CAS No.109-74-0,n-Butanenitrile Suppliers,MSDS download

Hunan Russell Chemicals Technology Co.,Ltd

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Butyronitrile, 99% 109-74-0

Cas:109-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

: 110-69-0
butyraldehyde oxime

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With nickel(II) chloride dihydrate In acetonitrile at 80℃; Molecular sieve; Inert atmosphere;	100%
With oxalyl dichloride; Triphenylphosphine oxide In chloroform-d1 at 20℃; for 1h;	99%
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In tetrahydrofuran; ethyl acetate at 20℃; Beckmann rearrangement; Inert atmosphere;	95%

: 109-73-9
N-butylamine

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With copper(I) chloride; 4 A molecular sieve; oxygen In pyridine at 60℃; for 24h;	96%
With potassium hydroxide; nickel copper formate; (Bu4N)2S2O8 In 1,2-dichloro-ethane at 20℃; for 10h; Oxidation;	92%
With potassium hydroxide In water at 30℃; for 4h; electrolysis at a Ni(OH)2 anode and a steel cathode, current - 2 A, cell voltage - 2.0 V;	90%

: 123-72-8
butyraldehyde

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With aluminum oxide; hydroxylamine hydrochloride; methanesulfonyl chloride at 100℃; for 0.75h;	95%
With ammonium hydroxide; N-Bromosuccinimide at 0℃; for 0.166667h;	94%
With hydroxylamine hydrochloride; methanesulfonyl chloride In neat (no solvent) at 70℃; for 2h;	91%

: 541-35-5
butanamide

: 603-35-0
triphenylphosphine

A: 109-74-0
propyl cyanide

B: 791-28-6
Triphenylphosphine oxide

Conditions

Conditions	Yield
With aluminum oxide; LutClO4 In dichloromethane constant current electrolysis;	A 95% B n/a

...Expand

: 5775-75-7
(E)-butanal oxime

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With aluminum oxide; methanesulfonyl chloride at 100℃; for 0.0833333h;	95%
With N,N-dimethyl-formamide at 135℃; for 48h;	76%

: 71-36-3
butan-1-ol

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With nitrogen; ammonia at 240℃; Catalytic behavior; Heating;	94%
With ammonia at 230℃; Inert atmosphere;	86%
With potassium hydroxide; ammonium bicarbonate; (Bu4N)2S2O8; copper(II) formate; nikel(II) formate In isopropyl alcohol at 25℃; for 2h;	85%

: 60-01-5
tributyrin

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With ammonia at 220℃; for 40h; Autoclave;	94%

: 5775-76-8, 5780-42-7, 628-79-5
valeraldoxime

: 1885-29-6
anthranilic acid nitrile

A: 109-74-0
propyl cyanide

B: 28144-70-9
anthranilic acid amide

Conditions

Conditions	Yield
With linear poly(4-vinylpyridine) supported [Cp*IrCl2]2 complex by coordinative immobilization In tert-Amyl alcohol at 125℃; for 15h; Schlenk technique; Inert atmosphere;	A n/a B 93%

...Expand

: 71-36-3
butan-1-ol

A: 109-74-0
propyl cyanide

B: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With ammonia; zinc(II) oxide at 420℃;	A 92.2% B n/a
With ammonia; zinc(II) oxide at 340℃; Product distribution; 1:4 molar ratio n-butyl alcohol/NH3, other temperature (300-420 deg C), other catalyst (oxidized form of SMS-4 Zn-Cr-O);;	A 86.7% B 6%

: 541-35-5
butanamide

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With lead acetate In dichloromethane for 12h; Catalytic behavior; Solvent; Reagent/catalyst; Time; Reflux;	92%
With pyridine; <(chlorosulfinyloxy)methylene>dimethylammonium chloride In dichloromethane for 6h; Ambient temperature;	70%
With phosphorus pentoxide

: 109-73-9
N-butylamine

A: 109-74-0
propyl cyanide

B: 4853-56-9
(butylidene)butylamine

Conditions

Conditions	Yield
With oxygen In para-xylene at 110℃; for 1h;	A 10% B 90%

: 5332-06-9
4-bromobutanenitrile

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With nickel In tetrahydrofuran at 20℃; for 12h;	85%

: 16536-93-9
butanethioamide

: 100-44-7
benzyl chloride

A: 109-74-0
propyl cyanide

B: 538-74-9
dibenzyl sulfide

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide In water; benzene at 30℃; for 2h; Product distribution;	A 75% B 80%

...Expand

: 75-05-8
acetonitrile

: 107-92-6
butyric acid

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With bis(acetylacetonate)oxovanadium In tetrachloromethane at 150℃; for 6h; Autoclave;	80%

: 110-69-0
butyraldehyde oxime

: 50450-21-0
dimethylbromosulphonium bromide

A: 109-74-0
propyl cyanide

B: 67-68-5
dimethyl sulfoxide

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 4h;	A 76% B n/a

...Expand

: 4786-20-3
but-2-enenitrile

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With sodium tetrahydroborate In pyridine; methanol at 120℃; for 2h;	75%
With Amberlite IRA-400; borohydride form; copper(II) sulfate; cyclohexene In methanol at 20℃; for 1h; Reduction;	99 % Chromat.
With triethylsilane; sulfuric acid; 5%-palladium/activated carbon In tetrahydrofuran at 20℃; for 16h;	67 %Spectr.
With 1,2,3-trimethoxybenzene; hydrogen In ethyl acetate at 20℃; under 750.075 Torr; Flow reactor; Green chemistry; chemoselective reaction;	99 %Spectr.

: 628-20-6
4-Chlorobutyronitrile

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With nickel In tetrahydrofuran for 15h; Heating;	75%

: 10424-98-3
butanal N,N-dimethylhydrazone

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 4h;	71%

: 22264-50-2
1-aminocyclobutane-1-carboxylic acid

A: 109-74-0
propyl cyanide

B: 4043-88-3
3,4-dehydro-L-proline

Conditions

Conditions	Yield
With ammonium hydroxide; [CuII(2,2'-bipyridine)(1-aminocyclobutane-1-carboxylic acid(H-))]ClO4*H2O; dihydrogen peroxide In water; N,N-dimethyl-formamide at 35℃; Kinetics; Overall yield = 20 %;	A 33% B 67%

: 75917-32-7
methylazodiphenylmethanol

: 107-13-1
acrylonitrile

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
phenol In benzene at 35 - 50℃; for 16h;	52%

: 1-aminocyclobutane-1-carbonitrile

A: 109-74-0
propyl cyanide

B: cyclobutanimine

Conditions

Conditions	Yield
With potassium hydroxide at 90℃; under 0.0750075 Torr;	A 7% B 51%

: 106-94-5
propyl bromide

: 75-86-5
2-hydroxy-2-methylpropanenitrile

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With potassium carbonate; dibenzo-18-crown-6 In benzene for 5h; Heating;	46%

: 109-73-9
N-butylamine

A: 109-74-0
propyl cyanide

B: 4853-56-9
(butylidene)butylamine

C: 123-72-8
butyraldehyde

Conditions

Conditions	Yield
With oxygen In water at 225℃; under 750.075 Torr; for 1h; Catalytic behavior; Mechanism; Time; Concentration; Flow reactor;	A 34% B n/a C n/a

...Expand

: 491-35-0
C6H4NCH2CHCCH2

A: 109-74-0
propyl cyanide

B: 97580-20-6
1-(4-methylquinolin-2-yl)butan-1-ol

Conditions

Conditions	Yield
With sulfuric acid; hydroxylamine-O-sulfonic acid; iron(II) sulfate In water at 80℃; for 2h;	A 30% B 0.1%

: 4786-20-3
but-2-enenitrile

A: 109-74-0
propyl cyanide

B: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With C26H41Br2FeNP2; hydrogen; potassium hexamethylsilazane; sodium triethylborohydride In tetrahydrofuran at 140℃; under 45004.5 Torr; for 36h; High pressure; Autoclave;	A 19% B 66 %Chromat.

: 4786-20-3
but-2-enenitrile

A: 109-74-0
propyl cyanide

B: 40651-89-6
2-aminobutyronitrile

C: 90196-92-2
2,3-Diethylsuccinodinitril

Conditions

Conditions	Yield
With ammonia for 3h; Irradiation;	A 6% B 4.5% C 6%

...Expand

: 51789-75-4
1-cyano-propane-1-carboxylic acid

A: 109-74-0
propyl cyanide

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

Conditions

Conditions	Yield
beim Erhitzen;

: 102-82-9
tributyl-amine

: 109-74-0
propyl cyanide

Conditions

Conditions	Yield
With nickel at 360 - 380℃;

: 109-74-0
propyl cyanide

: 14389-13-0
5‐propyl‐1H‐1,2,3,4‐tetrazole

Conditions

Conditions	Yield
With sodium azide; triethylamine hydrochloride In toluene at 110℃; for 16h; Inert atmosphere;	100%
With sodium azide; triethylamine hydrochloride In toluene at 110℃; for 16h; Inert atmosphere;	100%
With sodium azide; triethylamine hydrochloride In N,N-dimethyl-formamide at 130℃; for 4h; Microwave irradiation; Inert atmosphere;	95%

: 109-74-0
propyl cyanide

: 541-35-5
butanamide

Conditions

Conditions	Yield
With manganese(IV) oxide; silica gel In hexane for 16h; Heating;	100%
With potassium hydroxide In water; dimethyl sulfoxide at 60℃; for 8h; High pressure; Green chemistry;	99.9%
With [2,2]bipyridinyl; water; palladium diacetate at 70℃; for 24h; Catalytic behavior; Mechanism; Temperature; Reagent/catalyst; Schlenk technique; Sealed tube;	97%

: 109-74-0
propyl cyanide

: 2016-57-1
1-aminodecane

: N,N-dibutyldecan-1-amine

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 29h;	100%
With palladium 10% on activated carbon; ammonium acetate; hydrogen In methanol at 20℃; under 760.051 Torr; for 29h;	82%

: 109-74-0
propyl cyanide

: 100-17-4
para-methoxynitrobenzene

A: 61829-43-4
N-butyl-4-methoxyaniline

B: 82749-62-0
N,N-dibutyl-4-methoxylaniline

Conditions

Conditions	Yield
Stage #1: para-methoxynitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; Stage #2: propyl cyanide In methanol; water	A 100% B n/a

...Expand

: 109-74-0
propyl cyanide

: 91-23-6
2-Nitroanisole

: 65570-20-9
butyl-(2-methoxy-phenyl)amine

Conditions

Conditions	Yield
Stage #1: 2-Nitroanisole With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; Stage #2: propyl cyanide In methanol; water	100%

: 109-74-0
propyl cyanide

: 99-08-1
1-methyl-3-nitrobenzene

A: 60995-75-7
N-butyl-m-toluidine

B: 74878-72-1
N-butyl-N-(3-methyl-n-propyl)-m-toluidine

Conditions

Conditions	Yield
Stage #1: 1-methyl-3-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; Stage #2: propyl cyanide In methanol; water	A 100% B n/a

...Expand

: 109-74-0
propyl cyanide

: 99-99-0
1-methyl-4-nitrobenzene

A: 31144-33-9
N,N-dibutyl-4-methylaniline

B: 10387-24-3
N-butyl-4-methylaniline

Conditions

Conditions	Yield
Stage #1: 1-methyl-4-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; Stage #2: propyl cyanide In methanol; water	A n/a B 100%

...Expand

: 109-74-0
propyl cyanide

: 88-72-2
1-methyl-2-nitrobenzene

: 7277-86-3
N-butyl-2-methylaniline

Conditions

Conditions	Yield
Stage #1: 1-methyl-2-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 4.5h; Stage #2: propyl cyanide In methanol; water	100%

: 109-74-0
propyl cyanide

: 536-90-3
m-Anisidine

: 31084-55-6
butyl-(3-methoxy-phenyl)amine

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 4.5h;	100%

: 109-74-0
propyl cyanide

: 90-04-0
2-methoxy-phenylamine

: 65570-20-9
butyl-(2-methoxy-phenyl)amine

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 3.5h;	100%

: 109-74-0
propyl cyanide

: 106-49-0
p-toluidine

A: 31144-33-9
N,N-dibutyl-4-methylaniline

B: 10387-24-3
N-butyl-4-methylaniline

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 5.5h;	A n/a B 100%

...Expand

: 109-74-0
propyl cyanide

: 104-94-9
4-methoxy-aniline

A: 61829-43-4
N-butyl-4-methoxyaniline

B: 82749-62-0
N,N-dibutyl-4-methoxylaniline

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 3.9h;	A 100% B n/a

...Expand

: 109-74-0
propyl cyanide

: 62-53-3
aniline

A: 1126-78-9
N-(n-butyl)aniline

B: 613-29-6
N-Dibutylaniline

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 8.6h;	A 100% B n/a

...Expand

: 109-74-0
propyl cyanide

: 108-44-1
1-amino-3-methylbenzene

A: 60995-75-7
N-butyl-m-toluidine

B: 74878-72-1
N-butyl-N-(3-methyl-n-propyl)-m-toluidine

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 2.5h;	A 100% B n/a

...Expand

: 109-74-0
propyl cyanide

: 95-53-4
o-toluidine

: 7277-86-3
N-butyl-2-methylaniline

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃;	100%

: 109-74-0
propyl cyanide

: 24424-99-5
di-tert-butyl dicarbonate

: 1114-82-5
2-cyanobutyric acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: propyl cyanide With lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran at -78℃; for 2.5h; Inert atmosphere;	100%
Stage #1: propyl cyanide With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #1: propyl cyanide With lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; for 1.5h; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran at -78℃; for 16h;

: 109-74-0
propyl cyanide

: 111-86-4
n-Octylamine

: 41145-51-1
octyldibutylamine

Conditions

Conditions	Yield
With palladium 10% on activated carbon; ammonium acetate; hydrogen In methanol at 20℃; under 760.051 Torr; for 31h;	100%

: 109-74-0
propyl cyanide

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

: C4H7N*F6Sb(1-)*H(1+)

Conditions

Conditions	Yield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube; Stage #2: propyl cyanide at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;	100%

...Expand

: 109-74-0
propyl cyanide

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

: C4H7N*F11Sb2(1-)*H(1+)

Conditions

Conditions	Yield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube; Stage #2: propyl cyanide at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;	100%

...Expand

: 109-74-0
propyl cyanide

: AsF6(1-)*C4H7N*H(1+)

Conditions

Conditions	Yield
With arsenic pentafluoride; hydrogen fluoride at -196 - 20℃; for 0.5h; Sealed tube;	100%

: 109-74-0
propyl cyanide

: 7783-70-2
antimony pentafluoride

: F5Sb*C4H7N

Conditions

Conditions	Yield
at -196 - -64℃; for 0.166667h; Sealed tube;	100%

: 109-74-0
propyl cyanide

: AsF5*C4H7N

Conditions

Conditions	Yield
With arsenic pentafluoride at -196 - -64℃; for 0.166667h; Sealed tube;	100%

: 109-74-0
propyl cyanide

: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With sodium tetrahydroborate In water; dimethyl sulfoxide at 60℃; for 4.5h; High pressure; Green chemistry;	99.9%
With sodium tetrahydroborate; nickel; sodium hydroxide In methanol; water at 30 - 60℃;	93%
With [DBUH(+)][C4H9COO(-)]; water; potassium formate at 70℃; for 3h; Ionic liquid;	82%

: 109-74-0
propyl cyanide

: 123-72-8
butyraldehyde

Conditions

Conditions	Yield
With potassium carbonate In water; dimethyl sulfoxide at 60℃; for 8h; High pressure; Green chemistry;	99.9%
Stage #1: propyl cyanide With diisobutylaluminium hydride In toluene at -20℃; for 0.222222h; Flow reactor; Stage #2: With water; sodium L-tartrate In toluene at 0℃; chemoselective reaction;	64%
With Diisobutylaluminium hydride(1 M solution in tetrahydrofuran, 4.9 mL, 4.9 mmol) In dichloromethane at -78℃; for 1h;

: 109-74-0
propyl cyanide

: 108-24-7
acetic anhydride

: 1119-49-9
N-butylacetamide

Conditions

Conditions	Yield
With sodium tetrahydroborate; nickel dichloride In methanol at 0 - 20℃; Reduction;	99%

: 109-74-0
propyl cyanide

: 1119-51-3
bromopentene

: 2-ethylhept-6-enenitrile

Conditions

Conditions	Yield
Stage #1: propyl cyanide With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 0.166667h; Stage #2: bromopentene In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Further stages.;	99%
Stage #1: propyl cyanide With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h; Stage #2: bromopentene In tetrahydrofuran	99%
With lithium diisopropyl amide In tetrahydrofuran at -78℃;	99%

: 109-74-0
propyl cyanide

: tetramethylammonium tetrachloroplatinate(II)

: 146143-86-4, 146143-89-7, 94735-77-0
cis-bis(n-butyronitrile)dichloroplatinum(II)

Conditions

Conditions	Yield
In not given excess nitrile;	99%

: 109-99-9
tetrahydrofuran

: 109-74-0
propyl cyanide

: 34807-89-1
cyclopentadienylmanganese tricarbonyl

: 200728-83-2
((CH3)5C5)Mn(CO)2(NCC3H7)

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); Ar-atmosphere; irradn. (120 W Hg lamp, 1 h, stirring, 3°C), nitrile addn., stirring (room temp., 4 h, dark); evapn.;	99%

...Expand

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