln. placed in a pressure tube fitted with a Teflon stopcock, degassed (vac.), acetyl chloride distilled onto the soln., stirred (1 h); solvent removed by vac. distillation; relation of yield to by-product yield depending on the purity of CH3COCl used and on the care of work up;A n/a
B n/a
C 91%
(acetoxymethyl)dimethylmethoxysilane
18162-90-8

(acetoxymethyl)dimethylmethoxysilane

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

2,2,5,5-tetramethyl-1,4-dioxa-2,5-disilacyclohexane
5895-82-9

2,2,5,5-tetramethyl-1,4-dioxa-2,5-disilacyclohexane

Conditions
ConditionsYield
With dioctyltin(IV) oxide at 120℃; under 52.5053 Torr; for 3h; Concentration; Reagent/catalyst; Inert atmosphere;A 17.9 g
B 91%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

acetic acid methyl ester; deprotonated form
64723-96-2

acetic acid methyl ester; deprotonated form

Conditions
ConditionsYield
With helium; methoxide-d3 anion at 24.85℃; under 0.5 Torr; Kinetics; proton transfer; flowing afterglow;100%
With trifluoromethanide In gas Rate constant; Thermodynamic data; ΔH0, nucleophilic reactions of F3C- at sp2 and sp3 carbon in the gas phase, competitive reactions;
With fluoride In gas production of ionic species in an ion cyclotron spectrometer for laser photodissociation studies;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

acrolein
107-02-8

acrolein

3-hydroxypent-4-enoic acid methyl ester
80959-53-1

3-hydroxypent-4-enoic acid methyl ester

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: acrolein In tetrahydrofuran for 0.0833333h;
100%
With lithium diisopropyl amide 1.) THF, -95 deg C, 3 min, 2. ) THF, -95 deg C; Multistep reaction;
With lithium diisopropyl amide 1.) THF, hexanes, -78 deg C, 50 min, 2.) THF, hexanes, -78 deg C, 5 min; Yield given. Multistep reaction;
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; Inert atmosphere;
Stage #2: acrolein In tetrahydrofuran; hexane for 0.0833333h; Inert atmosphere;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Temperature; Inert atmosphere; Molecular sieve;100%
1,3-dicyclohexyl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 1h;95%
With 4 A molecular sieve; 1,3-di-tBu-2,3-dihydroimidazole carbene-polydimethylsiloxane at 20℃; for 6h;95%
trans-dichloro(ethylene)(2,4,6-trimethylpyridine)platinum
52341-13-6, 12264-20-9

trans-dichloro(ethylene)(2,4,6-trimethylpyridine)platinum

acetic acid methyl ester
79-20-9

acetic acid methyl ester

trans-dichloro(methyl acetate)(2,4,6-trimethylpyridine)platinum(II)
91068-21-2

trans-dichloro(methyl acetate)(2,4,6-trimethylpyridine)platinum(II)

Conditions
ConditionsYield
In acetic acid methyl ester byproducts: ethylene; Irradiation (UV/VIS);100%
In acetic acid methyl ester Irradiation (UV/VIS); the Pt-complex dissolved in methyl acetate was introduced into a muffshaped Schlenk tube surrounding a 125-W medium-pressure mercury lamp, Philips HPK 125, irradn. for 15 min at room temp., λ<310 nm was eliminated by Pyrex filter; the solvent was removed under reduced pressure at -30°C, the solid was recrystd. at -30°C in pentane-CH2Cl2;85%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

C39H52O5Si
1365268-33-2

C39H52O5Si

C42H58O7Si
1365268-48-9

C42H58O7Si

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: C39H52O5Si In tetrahydrofuran at -78℃;
100%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

(4R,5R,6R)-7-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-4,6-dimethylhept-2-ynoic acid ethyl ester

(4R,5R,6R)-7-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-4,6-dimethylhept-2-ynoic acid ethyl ester

C26H40O6Si

C26H40O6Si

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere;
Stage #2: (4R,5R,6R)-7-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-4,6-dimethylhept-2-ynoic acid ethyl ester In tetrahydrofuran; hexane at -78 - 20℃; for 18h; Inert atmosphere;
100%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

(4R,5R,6R)-7-benzyloxy-5-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-2-ynoic acid ethylester

(4R,5R,6R)-7-benzyloxy-5-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-2-ynoic acid ethylester

C27H32O6

C27H32O6

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere;
Stage #2: (4R,5R,6R)-7-benzyloxy-5-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-2-ynoic acid ethylester In tetrahydrofuran; Hexachlorobutadiene at -78 - 20℃; for 18h; Inert atmosphere;
100%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

(S)-(thiazol-2-ylmethilidene)-p-toluenesulfinamide
1138161-37-1

(S)-(thiazol-2-ylmethilidene)-p-toluenesulfinamide

C14H16N2O3S2

C14H16N2O3S2

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; diastereoselective reaction;100%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

propan-1-ol-3-amine
156-87-6

propan-1-ol-3-amine

N-(3-hydroxypropyl)acetamide
10601-73-7

N-(3-hydroxypropyl)acetamide

Conditions
ConditionsYield
for 12h; Heating;99%
In toluene for 120h; Heating / reflux;93%
With Merrifield resin-supported N3=P(MeNCH2CH2)3N In tetrahydrofuran at 23 - 25℃; Inert atmosphere;74%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

ethanolamine
141-43-5

ethanolamine

2-acetylaminoethanol
142-26-7

2-acetylaminoethanol

Conditions
ConditionsYield
With N,N'-Mes2imidazol-2-ylidene In tetrahydrofuran at 23℃; for 24h;99%
With 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In acetonitrile at 20℃; for 15h; Schlenk technique; Inert atmosphere;97%
With Merrifield resin-supported N3=P(MeNCH2CH2)3N In tetrahydrofuran at 23 - 25℃; Inert atmosphere;66%
for 6h; Acylation; Heating;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

A

acetic acid methyl ester; deprotonated form
64723-96-2

acetic acid methyl ester; deprotonated form

B

acetamide anion
63285-19-8

acetamide anion

Conditions
ConditionsYield
With helium; amide at 24.85℃; under 0.5 Torr; Kinetics; Substitution; proton transfer; flowing afterglow;A 99%
B 1%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

(2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanoxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal

(2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanoxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal

5-[2-[3-(2-bromo-allyl)-oxiranyl]-2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-hydroxy-4-methyl-hex-5-enoic acid methyl ester

5-[2-[3-(2-bromo-allyl)-oxiranyl]-2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-hydroxy-4-methyl-hex-5-enoic acid methyl ester

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: (2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanoxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal In tetrahydrofuran; hexane at -78℃; for 0.333333h; Inert atmosphere;
99%
(2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanyloxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal

(2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanyloxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal

acetic acid methyl ester
79-20-9

acetic acid methyl ester

(4R,7S)-7-[(2R,3R)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-5-methylene-heptanoic acid methyl ester

(4R,7S)-7-[(2R,3R)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-5-methylene-heptanoic acid methyl ester

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 0.25h; Metallation;
Stage #2: (2R,5S,6S,7S)-9-bromo-5-(tert-butyldimethylsilanyloxy)-6,7-epoxy-2-methyl-3-methylene-dec-9-enal In tetrahydrofuran for 0.166667h; Addition; aldol reaction; Further stages.;
99%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

(-)-(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalene-2-carbaldehyde
1187676-83-0

(-)-(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalene-2-carbaldehyde

3-[(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalen-2-yl]-3-hydroxy-propionic acid methyl ester
1187676-94-3

3-[(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalen-2-yl]-3-hydroxy-propionic acid methyl ester

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 0.333333h; Inert atmosphere;
Stage #2: (-)-(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalene-2-carbaldehyde In tetrahydrofuran; hexane
99%
Stage #1: acetic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere;
Stage #2: (-)-(1S,2R,3S,4aR,5S,8S,8aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3,8-dimethyl-5-triisopropylsilanyloxy-decahydro-naphthalene-2-carbaldehyde In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

ethyl 2-diazo-3-oxobutanoate
2009-97-4

ethyl 2-diazo-3-oxobutanoate

ethyl 2-diazo-3-hydroxy-3-methyl-4-(methoxycarbonyl)butanoate
1443778-65-1

ethyl 2-diazo-3-hydroxy-3-methyl-4-(methoxycarbonyl)butanoate

Conditions
ConditionsYield
Stage #1: acetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: ethyl 2-diazo-3-oxobutanoate In tetrahydrofuran; hexane at -70℃; for 1.5h; Inert atmosphere;
Stage #3: With acetic acid In tetrahydrofuran; hexane at -70 - 20℃; for 0.333333h; Inert atmosphere;
99%
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