Product Name: Allylbenzene Synonyms: 1-benzylethene;1-Phenyl-2-propene;1-Propene, 3-phenyl-;1-propene,3-phenyl-;Allylbenzene,98%;Allylbenzol, 3-Phenyl-1-propen, 2-Propenylbenzol;benzyl ethylene;ALLYBENZENE CAS: 300-57-2 MF: C9H10 MW: 1
Cas:300-57-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a
ISO9001 Exporting Japan, Korea regularly. Appearance:Colorless liquid Storage:Store in dry and cool place with good seal Package:25liter/200liter plastic drum Application:Colorless liquid Transportation:by courier,by Air,by Sea ... Port:Chinese
Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi
Cas:300-57-2
Min.Order:100 Gram
Negotiable
Type:Manufacturers
inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:300-57-2
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:300-57-2
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so
Cas:300-57-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $10.0 / 20.0
Type:Trading Company
inquiryChemical Name: Allylbenzene CAS No.: 300-57-2 Molecular Fomula:C9H10 Chemical Structure: Molecular weight: 118.18 Appearance: Colorless liquid Assay:98%MIN Appearance: Colorless Liquid Storage:Store in cool and dry place, away from su
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:300-57-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $153.0 / 187.7
Type:Trading Company
inquiryAllylbenzene CAS: 300-57-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates
Cas:300-57-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:300-57-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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Cas:300-57-2
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Allylbenzene CAS 300-57-2 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly. 2 Pr
Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $10.0 / 50.0
Type:Trading Company
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Allylbenzene CAS 300-57-2 Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality control syste
Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $10.0 / 50.0
Type:Trading Company
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:300-57-2
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
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Cas:300-57-2
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquirySuperior quality, moderate price & quick delivery. Appearance:colorless liquid Storage:Stored in a cool, well-ventilated place at temperatures not higher than 35 ° C Package:in 170kgs net new galvanized steel drum; or as per your request. Appli
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Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0) In N,N,N,N,N,N-hexamethylphosphoric triamide for 6h; | 100% |
With [Pd(triphenylphosphine)(allyl)(chloride)] In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 5h; | 96 % Chromat. |
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; diethyl ether at 25℃; for 3h; | 100% |
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; diethyl ether at 25℃; for 1.5h; | 100% |
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 3.5 h); | A 100% B 0% C n/a |
bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 3 h); | A 55% B 40% C n/a |
Allyl acetate
phenylzinc chloride
A
allylbenzene
B
biphenyl
C
zinc diacetate
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 5 h); | A 100% B 0% C n/a |
C14H15NSe
cyclohexene
A
allylbenzene
B
cyclohexane-1,2-epoxide
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In chloroform-d1 at 20℃; | A 100% B 100% |
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Electrochemical reaction; Inert atmosphere; | A 1% B 99% |
Conditions | Yield |
---|---|
Stage #1: bromobenzene With iodine; magnesium In diethyl ether Inert atmosphere; Reflux; Stage #2: allyl bromide In diethyl ether at 0 - 20℃; for 2.08333h; Inert atmosphere; | 99% |
Stage #1: bromobenzene With magnesium In tetrahydrofuran Stage #2: allyl bromide In tetrahydrofuran Stage #3: With ammonium chloride In water | |
With magnesium In tetrahydrofuran at 20℃; | |
Stage #1: bromobenzene With iodine; magnesium In tetrahydrofuran at 20℃; Stage #2: allyl bromide In tetrahydrofuran for 1h; |
propargyl benzene
allylbenzene
Conditions | Yield |
---|---|
With hydrogen In toluene at 20℃; under 38002.6 Torr; for 12h; Autoclave; chemoselective reaction; | 99% |
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 3h; | 96% |
With hydrogen In acetonitrile at 120℃; under 22502.3 Torr; for 15h; Autoclave; Sealed tube; | 72% |
Conditions | Yield |
---|---|
Cu(acac)2-PPh3 In tetrahydrofuran at 40℃; for 4h; | 98% |
Cu(acac)2-PPh3 In tetrahydrofuran at 40℃; for 4h; Product distribution; effects of solvent, catalyst and catalyst activator; further solvents, further catalysts; |
Allyl acetate
diphenylmagnesium
A
allylbenzene
B
1,1-diphenylethanol
Conditions | Yield |
---|---|
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 40℃; for 4h; | A 98% B n/a |
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 40℃; for 4h; Product distribution; effect of catalysts, activator ligands, solvents on yield; effect of variation of ester residue in the allyl ester partner; reactions between further dialkyl- and diarylmagnesiums and allyl esters; | A 98% B n/a |
Conditions | Yield |
---|---|
With 2C2H3O2(1-)*Pd(2+)*3Na(1+)*C18H12O9PS3(3-); potassium tert-butylate; glycerol at 100℃; for 2h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 98% |
With potassium tert-butylate; (1,3-di(2,4,6-(CH3)3-C6H2)-imidazol-2-ylidene)Pd(OAc)2 In isopropyl alcohol at 20℃; for 2h; Suzuki-Miyaura coupling; | 93% |
With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate In toluene at 110℃; for 15h; Suzuki-Miyaura coupling; Inert atmosphere; | 90% |
allyl phenyl ether
phenylzinc chloride
A
allylbenzene
B
biphenyl
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h); | A 98% B 0% C n/a |
Conditions | Yield |
---|---|
With C11H22P(1+)*Br(1-); lithium tri-t-butoxyaluminum hydride In tetrahydrofuran; dodecane; toluene at 90℃; for 16h; Reagent/catalyst; regioselective reaction; | 96% |
With hydrogenchloride; indium 1.) DMF, 1 h, RT, 2.) 1 min; Yield given. Multistep reaction; |
2-(tosyloxy)dodecane
allylbenzene
Conditions | Yield |
---|---|
With Pd(P(t-Bu)2Me)2; potassium tert-butylate; N-cyclohexyl-cyclohexanamine In 1,4-dioxane at 80℃; for 8h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 70℃; | 95% |
With bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 70℃; for 3h; | 95% |
carbon monoxide
(2E)-3-phenylprop-2-en-1-yl formate
A
allylbenzene
B
1-phenylpropene
C
trans-styrylacetic acid
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine In toluene at 60℃; under 45600 Torr; for 15h; | A 1% B 1% C 95% |
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine In toluene under 15200 Torr; for 96h; Product distribution; Ambient temperature; other reagents, other solvents, var. temp., pressure, time; |
allylbenzene
Conditions | Yield |
---|---|
Cu(acac)2-PPh3 In tetrahydrofuran | 95% |
Conditions | Yield |
---|---|
With 2C2H3O2(1-)*Pd(2+)*3Na(1+)*C18H12O9PS3(3-); potassium tert-butylate; glycerol at 100℃; for 12h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 95% |
With potassium tert-butylate; (1,3-di(2,4,6-(CH3)3-C6H2)-imidazol-2-ylidene)Pd(OAc)2 In isopropyl alcohol at 20℃; for 0.5h; Suzuki-Miyaura coupling; | 72% |
With potassium tert-butylate In isopropyl alcohol at 50℃; for 12h; Inert atmosphere; | 71% |
With potassium hydroxide; phenone oxime-derived palladacycle; tetrabutylammomium bromide In water; acetone at 20℃; for 2h; Suzuki coupling; | 69% |
With dichloro(N-(diphenylphosphino)-N-isopropyl-1,1-diphenylphosphinamine) digold(I); caesium carbonate In acetonitrile at 80℃; for 18h; Temperature; chemoselective reaction; | 21 %Spectr. |
Conditions | Yield |
---|---|
With dichloro bis(acetonitrile) palladium(II); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran at 20℃; for 14h; Kumada-Corriu reaction; Inert atmosphere; | 95% |
Stage #1: vinyl magnesium bromide With indium(III) chloride In tetrahydrofuran Stage #2: benzyl bromide With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Heating; | 82% |
trimethyl(phenyl)stannane
allyl bromide
A
allylbenzene
B
trimethyltin bromide
Conditions | Yield |
---|---|
With ((π-C3H5)PdCl)2 In N,N-dimethyl-formamide 70°C; | A 95% B n/a |
Conditions | Yield |
---|---|
Stage #1: C14H15NSe With Dess-Martin periodane In dichloromethane at 20℃; Stage #2: With water; sodium carbonate at 20℃; | A 95% B n/a |
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 1h; Heating; | 94% |
phenylaluminium dichloride
allyl bromide
A
allylbenzene
B
biphenyl
C
aluminium bromide
Conditions | Yield |
---|---|
bis(η3-allyl-μ-chloropalladium(II)) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h); | A 94% B <1 C n/a |
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h); | A <1 B <1 C n/a |
3-benzyl propionaldehyde
allylbenzene
Conditions | Yield |
---|---|
With methoxy(cyclooctadiene)rhodium(I) dimer; N,N-Dimethylacrylamide; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 90℃; for 3h; Time; | 94% |
With methoxy(cyclooctadiene)rhodium(I) dimer; N,N-Dimethylacrylamide; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 90℃; for 3h; | 94% |
With methoxy(cyclooctadiene)rhodium(I) dimer; 3-Methoxybenzoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran at 40 - 80℃; chemoselective reaction; | 90 %Spectr. |
Conditions | Yield |
---|---|
bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 60℃; for 12h; | 93% |
Conditions | Yield |
---|---|
With 6,6'-dimethyl-2,2'-bipyridine; (1,2-dimethoxyethane)dichloronickel(II); bis(pinacol)diborane; lithium tert-butoxide In N,N-dimethyl acetamide; water at 30℃; for 24h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
With hydrogen; triethyl phosphite In isopropyl alcohol at 100℃; under 4500.45 Torr; for 25h; Glovebox; chemoselective reaction; | 92% |
With bis(acetylacetonate)nickel(II); diethylzinc In 1,2-dimethoxyethane; hexane at 80℃; for 48h; Inert atmosphere; | 88% |
With carbon monoxide In water at 27℃; under 760.051 Torr; for 24h; chemoselective reaction; | 69% |
Conditions | Yield |
---|---|
With copper acetylacetonate; triphenylphosphine In tetrahydrofuran at 60℃; for 4h; further reagents and solvents; | 92% |
Conditions | Yield |
---|---|
With tetramethyldialuminoxane; [Zr(NPhPPh2)4] In tetrahydrofuran-d8 at 20℃; for 0.25h; Isomerization; | 100% |
With tetramethyldialuminoxane; [{N(SiMe3)C(Ph)}2CH]2TiCl2 In (2)H8-toluene at 25℃; for 1h; Kinetics; Further Variations:; Catalysts; | 99.5% |
With C44H58Cl2N4Pd In isopropyl alcohol at 70℃; for 3h; optical yield given as %de; diastereoselective reaction; | 98% |
Conditions | Yield |
---|---|
With potassium hydroxide In 1,2-dimethoxyethane at 40℃; for 0.5h; | 100% |
With potassium hydroxide In butan-1-ol for 3h; Heating; | 100% |
With bis(1,5-cyclooctadiene)nickel(0); [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene In toluene at 130℃; for 1h; Reagent/catalyst; Temperature; Time; | 99% |
Conditions | Yield |
---|---|
With Pt-Sn-citrate; hydrogen In methanol at 50℃; under 3800 Torr; for 3h; var. temperatures; var. pressures; | 100% |
With Pt-Sn-citrate; hydrogen In methanol at 50℃; under 3800 Torr; for 3h; | 100% |
With C49H60BF2IrN5(1+)*C32H12BF24(1-); hydrogen In 1,2-dichloro-ethane at 20℃; for 0.166667h; Reagent/catalyst; Schlenk technique; | 100% |
allylbenzene
1-(2,3-dichloropropyl)benzene
Conditions | Yield |
---|---|
With tetraethylammonium trichloride In dichloromethane | 100% |
With Phenylselenyl chloride; tetrabutyl-ammonium chloride; chlorine In tetrachloromethane; acetonitrile for 0.666667h; Heating; | 94% |
With hydrogenchloride; potassium permanganate In acetonitrile | 69% |
allylbenzene
3-phenylpropane-1,2-diol
Conditions | Yield |
---|---|
With water; 4-methylmorpholine N-oxide; osmium; Cu-Al-hydrotalcite In toluene at 60℃; for 11h; | 100% |
With potassium osmate; potassium carbonate; potassium hexacyanoferrate(III) In water; tert-butyl alcohol at 20℃; for 24h; | 91% |
With water; oxygen; palladium diacetate; sodium carbonate at 100℃; under 6080.41 Torr; for 24h; Autoclave; | 82% |
allylbenzene
Conditions | Yield |
---|---|
With tellurium tetrachloride In tetrachloromethane at 0 - 25℃; for 9h; regioselective reaction; | 100% |
With tellurium tetrachloride In tetrachloromethane for 1h; Ambient temperature; | 70% |
allylbenzene
cis-1,4-bis(acetyloxy)but-2-ene
(E/Z)-4-phenyl-2-buten-1-yl acetate
Conditions | Yield |
---|---|
With [Ru(dmf)3(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-(2-PrO)-C6H4)][(BF4)2] In toluene at 100℃; for 1h; | 100% |
Cl2Ru(SIMes)(2-(isopropyl)oxy-5-nitrobenzylidene) In toluene at 70℃; for 18h; Product distribution; Further Variations:; Catalysts; reaction time; | 68% |
With C70H113Cl2N3O4Ru In neat (no solvent) at 40℃; for 16h; Cross Metathesis; Inert atmosphere; | 57% |
Conditions | Yield |
---|---|
With dihydrogen peroxide In water at 75℃; for 6h; | 100% |
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique; | 96% |
Stage #1: allylbenzene With sodium periodate; C22H23N7Ru(2+)*F6P(1-)*CF3O3S(1-) In water; acetone at 20℃; for 2h; Stage #2: With sodium sulfite In dichloromethane; water for 0.166667h; Catalytic behavior; Reagent/catalyst; | 65% |
allylbenzene
ethyl-3,3,3-trifluoropyruvate
Conditions | Yield |
---|---|
silver hexafluoroantimonate; (S)-SEGPHOS-PdCl2 In dichloromethane at 20℃; for 0.5h; Ene reaction; | 100% |
With silver hexafluoroantimonate; (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)dichloroplatinum(II) In dichloromethane at -20℃; for 1h; | 83% |
allylbenzene
ethyl-3,3,3-trifluoropyruvate
Conditions | Yield |
---|---|
With silver hexafluoroantimonate; chiral SEGPHOS-Pd(II) In dichloromethane at 20℃; for 0.5h; Friedel-Crafts reaction; | 100% |
Conditions | Yield |
---|---|
With 3-Methyl-1H-pyridin-2-one; dimethyl-amine; tantalum (V)-pentakis-dimethylamide In toluene at 110℃; for 16h; Glovebox; Inert atmosphere; | 100% |
With (N-[2,6-diisopropylphenyl]pivalamidate)tetrakis(dimethylamido)tantalum In (2)H8-toluene at 130℃; for 19h; Inert atmosphere; | 85% |
Stage #1: allylbenzene With N,N'-bis(2,6-dicyclopentyl-4-methoxyphenyl)formamidine; tetrabenzyl titanium at 20℃; for 0.333333h; Glovebox; Inert atmosphere; Stage #2: N-methylaniline at 155℃; for 0.1h; Sealed tube; | 85% |
Ta[N(CH3)2]5 at 160 - 165℃; for 41h; | 77% |
allylbenzene
(S)-(2,3-epoxypropyl)benzene
Conditions | Yield |
---|---|
With whole E. coli cells expressing monooxygenase from Herbaspirillum huttiense HhMO and NADH-dependent flavin oxidoreductase PsStyB In aq. phosphate buffer; octane at 37℃; pH=6; Catalytic behavior; Kinetics; Reagent/catalyst; Temperature; Solvent; pH-value; Concentration; Green chemistry; Enzymatic reaction; enantioselective reaction; | 100% |
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C 2: [(S,S)-N,N’-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(II); water; acetic acid / tetrahydrofuran / 20 h / Cooling with ice View Scheme | |
With FAD; 1-Benzyl-1,4-dihydronicotinamide; styrene monooxygenase In aq. buffer at 30℃; for 1h; pH=7; enantioselective reaction; | n/a |
With D-glucose; recombinant Marinobacterium litorale styrene monooxygenase expressed as a fused protein in Escherichia coli BL21(DE3) In aq. phosphate buffer; deuteromethanol for 9h; pH=8; Enzymatic reaction; enantioselective reaction; | 26 mg |
allylbenzene
methyl dimethyl 2-(trifluoromethyl)propanedioate
(E)-dimethyl 2-cinnamyl-2-(trifluoromethyl)malonate
Conditions | Yield |
---|---|
With 2,6-dimethoxy-p-quinone; palladium diacetate; triphenylphosphine In 1-methyl-pyrrolidin-2-one at 20℃; for 12h; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique; | 100% |
Conditions | Yield |
---|---|
With tellurium(IV) tetrabromide at 20 - 60℃; for 6h; regioselective reaction; | 100% |
Conditions | Yield |
---|---|
With tellurium tetrachloride In dichloromethane at 20 - 25℃; for 20h; regioselective reaction; | 100% |
allylbenzene
pyridin-2-yl sulfenyl chloride
Conditions | Yield |
---|---|
Stage #1: pyridin-2-yl sulfenyl chloride With bromine In dichloromethane at 20℃; for 0.5h; Stage #2: allylbenzene In dichloromethane at 20℃; for 60h; regioselective reaction; | 100% |
allylbenzene
1-(2,3-dideuteropropyl)benzene
Conditions | Yield |
---|---|
With deuterium; Wilkinson's catalyst In toluene | 99.4% |
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane Cooling with ice; Inert atmosphere; | 99% |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 2h; Inert atmosphere; | 99% |
With NH-pyrazole; water; dihydrogen peroxide; methyltrioxorhenium(VII) In various solvent(s) for 21h; Ambient temperature; | 97% |
Conditions | Yield |
---|---|
With tetrapropylammonium nonabromide In dichloromethane at 0 - 23℃; for 0.0166667h; Reagent/catalyst; Inert atmosphere; | 99% |
With acetic acid; lithium bromide Ambient temperature; | 98% |
With aluminum (III) chloride; ammonium metavanadate; tetrabutylammomium bromide; oxygen In 1,2-dimethoxyethane at 50℃; for 18h; | 95% |
allylbenzene
bis(methoxycarbonyl)(phenyliodinio)methanide
dimethyl 2-(phenylmethyl)cyclopropane-1,1-dicarboxylate
Conditions | Yield |
---|---|
dirhodium tetraacetate at 120℃; for 0.0166667h; | 99% |
With dirhodium tetraacetate In dichloromethane at 25℃; for 3h; | 53% |
Conditions | Yield |
---|---|
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane for 12h; Heating; | 99% |
With Hoveyda-Grubbs catalyst second generation In 1,2-dichloro-ethane Reflux; Inert atmosphere; | 81% |
allylbenzene
acrylic acid methyl ester
methyl (E)-4-phenyl-2-butenoate
Conditions | Yield |
---|---|
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane for 12h; Heating; | 99% |
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Cross Metathesis; Inert atmosphere; Sealed tube; Irradiation; | 60% |
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Alkene (Olefin) Metathesis; Inert atmosphere; Irradiation; Sealed tube; | 60% |
With RuCl2(CHPh)(IMes)2; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; for 4h; Irradiation; Sealed tube; Inert atmosphere; | 60% |
allylbenzene
S-(5-(2,4-difluorophenyl)-5-oxo-1-phenylpentan-2-yl) O-ethyl carbonodithioate
Conditions | Yield |
---|---|
With dilauryl peroxide In cyclohexane Inert atmosphere; Reflux; | 99% |
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