1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h; | 99% |
Conditions | Yield |
---|---|
With aluminum oxide; copper(ll) bromide In tetrachloromethane at 80℃; for 1h; | 98% |
With ammonium cerium(IV) nitrate; lithium bromide In acetonitrile at 20℃; for 6h; | 98% |
With 1-dodecyl-3-methylimidazol-1-ium bromide at 50℃; for 2h; | 98% |
1-Naphthylboronic acid
1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In acetonitrile at 80℃; for 14h; | 98% |
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube; | 87% |
1-naphthylboronic acid pinacol ester
1-Bromonaphthalene
Conditions | Yield |
---|---|
With copper(ll) bromide In methanol Heating; | 95% |
Conditions | Yield |
---|---|
With carbon tetrabromide; iron In ethanol at 20℃; for 2h; Solvent; Reagent/catalyst; Irradiation; | 94% |
1-naphthyltrimethylsilane
1-Bromonaphthalene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In 1,2-dichloro-ethane; acetonitrile at 85℃; for 12h; | 92% |
6-Bromo-2,3-dihydro-naphtho[1,2-b][1,4]dithiine
1-Bromonaphthalene
Conditions | Yield |
---|---|
With Ni(Ra)-W2 In acetic acid at 40℃; for 0.833333h; | 90% |
potassium trifluoro(naphth-1-yl)borate
1-Bromonaphthalene
Conditions | Yield |
---|---|
With pyridinium hydrobromide perbromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 90% |
With acetic acid; lithium bromide In dimethyl sulfoxide at 100℃; for 8h; Schlenk technique; | 42% |
1-Bromonaphthalene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution; | 87% |
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 81% |
Conditions | Yield |
---|---|
With trimethylsilyl bromide; N-benzyl-N,N,N-triethylammonium chloride; sodium nitrite In tetrachloromethane 1.) 0 deg C, 1.5 h, 2.) r.t., 17 h; | 85% |
With dinitrogen trioxide; hydrogen bromide; acetic acid at 5 - 10℃; anschliessendes Erhitzen bis auf Siedetemperatur; |
A
1,8-dibromonaphthalene
B
1-Bromonaphthalene
Conditions | Yield |
---|---|
With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination; | A 81% B 13% |
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 4h; Reflux; | 72% |
1,2-diethynylbenzene
1-Bromonaphthalene
Conditions | Yield |
---|---|
With hydrogen bromide; platinum(II) chloride In water at 100℃; for 4h; | 71% |
Multi-step reaction with 2 steps 1: 98 percent / HBr / H2O; various solvent(s) / 1.5 h / 100 °C 2: PtCl2 / H2O; various solvent(s) / 12 h / 100 °C View Scheme |
tetralin
A
naphthalene
B
1-Bromonaphthalene
C
1,4-dibromo-1,2,3,4-tetrahydronaphthalene
trans-2-bromo-1,2,3,4-tetrahydronaphthalen-1-ol
Conditions | Yield |
---|---|
With bromine In tetrachloromethane at 77℃; for 0.166667h; Further byproducts given; | A 14% B 10% C 63% D 8% |
Conditions | Yield |
---|---|
With iodine In benzene-d6 Inert atmosphere; | A 37% B 56% |
Conditions | Yield |
---|---|
With iodine In benzene-d6 Inert atmosphere; | A 43% B 52% |
Conditions | Yield |
---|---|
With oxygen; potassium bromide; sodium nitrite In water; trifluoroacetic acid at 20℃; for 5h; Product distribution; | A 49% B n/a |
Conditions | Yield |
---|---|
With 1,2-dichloro-ethane; copper(l) chloride; 1,3-bis(pyridin-2-ylmethyl)-1H-imidazolium chloride at 200℃; for 2h; Product distribution / selectivity; Microwave irradiation; | A 49% B n/a |
Conditions | Yield |
---|---|
In tetrahydrofuran at 25℃; for 60h; | 40% |
With bromobenzene; tetrabutylammomium bromide; o-CH3C6H4NiBr(PEt3)2 In benzene at 80℃; for 20h; sealed tube; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With bromine In tetrachloromethane at 30℃; for 7h; Bromination; Irradiation; | A 25% B 3% C 35% D 6% |
naphthalene
A
1-Bromonaphthalene
B
1,2,3,4-tetrabromo-1,2,3,4-tetrahydronaphthalene
Conditions | Yield |
---|---|
With bromine In tetrachloromethane for 8h; | A 35% B n/a C n/a |
Conditions | Yield |
---|---|
at 250℃; | |
at 250℃; |
Conditions | Yield |
---|---|
at 150 - 180℃; |
Conditions | Yield |
---|---|
With bromine; iron(III) chloride at 150 - 200℃; | |
With bromine in der Gasphase bei 550-600grad in Gegenwart oder Abwesenheit von FeBr3; |
tetrachloromethane
naphthalene
1,3-dibromo-5-ethyl-5-methyl-imidazolidine-2,4-dione
1-Bromonaphthalene
Conditions | Yield |
---|---|
Isomerisierung; |
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessende Behandlung mit Wasser; | |
With magnesium; benzene anschliessende Behandlung mit Wasser; |
1,6-dibromonaphthalene
1-Bromonaphthalene
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessende Behandlung mit Wasser; | |
With magnesium; benzene anschliessende Behandlung mit Wasser; |
Conditions | Yield |
---|---|
With copper(ll) bromide |
Conditions | Yield |
---|---|
durch Diazotieren des salpetersauren Salzes und Behandeln des Diazoniumnitrats mit Alkohol; |
Conditions | Yield |
---|---|
With iodine; magnesium In diethyl ether for 3h; Grignard reaction; Heating; | 100% |
With iodine; magnesium 1.) ether, reflux, 2.) ether, benzene, RT, 2 h; Yield given. Multistep reaction; | |
Stage #1: 1-Bromonaphthalene With magnesium In diethyl ether Stage #2: cyclopentanone In diethyl ether for 3h; Grignard reaction; | |
Stage #1: 1-Bromonaphthalene With magnesium In diethyl ether for 0.5h; Reflux; Stage #2: cyclopentanone In diethyl ether at 0℃; for 1h; |
Conditions | Yield |
---|---|
With C31H26N6O4Pd; potassium carbonate In water at 100℃; for 3h; Suzuki-Miyaura coupling; | 100% |
With potassium phosphate; 1,1'-bis(4-methoxyphenyl)-3,3'-methylene-diimidazoline-2,2'-diylidene-palladium(II)-dibromide In toluene at 40℃; for 2h; Reagent/catalyst; Temperature; Time; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
With C16H21ClN2Pd; sodium carbonate In methanol at 85℃; for 1h; Reagent/catalyst; Suzuki-Miyaura Coupling; | 100% |
Conditions | Yield |
---|---|
In benzene at 10℃; for 24h; | 100% |
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane for 2h; Heating; | 100% |
Stage #1: 1-Bromonaphthalene; dimethyl zinc(II) With n-butyllithium In tetrahydrofuran; diethyl ether; hexane at 0℃; for 0.5h; Substitution; Stage #2: With oxovanadium(V) ethoxydichloride In tetrahydrofuran; diethyl ether; hexane at 20℃; for 3h; Oxidation; Alkylation; Further stages.; | 73% |
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With iodine; magnesium In diethyl ether Grignard reaction; Stage #2: cyclopentadecanone In diethyl ether Grignard reaction; | 100% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate In tetrahydrofuran at 20℃; for 6h; Suzuki coupling; Inert atmosphere; | 100% |
With C64H76Br2N4O2Pd; potassium carbonate In N,N-dimethyl acetamide at 20 - 140℃; for 24h; Suzuki coupling; Inert atmosphere; | 99% |
With potassium fluoride; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 20℃; for 48h; Suzuki coupling; | 97% |
1-Bromonaphthalene
3-(trimethoxysilyl)propan-1-amine
Methyl 1-naphthylphosphinate
Conditions | Yield |
---|---|
With anilinium hypophosphorous salt; 1,3-bis-(diphenylphosphino)propane; palladium diacetate In acetonitrile Heating; | 100% |
2-Acetylthiophene
1-Bromonaphthalene
1-(5-(naphthalen-1-yl)thiophen-2-yl)ethan-1-one
Conditions | Yield |
---|---|
With dichloro[1-(β-methallyl)-3-(2,4,6-trimethyl)benzylbenzimidazole-2-ylidene]pyridine palladium(II); potassium acetate In N,N-dimethyl acetamide at 130℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 100% |
With PdCl(1,4-bis(diphenylphosphino)butane)(C3H5); potassium acetate at 150℃; for 16h; Inert atmosphere; Schlenk technique; | 82% |
With sodium acetate; bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl acetamide at 150℃; for 20h; | 77% |
With sodium carbonate; silver(l) oxide; Trimethylacetic acid In N,N-dimethyl-formamide at 120℃; for 18h; Quantum yield; Green chemistry; | 52% |
Conditions | Yield |
---|---|
With sodium carbonate; palladium diacetate In 1-methyl-pyrrolidin-2-one; Hexadecane at 140℃; for 16h; | 100% |
With 1-methyl-pyrrolidin-2-one; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium carbonate at 120℃; for 12h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere; | 95% |
With dichlorobis(dibenzyl diisopropylphosphoramidite)palladium(II); sodium fluoride In N,N-dimethyl-formamide at 130℃; for 16h; | 94% |
(4R,5R)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one
1-Bromonaphthalene
(3R,4R)-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxy-4-methyl-1-(1-naphthyl)pentan-1-one
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In tetrahydrofuran at -78℃; Stage #2: With cerium chloride In tetrahydrofuran; pentane for 2h; Cooling; Stage #3: (4R,5R)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one In tetrahydrofuran; pentane at -100℃; for 0.5h; | 100% |
(4S,5S)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one
1-Bromonaphthalene
(3S,4S)-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxy-4-methyl-1-(1-naphthyl)pentan-1-one
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In tetrahydrofuran at -78℃; Stage #2: With cerium chloride In tetrahydrofuran; pentane for 2h; Cooling; Stage #3: (4S,5S)-4-(tert-butyldimethylsiloxy)-5-[(tert-butyldimethylsiloxy)methyl]-5-methyldihydrofuran-2(3H)-one In tetrahydrofuran; pentane at -100℃; for 0.5h; | 100% |
Conditions | Yield |
---|---|
Stage #1: phenylmethanethiol With sodium t-butanolate In tetrahydrofuran at 23℃; for 0.166667h; Inert atmosphere; Stage #2: With zinc(II) chloride In tetrahydrofuran for 0.166667h; Inert atmosphere; Stage #3: 1-Bromonaphthalene With di-μ-bromobis(tri-tert-butylphosphino)dipalladium(I); lithium iodide In tetrahydrofuran at 90℃; for 2h; Inert atmosphere; | 100% |
2-(n-propyl)-thiazole
1-Bromonaphthalene
5-(naphthalen-1-yl)-2-propylthiazole
Conditions | Yield |
---|---|
With dichloro[1-(β-methallyl)-3-(2,3,5,6-tetramethyl)benzylbenzimidazole-2-ylidene]pyridine palladium(II); potassium acetate In N,N-dimethyl acetamide at 130℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 100% |
Conditions | Yield |
---|---|
With sodium hydroxide; cobalt(II) acetate In ethanol at 65℃; under 1520 Torr; for 4h; Irradiation; | 99.3% |
With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl In water; benzene at 65℃; under 760 Torr; for 5h; Irradiation; | 96% |
With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 4.5h; Irradiation; | 95% |
With tributyl-amine; water; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride at 110 - 130℃; under 3 Torr; for 24h; | 48% |
With water; sodium acetate; triethylamine; Pd-bis(1-methylbenzothiazole-2-carbene) In N,N-dimethyl acetamide at 130℃; for 7h; | 55 % Chromat. |
Conditions | Yield |
---|---|
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Catalytic behavior; Reagent/catalyst; Solvent; Schlenk technique; | 99% |
Stage #1: 1-Bromonaphthalene With bis(tri-tert-butylphosphine)palladium(0); sodium chloride In water at 20℃; for 0.166667h; Negishi Coupling; Schlenk technique; Stage #2: n-butyllithium With zinc(II) chloride In 2-methyltetrahydrofuran; water at 10℃; for 0.00555556h; Schlenk technique; chemoselective reaction; | 98% |
Stage #1: n-butyllithium With zinc(II) chloride In tetrahydrofuran at 20℃; for 0.5h; Stage #2: 1-Bromonaphthalene; dichloro bis(acetonitrile) palladium(II) In toluene at 60℃; for 3h; Negishi coupling; Further stages.; | 96% |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 6h; ultrasonic acceleration of reduction; | 99% |
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 18h; Heating; | 99% |
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 18h; Heating; | 99% |
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene With tert.-butyl lithium In diethyl ether at -78℃; Stage #2: In diethyl ether Stage #3: With Duroquinone In diethyl ether | 99% |
With DPEPhos; potassium tert-butylate; palladium diacetate; bis(pinacol)diborane for 12h; Heating; | 99% |
With chromium dichloride; manganese; nickel dichloride; bipyridyl-type ligand In tetrahydrofuran at 20℃; for 17h; Arylation; Homocoupling reaction; | 98% |
carbon monoxide
1-Bromonaphthalene
butan-1-ol
naphthalene-1-carboxylic acid butyl ester
Conditions | Yield |
---|---|
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; triethylamine; palladium dichloride at 120℃; under 760.051 Torr; for 12h; | 99% |
With tributyl-amine; triphenylphosphine; silica-supported poly<3-(2-cyanoethylsulfanyl)propylsiloxane palladium> at 100℃; under 760 Torr; for 72h; | 34% |
With bis(triphenylphosphine)palladium dibromide; tributyl-amine |
Conditions | Yield |
---|---|
With potassium phosphate; d(4)-methanol; palladium diacetate; catacxium A In toluene at 80℃; for 16h; | 99% |
With sodium amalgam; deuteromethanol for 2h; Heating; | 95% |
With tetrahydrofuran-d8; 2,2'-azobis-(2,4-dimethylvaleronitrile); tri-n-butyl-tin hydride for 5h; Reflux; regioselective reaction; | 68% |
With water-d2; magnesium 1.) Grignard; Multistep reaction; | |
With water-d2; potassium carbonate In acetonitrile at 20℃; pH=12.15; Electrochemical reaction; |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃; for 15h; | 99% |
1-Bromonaphthalene
4-methylphenylboronic acid
1-(4-methylphenyl)naphthalene
Conditions | Yield |
---|---|
With potassium phosphate; N-[(4-diphenylphosphinophenyl)methyl] D-gluconamide; PdCl2(GLCAphos)2 In water at 80℃; for 16h; | 99% |
With 3,5-di-tert-butyl-2-hydroxybenzaldehyde; potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 2h; Suzuki-Miyaura Coupling; | 99% |
With potassium carbonate; palladium diacetate In various solvent(s) at 110℃; for 15h; Suzuki reaction; | 97% |
Conditions | Yield |
---|---|
With magnesium; ethylene dibromide In tetrahydrofuran at 20℃; for 1h; | 99% |
Stage #1: 1-Bromonaphthalene With iodine; magnesium In tetrahydrofuran at 65℃; for 2h; Inert atmosphere; Stage #2: formic acid ethyl ester In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Heating; | 93% |
Stage #1: 1-Bromonaphthalene With iodine; magnesium In tetrahydrofuran at 20℃; for 2.15h; Stage #2: formic acid ethyl ester In tetrahydrofuran at 20℃; for 2h; | 90% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 24h; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); sodium tert-pentoxide; (R)-tol-BINAP In toluene at 80℃; for 18h; Inert atmosphere; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4h; Inert atmosphere; | 92% |
With C37H55O2PPd(1+)*CF3O3S(1-); sodium t-butanolate In toluene at 90℃; for 6h; Schlenk technique; Inert atmosphere; | 75% |
With [Pd(allyl)(BrettPhos)]OTf; sodium t-butanolate In toluene at 90℃; Schlenk technique; Inert atmosphere; | 72% |
acrylic acid n-butyl ester
1-Bromonaphthalene
butyl (E)-3-(naphthalen-1-yl)acrylate
Conditions | Yield |
---|---|
With C68H96Br2N2O8P2Pd2; triethylamine; 3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl diisopropylphosphoramidite In 1-methyl-pyrrolidin-2-one at 80℃; for 16h; Mizoroki-Heck reaction; Inert atmosphere; regioselective reaction; | 99% |
With phenyl carbamate; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 130℃; for 2h; Heck-type reaction; | 98% |
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 4h; Heck Reaction; Inert atmosphere; Schlenk technique; | 97% |
1-Bromonaphthalene
ethyl 2-cyanoacetate
ethyl 2-cyano-2-(naphthalen-1-yl)acetate
Conditions | Yield |
---|---|
With P(i-BuNCH2CH2)3N; potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 90℃; for 5h; | 99% |
With tri-tert-butyl phosphine; sodium phosphate; bis(dibenzylideneacetone)-palladium(0) In toluene at 70℃; for 4h; | 83% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride In 1,2-dimethoxyethane for 16h; Heating; | 99% |
1-Bromonaphthalene
4-methoxyphenylboronic acid
1-(4-methoxyphenyl)naphthalene
Conditions | Yield |
---|---|
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 99% |
With tetraamminepalladium(II) chloride; tetra(n-butyl)ammonium hydroxide In water at 45℃; for 2h; Suzuki-Miyaura Coupling; Green chemistry; | 99% |
With Ti0.97Pd0.03O1.97; potassium carbonate In water at 100℃; for 6h; Suzuki-Miyaura Coupling; | 99% |
IUPAC Name: 1-Bromonaphthalene
CAS: 90-11-9
Formula: C10H7Br
Molecular Weight: 207.07
Molecular Structure of 1-Bromonaphthalene (90-11-9):
Density: 1.481 g/cm3
Flash Point: 127.8 °C
Boiling Point: 282.7 °C at 760 mmHg
Appearance: clear yellow to yellow-brown liquid
Index of Refraction: 1.663
Molar Refractivity: 51.78 cm3
Molar Volume: 139.7 cm3
Polarizability: 20.52×10-24cm3
Surface Tension: 44.8 dyne/cm
Enthalpy of Vaporization: 50.06 kJ/mol
Vapour Pressure: 0.00565 mmHg at 25°C
Water Solubility: 13.75(mg/L) at 25 °C
Product Categories: aromatic compounds;naphthalene derivatives;aryl;C9 to C12;halogenated hydrocarbons.
1. | ipr-mus LD50:810 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 20 (12)(1976),52. |
Reported in EPA TSCA Inventory.
Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic vapors of Br−.
Safety Information about 1-Bromonaphthalene (90-11-9):
Hazard Codes:
Xn:
Xi:
Risk Statements about 1-Bromonaphthalene (90-11-9):
R22: Harmful if swallowed.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R36: Irritating to the eyes.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements about 1-Bromonaphthalene (90-11-9):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
F8: Photosensitive.
RIDADR: 2810
WGK Germany: 3
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29036990
The chemical synonyms of 1-Bromonaphthalene (90-11-9) are 1-Bromo-naphthalen ; 1-Naphthyl bromide ; 1-Naphthylbromide ; I-Bromnaphthalin ; Naphthalene,1-Bromo- ; α-Bromonaphthalene ; A-bromonaphthalene .As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.Use water spray, dry chemical, carbon dioxide, or chemical foam. Wear chemical splash goggles to prevent eyes.Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. It can be used as a raw material in organic synthesis, used as a refrigerant and solvent molecular weight substances, but also dry goods heat carrier.
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