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Shanghai Minstar Chemical Co., Ltd

Product Name: Allylbenzene Synonyms: 1-benzylethene;1-Phenyl-2-propene;1-Propene, 3-phenyl-;1-propene,3-phenyl-;Allylbenzene,98%;Allylbenzol, 3-Phenyl-1-propen, 2-Propenylbenzol;benzyl ethylene;ALLYBENZENE CAS: 300-57-2 MF: C9H10 MW: 1

Allylbenzene 300-57-2 C9H10

Cas:300-57-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

Allylbenzene

Cas:300-57-2

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:Colorless liquid Storage:Store in dry and cool place with good seal Package:25liter/200liter plastic drum Application:Colorless liquid Transportation:by courier,by Air,by Sea ... Port:Chinese

Allylbenzene

Cas:300-57-2

Min.Order:10 Gram

Negotiable

Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

professional supplier Allylbenzene best price

Cas:300-57-2

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 300-57-2 Allylbenzene Manufacturer

Cas:300-57-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Phenyl-1-propene

Cas:300-57-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

1-Phenyl-2-propene

Cas:300-57-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Allylbenzene

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 300-57-2 with best price

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

AllylbenzeneCAS300-57-2

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Chemical Name: Allylbenzene CAS No.: 300-57-2 Molecular Fomula:C9H10 Chemical Structure: Molecular weight: 118.18 Appearance: Colorless liquid Assay:98%MIN Appearance: Colorless Liquid Storage:Store in cool and dry place, away from su

Allylbenzene

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene, 2-propen-1-yl- 300-57-2

Cas:300-57-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Allylbenzene /CAS:300-57-2

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $153.0 / 187.7

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Allylbenzene CAS: 300-57-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

Allylbenzene CAS: 300-57-2

Cas:300-57-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene, 2-propen-1-yl-

Cas:300-57-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:300-57-2

Cas:300-57-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

prop-2-enylbenzene

Cas:300-57-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

ALLYLBENZENE

Cas:300-57-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Miheng Trading Co., Ltd.

Allylbenzene CAS 300-57-2 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly. 2 Pr

Allylbenzene CAS 300-57-2

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply allylbenzene

Cas:300-57-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

Allylbenzene

Cas:300-57-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Phenyl-1-propene

Cas:300-57-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hefei Zhaobo Technology Co., Ltd.

Allylbenzene CAS 300-57-2 Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality control syste

Allylbenzene CAS 300-57-2

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

legal supply allylbenzene

Cas:300-57-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Allylbenzene

Cas:300-57-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Reliable Quality Allylbenzene

Cas:300-57-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Allylbenzene

Cas:300-57-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless liquid Storage:Stored in a cool, well-ventilated place at temperatures not higher than 35 ° C Package:in 170kgs net new galvanized steel drum; or as per your request. Appli

Allylbenzene

Cas:300-57-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Allylbenzene

Cas:300-57-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Allylbenzene

Cas:300-57-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

Allyl acetate
591-87-7

Allyl acetate

trimethyl(phenyl)stannane
934-56-5

trimethyl(phenyl)stannane

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In N,N,N,N,N,N-hexamethylphosphoric triamide for 6h;100%
With [Pd(triphenylphosphine)(allyl)(chloride)] In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 5h;96 % Chromat.
allyl bromide
106-95-6

allyl bromide

phenyltriethoxytitanium
95576-66-2

phenyltriethoxytitanium

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; diethyl ether at 25℃; for 3h;100%
3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

phenyltriethoxytitanium
95576-66-2

phenyltriethoxytitanium

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; diethyl ether at 25℃; for 1.5h;100%
phenylzinc chloride
28557-00-8

phenylzinc chloride

allyl bromide
106-95-6

allyl bromide

A

allylbenzene
300-57-2

allylbenzene

B

biphenyl
92-52-4

biphenyl

C

zinc dibromide

zinc dibromide

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 3.5 h);A 100%
B 0%
C n/a
bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 3 h);A 55%
B 40%
C n/a
Allyl acetate
591-87-7

Allyl acetate

phenylzinc chloride
28557-00-8

phenylzinc chloride

A

allylbenzene
300-57-2

allylbenzene

B

biphenyl
92-52-4

biphenyl

C

zinc diacetate
557-34-6

zinc diacetate

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 5 h);A 100%
B 0%
C n/a
C14H15NSe
1224431-84-8

C14H15NSe

cyclohexene
110-83-8

cyclohexene

A

allylbenzene
300-57-2

allylbenzene

B

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In chloroform-d1 at 20℃;A 100%
B 100%
1-iodo-3-phenylpropan
4119-41-9

1-iodo-3-phenylpropan

A

allylbenzene
300-57-2

allylbenzene

B

1,6-diphenylhexane
1087-49-6

1,6-diphenylhexane

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Electrochemical reaction; Inert atmosphere;A 1%
B 99%
bromobenzene
108-86-1

bromobenzene

allyl bromide
106-95-6

allyl bromide

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
Stage #1: bromobenzene With iodine; magnesium In diethyl ether Inert atmosphere; Reflux;
Stage #2: allyl bromide In diethyl ether at 0 - 20℃; for 2.08333h; Inert atmosphere;
99%
Stage #1: bromobenzene With magnesium In tetrahydrofuran
Stage #2: allyl bromide In tetrahydrofuran
Stage #3: With ammonium chloride In water
With magnesium In tetrahydrofuran at 20℃;
Stage #1: bromobenzene With iodine; magnesium In tetrahydrofuran at 20℃;
Stage #2: allyl bromide In tetrahydrofuran for 1h;
propargyl benzene
10147-11-2

propargyl benzene

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With hydrogen In toluene at 20℃; under 38002.6 Torr; for 12h; Autoclave; chemoselective reaction;99%
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 3h;96%
With hydrogen In acetonitrile at 120℃; under 22502.3 Torr; for 15h; Autoclave; Sealed tube;72%
Allyl acetate
591-87-7

Allyl acetate

diphenylmagnesium
555-54-4

diphenylmagnesium

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
Cu(acac)2-PPh3 In tetrahydrofuran at 40℃; for 4h;98%
Cu(acac)2-PPh3 In tetrahydrofuran at 40℃; for 4h; Product distribution; effects of solvent, catalyst and catalyst activator; further solvents, further catalysts;
Allyl acetate
591-87-7

Allyl acetate

diphenylmagnesium
555-54-4

diphenylmagnesium

A

allylbenzene
300-57-2

allylbenzene

B

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

Conditions
ConditionsYield
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 40℃; for 4h;A 98%
B n/a
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 40℃; for 4h; Product distribution; effect of catalysts, activator ligands, solvents on yield; effect of variation of ester residue in the allyl ester partner; reactions between further dialkyl- and diarylmagnesiums and allyl esters;A 98%
B n/a
allyl bromide
106-95-6

allyl bromide

phenylboronic acid
98-80-6

phenylboronic acid

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With 2C2H3O2(1-)*Pd(2+)*3Na(1+)*C18H12O9PS3(3-); potassium tert-butylate; glycerol at 100℃; for 2h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;98%
With potassium tert-butylate; (1,3-di(2,4,6-(CH3)3-C6H2)-imidazol-2-ylidene)Pd(OAc)2 In isopropyl alcohol at 20℃; for 2h; Suzuki-Miyaura coupling;93%
With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate In toluene at 110℃; for 15h; Suzuki-Miyaura coupling; Inert atmosphere;90%
allyl phenyl ether
1746-13-0

allyl phenyl ether

phenylzinc chloride
28557-00-8

phenylzinc chloride

A

allylbenzene
300-57-2

allylbenzene

B

biphenyl
92-52-4

biphenyl

C

zinc phenate

zinc phenate

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h);A 98%
B 0%
C n/a
Cinnamyl bromide
4392-24-9

Cinnamyl bromide

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With C11H22P(1+)*Br(1-); lithium tri-t-butoxyaluminum hydride In tetrahydrofuran; dodecane; toluene at 90℃; for 16h; Reagent/catalyst; regioselective reaction;96%
With hydrogenchloride; indium 1.) DMF, 1 h, RT, 2.) 1 min; Yield given. Multistep reaction;
2-(tosyloxy)dodecane
102736-19-6

2-(tosyloxy)dodecane

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With Pd(P(t-Bu)2Me)2; potassium tert-butylate; N-cyclohexyl-cyclohexanamine In 1,4-dioxane at 80℃; for 8h; Inert atmosphere;96%
trimethyl(phenyl)stannane
934-56-5

trimethyl(phenyl)stannane

allyl bromide
106-95-6

allyl bromide

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 70℃;95%
With bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 70℃; for 3h;95%
carbon monoxide
201230-82-2

carbon monoxide

(2E)-3-phenylprop-2-en-1-yl formate
23510-72-7

(2E)-3-phenylprop-2-en-1-yl formate

A

allylbenzene
300-57-2

allylbenzene

B

1-phenylpropene
637-50-3

1-phenylpropene

C

trans-styrylacetic acid
2243-53-0, 59744-46-6, 1914-58-5

trans-styrylacetic acid

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine In toluene at 60℃; under 45600 Torr; for 15h;A 1%
B 1%
C 95%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine In toluene under 15200 Torr; for 96h; Product distribution; Ambient temperature; other reagents, other solvents, var. temp., pressure, time;
CH2=CH-CH2-OR'', PhCCMgR'

CH2=CH-CH2-OR'', PhCCMgR'

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
Cu(acac)2-PPh3 In tetrahydrofuran95%
3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

phenylboronic acid
98-80-6

phenylboronic acid

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With 2C2H3O2(1-)*Pd(2+)*3Na(1+)*C18H12O9PS3(3-); potassium tert-butylate; glycerol at 100℃; for 12h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;95%
With potassium tert-butylate; (1,3-di(2,4,6-(CH3)3-C6H2)-imidazol-2-ylidene)Pd(OAc)2 In isopropyl alcohol at 20℃; for 0.5h; Suzuki-Miyaura coupling;72%
With potassium tert-butylate In isopropyl alcohol at 50℃; for 12h; Inert atmosphere;71%
With potassium hydroxide; phenone oxime-derived palladacycle; tetrabutylammomium bromide In water; acetone at 20℃; for 2h; Suzuki coupling;69%
With dichloro(N-(diphenylphosphino)-N-isopropyl-1,1-diphenylphosphinamine) digold(I); caesium carbonate In acetonitrile at 80℃; for 18h; Temperature; chemoselective reaction;21 %Spectr.
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

benzyl bromide
100-39-0

benzyl bromide

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran at 20℃; for 14h; Kumada-Corriu reaction; Inert atmosphere;95%
Stage #1: vinyl magnesium bromide With indium(III) chloride In tetrahydrofuran
Stage #2: benzyl bromide With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Heating;
82%
trimethyl(phenyl)stannane
934-56-5

trimethyl(phenyl)stannane

allyl bromide
106-95-6

allyl bromide

A

allylbenzene
300-57-2

allylbenzene

B

trimethyltin bromide
1066-44-0

trimethyltin bromide

Conditions
ConditionsYield
With ((π-C3H5)PdCl)2 In N,N-dimethyl-formamide 70°C;A 95%
B n/a
C14H15NSe
1224431-84-8

C14H15NSe

A

allylbenzene
300-57-2

allylbenzene

B

PySeOH
428876-71-5

PySeOH

Conditions
ConditionsYield
Stage #1: C14H15NSe With Dess-Martin periodane In dichloromethane at 20℃;
Stage #2: With water; sodium carbonate at 20℃;
A 95%
B n/a
benzyl bromide
100-39-0

benzyl bromide

trivinyl indium
75076-64-1

trivinyl indium

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 1h; Heating;94%
phenylaluminium dichloride
3530-39-0

phenylaluminium dichloride

allyl bromide
106-95-6

allyl bromide

A

allylbenzene
300-57-2

allylbenzene

B

biphenyl
92-52-4

biphenyl

C

aluminium bromide
7727-15-3

aluminium bromide

Conditions
ConditionsYield
bis(η3-allyl-μ-chloropalladium(II)) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h);A 94%
B <1
C n/a
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h);A <1
B <1
C n/a
3-benzyl propionaldehyde
18328-11-5

3-benzyl propionaldehyde

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With methoxy(cyclooctadiene)rhodium(I) dimer; N,N-Dimethylacrylamide; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 90℃; for 3h; Time;94%
With methoxy(cyclooctadiene)rhodium(I) dimer; N,N-Dimethylacrylamide; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 90℃; for 3h;94%
With methoxy(cyclooctadiene)rhodium(I) dimer; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran at 40 - 80℃; chemoselective reaction;90 %Spectr.
bromobenzene
108-86-1

bromobenzene

C10H20AlNO

C10H20AlNO

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 60℃; for 12h;93%
3-Cinnamyloxy-methoxy-benzol
4646-99-5

3-Cinnamyloxy-methoxy-benzol

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With 6,6'-dimethyl-2,2'-bipyridine; (1,2-dimethoxyethane)dichloronickel(II); bis(pinacol)diborane; lithium tert-butoxide In N,N-dimethyl acetamide; water at 30℃; for 24h; Inert atmosphere;93%
1,2-epoxy-3-phenylpropane
4436-24-2

1,2-epoxy-3-phenylpropane

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With hydrogen; triethyl phosphite In isopropyl alcohol at 100℃; under 4500.45 Torr; for 25h; Glovebox; chemoselective reaction;92%
With bis(acetylacetonate)nickel(II); diethylzinc In 1,2-dimethoxyethane; hexane at 80℃; for 48h; Inert atmosphere;88%
With carbon monoxide In water at 27℃; under 760.051 Torr; for 24h; chemoselective reaction;69%
(allylsulfonyl)benzene
16212-05-8

(allylsulfonyl)benzene

phenylmagnesium bromide

phenylmagnesium bromide

allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 60℃; for 4h; further reagents and solvents;92%
allylbenzene
300-57-2

allylbenzene

1-propenylbenzene
873-66-5

1-propenylbenzene

Conditions
ConditionsYield
With tetramethyldialuminoxane; [Zr(NPhPPh2)4] In tetrahydrofuran-d8 at 20℃; for 0.25h; Isomerization;100%
With tetramethyldialuminoxane; [{N(SiMe3)C(Ph)}2CH]2TiCl2 In (2)H8-toluene at 25℃; for 1h; Kinetics; Further Variations:; Catalysts;99.5%
With C44H58Cl2N4Pd In isopropyl alcohol at 70℃; for 3h; optical yield given as %de; diastereoselective reaction;98%
allylbenzene
300-57-2

allylbenzene

1-phenylpropene
637-50-3

1-phenylpropene

Conditions
ConditionsYield
With potassium hydroxide In 1,2-dimethoxyethane at 40℃; for 0.5h;100%
With potassium hydroxide In butan-1-ol for 3h; Heating;100%
With bis(1,5-cyclooctadiene)nickel(0); [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene In toluene at 130℃; for 1h; Reagent/catalyst; Temperature; Time;99%
allylbenzene
300-57-2

allylbenzene

Propylbenzene
103-65-1

Propylbenzene

Conditions
ConditionsYield
With Pt-Sn-citrate; hydrogen In methanol at 50℃; under 3800 Torr; for 3h; var. temperatures; var. pressures;100%
With Pt-Sn-citrate; hydrogen In methanol at 50℃; under 3800 Torr; for 3h;100%
With C49H60BF2IrN5(1+)*C32H12BF24(1-); hydrogen In 1,2-dichloro-ethane at 20℃; for 0.166667h; Reagent/catalyst; Schlenk technique;100%
allylbenzene
300-57-2

allylbenzene

1-(2,3-dichloropropyl)benzene
67168-93-8

1-(2,3-dichloropropyl)benzene

Conditions
ConditionsYield
With tetraethylammonium trichloride In dichloromethane100%
With Phenylselenyl chloride; tetrabutyl-ammonium chloride; chlorine In tetrachloromethane; acetonitrile for 0.666667h; Heating;94%
With hydrogenchloride; potassium permanganate In acetonitrile69%
allylbenzene
300-57-2

allylbenzene

Conditions
ConditionsYield
With water; 4-methylmorpholine N-oxide; osmium; Cu-Al-hydrotalcite In toluene at 60℃; for 11h;100%
With potassium osmate; potassium carbonate; potassium hexacyanoferrate(III) In water; tert-butyl alcohol at 20℃; for 24h;91%
With water; oxygen; palladium diacetate; sodium carbonate at 100℃; under 6080.41 Torr; for 24h; Autoclave;82%
allylbenzene
300-57-2

allylbenzene

trichloro(2-chloro-3-phenylpropyl)-λ4-tellane

trichloro(2-chloro-3-phenylpropyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium tetrachloride In tetrachloromethane at 0 - 25℃; for 9h; regioselective reaction;100%
With tellurium tetrachloride In tetrachloromethane for 1h; Ambient temperature;70%
allylbenzene
300-57-2

allylbenzene

cis-1,4-bis(acetyloxy)but-2-ene
25260-60-0

cis-1,4-bis(acetyloxy)but-2-ene

(E/Z)-4-phenyl-2-buten-1-yl acetate
83540-71-0, 36215-15-3

(E/Z)-4-phenyl-2-buten-1-yl acetate

Conditions
ConditionsYield
With [Ru(dmf)3(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-(2-PrO)-C6H4)][(BF4)2] In toluene at 100℃; for 1h;100%
Cl2Ru(SIMes)(2-(isopropyl)oxy-5-nitrobenzylidene) In toluene at 70℃; for 18h; Product distribution; Further Variations:; Catalysts; reaction time;68%
With C70H113Cl2N3O4Ru In neat (no solvent) at 40℃; for 16h; Cross Metathesis; Inert atmosphere;57%
allylbenzene
300-57-2

allylbenzene

phenylacetaldehyde
122-78-1

phenylacetaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide In water at 75℃; for 6h;100%
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique;96%
Stage #1: allylbenzene With sodium periodate; C22H23N7Ru(2+)*F6P(1-)*CF3O3S(1-) In water; acetone at 20℃; for 2h;
Stage #2: With sodium sulfite In dichloromethane; water for 0.166667h; Catalytic behavior; Reagent/catalyst;
65%
allylbenzene
300-57-2

allylbenzene

ethyl-3,3,3-trifluoropyruvate
13081-18-0

ethyl-3,3,3-trifluoropyruvate

(E)-2-hydroxy-5-phenyl-2-trifluoromethyl-pent-4-enoic acid ethyl ester

(E)-2-hydroxy-5-phenyl-2-trifluoromethyl-pent-4-enoic acid ethyl ester

Conditions
ConditionsYield
silver hexafluoroantimonate; (S)-SEGPHOS-PdCl2 In dichloromethane at 20℃; for 0.5h; Ene reaction;100%
With silver hexafluoroantimonate; (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)dichloroplatinum(II) In dichloromethane at -20℃; for 1h;83%
allylbenzene
300-57-2

allylbenzene

ethyl-3,3,3-trifluoropyruvate
13081-18-0

ethyl-3,3,3-trifluoropyruvate

2-hydroxy-5-phenyl-2-trifluoromethyl-pent-4-enoic acid ethyl ester

2-hydroxy-5-phenyl-2-trifluoromethyl-pent-4-enoic acid ethyl ester

Conditions
ConditionsYield
With silver hexafluoroantimonate; chiral SEGPHOS-Pd(II) In dichloromethane at 20℃; for 0.5h; Friedel-Crafts reaction;100%
allylbenzene
300-57-2

allylbenzene

N-methylaniline
100-61-8

N-methylaniline

N-(2-Methyl-3-phenylpropyl)-anilin
96594-31-9

N-(2-Methyl-3-phenylpropyl)-anilin

Conditions
ConditionsYield
With 3-Methyl-1H-pyridin-2-one; dimethyl-amine; tantalum (V)-pentakis-dimethylamide In toluene at 110℃; for 16h; Glovebox; Inert atmosphere;100%
With (N-[2,6-diisopropylphenyl]pivalamidate)tetrakis(dimethylamido)tantalum In (2)H8-toluene at 130℃; for 19h; Inert atmosphere;85%
Stage #1: allylbenzene With N,N'-bis(2,6-dicyclopentyl-4-methoxyphenyl)formamidine; tetrabenzyl titanium at 20℃; for 0.333333h; Glovebox; Inert atmosphere;
Stage #2: N-methylaniline at 155℃; for 0.1h; Sealed tube;
85%
Ta[N(CH3)2]5 at 160 - 165℃; for 41h;77%
allylbenzene
300-57-2

allylbenzene

(S)-(2,3-epoxypropyl)benzene
91420-74-5

(S)-(2,3-epoxypropyl)benzene

Conditions
ConditionsYield
With whole E. coli cells expressing monooxygenase from Herbaspirillum huttiense HhMO and NADH-dependent flavin oxidoreductase PsStyB In aq. phosphate buffer; octane at 37℃; pH=6; Catalytic behavior; Kinetics; Reagent/catalyst; Temperature; Solvent; pH-value; Concentration; Green chemistry; Enzymatic reaction; enantioselective reaction;100%
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C
2: [(S,S)-N,N’-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(II); water; acetic acid / tetrahydrofuran / 20 h / Cooling with ice
View Scheme
With FAD; 1-Benzyl-1,4-dihydronicotinamide; styrene monooxygenase In aq. buffer at 30℃; for 1h; pH=7; enantioselective reaction;n/a
With D-glucose; recombinant Marinobacterium litorale styrene monooxygenase expressed as a fused protein in Escherichia coli BL21(DE3) In aq. phosphate buffer; deuteromethanol for 9h; pH=8; Enzymatic reaction; enantioselective reaction;26 mg
allylbenzene
300-57-2

allylbenzene

methyl dimethyl 2-(trifluoromethyl)propanedioate
5838-00-6

methyl dimethyl 2-(trifluoromethyl)propanedioate

(E)-dimethyl 2-cinnamyl-2-(trifluoromethyl)malonate
1440140-61-3

(E)-dimethyl 2-cinnamyl-2-(trifluoromethyl)malonate

Conditions
ConditionsYield
With 2,6-dimethoxy-p-quinone; palladium diacetate; triphenylphosphine In 1-methyl-pyrrolidin-2-one at 20℃; for 12h; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique;100%
methanol
67-56-1

methanol

allylbenzene
300-57-2

allylbenzene

tribromo(2-methoxy-3-phenylpropyl)-λ4-tellane

tribromo(2-methoxy-3-phenylpropyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium(IV) tetrabromide at 20 - 60℃; for 6h; regioselective reaction;100%
methanol
67-56-1

methanol

allylbenzene
300-57-2

allylbenzene

trichloro(2-methoxy-3-phenylpropyl)-λ4-tellane

trichloro(2-methoxy-3-phenylpropyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium tetrachloride In dichloromethane at 20 - 25℃; for 20h; regioselective reaction;100%
allylbenzene
300-57-2

allylbenzene

pyridin-2-yl sulfenyl chloride
59089-57-5

pyridin-2-yl sulfenyl chloride

2-(phenylmethyl)-2H,3H-thiazolo[3,2-]pyridine-4-ium chloride

2-(phenylmethyl)-2H,3H-thiazolo[3,2-]pyridine-4-ium chloride

Conditions
ConditionsYield
Stage #1: pyridin-2-yl sulfenyl chloride With bromine In dichloromethane at 20℃; for 0.5h;
Stage #2: allylbenzene In dichloromethane at 20℃; for 60h; regioselective reaction;
100%
allylbenzene
300-57-2

allylbenzene

1-(2,3-dideuteropropyl)benzene
118297-06-6

1-(2,3-dideuteropropyl)benzene

Conditions
ConditionsYield
With deuterium; Wilkinson's catalyst In toluene99.4%
allylbenzene
300-57-2

allylbenzene

1,2-epoxy-3-phenylpropane
4436-24-2

1,2-epoxy-3-phenylpropane

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane Cooling with ice; Inert atmosphere;99%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 2h; Inert atmosphere;99%
With NH-pyrazole; water; dihydrogen peroxide; methyltrioxorhenium(VII) In various solvent(s) for 21h; Ambient temperature;97%
allylbenzene
300-57-2

allylbenzene

(2,3-dibromopropyl)benzene
1586-98-7

(2,3-dibromopropyl)benzene

Conditions
ConditionsYield
With tetrapropylammonium nonabromide In dichloromethane at 0 - 23℃; for 0.0166667h; Reagent/catalyst; Inert atmosphere;99%
With acetic acid; lithium bromide Ambient temperature;98%
With aluminum (III) chloride; ammonium metavanadate; tetrabutylammomium bromide; oxygen In 1,2-dimethoxyethane at 50℃; for 18h;95%
allylbenzene
300-57-2

allylbenzene

bis(methoxycarbonyl)(phenyliodinio)methanide
145838-86-4

bis(methoxycarbonyl)(phenyliodinio)methanide

dimethyl 2-(phenylmethyl)cyclopropane-1,1-dicarboxylate
3709-22-6

dimethyl 2-(phenylmethyl)cyclopropane-1,1-dicarboxylate

Conditions
ConditionsYield
dirhodium tetraacetate at 120℃; for 0.0166667h;99%
With dirhodium tetraacetate In dichloromethane at 25℃; for 3h;53%
allylbenzene
300-57-2

allylbenzene

methyl vinyl ketone
78-94-4

methyl vinyl ketone

(E)-5-phenyl-3-penten-2-one
42762-51-6

(E)-5-phenyl-3-penten-2-one

Conditions
ConditionsYield
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane for 12h; Heating;99%
With Hoveyda-Grubbs catalyst second generation In 1,2-dichloro-ethane Reflux; Inert atmosphere;81%
allylbenzene
300-57-2

allylbenzene

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl (E)-4-phenyl-2-butenoate
63158-17-8, 73845-39-3, 34541-75-8

methyl (E)-4-phenyl-2-butenoate

Conditions
ConditionsYield
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane for 12h; Heating;99%
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Cross Metathesis; Inert atmosphere; Sealed tube; Irradiation;60%
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Alkene (Olefin) Metathesis; Inert atmosphere; Irradiation; Sealed tube;60%
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Irradiation; Sealed tube; Inert atmosphere;60%
allylbenzene
300-57-2

allylbenzene

dithiocarbonic acid S-[2-(2,4-difluoro-phenyl)-2-oxo-ethyl] ester O-ethyl ester

dithiocarbonic acid S-[2-(2,4-difluoro-phenyl)-2-oxo-ethyl] ester O-ethyl ester

S-(5-(2,4-difluorophenyl)-5-oxo-1-phenylpentan-2-yl) O-ethyl carbonodithioate
1246016-64-7

S-(5-(2,4-difluorophenyl)-5-oxo-1-phenylpentan-2-yl) O-ethyl carbonodithioate

Conditions
ConditionsYield
With dilauryl peroxide In cyclohexane Inert atmosphere; Reflux;99%
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