m-Anisidine CAS#536-90-3 Xiamen Aeco Chemical Industrial Co., Ltd. (short as Aecochem) Your Partner in China, a Professional chemical raw material supplier, our main products including the Epxoy Chemical ,Petro Chemical,Pharma Intermediate,F
Cas:536-90-3
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryDayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
Cas:536-90-3
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryProduct description: Product name m-Anisidine CAS number 536-90-3 Assay ≥98% Appearance Light yellow liquid or dark red liquid Capacity 200mt/year Application Pharmaceutical/
Cas:536-90-3
Min.Order:1 Kilogram
FOB Price: $12.0
Type:Lab/Research institutions
inquiryhigh quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Product Name: m-Anisidine Synonyms: M-METHOXYANILINE;1-Amino-3-methoxybenzene;3-Aminophenol methyl ether;3-Methoxy-1-aminobenzene;3-methoxy-benzenamin;3-Methoxybenzenamine;3-methoxy-Benzenamine;Benzenamine,3-methoxy- CAS: 536-90-
Cas:536-90-3
Min.Order:1 Gram
FOB Price: $8900.0
Type:Lab/Research institutions
inquiryProduct Name:m-Anisidine Molecular Formula:C7H9NO Molecular Weight:123.15 CAS Number: 90-04-0 Melting point: -1-1°C Boiling point: 251°C Density: 1.096 g/ml HS Code: 29222200 Appearance: yellow transparent liquid Storage: Preserve in
We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED
Cas:536-90-3
Min.Order:1 Gram
FOB Price: $4.0
Type:Lab/Research institutions
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:536-90-3
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h
Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier
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Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:536-90-3
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Cas:536-90-3
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
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Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa
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Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int
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Conditions | Yield |
---|---|
With bis(tri-ortho-tolylphosphine)palladium(0); (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl-di-tert-butylphosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 80℃; for 5h; Inert atmosphere; | 99% |
With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 80℃; for 23h; Inert atmosphere; | 93% |
With ammonium hydroxide; copper(l) iodide; diethylenetriaminopentaacetic acid; potassium hydroxide In water at 100℃; for 12h; Sealed tube; | 90% |
Conditions | Yield |
---|---|
With bis(tri-ortho-tolylphosphine)palladium(0); (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl-di-tert-butylphosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 100℃; for 12h; Inert atmosphere; | 99% |
With C43H63ClFeNiP2; ammonia; sodium t-butanolate In 1,4-dioxane; toluene at 100℃; for 16h; Reagent/catalyst; Inert atmosphere; | 91% |
With ammonium sulfate; bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate at 100 - 110℃; for 12h; | 88% |
With bis(1,5-cyclooctadiene)nickel (0); (R)-1-[(Sp)-2-(dicyclohexylphosphanyl)ferrocenyl]ethyldicyclohexylphosphane; ammonia; sodium t-butanolate In 1,4-dioxane; toluene at 110℃; for 16h; Sealed tube; |
Conditions | Yield |
---|---|
With dimanganese decacarbonyl at 180℃; for 1h; | 99% |
Conditions | Yield |
---|---|
With isopropyl alcohol; potassium hydroxide for 0.133333h; Microwave irradiation; regioselective reaction; | 98% |
With hydrogen In ethanol; water at 25℃; under 11251.1 Torr; for 6h; chemoselective reaction; | 98% |
With nickel(II) oxide; ethanol; potassium hydroxide for 0.183333h; Microwave irradiation; sealed vessel; | 97% |
Conditions | Yield |
---|---|
With ammonium hydroxide at 90℃; for 0.166667h; | 98% |
With zinc In methanol at 20℃; for 6h; | 94% |
With aluminium(III) iodide In benzene for 0.166667h; Reduction; Heating; | 93% |
m-Anisidine
Conditions | Yield |
---|---|
With hydrogen; palladium dihydroxide In water; tert-butyl alcohol at 20℃; under 3361.46 Torr; for 12h; Hydrogenolysis; | 98% |
tert-butyl 3-methoxyphenylcarbamate
m-Anisidine
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 150℃; for 1h; microwave irradiation; | 95% |
With 2,2,2-trifluoroethanol at 150℃; for 1h; Product distribution / selectivity; Microwave irradiation; | 95% |
With 2,2,2-trifluoroethanol at 150℃; for 1h; Product distribution / selectivity; Microwave irradiation; | 95% |
With 1,1,1,3',3',3'-hexafluoro-propanol at 150℃; for 0.5h; Product distribution / selectivity; Microwave irradiation; | 89% |
Conditions | Yield |
---|---|
With formic acid; zinc In methanol at 20℃; for 0.116667h; | 94% |
With hydrazine hydrate In ethanol Heating; | 94% |
With hydrazine hydrate; aluminium In ethanol Heating; | 94% |
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; N-((1-oxy-pyridin-2-yl)methyl)oxalamic acid; ammonia In water; dimethyl sulfoxide at 25℃; Schlenk technique; Inert atmosphere; Sealed tube; chemoselective reaction; | 94% |
Stage #1: 3-methoxy-1-iodobenzene With copper(l) iodide; D-glucosamine hydrochloride; potassium carbonate In water; acetone at 90℃; for 0.166667h; Stage #2: With ammonia In water; acetone at 90℃; for 24h; | 90% |
With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 50℃; for 23h; Inert atmosphere; | 90% |
3-methoxy-N-methylaniline
m-Anisidine
Conditions | Yield |
---|---|
With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine In acetonitrile at -78℃; for 24h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation; | 94% |
m-Anisidine
Conditions | Yield |
---|---|
With hydrogen; palladium dihydroxide In water; tert-butyl alcohol under 3620.04 Torr; Ambient temperature; | 90% |
With hydrogen; palladium dihydroxide In water; tert-butyl alcohol at 20℃; under 2844.31 Torr; for 5h; Hydrogenolysis; | 90% |
3-methoxyphenyl triflate
m-Anisidine
Conditions | Yield |
---|---|
Stage #1: 3-methoxyphenyl triflate With bis(bis(trimethylsilyl)amido)zinc(II); tri-tert-butyl phosphine; tetrabutylammomium bromide; lithium chloride; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 50℃; for 24h; Stage #2: With hydrogenchloride In tetrahydrofuran; diethyl ether | 90% |
1-(m-methoxyphenyl)-4,5-dihydro-5-hydroxy-1H-1,2,3-triazole
A
3-Methoxy-formanilid
B
m-Anisidine
Conditions | Yield |
---|---|
With n-butyllithium In tetrahydrofuran for 1.5h; Ambient temperature; | A 89% B 10% |
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran at 0 - 20℃; | 87% |
3-methoxyphenylboronic acid
m-Anisidine
Conditions | Yield |
---|---|
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 16h; | 87% |
With sodium hydroxide; hydroxylamine-O-sulfonic acid In water; acetonitrile at 100℃; for 0.25h; Microwave irradiation; | 87% |
With copper(ll) sulfate pentahydrate; ammonia; sodium hydroxide In water at 20℃; under 760.051 Torr; for 4h; | 84% |
With copper(I) oxide; ammonium hydroxide; oxygen; sodium hydroxide In water at 25℃; for 15h; | 82% |
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h; | 78% |
2-(3-methoxyphenoxy)propanamide
m-Anisidine
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 140℃; for 8h; Green chemistry; | 87% |
m-Anisidine
Conditions | Yield |
---|---|
With ammonium sulfate; bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate at 100 - 110℃; for 12h; | 87% |
benzyl (3-methoxyphenyl)carbamate
m-Anisidine
Conditions | Yield |
---|---|
With methylmagnesium bromide; hydrogen; palladium diacetate; nickel diacetate In water at 45℃; for 16h; | 85% |
Conditions | Yield |
---|---|
With thiophenol In toluene for 0.5h; Heating; | A 2% B 3% C 83% |
Conditions | Yield |
---|---|
With copper(ll) sulfate pentahydrate; potassium phosphate tribasic heptahydrate; water; Sucrose In water at 90℃; for 15h; Catalytic behavior; Green chemistry; | 82% |
Conditions | Yield |
---|---|
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate at 110℃; for 21h; | 78% |
Conditions | Yield |
---|---|
With CuI; caesium carbonate In methanol | 78% |
1-(3-methoxyphenyl)-2,5-dimethyl-1 H-pyrrole
m-Anisidine
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; triethylamine In ethanol at 80℃; for 16h; | 76% |
Conditions | Yield |
---|---|
In aq. phosphate buffer for 0.5h; pH=7.4; | A n/a B 76% C n/a |
m-Anisidine
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine-O-sulfonic acid In water; acetonitrile at 100℃; for 0.25h; Microwave irradiation; | 76% |
Conditions | Yield |
---|---|
Stage #1: O-methylresorcine With Nonafluorobutanesulfonyl fluoride; tris(trimethylsilyl)amine; potassium hexamethylsilazane In tetrahydrofuran at 60℃; for 5h; Schlenk technique; Inert atmosphere; Stage #2: With hydrogenchloride In water at 20℃; for 0.0833333h; pH=3 - 4; | 75% |
Multi-step reaction with 2 steps 1.1: 81 percent / K3PO4 / toluene; H2O / 0 - 20 °C 2.1: P(t-Bu)3; Zn[N(SiMe3)2]2; Bu4NBr / Pd(dba)2; LiCl / tetrahydrofuran / 24 h / 50 °C 2.2: 90 percent / aq. HCl / tetrahydrofuran; diethyl ether View Scheme |
Conditions | Yield |
---|---|
Stage #1: 2-methoxy-phenol With Nonafluorobutanesulfonyl fluoride; tris(trimethylsilyl)amine; potassium hexamethylsilazane In tetrahydrofuran at 60℃; for 5h; Schlenk technique; Inert atmosphere; Stage #2: With hydrogenchloride In water at 20℃; for 0.0833333h; pH=3 - 4; | 72% |
1-(3-methoxyphenyl)urea
benzoic acid
A
1-benzoyl-3-(3-methoxyphenyl)urea
B
m-Anisidine
Conditions | Yield |
---|---|
With ethyl phosphate; ethyl polyphosphate (ppe) at 100 - 105℃; for 1.5h; | A 71% B 4% |
(3-methoxyphenyl)hydrazine
m-Anisidine
Conditions | Yield |
---|---|
With titanium tetrachloride; magnesium In tetrahydrofuran at 20℃; Inert atmosphere; | 71% |
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 0 - 20℃; | 100% |
With cadmium(II) oxide at 80℃; for 0.0833333h; Neat (no solvent); Microwave irradiation; | 97% |
With 2,3,4,5,7,8,9,10-octahydropyrimido[1,2-a]azepin-1-ium acetate In neat (no solvent) at 50℃; for 0.5h; Green chemistry; | 96% |
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 20℃; for 28h; | 100% |
With triethylamine In dichloromethane at 4℃; | 100% |
With triethylamine In tetrahydrofuran at 20℃; for 15h; | 95% |
m-Anisidine
[1,4]naphthoquinone
2-(3-methoxyphenylamino)naphthalene-1,4-dione
Conditions | Yield |
---|---|
In ethanol at 20℃; Reagent/catalyst; | 100% |
With copper(II) acetate monohydrate; acetic acid at 60 - 70℃; for 0.5h; Under air; | 93% |
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 2h; | 76% |
Conditions | Yield |
---|---|
With tert.-butylnitrite; trimethylsilylazide In acetonitrile at 0 - 20℃; for 1h; | 100% |
With tert.-butylnitrite; trimethylsilylazide In acetonitrile at 0 - 20℃; for 3h; Inert atmosphere; | 99% |
Stage #1: m-Anisidine With sulfuric acid; sodium nitrite In water; acetic acid at 0 - 5℃; for 0.166667h; Stage #2: With sodium azide In water; acetic acid at 0 - 5℃; for 3h; | 94% |
m-Anisidine
methanesulfonyl chloride
N-(3-methoxyphenyl)methanesulfonamide
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; Cooling with ice; | 100% |
With pyridine In dichloromethane Ambient temperature; | 89% |
With pyridine In dichloromethane at 20℃; for 12h; | 52.6% |
m-Anisidine
trifluoroacetic anhydride
N-(3-methoxyphenyl)-2,2,2-trifluoroacetamide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 0 - 20℃; for 0.75h; | 100% |
In diethyl ether | |
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere; | |
With triethylamine | |
at 20℃; for 3h; Inert atmosphere; |
Conditions | Yield |
---|---|
In methanol at 20℃; for 24h; | 100% |
for 2h; Yield given; | |
With magnesium sulfate In ethanol at 20℃; |
Conditions | Yield |
---|---|
With pyridine; dmap In dichloromethane at 0℃; for 1h; | 100% |
With sodium carbonate monohydrate In water; ethyl acetate at 0℃; for 1h; Inert atmosphere; | 99.5% |
With sodium carbonate monohydrate In water; ethyl acetate at 0℃; for 1h; Inert atmosphere; | 99.5% |
di-tert-butyl dicarbonate
m-Anisidine
tert-butyl 3-methoxyphenylcarbamate
Conditions | Yield |
---|---|
copper(II) bis(tetrafluoroborate) at 30 - 33℃; for 0.166667h; | 100% |
In tetrahydrofuran at 20℃; | 100% |
With zinc(II) perchlorate In tert-butyl alcohol at 20℃; for 10h; | 99% |
Conditions | Yield |
---|---|
In ethanol for 1h; Sonication; | 100% |
In toluene for 0.5h; Heating; | 85% |
In ethanol for 1h; Heating; |
m-Anisidine
2-isothiocyanatobenzylpyridinium bromide
1-{2-[3-(3-Methoxy-phenyl)-thioureido]-benzyl}-pyridinium; bromide
Conditions | Yield |
---|---|
In methanol for 5h; | 100% |
m-Anisidine
diethyl 2-ethoxymethylenemalonate
Diethyl 2-<(3-methoxyphenylamino)methylene>malonate
Conditions | Yield |
---|---|
at 90 - 110℃; for 1h; | 100% |
at 125℃; for 3h; | 99% |
In neat (no solvent) at 120℃; for 0.75h; | 98% |
m-Anisidine
Conditions | Yield |
---|---|
Stage #1: trifluoromethyl dihydro-1,4-dioxin-3-carbonyl chloride With pyridine; polystyrene-bound 4-hydroxy-3-nitrobenzophenone In dichloromethane at 20℃; for 24h; Acylation; Stage #2: m-Anisidine With triethylamine In acetonitrile for 2.5h; Acylation; Heating; | 100% |
bis(trichloromethyl) carbonate
m-Anisidine
3-methoxyphenyl isocyanate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane | 100% |
In dichloromethane at 20℃; for 1.5h; | |
In toluene at 100℃; Cooling with ice; |
m-Anisidine
3-tert-butyl-4-chloro-1-methyl-1H-pyrazolo[3,4-b]pyridine-5-carboxylic acid amide
Conditions | Yield |
---|---|
In 1,4-dioxane Heating; | 100% |
m-Anisidine
4-chloro-1-cyclohexyl-3-methyl-1H-pyrazolo[3,4-b]pyridine-5-carboxylic acid amide
Conditions | Yield |
---|---|
In 1,4-dioxane Heating; | 100% |
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 4.5h; | 100% |
m-Anisidine
propiononitrile
A
3‐methoxy‐N‐propylaniline
B
2-methoxy-N,N-dipropylaniline
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 3h; | A 100% B n/a |
3-methoxyphenyl bromide
m-Anisidine
3-methoxy-N-(3-methoxyphenyl)benzenamine
Conditions | Yield |
---|---|
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 110℃; for 48h; Buchwald-Hartwig amination; | 100% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium t-butanolate In toluene at 100℃; for 18h; Buchwald-Hartwig Coupling; Inert atmosphere; | 72% |
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 120℃; | 40% |
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 72h; Reflux; Inert atmosphere; |
1,3-dibromobenzene
m-Anisidine
N,N'-bis(3-methoxyphenyl)-1,3-benzenediamine
Conditions | Yield |
---|---|
With sodium t-butanolate; palladium diacetate; bis(diphenylphosphinyl)ferrocene In toluene at 100 - 110℃; for 12h; | 100% |
With [(π-cinnamyl)Pd(tBuXPhos)]OTf In water at 45℃; for 36h; | 91% |
Conditions | Yield |
---|---|
With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; palladium diacetate In toluene for 16h; Buchwald-Hartwig amination; Heating; | 100% |
With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; palladium diacetate In toluene | 100% |
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 16h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere; | 100% |
5-methoxymethylene-2,2-dimethyl-1,3-dioxane-4,6-dione
m-Anisidine
5-(((3-methoxyphenyl)amino)methylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 0.25h; | 100% |
In isopropyl alcohol Heating; | 96% |
In isopropyl alcohol at 70℃; for 1h; | 44% |
6-fluoronicotinic acid
m-Anisidine
6-fluoro-N-(3-methoxy-phenyl)-nicotinamide
Conditions | Yield |
---|---|
With dicyclohexyl-carbodiimide; dmap In dichloromethane at 0 - 20℃; for 1h; | 100% |
4-Trifluoromethylphenylacetic acid
m-Anisidine
N-(3-methoxy-phenyl)-2-(4-trifluoromethyl-phenyl)-acetamide
Conditions | Yield |
---|---|
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0 - 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; triethylamine In methanol | 100% |
Conditions | Yield |
---|---|
Stage #1: m-Anisidine With boron trifluoride diethyl etherate; isopentyl nitrite In tetrahydrofuran at -20℃; for 2h; Stage #2: N-benzylaminomethyl resin In tetrahydrofuran; pyridine; acetonitrile at 20℃; Cooling; solid phase reaction; | 100% |
Stage #1: m-Anisidine With boron trifluoride diethyl etherate; isopentyl nitrite In tetrahydrofuran at -20℃; for 2h; Stage #2: N-benzylaminomethyl resin With pyridine In tetrahydrofuran at -20 - 20℃; solid phase reaction; | 100% |
Stage #1: m-Anisidine With boron trifluoride diethyl etherate; isopentyl nitrite In tetrahydrofuran at -20℃; for 2h; Stage #2: N-benzylaminomethyl resin With pyridine In tetrahydrofuran; acetonitrile at -20 - 20℃; |
m-Anisidine
4-methoxy-benzaldehyde
(4-methoxybenzylidene)(3-methoxyphenyl)amine
Conditions | Yield |
---|---|
With acetic acid In N,N-dimethyl-formamide for 1h; | 100% |
With TiO2 nanotubes at 20℃; for 3h; Neat (no solvent); Sunlight; | 98% |
In methanol for 12h; Reflux; |
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 18h; Inert atmosphere; | 100% |
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere; | 82% |
In dichloromethane | |
Stage #1: m-Anisidine With triethylamine In tetrahydrofuran at 0℃; for 0.333333h; Stage #2: butyryl chloride In tetrahydrofuran at 20℃; for 13h; | |
Stage #1: m-Anisidine With triethylamine In tetrahydrofuran at 25℃; for 0.166667h; Stage #2: butyryl chloride In tetrahydrofuran at 25℃; for 3h; Sealed tube; |
methyl 4-iodosalicylate
m-Anisidine
methyl 2-hydroxy-4-(3-methoxyphenylamino)benzoate
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; caesium carbonate In toluene at 100℃; for 15.25h; Buchwald-Hartwig Coupling; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); potassium tert-butylate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 20h; Inert atmosphere; | 100% |
Stage #1: para-iodoanisole With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 0.75h; Inert atmosphere; Stage #2: m-Anisidine In toluene at 90℃; for 14h; Inert atmosphere; | 81% |
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 100℃; for 12h; Inert atmosphere; | 77.7% |
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 100℃; for 23h; Inert atmosphere; |
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