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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Crotononitrile Manufacturer/High quality/Best price/In stock

Cas:4786-20-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Crotononitrile

Cas:4786-20-3

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Crotononitrile

Cas:4786-20-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti

4786-20-3

Cas:4786-20-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:CLEAR LIGHT YELLOW LIQUID Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used t

Crotononitrile

Cas:4786-20-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Established in 2010, located in Hangzhou Qinglan science park, lingruichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Our credo is committed to your reliable business partne

2-Butenenitrile

Cas:4786-20-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Crotononitrile

Cas:4786-20-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

CrotononitrileCAS NO.: 4786-20-3

Cas:4786-20-3

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Other

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

2-Butenenitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Crotononitrile (cis- and trans- mixture)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Crotononitrile (cis- and trans- Mixture)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Butenenitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 4786-20-3 with competitive price

Cas:4786-20-3

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

Crotonitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Name Crotononitrile Synonyms 2-Butenenitrile Molecular Structure Molecular Formula C4H5N

Crotononitrile

Cas:4786-20-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

4786-20-3 Crotononitrile (pract) Application:4786-20-3 Crotononitrile (pract)

4786-20-3 Crotononitrile (pract)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

we produce and sell good chemicals around the world.Appearance:white power Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:SEA OR AIR Port:China Main Po

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

4786-20-3 Crotononitrile (pract)Appearance:Powder Storage:Flammables area Package:1KG -200KG Drum with pallet Application:Pharma intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airpo

4786-20-3 Crotononitrile (pract)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Crotononitrile

Cas:4786-20-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

Crotononitrile

Cas:4786-20-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

Crotononitrile Manufacturer/High quality/Best price/In stock

Cas:4786-20-3

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

Crotononitrile (pract)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Crotononitrile

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Crotononitrile (pract)

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutical Tran

Crotononitrile manufacturer

Cas:4786-20-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

potassium cyanide
151-50-8

potassium cyanide

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With 18-crown-6 ether; tetrakis(triphenylphosphine) palladium(0) In benzene at 80℃; for 50h; Rate constant; Product distribution;89%
With potassium hydroxide; (Z)-1-propenyl bromide; hydrogen In water at 45℃; for 4h; Yield given;
trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride; hydroxylamine hydrochloride In N,N-dimethyl-formamide at 100℃; for 9h;78%
N2-<(E)-2-Propenyliden>glycinnitril

N2-<(E)-2-Propenyliden>glycinnitril

A

pyrrole
109-97-7

pyrrole

B

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

C

crotononitrile
4786-20-3

crotononitrile

D

but-3-enenitrile
109-75-1

but-3-enenitrile

Conditions
ConditionsYield
at 650℃; under 0.2 Torr; Product distribution; Irradiation;A 74%
B 7%
C 8%
D 0.7%
trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

copper(I) cyanide
544-92-3

copper(I) cyanide

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; Product distribution; Rate constant; other solvent;A 25%
B 62%
(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

copper(I) cyanide
544-92-3

copper(I) cyanide

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; Product distribution; Rate constant; other solvent;A 27%
B 60%
4-butannitril

4-butannitril

A

pyrrole
109-97-7

pyrrole

B

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

C

crotononitrile
4786-20-3

crotononitrile

D

acrylonitrile
107-13-1

acrylonitrile

Conditions
ConditionsYield
at 500 - 700℃; under 0.2 Torr; Product distribution; Irradiation; mol. sieve (3 Angstroem);A 59%
B n/a
C n/a
D 6%
cis-1-(p-fluorophenyl)-4-cyano-3-methylazetidin-2-one

cis-1-(p-fluorophenyl)-4-cyano-3-methylazetidin-2-one

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

C

(p-fluorophenyl)iminoacetonitrile
1204614-44-7

(p-fluorophenyl)iminoacetonitrile

D

para-fluorophenyl isocyanate
1195-45-5

para-fluorophenyl isocyanate

Conditions
ConditionsYield
at 720℃; under 0.0015 Torr; regioselective reaction;A n/a
B n/a
C 33%
D n/a
cis-4-cyano-3-methyl-1-(p-tolyl)azetidin-2-one

cis-4-cyano-3-methyl-1-(p-tolyl)azetidin-2-one

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

C

(p-tolyl)iminoacetonitrile
1204614-43-6

(p-tolyl)iminoacetonitrile

D

p-Tolylisocyanate
622-58-2

p-Tolylisocyanate

Conditions
ConditionsYield
at 720℃; under 0.0015 Torr; regioselective reaction;A n/a
B n/a
C 30%
D n/a
cis-1-(p-chlorophenyl)-4-cyano-3-methylazetidin-2-one

cis-1-(p-chlorophenyl)-4-cyano-3-methylazetidin-2-one

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

C

(p-chlorophenyl)iminoacetonitrile
1204614-45-8

(p-chlorophenyl)iminoacetonitrile

D

p-chlorphenylisocyanate
104-12-1

p-chlorphenylisocyanate

Conditions
ConditionsYield
at 720℃; under 0.0015 Torr; regioselective reaction;A n/a
B n/a
C 30%
D n/a
cis-4-cyano-3-methyl-1-(p-methoxyphenyl)azetidin-2-one

cis-4-cyano-3-methyl-1-(p-methoxyphenyl)azetidin-2-one

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

C

(p-methoxyphenyl)iminoacetonitrile
1204614-42-5

(p-methoxyphenyl)iminoacetonitrile

D

4-Methoxyphenyl isocyanate
5416-93-3

4-Methoxyphenyl isocyanate

Conditions
ConditionsYield
at 720℃; under 0.0015 Torr; regioselective reaction;A n/a
B n/a
C 25%
D n/a
oxirane
75-21-8

oxirane

acetonitrile
75-05-8

acetonitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With aluminium oxide catalyst at 315℃;
With silica-alumina at 200℃;
pyridine
110-86-1

pyridine

3-chlorobutyronitrile
53778-71-5

3-chlorobutyronitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
beide isom. entstehen;
pyridine
110-86-1

pyridine

β-bromobutyronitrile
20965-20-2

β-bromobutyronitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
beide isom. Crotonsaeurenitrile entstehen;
pyridine
110-86-1

pyridine

acetaldehyde
75-07-0

acetaldehyde

cyanoacetic acid
372-09-8

cyanoacetic acid

A

3-methyl glutarimide
25077-26-3

3-methyl glutarimide

B

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

C

crotononitrile
4786-20-3

crotononitrile

D

(E+Z)-4-cyano-3-methyl-4-hexenenitrile
50870-55-8

(E+Z)-4-cyano-3-methyl-4-hexenenitrile

Conditions
ConditionsYield
erst in der Kaelte, zuletzt bei 60grad;
quinoline
91-22-5

quinoline

3-chlorobutyronitrile
53778-71-5

3-chlorobutyronitrile

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

3-chlorobutyronitrile
53778-71-5

3-chlorobutyronitrile

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With quinoline
3-(piperidin-1-yl)butanenitrile
32813-37-9

3-(piperidin-1-yl)butanenitrile

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
bei langsamer Destillation;
propyl cyanide
109-74-0

propyl cyanide

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With chromium(III) oxide at 615℃; Dehydrierung;
propyl cyanide
109-74-0

propyl cyanide

A

crotononitrile
4786-20-3

crotononitrile

B

but-3-enenitrile
109-75-1

but-3-enenitrile

Conditions
ConditionsYield
With chromium(III) oxide at 580 - 615℃;
4-Chlorobutyronitrile
628-20-6

4-Chlorobutyronitrile

A

but-2-enenitrile
4786-20-3

but-2-enenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
β-crotonic acid nitrile (cis-form);
4-Chlorobutyronitrile
628-20-6

4-Chlorobutyronitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
bei wiederholter langsamer Destillation; beide isom.Crotonsaeurenitrile entstehen;
2-chlorobutyronitrile
4158-37-6

2-chlorobutyronitrile

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With quinoline
2-hydroxybutanenitrile
4476-02-2

2-hydroxybutanenitrile

A

but-2-enenitrile
4786-20-3

but-2-enenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With phosphorus pentaoxide β-crotonic acid nitrile (cis-form);
2-hydroxybutanenitrile
4476-02-2

2-hydroxybutanenitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With phosphoric acid; water at 600℃; under 20 Torr;
(+-)-3-amino-butyronitrile
16750-40-6

(+-)-3-amino-butyronitrile

A

but-2-enenitrile
4786-20-3

but-2-enenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
β-crotonic acid nitrile (cis-form);
3-hydroxybutanenitrile
4368-06-3

3-hydroxybutanenitrile

A

but-2-enenitrile
4786-20-3

but-2-enenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With phosphorus pentaoxide β-crotonic acid nitrile (cis-form);
3-hydroxybutanenitrile
4368-06-3

3-hydroxybutanenitrile

A

(Z)-2-butenenitrile
1190-76-7

(Z)-2-butenenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With sulfuric acid
With sodium borate at 190℃;
With sodium phosphate at 190℃;
3-hydroxybutanenitrile
4368-06-3

3-hydroxybutanenitrile

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With phosphorus pentaoxide
crotonaldoxime
5314-34-1

crotonaldoxime

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With diethyl ether; acetic anhydride
ethyl crotonate
10544-63-5

ethyl crotonate

A

but-2-enenitrile
4786-20-3

but-2-enenitrile

B

crotononitrile
4786-20-3

crotononitrile

Conditions
ConditionsYield
With aluminum oxide; ammonia at 480 - 500℃; β-crotonic acid nitrile (cis-form);
ethanol
64-17-5

ethanol

crotononitrile
4786-20-3

crotononitrile

3-ethoxy-butyronitrile
33546-80-4

3-ethoxy-butyronitrile

Conditions
ConditionsYield
With tributylphosphine at 50℃; under 2250180 Torr; for 3h; Michael-like addition;99%
morpholine
110-91-8

morpholine

crotononitrile
4786-20-3

crotononitrile

3-(morpholin-4-yl)butanenitrile
38405-81-1

3-(morpholin-4-yl)butanenitrile

Conditions
ConditionsYield
[Ni((R)-(S)-Pigiphos)(THF)](ClO4)2 In tetrahydrofuran at 20℃; for 24h;99%
With [Ni((R)-(S)-Pigiphos)(THF)](ClO4)2 In tetrahydrofuran at 20℃; for 24h;
With [{kp,kc,kp-2,6-(i-Pr2PO)2C6H3}Ni(NCMe)][OSO2CF3]; triethylamine In benzene-d6 at 20℃; for 0.166667h; Michael condensation;100 %Spectr.
piperidine
110-89-4

piperidine

crotononitrile
4786-20-3

crotononitrile

3-(piperidin-1-yl)butanenitrile
32813-37-9

3-(piperidin-1-yl)butanenitrile

Conditions
ConditionsYield
2,6-bis((di-tertbutylphosphino)methyl)pyridine; palladium(II) trifluoroacetate In toluene at 20℃; for 12h; Conversion of starting material;99%
palladium(II) trifluoroacetate In toluene at 20℃; for 12h; Conversion of starting material;21%
crotononitrile
4786-20-3

crotononitrile

C4H7ClMn
129433-53-0

C4H7ClMn

3,4-dimethyl-5-hexenoic acid nitrile
98096-32-3, 115092-90-5

3,4-dimethyl-5-hexenoic acid nitrile

Conditions
ConditionsYield
In tetrahydrofuran at -60℃;96%
crotononitrile
4786-20-3

crotononitrile

4-methylbenzimidazole
4887-83-6

4-methylbenzimidazole

A

4-methyl-1H-benzimidazole-1-(3-methyl)propanenitrile
172839-53-1

4-methyl-1H-benzimidazole-1-(3-methyl)propanenitrile

B

3-(7-Methyl-benzoimidazol-1-yl)-butyronitrile

3-(7-Methyl-benzoimidazol-1-yl)-butyronitrile

Conditions
ConditionsYield
With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;A 96%
B n/a
crotononitrile
4786-20-3

crotononitrile

benzyl alcohol
100-51-6

benzyl alcohol

3-(benzyloxy)butanenitrile

3-(benzyloxy)butanenitrile

Conditions
ConditionsYield
With caesium carbonate; copper dichloride In dichloromethane for 12h; Michael Addition; Reflux;96%
crotononitrile
4786-20-3

crotononitrile

1-iodocyclohexane
626-62-0

1-iodocyclohexane

3-cyclohexylbutyronitrile
64198-20-5

3-cyclohexylbutyronitrile

Conditions
ConditionsYield
With indium; N-ethylpiperidine hypophosphite; cetyltrimethylammonim bromide; triethyl borane In 1,4-dioxane; water at 80℃; for 2h;94%
With borohydride exchange resin; nickel diacetate In methanol at 65℃; for 1h;93%
With zinc copper In ethanol for 1h; Irradiation;63%
crotononitrile
4786-20-3

crotononitrile

4-(2-pyridinyl)piperidine
30532-37-7

4-(2-pyridinyl)piperidine

3-[4-(pyridin-2-yl)-piperidin-1-yl)-3-methylpropionitrile

3-[4-(pyridin-2-yl)-piperidin-1-yl)-3-methylpropionitrile

Conditions
ConditionsYield
In methanol; ethanol94%
2-iodohexane
18589-27-0

2-iodohexane

crotononitrile
4786-20-3

crotononitrile

3,4-Dimethyl-octanenitrile

3,4-Dimethyl-octanenitrile

Conditions
ConditionsYield
With borohydride exchange resin; nickel diacetate In methanol at 65℃; for 1h;92%
crotononitrile
4786-20-3

crotononitrile

1-(isocyanomethyl)-1H-benzo[d][1,2,3]triazole
87022-42-2

1-(isocyanomethyl)-1H-benzo[d][1,2,3]triazole

4-methyl-1H-pyrrole-3-carbonitrile
40167-38-2

4-methyl-1H-pyrrole-3-carbonitrile

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran Heating;92%
crotononitrile
4786-20-3

crotononitrile

β-bromobutyronitrile
20965-20-2

β-bromobutyronitrile

Conditions
ConditionsYield
With 1-oxothiolane; phenyltribromosilane In dichloromethane at 20℃; for 16h; Michael Addition;92%
crotononitrile
4786-20-3

crotononitrile

methyl 2-cyanoacetate
105-34-0

methyl 2-cyanoacetate

3-methyl glutarimide
25077-26-3

3-methyl glutarimide

Conditions
ConditionsYield
With IrH5(P-(i-Pr)3)2; water In tetrahydrofuran at 150℃; for 20h;91%
crotononitrile
4786-20-3

crotononitrile

2-diazopropane
2684-60-8

2-diazopropane

4,5,5-Trimethyl-4,5-dihydro-1H-pyrazole-3-carbonitrile
86556-95-8

4,5,5-Trimethyl-4,5-dihydro-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
In diethyl ether from -20 deg C to 0 deg C;90%
4-iodopyridine
15854-87-2

4-iodopyridine

crotononitrile
4786-20-3

crotononitrile

(+/-)-3-(pyridin-4-yl)butyronitrile
79190-37-7

(+/-)-3-(pyridin-4-yl)butyronitrile

Conditions
ConditionsYield
With copper(l) iodide; n-butyllithium; Dibutyl sulfide In diethyl ether; hexane at 20℃; for 1h;90%
crotononitrile
4786-20-3

crotononitrile

aniline
62-53-3

aniline

2-Anilinopropyl Cyanide
80935-75-7

2-Anilinopropyl Cyanide

Conditions
ConditionsYield
1,3-bis[(di-tert-butylphosphino)methyl]benzene; palladium diacetate In toluene at 100℃; for 36h; Conversion of starting material;90%
With [Ni((R)-(S)-Pigiphos)(THF)](ClO4)2 In tetrahydrofuran at 20℃; for 24h;65%
crotononitrile
4786-20-3

crotononitrile

(3R,4R)-1-benzyl-3,4-bis(benzyloxy)-5-oxo-2-(trifluoromethyl)-pyrrolidin-2-yl acetate

(3R,4R)-1-benzyl-3,4-bis(benzyloxy)-5-oxo-2-(trifluoromethyl)-pyrrolidin-2-yl acetate

(3aR,6R,6aS)-4-benzyl-6-(benzyloxy)-2-((E)-prop-1-en-1-yl)-3a-(trifluoromethyl)-6,6a-dihydro-3aH-pyrrolo[2,3-d]oxazol-5(4H)-one

(3aR,6R,6aS)-4-benzyl-6-(benzyloxy)-2-((E)-prop-1-en-1-yl)-3a-(trifluoromethyl)-6,6a-dihydro-3aH-pyrrolo[2,3-d]oxazol-5(4H)-one

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 20℃; for 21h; Inert atmosphere; diastereoselective reaction;89%
crotononitrile
4786-20-3

crotononitrile

7-(1-morpholino-1-cyanomethyl)tetrazolo<1,5-a>quinoline
123959-20-6

7-(1-morpholino-1-cyanomethyl)tetrazolo<1,5-a>quinoline

7-(1,3-dicyano-2-methyl-1-morpholinopropyl)tetrazolo<1,5-a>quinoline
123959-21-7

7-(1,3-dicyano-2-methyl-1-morpholinopropyl)tetrazolo<1,5-a>quinoline

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide Ambient temperature;88%
sodium cyanide
773837-37-9

sodium cyanide

crotononitrile
4786-20-3

crotononitrile

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-(4-chlorophenyl)-3-methyl-4-oxobutyronitrile
53012-96-7

4-(4-chlorophenyl)-3-methyl-4-oxobutyronitrile

Conditions
ConditionsYield
Stage #1: sodium cyanide; 4-chlorobenzaldehyde In N,N-dimethyl-formamide at 35 - 38℃; for 2h; Michael Addition; Inert atmosphere;
Stage #2: crotononitrile In N,N-dimethyl-formamide at 40℃; for 3.5h; Inert atmosphere;
88%
crotononitrile
4786-20-3

crotononitrile

7-(1-morpholino-1-cyanomethyl)-1,2,4-triazolo<4,3-a>quinoline
123959-24-0

7-(1-morpholino-1-cyanomethyl)-1,2,4-triazolo<4,3-a>quinoline

7-(1,3-dicyano-2-methyl-1-morpholinopropyl)-1,2,4-triazolo<4,3-a>quinoline
123959-25-1

7-(1,3-dicyano-2-methyl-1-morpholinopropyl)-1,2,4-triazolo<4,3-a>quinoline

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide for 3h; Ambient temperature;86%
crotononitrile
4786-20-3

crotononitrile

3-imino-5methylpyrazolidine hydrochloride

3-imino-5methylpyrazolidine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; hydrazine hydrate In methanol; toluene85%
crotononitrile
4786-20-3

crotononitrile

1,2-propanediene
463-49-0

1,2-propanediene

dimethyl(phenyl)silyllithium
3839-31-4

dimethyl(phenyl)silyllithium

2-(dimethylphenylsilyl)-7-[(dimethylphenylsilyl)methyl]-6-methylocta-1,7-dien-4-one
374572-22-2

2-(dimethylphenylsilyl)-7-[(dimethylphenylsilyl)methyl]-6-methylocta-1,7-dien-4-one

Conditions
ConditionsYield
Stage #1: 1,2-propanediene; dimethyl(phenyl)silyllithium With copper(l) cyanide In tetrahydrofuran at -78℃; for 1h;
Stage #2: crotononitrile With boron trifluoride diethyl etherate In tetrahydrofuran at -78 - 0℃;
83%
C8H11CuSi*LiCN

C8H11CuSi*LiCN

crotononitrile
4786-20-3

crotononitrile

1,2-propanediene
463-49-0

1,2-propanediene

2-(dimethylphenylsilyl)-7-[(dimethylphenylsilyl)methyl]-6-methylocta-1,7-dien-4-one
374572-22-2

2-(dimethylphenylsilyl)-7-[(dimethylphenylsilyl)methyl]-6-methylocta-1,7-dien-4-one

Conditions
ConditionsYield
Stage #1: C8H11CuSi*LiCN; 1,2-propanediene In tetrahydrofuran at -40℃; for 1h;
Stage #2: crotononitrile With boron trifluoride diethyl etherate In tetrahydrofuran at -40 - 0℃;
Stage #3: With ammonium chloride In tetrahydrofuran at 0℃; Further stages.;
83%
crotononitrile
4786-20-3

crotononitrile

ethyl 2-cyanopropionate
1572-99-2

ethyl 2-cyanopropionate

ethyl 2,4-dicyano-2,3-dimethylbutanoate

ethyl 2,4-dicyano-2,3-dimethylbutanoate

Conditions
ConditionsYield
With dihydridotetrakis(triphenylphosphine)ruthenium In tetrahydrofuran for 24h; Ambient temperature;82%
crotononitrile
4786-20-3

crotononitrile

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

3-phenyl-butyronitrile
20132-76-7

3-phenyl-butyronitrile

Conditions
ConditionsYield
bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate In 1,4-dioxane; water at 90℃; for 20h;82%
crotononitrile
4786-20-3

crotononitrile

4-methylbenzimidazole
4887-83-6

4-methylbenzimidazole

4-methyl-1H-benzimidazole-1-(3-methyl)propanenitrile
172839-53-1

4-methyl-1H-benzimidazole-1-(3-methyl)propanenitrile

Conditions
ConditionsYield
With benzyltriethylammonium hydroxide Heating;81%
2-bromo-3-picoline
3430-17-9

2-bromo-3-picoline

crotononitrile
4786-20-3

crotononitrile

(+/-)-3-(3-methylpyridin-2-yl)-butyronitrile

(+/-)-3-(3-methylpyridin-2-yl)-butyronitrile

Conditions
ConditionsYield
With copper(l) iodide; n-butyllithium; Dibutyl sulfide In diethyl ether; hexane at 20℃; for 1h;81%
1-Iodooctane
629-27-6

1-Iodooctane

crotononitrile
4786-20-3

crotononitrile

3-methylundecanenitrile

3-methylundecanenitrile

Conditions
ConditionsYield
With borohydride exchange resin; nickel diacetate In methanol at 65℃; for 1h;80%
Rh(ClO4)(CO)(PPh3)2
32354-26-0, 36593-52-9

Rh(ClO4)(CO)(PPh3)2

crotononitrile
4786-20-3

crotononitrile

Rh(CH3CHCHCN)(CO)(P(C6H5)3)2(1+)*ClO4(1-)={Rh(CH3CHCHCN)(CO)(P(C6H5)3)2}ClO4

Rh(CH3CHCHCN)(CO)(P(C6H5)3)2(1+)*ClO4(1-)={Rh(CH3CHCHCN)(CO)(P(C6H5)3)2}ClO4

Conditions
ConditionsYield
In benzene under N2 at 25°C;; filtration; ppt. washed with benzene, dried in vac.; elem. anal.;;80%
crotononitrile
4786-20-3

crotononitrile

crotonamide
625-37-6

crotonamide

Conditions
ConditionsYield
With Acetaldehyde oxime; [(eta.(5)-pentamethylcyclopentadienyl)Rh(H2O)3](OTf)2 In water Schlenk technique;80%

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