CAS No.108-22-5,Isopropenyl acetate Suppliers,MSDS download

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Amadis Chemical offer CAS#108-22-5;CAT#A801825

Cas:108-22-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

: 64-19-7
acetic acid

: 67-64-1
acetone

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
Stage #1: acetic acid In water at 800℃; Stage #2: acetone In water for 1h; Temperature;	99.5%

: 187737-37-7
propene

: 3375-31-3
palladium diacetate

A: 108-22-5
Isopropenyl acetate

B: 591-87-7
Allyl acetate

C: 3249-50-1
1-propenyl acetate

Conditions

Conditions	Yield
With p-benzoquinone; bis(triphenylphosphoranylidene)-ammonium acetate In acetic acid at 25℃; under 760 Torr; for 3h; Oxidation; acylation;	A 0.986 mol B 0.009% C 0.005%
With p-benzoquinone; bis(triphenylphosphoranylidene)-ammonium acetate In chloroform at 25℃; under 760 Torr; for 3h; Oxidation; acylation;	A 0.01% B 0.99 mol C 0.01%

...Expand

: 64-19-7
acetic acid

: 74-99-7
prop-1-yne

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate; mercury(II) oxide

: 463-51-4
Ketene

: 67-64-1
acetone

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
With sulfuric acid at 55 - 70℃;
With 2-sulfo-acetoacetic acid
With naphthalene-1,5-disulfonate at 80℃;

: 123-54-6
acetylacetone

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
Reversible Isomerisierung;

: 187737-37-7
propene

: 64-19-7
acetic acid

A: 108-22-5
Isopropenyl acetate

B: 591-87-7
Allyl acetate

C: 627-69-0
2-hydroxypropyl acetate

D: 36678-05-4
6-hydroxy-3-oxa-2-hexanone

E: 6214-01-3
propane-1,2-diol 2-monoacetate

F: 3249-50-1
(E)-1-propen-1-yl acetate

Conditions

Conditions	Yield
With bis(acetonitrile)chloronitropalladium(II) at 25℃; for 2h; Product distribution; various catalysts, times, O2 atmosphere with 18O containing complex; further products;

...Expand

: 187737-37-7
propene

: 3375-31-3
palladium diacetate

A: 108-22-5
Isopropenyl acetate

B: 591-87-7
Allyl acetate

C: 3249-50-1
(E)-1-propen-1-yl acetate

D: 67-64-1
acetone

Conditions

Conditions	Yield
In carbon dioxide at 25℃; under 68400 Torr; for 3h; Product distribution; Mechanism; var. solv. and temp.;

...Expand

: 463-51-4
Ketene

: 7664-93-9
sulfuric acid

: 67-64-1
acetone

A: 674-82-8
4-methyleneoxetan-2-one

B: 108-22-5
Isopropenyl acetate

C: 108-24-7
acetic anhydride

D 4-oxo-2.2.6-trimethyl-1.3-dioxime: 4-oxo-2.2.6-trimethyl-1.3-dioxime

Conditions

Conditions	Yield
at 55℃;

...Expand

: 463-51-4
Ketene

: 67-64-1
acetone

ZnCl2: ZnCl2

A: 674-82-8
4-methyleneoxetan-2-one

B: 108-22-5
Isopropenyl acetate

C: 108-24-7
acetic anhydride

D 4-oxo-2.2.6-trimethyl-1.3-dioxime: 4-oxo-2.2.6-trimethyl-1.3-dioxime

Conditions

Conditions	Yield
at 100℃;

...Expand

: 463-51-4
Ketene

: 7664-93-9
sulfuric acid

: 67-64-1
acetone

: 108-22-5
Isopropenyl acetate

...Expand

: 187737-37-7
propene

palladium (II) acetate bis(triphenylphosphoranylidene)ammonium complexes: palladium (II) acetate bis(triphenylphosphoranylidene)ammonium complexes

A: 108-22-5
Isopropenyl acetate

B: 591-87-7
Allyl acetate

C: 3249-50-1
1-propenyl acetate

D: 67-64-1
acetone

Conditions

Conditions	Yield
In chloroform at 25℃; Product distribution; Further Variations:; Solvents; Reagents; oxidative acetoxylation;

...Expand

: 187737-37-7
propene

: 64-19-7
acetic acid

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
With oxygen; Pd147(o-phenanthroline)32O60(OC(O)tBu)30 at 60℃; Kinetics; Further Variations:; Catalysts;

: 74045-59-3
(1-benzotriazolyl)-5 pentanone-2

A: (S)-5-(benzotriazol-1-yl)-pentan-2-ol

B: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
With Saccharomyces cerevisiae; ammonium sulfate; magnesium chloride In water; toluene at 30℃; for 48h;

: 29456-04-0
propen-2-ol

: 75-36-5
acetyl chloride

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
Stage #1: propen-2-ol With triethylamine In 1,2-dichloro-ethane at 20℃; for 0.0833333h; Stage #2: acetyl chloride In 1,2-dichloro-ethane

: 591-87-7
Allyl acetate

: 67-64-1
acetone

: 108-22-5
Isopropenyl acetate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid Reflux;

: 814-78-8
3-Methyl-3-buten-2-one

A: 108-22-5
Isopropenyl acetate

B: 80-62-6
methacrylic acid methyl ester

Conditions

Conditions	Yield
With wild type cyclohexanonemonooxygenase T56S/I491A mutant from Acinetobacter calcoaceticus; NADPH In aq. phosphate buffer at 25℃; for 5.5h; pH=7; Baeyer-Villiger Ketone Oxidation; Enzymatic reaction; regioselective reaction;

: 108-22-5
Isopropenyl acetate

: 58-27-5
menadione

: 75858-24-1
Acetic acid (1S,2aR,8aR)-1,8a-dimethyl-3,8-dioxo-1,2,2a,3,8,8a-hexahydro-cyclobuta[b]naphthalen-1-yl ester

Conditions

Conditions	Yield
In benzene for 1h; Irradiation;	100%

: 108-22-5
Isopropenyl acetate

: 130530-19-7
(1R*,3S*,3aS*,4R*,5R*,7aS*)-1-acetoxy-5-bromo-3,3a-epoxy-4-hydroxy-4,7a-dimethyl-1,3,3a,4,5,6,7,7a-octahydro-2H-inden-2-one

: 130530-20-0
(1R*,3R*,3aS*,4R*,5R*,7aS*)-1,4-diacetoxy-5-bromo-3,3a-epoxy-4,7a-dimethyl-1,3,3a,4,5,6,7,7a-octahydro-2H-inden-2-one

Conditions

Conditions	Yield
With toluene-4-sulfonic acid for 48h; Ambient temperature;	100%

: 108-22-5
Isopropenyl acetate

: 114522-83-7
3-isopropyl-2,4-dimethylaziridine

: 114522-81-5
3-acetamido-2,4-dimethylpent-1-ene

Conditions

Conditions	Yield
at 220℃; for 4h; in sealed, base-washed Pyrex tube;	100%

: 108-22-5
Isopropenyl acetate

: 54878-16-9, 77982-46-8
C17H24O3

: 77912-60-8
C19H26O4

Conditions

Conditions	Yield
With toluene-4-sulfonic acid for 72h; Heating;	100%

: 108-22-5
Isopropenyl acetate

: 64-17-5
ethanol

Conditions

Conditions	Yield
With sodium aluminum tetrahydride In tetrahydrofuran at 0℃; for 1h;	100%

: 108-22-5
Isopropenyl acetate

: 50-89-5
thymidine

: 35898-31-8
5'-O-acetylthymidine

Conditions

Conditions	Yield
With subtilisin 8350 In N,N-dimethyl-formamide at 45℃; for 36h;	100%

: 108-22-5
Isopropenyl acetate

: 108-95-2
phenol

A: 67-64-1
acetone

B: 122-79-2
Phenyl acetate

Conditions

Conditions	Yield
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h;	A n/a B 100%
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h; Product distribution;	A n/a B 100%

...Expand

: 108-22-5
Isopropenyl acetate

: (+/-)-11-Hydroxyferruginol

: 11,12-Diacetoxyabieta-8,11,13-triene

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene for 10h; Heating;	100%

: 108-22-5
Isopropenyl acetate

: (1S,2R,6R)-Bicyclo[4.4.1]undeca-3,7,9-trien-2-ol

A: (1S,2R,6R)-Bicyclo[4.4.1]undeca-3,7,9-trien-2-ol

B: (1R,2S,6S)-Bicyclo[4.4.1]undeca-3,7,9-trien-2-ol

C: Acetic acid (1S,2R,6R)-bicyclo[4.4.1]undeca-3,7,9-trien-2-yl ester

Conditions

Conditions	Yield
With PS-30 lipase Yields of byproduct given;	A n/a B n/a C 100%

...Expand

: 108-22-5
Isopropenyl acetate

: 111659-96-2
methyl 12α-acetoxy-3-oxo-4-cholen-24-oate

: 203630-69-7
3.12α-diacetoxy-choladien-(3.5)-oic acid-(24)-methyl ester

Conditions

Conditions	Yield
With sulfuric acid Heating;	100%

: 108-22-5
Isopropenyl acetate

: benzyl (1R,2S)-1-hydroxy-2,3-dihydro-1H-inden-2-ylcarbamate

: benzyl (1R,2S)-N-(2-acetoxyindan-1-yl)carbamate

Conditions

Conditions	Yield
With Pseudomonas cepacia lipase In various solvent(s) at 40℃; for 144h;	100%

: 108-22-5
Isopropenyl acetate

: 258504-47-1
1-(Tribromomethyl)cyclooctan-1-ol

: 258504-52-8
1-(Tribromomethyl)-1-acetoxycyclooctane

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 30℃; Acetylation;	100%

: 108-22-5
Isopropenyl acetate

: 100-51-6
benzyl alcohol

: 140-11-4
Benzyl acetate

Conditions

Conditions	Yield
Y5(OiPr)13O at 20℃; for 1h; Acetylation; transesterification;	100%
With indium(III) perchlorate; lithium perchlorate In ethyl acetate at 20℃; for 0.75h;	99%
With iodine at 85 - 90℃; for 0.0833333h;	98%

: 108-22-5
Isopropenyl acetate

: 26268-94-0
(+/-)-3-hydroxy-2-propionyl-isoindolin-1-one

: (1R)-3-oxo-2-propionyl-2,3-dihydro-1H-isoindol-1-yl acetate

Conditions

Conditions	Yield
With Alcaligenes species lipase QL In hexane at 60℃; for 1h;	100%

: 108-22-5
Isopropenyl acetate

: 26004-86-4
(+/-)-3-hydroxy-2-isobutyryl-isoindolin-1-one

: (1R)-2-isobutyryl-3-oxo-2,3-dihydro-1H-isoindol-1-yl acetate

Conditions

Conditions	Yield
With Alcaligenes species lipase QL In hexane at 60℃; for 1h;	100%

: 108-22-5
Isopropenyl acetate

: 26322-35-0
(+/-)-2-butyryl-3-hydroxy-isoindolin-1-one

: (1R)-2-butyryl-3-oxo-2,3-dihydro-1H-isoindol-1-yl acetate

Conditions

Conditions	Yield
With Alcaligenes species lipase QL In hexane at 60℃; for 1h;	100%

: 108-22-5
Isopropenyl acetate

: 26004-87-5
(+/-)-3-hydroxy-2-pivaloyl-isoindolin-1-one

: (1R)-3-oxo-2-pivaloyl-2,3-dihydro-1H-isoindol-1-yl acetate

Conditions

Conditions	Yield
With Alcaligenes species lipase QL In hexane at 60℃; for 1h;	100%

: 108-22-5
Isopropenyl acetate

: 106-38-7
para-bromotoluene

: 1195-32-0
1-methyl-4-isopropenylbenzene

Conditions

Conditions	Yield
Stage #1: para-bromotoluene With magnesium; lithium chloride In tetrahydrofuran at 0 - 20℃; for 2h; Schlenk technique; Inert atmosphere; Stage #2: Isopropenyl acetate With iron(III) chloride In tetrahydrofuran at 0℃; for 3h; Schlenk technique; Inert atmosphere;	100%
With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; cobalt(II) bromide In pyridine; acetonitrile at 20℃; Electrolysis;	47%
Stage #1: para-bromotoluene With magnesium; lithium chloride In tetrahydrofuran at 0 - 20℃; for 2h; Schlenk technique; Inert atmosphere; Stage #2: Isopropenyl acetate With iron(III) chloride In tetrahydrofuran at 0℃; for 5h; Reagent/catalyst; Schlenk technique; Inert atmosphere;

: 108-22-5
Isopropenyl acetate

: (+/-)-2-benzoyl-3-hydroxy-isoindolin-1-one

: (1R)-2-benzoyl-3-oxo-2,3-dihydro-1H-isoindol-1-yl acetate

Conditions

Conditions	Yield
With Alcaligenes species lipase QL In hexane at 60℃; for 1h;	100%

: 873956-26-4
4-(2'-chloroethyl)-7aR-ethyl-1,2,3,6,7,7a-hexahydroinden-5-one

: 108-22-5
Isopropenyl acetate

: acetic acid 4-(2-chloro-ethyl)-7a-ethyl-2,6,7,7a-tetrahydro-1H-inden-5-yl ester

Conditions

Conditions	Yield
With toluene-4-sulfonic acid for 1.5h; Heating;	100%

: 930280-13-0
C31H46O10

: 108-22-5
Isopropenyl acetate

: 123269-04-5
Octanoic acid (2aS,5aS,7S,7aR,8S,9S,10bS,10cR)-7-acetoxy-10c-hydroxy-2a,4,4,7,10-pentamethyl-9-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-2,2a,5a,6,7,7a,8,9,10b,10c-decahydro-1,3,5-trioxa-benzo[cd]cyclopenta[h]azulen-8-yl ester

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 20℃; for 1.75h;	100%
With toluene-4-sulfonic acid at 20℃; for 1.75h;	100%

: 956107-37-2
methyl (1-adamantanyl 5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-2-thio-D-glycero-β-D-galacto-non-2-ulopyranosid)onate

: 108-22-5
Isopropenyl acetate

: methyl (1-adamantyl 5-(N-acetylacetamido)-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-2-thio-D-glycero-β-D-galacto-non-2-ylopyranosid)onate

Conditions

Conditions	Yield
With camphor-10-sulfonic acid at 65℃; for 16h;	100%

: 6786-30-7
3,4-dihydro-1-benzoxepin-5(2H)-one

: 108-22-5
Isopropenyl acetate

: C12H12O3

Conditions

Conditions	Yield
toluene-4-sulfonic acid Reflux;	100%

: 108-22-5
Isopropenyl acetate

: 64-04-0
phenethylamine

: 877-95-2
methyl-N-(benzyl-methyl)-formamide

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 3h; Green chemistry;	100%
With iron(III) trifluoromethanesulfonate at 20℃; for 24h; Schlenk technique;	73%
at 60℃; for 3h;