As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c
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inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualified
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inquiryCHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD. founded in 1984, engages in pharmaceutical research, development, production, process design and technical consultation of synthetic and fermentation pharmaceutical products. The organizational s
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryOur Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiryLinchuan's expertise and flexibility have made the company become one of the leading manufacturer of Naphthalene series, Biphenyl series , Anthracene series and 1-(CHLOROMETHYL)-4-ETHENYLBENZENE series, which are wildly used in the field of ele
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryTIANFUCHEM--90-11-9--1-Bromonaphthalene factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relat
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryEnglish name: 1-Bromonaphthalene CAS No.: 90-11-9 Formula: C10H7Br Molecular Weight: 207.06658 Synonyms: 1-naphthylbromide;-Bromonaphthalene;I-Bromnaphthalin;Naphthalene,1-bromo-;α-bromonaphthalene;11 -BroMonaphthalene;1-bromo-naphth
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiryProduct Name: 1-Bromonaphthalene CAS: 90-11-9 MF: C10H7Br MW: 207.07 EINECS: 201-965-2 Mol File: 90-11-9.mol 1-Bromonaphthalene Structure 1-Bromonaphthalene Chemical Properties Melting point −2-−1 °C(lit.) Boil
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
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inquiryBeluga chemical professional supply High quality 1-Bromonaphthalene CAS 90-11-9 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in China
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryMinimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,
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inquiryName: Naphthalene,1-bromo- Synonyms: H293; B0618; A843449; LS11682; nsc6551; nsc-6551; nsc 6551; CJ-06554; AN-24185; AC1Q26ZQ; AC1Q24HY; AC1L1NS4; LS-94439; I14-7002; I14-0909; AJ-30212; CJ-28359; STR06472; BC201275; ANW-13635; TC-040330; KSC490O2R;
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Our Advantages Production: Advanced chemical equipment with years of experience.Staffs for producing various extract products. Quality Control:A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Speci
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inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
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inquiry1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h; | 99% |
Conditions | Yield |
---|---|
With aluminum oxide; copper(ll) bromide In tetrachloromethane at 80℃; for 1h; | 98% |
With ammonium cerium(IV) nitrate; lithium bromide In acetonitrile at 20℃; for 6h; | 98% |
With 1-dodecyl-3-methylimidazol-1-ium bromide at 50℃; for 2h; | 98% |
1-Naphthylboronic acid
1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In acetonitrile at 80℃; for 14h; | 98% |
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube; | 87% |
1-naphthylboronic acid pinacol ester
1-Bromonaphthalene
Conditions | Yield |
---|---|
With copper(ll) bromide In methanol Heating; | 95% |
Conditions | Yield |
---|---|
With carbon tetrabromide; iron In ethanol at 20℃; for 2h; Solvent; Reagent/catalyst; Irradiation; | 94% |
1-naphthyltrimethylsilane
1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In 1,2-dichloro-ethane; acetonitrile at 85℃; for 12h; | 92% |
6-Bromo-2,3-dihydro-naphtho[1,2-b][1,4]dithiine
1-Bromonaphthalene
Conditions | Yield |
---|---|
With Ni(Ra)-W2 In acetic acid at 40℃; for 0.833333h; | 90% |
potassium trifluoro(naphth-1-yl)borate
1-Bromonaphthalene
Conditions | Yield |
---|---|
With pyridinium hydrobromide perbromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 90% |
With acetic acid; lithium bromide In dimethyl sulfoxide at 100℃; for 8h; Schlenk technique; | 42% |
1-Bromonaphthalene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution; | 87% |
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 81% |
Conditions | Yield |
---|---|
With trimethylsilyl bromide; N-benzyl-N,N,N-triethylammonium chloride; sodium nitrite In tetrachloromethane 1.) 0 deg C, 1.5 h, 2.) r.t., 17 h; | 85% |
With dinitrogen trioxide; hydrogen bromide; acetic acid at 5 - 10℃; anschliessendes Erhitzen bis auf Siedetemperatur; |
A
1,8-dibromonaphthalene
B
1-Bromonaphthalene
Conditions | Yield |
---|---|
With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination; | A 81% B 13% |
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 4h; Reflux; | 72% |
1,2-diethynylbenzene
1-Bromonaphthalene
Conditions | Yield |
---|---|
With hydrogen bromide; platinum(II) chloride In water at 100℃; for 4h; | 71% |
Multi-step reaction with 2 steps 1: 98 percent / HBr / H2O; various solvent(s) / 1.5 h / 100 °C 2: PtCl2 / H2O; various solvent(s) / 12 h / 100 °C View Scheme |
tetralin
A
naphthalene
B
1-Bromonaphthalene
C
1,4-dibromo-1,2,3,4-tetrahydronaphthalene
trans-2-bromo-1,2,3,4-tetrahydronaphthalen-1-ol
Conditions | Yield |
---|---|
With bromine In tetrachloromethane at 77℃; for 0.166667h; Further byproducts given; | A 14% B 10% C 63% D 8% |
Conditions | Yield |
---|---|
With iodine In benzene-d6 Inert atmosphere; | A 37% B 56% |
Conditions | Yield |
---|---|
With iodine In benzene-d6 Inert atmosphere; | A 43% B 52% |
Conditions | Yield |
---|---|
With oxygen; potassium bromide; sodium nitrite In water; trifluoroacetic acid at 20℃; for 5h; Product distribution; | A 49% B n/a |
Conditions | Yield |
---|---|
With 1,2-dichloro-ethane; copper(l) chloride; 1,3-bis(pyridin-2-ylmethyl)-1H-imidazolium chloride at 200℃; for 2h; Product distribution / selectivity; Microwave irradiation; | A 49% B n/a |
Conditions | Yield |
---|---|
In tetrahydrofuran at 25℃; for 60h; | 40% |
With bromobenzene; tetrabutylammomium bromide; o-CH3C6H4NiBr(PEt3)2 In benzene at 80℃; for 20h; sealed tube; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With bromine In tetrachloromethane at 30℃; for 7h; Bromination; Irradiation; | A 25% B 3% C 35% D 6% |
naphthalene
A
1-Bromonaphthalene
B
1,2,3,4-tetrabromo-1,2,3,4-tetrahydronaphthalene
Conditions | Yield |
---|---|
With bromine In tetrachloromethane for 8h; | A 35% B n/a C n/a |
Conditions | Yield |
---|---|
at 250℃; | |
at 250℃; |
Conditions | Yield |
---|---|
at 150 - 180℃; |
Conditions | Yield |
---|---|
With bromine; iron(III) chloride at 150 - 200℃; | |
With bromine in der Gasphase bei 550-600grad in Gegenwart oder Abwesenheit von FeBr3; |
tetrachloromethane
naphthalene
1,3-dibromo-5-ethyl-5-methyl-imidazolidine-2,4-dione
1-Bromonaphthalene
Conditions | Yield |
---|---|
Isomerisierung; |
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessende Behandlung mit Wasser; | |
With magnesium; benzene anschliessende Behandlung mit Wasser; |
1,6-dibromonaphthalene
1-Bromonaphthalene
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessende Behandlung mit Wasser; | |
With magnesium; benzene anschliessende Behandlung mit Wasser; |
Conditions | Yield |
---|---|
With copper(ll) bromide |
Conditions | Yield |
---|---|
durch Diazotieren des salpetersauren Salzes und Behandeln des Diazoniumnitrats mit Alkohol; |
Conditions | Yield |
---|---|
With iodine; magnesium In diethyl ether for 3h; Grignard reaction; Heating; | 100% |
With iodine; magnesium 1.) ether, reflux, 2.) ether, benzene, RT, 2 h; Yield given. Multistep reaction; | |
Stage #1: 1-Bromonaphthalene With magnesium In diethyl ether Stage #2: cyclopentanone In diethyl ether for 3h; Grignard reaction; | |
Stage #1: 1-Bromonaphthalene With magnesium In diethyl ether for 0.5h; Reflux; Stage #2: cyclopentanone In diethyl ether at 0℃; for 1h; |
Conditions | Yield |
---|---|
With C31H26N6O4Pd; potassium carbonate In water at 100℃; for 3h; Suzuki-Miyaura coupling; | 100% |
With potassium phosphate; 1,1'-bis(4-methoxyphenyl)-3,3'-methylene-diimidazoline-2,2'-diylidene-palladium(II)-dibromide In toluene at 40℃; for 2h; Reagent/catalyst; Temperature; Time; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
With C16H21ClN2Pd; sodium carbonate In methanol at 85℃; for 1h; Reagent/catalyst; Suzuki-Miyaura Coupling; | 100% |
Conditions | Yield |
---|---|
In benzene at 10℃; for 24h; | 100% |
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane for 2h; Heating; | 100% |
Stage #1: 1-Bromonaphthalene; dimethyl zinc(II) With n-butyllithium In tetrahydrofuran; diethyl ether; hexane at 0℃; for 0.5h; Substitution; Stage #2: With oxovanadium(V) ethoxydichloride In tetrahydrofuran; diethyl ether; hexane at 20℃; for 3h; Oxidation; Alkylation; Further stages.; | 73% |
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With iodine; magnesium In diethyl ether Grignard reaction; Stage #2: cyclopentadecanone In diethyl ether Grignard reaction; | 100% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate In tetrahydrofuran at 20℃; for 6h; Suzuki coupling; Inert atmosphere; | 100% |
With C64H76Br2N4O2Pd; potassium carbonate In N,N-dimethyl acetamide at 20 - 140℃; for 24h; Suzuki coupling; Inert atmosphere; | 99% |
With potassium fluoride; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 20℃; for 48h; Suzuki coupling; | 97% |
1-Bromonaphthalene
3-(trimethoxysilyl)propan-1-amine
Methyl 1-naphthylphosphinate
Conditions | Yield |
---|---|
With anilinium hypophosphorous salt; 1,3-bis-(diphenylphosphino)propane; palladium diacetate In acetonitrile Heating; | 100% |
2-Acetylthiophene
1-Bromonaphthalene
1-(5-(naphthalen-1-yl)thiophen-2-yl)ethan-1-one
Conditions | Yield |
---|---|
With dichloro[1-(β-methallyl)-3-(2,4,6-trimethyl)benzylbenzimidazole-2-ylidene]pyridine palladium(II); potassium acetate In N,N-dimethyl acetamide at 130℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 100% |
With PdCl(1,4-bis(diphenylphosphino)butane)(C3H5); potassium acetate at 150℃; for 16h; Inert atmosphere; Schlenk technique; | 82% |
With sodium acetate; bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl acetamide at 150℃; for 20h; | 77% |
With sodium carbonate; silver(l) oxide; Trimethylacetic acid In N,N-dimethyl-formamide at 120℃; for 18h; Quantum yield; Green chemistry; | 52% |
Conditions | Yield |
---|---|
With sodium carbonate; palladium diacetate In 1-methyl-pyrrolidin-2-one; Hexadecane at 140℃; for 16h; | 100% |
With 1-methyl-pyrrolidin-2-one; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium carbonate at 120℃; for 12h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere; | 95% |
With dichlorobis(dibenzyl diisopropylphosphoramidite)palladium(II); sodium fluoride In N,N-dimethyl-formamide at 130℃; for 16h; | 94% |
(4R,5R)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one
1-Bromonaphthalene
(3R,4R)-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxy-4-methyl-1-(1-naphthyl)pentan-1-one
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In tetrahydrofuran at -78℃; Stage #2: With cerium chloride In tetrahydrofuran; pentane for 2h; Cooling; Stage #3: (4R,5R)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one In tetrahydrofuran; pentane at -100℃; for 0.5h; | 100% |
(4S,5S)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one
1-Bromonaphthalene
(3S,4S)-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxy-4-methyl-1-(1-naphthyl)pentan-1-one
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In tetrahydrofuran at -78℃; Stage #2: With cerium chloride In tetrahydrofuran; pentane for 2h; Cooling; Stage #3: (4S,5S)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one In tetrahydrofuran; pentane at -100℃; for 0.5h; | 100% |
Conditions | Yield |
---|---|
Stage #1: phenylmethanethiol With sodium t-butanolate In tetrahydrofuran at 23℃; for 0.166667h; Inert atmosphere; Stage #2: With zinc(II) chloride In tetrahydrofuran for 0.166667h; Inert atmosphere; Stage #3: 1-Bromonaphthalene With di-μ-bromobis(tri-tert-butylphosphino)dipalladium(I); lithium iodide In tetrahydrofuran at 90℃; for 2h; Inert atmosphere; | 100% |
2-(n-propyl)-thiazole
1-Bromonaphthalene
5-(naphthalen-1-yl)-2-propylthiazole
Conditions | Yield |
---|---|
With dichloro[1-(β-methallyl)-3-(2,3,5,6-tetramethyl)benzylbenzimidazole-2-ylidene]pyridine palladium(II); potassium acetate In N,N-dimethyl acetamide at 130℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 100% |
Conditions | Yield |
---|---|
With sodium hydroxide; cobalt(II) acetate In ethanol at 65℃; under 1520 Torr; for 4h; Irradiation; | 99.3% |
With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl In water; benzene at 65℃; under 760 Torr; for 5h; Irradiation; | 96% |
With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 4.5h; Irradiation; | 95% |
With tributyl-amine; water; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride at 110 - 130℃; under 3 Torr; for 24h; | 48% |
With water; sodium acetate; triethylamine; Pd-bis(1-methylbenzothiazole-2-carbene) In N,N-dimethyl acetamide at 130℃; for 7h; | 55 % Chromat. |
Conditions | Yield |
---|---|
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Catalytic behavior; Reagent/catalyst; Solvent; Schlenk technique; | 99% |
Stage #1: 1-Bromonaphthalene With bis(tri-tert-butylphosphine)palladium(0); sodium chloride In water at 20℃; for 0.166667h; Negishi Coupling; Schlenk technique; Stage #2: n-butyllithium With zinc(II) chloride In 2-methyltetrahydrofuran; water at 10℃; for 0.00555556h; Schlenk technique; chemoselective reaction; | 98% |
Stage #1: n-butyllithium With zinc(II) chloride In tetrahydrofuran at 20℃; for 0.5h; Stage #2: 1-Bromonaphthalene; dichloro bis(acetonitrile) palladium(II) In toluene at 60℃; for 3h; Negishi coupling; Further stages.; | 96% |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 6h; ultrasonic acceleration of reduction; | 99% |
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 18h; Heating; | 99% |
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 18h; Heating; | 99% |
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In diethyl ether at -78℃; Stage #2: In diethyl ether Stage #3: With Duroquinone In diethyl ether | 99% |
With DPEPhos; potassium tert-butylate; palladium diacetate; bis(pinacol)diborane for 12h; Heating; | 99% |
With chromium dichloride; manganese; nickel dichloride; bipyridyl-type ligand In tetrahydrofuran at 20℃; for 17h; Arylation; Homocoupling reaction; | 98% |
carbon monoxide
1-Bromonaphthalene
butan-1-ol
naphthalene-1-carboxylic acid butyl ester
Conditions | Yield |
---|---|
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; triethylamine; palladium dichloride at 120℃; under 760.051 Torr; for 12h; | 99% |
With tributyl-amine; triphenylphosphine; silica-supported poly<3-(2-cyanoethylsulfanyl)propylsiloxane palladium> at 100℃; under 760 Torr; for 72h; | 34% |
With bis(triphenylphosphine)palladium dibromide; tributyl-amine |
Conditions | Yield |
---|---|
With potassium phosphate; d(4)-methanol; palladium diacetate; catacxium A In toluene at 80℃; for 16h; | 99% |
With sodium amalgam; deuteromethanol for 2h; Heating; | 95% |
With tetrahydrofuran-d8; 2,2'-azobis-(2,4-dimethylvaleronitrile); tri-n-butyl-tin hydride for 5h; Reflux; regioselective reaction; | 68% |
With water-d2; magnesium 1.) Grignard; Multistep reaction; | |
With water-d2; potassium carbonate In acetonitrile at 20℃; pH=12.15; Electrochemical reaction; |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃; for 15h; | 99% |
1-Bromonaphthalene
4-methylphenylboronic acid
1-(4-methylphenyl)naphthalene
Conditions | Yield |
---|---|
With potassium phosphate; N-[(4-diphenylphosphinophenyl)methyl] D-gluconamide; PdCl2(GLCAphos)2 In water at 80℃; for 16h; | 99% |
With 3,5-di-tert-butyl-2-hydroxybenzaldehyde; potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 2h; Suzuki-Miyaura Coupling; | 99% |
With potassium carbonate; palladium diacetate In various solvent(s) at 110℃; for 15h; Suzuki reaction; | 97% |
Conditions | Yield |
---|---|
With magnesium; ethylene dibromide In tetrahydrofuran at 20℃; for 1h; | 99% |
Stage #1: 1-Bromonaphthalene With iodine; magnesium In tetrahydrofuran at 65℃; for 2h; Inert atmosphere; Stage #2: formic acid ethyl ester In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Heating; | 93% |
Stage #1: 1-Bromonaphthalene With iodine; magnesium In tetrahydrofuran at 20℃; for 2.15h; Stage #2: formic acid ethyl ester In tetrahydrofuran at 20℃; for 2h; | 90% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 24h; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); sodium tert-pentoxide; (R)-tol-BINAP In toluene at 80℃; for 18h; Inert atmosphere; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4h; Inert atmosphere; | 92% |
With C37H55O2PPd(1+)*CF3O3S(1-); sodium t-butanolate In toluene at 90℃; for 6h; Schlenk technique; Inert atmosphere; | 75% |
With [Pd(allyl)(BrettPhos)]OTf; sodium t-butanolate In toluene at 90℃; Schlenk technique; Inert atmosphere; | 72% |
acrylic acid n-butyl ester
1-Bromonaphthalene
butyl (E)-3-(naphthalen-1-yl)acrylate
Conditions | Yield |
---|---|
With C68H96Br2N2O8P2Pd2; triethylamine; 3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl diisopropylphosphoramidite In 1-methyl-pyrrolidin-2-one at 80℃; for 16h; Mizoroki-Heck reaction; Inert atmosphere; regioselective reaction; | 99% |
With phenyl carbamate; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 130℃; for 2h; Heck-type reaction; | 98% |
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 4h; Heck Reaction; Inert atmosphere; Schlenk technique; | 97% |
1-Bromonaphthalene
ethyl 2-cyanoacetate
ethyl 2-cyano-2-(naphthalen-1-yl)acetate
Conditions | Yield |
---|---|
With P(i-BuNCH2CH2)3N; potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 90℃; for 5h; | 99% |
With tri-tert-butyl phosphine; sodium phosphate; bis(dibenzylideneacetone)-palladium(0) In toluene at 70℃; for 4h; | 83% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride In 1,2-dimethoxyethane for 16h; Heating; | 99% |
1-Bromonaphthalene
4-methoxyphenylboronic acid
1-(4-methoxyphenyl)naphthalene
Conditions | Yield |
---|---|
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 99% |
With tetraamminepalladium(II) chloride; tetra(n-butyl)ammonium hydroxide In water at 45℃; for 2h; Suzuki-Miyaura Coupling; Green chemistry; | 99% |
With Ti0.97Pd0.03O1.97; potassium carbonate In water at 100℃; for 6h; Suzuki-Miyaura Coupling; | 99% |
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