DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:111-71-7
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Cas:111-71-7
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Product Name: Heptaldehyde Synonyms: 1-Heptanal, Aldehyde C7, Enanthaldehyde, Heptaldehyde, Oenanthaldehyde;1-Heptanal, Aldehyde C7, Enanthaldehyde, Oenanthaldehyde;1-Heptanal, Aldehyde C7, Enanthaldehyde, Heptanal, Oenanthaldehyde;Oenanthoaldehyd
Cas:111-71-7
Min.Order:1 Kilogram
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inquiryProduct Name: Heptaldehyde Synonyms: 1-Heptanal, Aldehyde C7, Enanthaldehyde, Heptaldehyde, Oenanthaldehyde;1-Heptanal, Aldehyde C7, Enanthaldehyde, Oenanthaldehyde;1-Heptanal, Aldehyde C7, Enanthaldehyde,
Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:111-71-7
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inquiryMinimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,
Heptaldehyde CAS:111-71-7 Specification Product Name: Heptaldehyde Synonyms: 1-Heptanal, Aldehyde C7, Enanthaldehyde, Heptaldehyde, Oenanthaldehyde;1-Heptanal, Aldehyde C7, Enanthaldehyde, Oenanthaldehyde;1-Heptanal, Alde
Cas:111-71-7
Min.Order:1 Kilogram
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inquiryAppearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Aliphatics;Isotope Labelled Compounds;... Transportation:Common products:Sea/Air/Courier D
Cas:111-71-7
Min.Order:100 Metric Ton
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J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:111-71-7
Min.Order:10 Gram
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inquirySuperior quality Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Labelled Heptanal. Bioconversion of heptanal to hept
Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
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high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:111-71-7
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Heptaldehyde,111-71-7 Application:Heptaldehyde,111-71-7
Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an
Heptaldehyde,111-71-7Appearance:white powder Storage:Room temperature. Package:normal packing Application:Pharmaceutical Intermediates, OLED Intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airpo
1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:111-71-7
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryHeptaldehyde Basic information Product Name: Heptaldehyde Synonyms: HEPTANAL;HEPTALDEHYDE;HEPTYL ALDEHYDE;FEMA 2540;FEMA 2541;FEMA 2542;ENANTHAL;ENANTHALDEHYDE
[Chinese] Heptyl aldehyde "English name" 1 - HEPTALDEHYDE 1 - HEPTANAL ALDEHYDE 7 C - ENANTHAL ENANTHALDEHYDE ENAPTHALDEHYDE FEMA 2540 FEMA 2541 FEMA 2542 HEPTALDEHYDE HEPTANAL HEPTYL ALDEHYDE N-HEPTALDEHYDE N-
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Cas:111-71-7
Min.Order:1 Gram
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Type:Trading Company
inquiryProfile HeBei Ruishun Trade Co.LTD, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,Seek development by credit
BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art
Conditions | Yield |
---|---|
With carbon monoxide; rhodium(I) acetylacetonate; hydrogen; triphenylphosphine In toluene at 100℃; under 10343.2 Torr; for 2h; Autoclave; | 81% |
Conditions | Yield |
---|---|
With pyridine chromium peroxide In dichloromethane for 1.25h; Ambient temperature; | 99% |
With polymeric complex of oxodiperoxochromium(VI) compound and pyrazine (Pyz-CrO5)n In dichloromethane for 1.5h; Ambient temperature; | 99% |
With pyridine chromium peroxide In dichloromethane for 1.25h; Product distribution; Ambient temperature; effect of various chromium(VI) based oxidants; | 99% |
Conditions | Yield |
---|---|
With 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide In methanol; dichloromethane at 20℃; for 0.1h; | 97% |
With iodosylbenzene In dichloromethane at 20℃; for 0.416667h; | 95% |
With silica gel In neat (no solvent) at 20℃; for 0.0833333h; | 93% |
With Clayan for 0.05h; Irradiation; microwave irradiation; | 81% |
Conditions | Yield |
---|---|
With synthesis gas; dicarbonylacetylacetonato rhodium (I); C44H33BrN2P2 In 5,5-dimethyl-1,3-cyclohexadiene at 150℃; under 7500.75 - 30003 Torr; for 3h; Autoclave; Inert atmosphere; | 96.3% |
Conditions | Yield |
---|---|
With oxidase In water at 40℃; for 1.5h; Reformatsky Reaction; | 100% |
With oxygen In neat (no solvent) at 45℃; for 7h; Solvent; Temperature; | 50 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In octane at 400℃; under 760.051 Torr; for 6h; Reagent/catalyst; | A 36.6% B 15.3% C 7.6% |
Conditions | Yield |
---|---|
With sodium periodate; [η5-C5H5Ru(CO)2NH2C6H11]BF4 In water; acetonitrile at 60℃; for 3h; Catalytic behavior; Schlenk technique; Inert atmosphere; | 98% |
With sodium periodate; C53H44As2N2O3Ru In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; | 98% |
With sodium periodate; C18H14Cl3N2Ru(1+)*F6P(1-) In water; tert-butyl alcohol at 60℃; for 1h; Catalytic behavior; Inert atmosphere; Schlenk technique; | 91% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; bromine In hexane; water at 20℃; for 24h; | A 9% B 91% |
With pyridine; 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 25℃; for 3h; | A 12.9% B 87.1% |
With chloro-tris-(2-methoxy-phenyl)-methane In dichloromethane for 9h; Ambient temperature; | A 28% B 57% |
With chromium(VI) oxide; aluminum oxide In hexane for 15h; Ambient temperature; | A 47% B 48% |
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 22℃; for 3h; | A 36 %Chromat. B 22 %Chromat. |
1,1-diacetoxy-heptane
heptanal
Conditions | Yield |
---|---|
With 2,6-dicarboxypyridinium chlorochromate In acetonitrile at 20℃; for 0.25h; | 96% |
With tetra-N-butylammonium tribromide In methanol at 20℃; for 0.25h; | 95% |
With carbon tetrabromide In acetonitrile for 3h; Heating; | 87% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; tetra(n-butyl)ammonium hydrogensulfate; sodium tungstate In tert-butyl alcohol at 90℃; | A 11% B 89% |
With 1-methyl-3-(2-oxo-2-(2,2,6,6-tetramethyl-1-ylooxy-4-piperidoxyl)ethyl)imidazolium chloride; 1-(carboxymethyl)-3-methylimidazolium chloride; oxygen; sodium nitrite In water at 59.84℃; under 7500.75 Torr; for 12h; Inert atmosphere; | A 76% B 12% |
With C30H24N2O7W; dihydrogen peroxide In water; acetonitrile for 17h; Reflux; | A 72% B 17% |
Conditions | Yield |
---|---|
With hydrogen; rhodium (III) acetate; trisodium tris(3-sulfophenyl)phosphine In water at 125℃; under 18751.9 - 22502.3 Torr; for 3h; | |
With 18-crown-6 ether; hydrogen; rhodium (III) acetate; trisodium tris(3-sulfophenyl)phosphine In water at 125℃; under 18751.9 - 37503.8 Torr; for 3h; |
1-hexene
carbon monoxide
A
heptanal
B
R-(-)-2-methylhexanal
C
S-(+)-2-methylhexanal
Conditions | Yield |
---|---|
With acetylacetonatodicarbonylrhodium(l); hydrogen; (R,S)-binaphos In benzene under 76000 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | A 76% B n/a C n/a |
With acetylacetonatodicarbonylrhodium(l); hydrogen; (R,S)-binaphos In benzene under 76000 Torr; Yields of byproduct given; | A 76% B n/a C n/a |
With hydrogen; Rh(acac)<(S)-(5,5'-dichloro-2-diphenylphosphino-4,4',6,6'-tetramethylbiphenyl-2'-yl)(R)-1,1'-binaphthalen-2,2'-diyl)phosphite> In benzene at 30℃; under 76000 Torr; for 40h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
heptanal
Conditions | Yield |
---|---|
With ozone In dichloromethane at -78℃; for 0.166667h; | 73% |
Conditions | Yield |
---|---|
With dicarbonylacetylacetonato rhodium (I); C41H26F4O8P2; hydrogen In toluene at 90℃; under 3750.38 - 7500.75 Torr; for 3h; Reagent/catalyst; regioselective reaction; | 98.8% |
With dicarbonylacetylacetonato rhodium (I); C64H46O12P4; hydrogen In dichloromethane at 80℃; for 2h; Catalytic behavior; regioselective reaction; | 98.9% |
With hydrogen; triethylamine; di(rhodium)tetracarbonyl dichloride; triphenylphosphine at 80℃; under 15001.2 Torr; for 0.333333h; | 71% |
Conditions | Yield |
---|---|
With dicarbonyl(acetylacotonato)rhodium(I); hydrogen; triphenylphosphine In water at 100℃; under 12001.2 Torr; Autoclave; Inert atmosphere; regioselective reaction; |
Conditions | Yield |
---|---|
With dicarbonylacetylacetonato rhodium (I); C44H34O8P2; hydrogen In toluene at 90℃; under 3750.38 - 7500.75 Torr; for 3h; regioselective reaction; | A 91.9% B n/a |
With hydrogen; 1-octyl-3-methyl-imidazolium bromide In water at 100℃; under 15001.5 Torr; for 3h; Product distribution; Further Variations:; Reagents; | A 90.2% B 8.95% |
With acetylacetonatodicarbonylrhodium(l); hydrogen; triphenylphosphine In neat (no solvent) at 80℃; under 7500.75 Torr; for 1h; Catalytic behavior; Pressure; Autoclave; | A 81% B 11% |
1,1-dimethoxyheptane
heptanal
Conditions | Yield |
---|---|
With water at 80℃; for 0.25h; microwave irradiation; | 99% |
With erbium(III) triflate In nitromethane at 20℃; for 1h; | 90% |
With (trimethylsilyl)bis(fluorosulfuryl)imide In dichloromethane at -78℃; for 12h; | 83% |
Conditions | Yield |
---|---|
With (2-(diphenylphosphino)-6-(2,4,6-triisopropylphenyl)pyridine); water; (η5-cyclopentadienyl) (η6-naphthalene)ruthenium hexafluorophosphate In acetone at 60℃; for 6.5h; | 91% |
Conditions | Yield |
---|---|
With poly[4-vinyl-N,N-dichlorobenzenesulfonamide] In tetrachloromethane at 40℃; for 5h; | 90% |
With CuCl*Kieselghur; oxygen In dichloromethane at 20℃; for 0.416667h; | 89% |
With iron(III) chloride In N,N-dimethyl-formamide at 25℃; for 0.2h; sonication; | 86% |
Conditions | Yield |
---|---|
With dicarbonyl(acetylacotonato)rhodium(I); carbon monoxide; hydrogen; C60H60N6P2 In toluene at 100℃; under 7500.75 Torr; for 12h; Sealed tube; |
1-hexene
carbon monoxide
A
heptanal
B
2-methylhexanal
C
n-heptan1ol
Conditions | Yield |
---|---|
With hydrogen; and zeolite X In ethanol; toluene at 120℃; under 38000 Torr; for 17h; Yields of byproduct given; | A n/a B n/a C 52% |
Conditions | Yield |
---|---|
With tert-butylhypochlorite; lead acetate; dibenzoyl peroxide In toluene at 20℃; for 0.25h; | 90% |
With oxygen; palladium diacetate; toluene-4-sulfonic acid In water at 100℃; under 6080.41 Torr; for 24h; | 89% |
With cerium(III) chloride heptahydrate; tetrabutyl-ammonium chloride In [D3]acetonitrile at 20℃; for 18h; Reagent/catalyst; Molecular sieve; Sealed tube; Irradiation; | 87 %Spectr. |
1-hexene
carbon monoxide
A
heptanal
B
5-methylhexanal
C
hexane
Conditions | Yield |
---|---|
With hydrogen In toluene at 129.84℃; under 37503.8 Torr; for 1h; Reagent/catalyst; Autoclave; |
heptanol trimethylsilyl ether
heptanal
Conditions | Yield |
---|---|
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 0.5h; Heating; | 93% |
With ammonium cerium(IV) nitrate; HZSM-5 zeolite In water for 0.0833333h; microwave irradiation; | 92% |
With quinolinium monofluorochromate(VI) In acetonitrile at 25℃; for 1.6h; | 86% |
1-hexene
carbon monoxide
A
heptanal
B
2-methylhexanal
C
2-ethylpentanal
D
hexane
Conditions | Yield |
---|---|
With hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine In water; butan-1-ol at 80℃; under 20701.7 Torr; for 14h; microemulsion/sol-gel; | A 52% B 23.9% C 3.8% D 0.6% |
With hydrogen In 1-methyl-pyrrolidin-2-one at 149.84℃; under 37503.8 Torr; for 17h; Autoclave; | |
With hydrogen at 70℃; under 37503.8 Torr; for 1h; |
Conditions | Yield |
---|---|
With dicarbonyl(acetylacotonato)rhodium(I); hydrogen; triphenylphosphine at 80℃; under 7500.75 Torr; Autoclave; Inert atmosphere; regioselective reaction; |
1-hexene
carbon monoxide
A
heptanal
B
2-methylhexanal
C
2-ethylpentanal
Conditions | Yield |
---|---|
With dicobalt octacarbonyl; hydrogen; silica gel In acetonitrile at 79.9℃; under 90007.2 - 105008 Torr; for 100h; Product distribution; other catalyst and support systems; | |
With dodecacarbonyltetrarhodium(0); hydrogen; di(3-natriumsulfonato-4-fluorophenyl)(4-fluorophenyl)phosphine; C18H9F3O9PS3(3-)*3Na(1+) In water at 120℃; under 37503 Torr; for 2h; Product distribution; other substituted triphenylphosphines-Rh4(CO)12 two-phase catalytic system; | |
With hydrogen; C10H3Co3O12Si In toluene at 120℃; under 52504.2 Torr; for 8h; Product distribution; further cobalt catalysts, various pressure, time, solvents; |
Conditions | Yield |
---|---|
With polyaniline-sulfate salt; water for 0.5h; Heating; | 96% |
potassium ferrate(VI); montmorillonite K-10 In dichloromethane for 0.25h; Heating; | 91% |
With ammonium nitrate; Montmorillonite-K10 for 0.05h; deprotection; microwave irradiation; | 90% |
2-(heptyloxy)tetrahydro-2H-pyran
heptanal
Conditions | Yield |
---|---|
With NTPPPODS In acetonitrile for 0.5h; Reflux; | 87% |
With HMTAB; silica gel for 0.0333333h; microwave irradiation; | 82% |
With potassium permanganate; tetrachlorosilane In acetonitrile at 20℃; for 0.5h; | 75% |
With aluminum oxide; [bis(acetoxy)iodo]benzene In acetonitrile for 0.833333h; Oxidation; Heating; | 70% |
With aluminium trichloride; silver bromate In acetonitrile for 1.5h; Heating; Yield given; |
Conditions | Yield |
---|---|
With methanesulfonic acid; oxygen; [(n-Bu)4N]3H2[IMo6O24] In acetonitrile at 80℃; under 1520.1 Torr; for 15h; | A 17% B 83% |
With oxygen; aluminum oxide; ruthenium In toluene at 99.84℃; for 24h; | |
With oxygen; Ru(PPh3)3Cl2/CW In various solvent(s) at 60℃; under 760.051 Torr; for 15h; Product distribution; Further Variations:; Catalysts; |
Conditions | Yield |
---|---|
With acetic acid; acetone oxime at 110℃; for 1.5h; | 100% |
With acetylhydroxamic acid; boron trifluoride diethyl etherate In methanol for 0.1h; Microwave irradiation; Sealed tube; | 82% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 0 - 20℃; | 76% |
Conditions | Yield |
---|---|
With Triethoxysilane; potassium fluoride at 25℃; for 20h; | 100% |
With Triethoxysilane; 1,3-Diphenylpropanone; potassium fluoride at 25℃; for 7h; | 100% |
With 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 25℃; for 6h; Inert atmosphere; Glovebox; Sealed tube; | 98% |
Conditions | Yield |
---|---|
With ammonium chloride; zinc In tetrahydrofuran for 1h; Ambient temperature; | 100% |
With silica gel; ammonium chloride; zinc for 16h; Product distribution; Mechanism; Ambient temperature; other carbonyl compounds; other allyl halides; var. solid or liquid phases; var. reaction time; | 98% |
With chloro-trimethyl-silane; Piperonyl butoxide; tetrabutylammomium bromide In N,N-dimethyl-formamide for 2h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
With triethylamine; magnesium bromide In tetrahydrofuran at 25℃; for 12h; | 100% |
(i) NaH, Et2O, (ii) /BRN= 1560236/; Multistep reaction; |
Conditions | Yield |
---|---|
at 25℃; | 100% |
Conditions | Yield |
---|---|
With [Sc3(3,5-disulfobenzoic acid)2(μ-O2H3)(μ-OH)2(H2O)2] In neat (no solvent) at 40℃; for 2h; Catalytic behavior; Schlenk technique; Inert atmosphere; | 100% |
With 2Zn(2+)*10H2O*3C10H8N2*2H(1+)*Co2Mo10H4O38(6-) In neat (no solvent) at 25℃; for 7h; Reagent/catalyst; Inert atmosphere; | 100% |
With tin-tungsten mixed oxide, Sn/W molar ratio = 2, calcined at 800 °C In 1,2-dichloro-ethane at 22 - 23℃; for 0.5h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; | 100% |
85% | |
In tetrahydrofuran for 1h; | 82% |
heptanal
(dichloro-fluoro-methyl)-tris-dimethylamino-phosphonium; chloride
1-chloro-1-fluoro-oct-1-ene
Conditions | Yield |
---|---|
With zinc copper In tetrahydrofuran | 100% |
Conditions | Yield |
---|---|
With tetrabutyl-ammonium chloride In dichloromethane; water Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With iodine In water; butanone at 20℃; for 0.5h; | 100% |
With poly(ethyleneglycol) linked dicationic sulfonic acid ionic liquid In toluene at 20 - 80℃; for 0.133333h; | 90% |
TiCl4 on montmorillonite In dichloromethane for 1h; Heating; | 89% |
Conditions | Yield |
---|---|
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere; Stage #2: heptanal In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere; | 100% |
With n-butyllithium 1.) THF, -78 deg C, 1 h, 2.) THF, room temp., 1 h; Multistep reaction; | |
With n-butyllithium 1) THF, -78 deg C, 1 h, 2) THF, r. t., 1 h; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With Tributylphosphine oxide; (R)-3,3'-bis(diphenylphosphinoylmethyl)-1,1'-binaphthalene-2,2'-dioxyaluminium chloride In dichloromethane at -40℃; for 58h; | 100% |
Conditions | Yield |
---|---|
Stage #1: heptanal; C21H32BNO3 Addition; Stage #2: With lithium hydroperoxide; dihydrogen peroxide In water Hydrolysis; | 100% |
Conditions | Yield |
---|---|
Stage #1: 1-bromo-4-methoxy-benzene; tri-n-butyllithium magnesate complex In tetrahydrofuran; hexane at 0℃; for 0.5h; Stage #2: heptanal In tetrahydrofuran; hexane at -78℃; for 0.5h; Further stages.; | 100% |
heptanal
acetoacetic acid methyl ester
5-hydroxy-3-oxo-undecanoic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: acetoacetic acid methyl ester With sodium hydride In tetrahydrofuran at 0℃; for 0.166667h; Stage #2: With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 0.333333h; Stage #3: heptanal In tetrahydrofuran; hexane at -78 - 20℃; for 1.08333h; | 100% |
Stage #1: acetoacetic acid methyl ester With sodium hydride In tetrahydrofuran at 0℃; Stage #2: With n-butyllithium In tetrahydrofuran at -78℃; Stage #3: heptanal In tetrahydrofuran Further stages.; |
Conditions | Yield |
---|---|
Stage #1: 2-bromo-3,3,3-trifluoropropene With n-butyllithium; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.333333h; Inert atmosphere; Stage #2: heptanal In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; | 100% |
With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 0.5h; | 90% |
With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 3h; |
Conditions | Yield |
---|---|
With polymer-supported scandium(III) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 0.5h; Strecker reaction; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In tetrahydrofuran at 20℃; | 100% |
Conditions | Yield |
---|---|
With magnesium sulfate In dichloromethane at 20℃; Inert atmosphere; | 100% |
heptanal
di-isopropyl azodicarboxylate
1-heptanoyl-1,2-hydrazinedicarboxylic acid 1,2-diisopropyl ester
Conditions | Yield |
---|---|
With Graphite In acetonitrile at 20℃; for 2h; Reagent/catalyst; Solvent; Irradiation; | 100% |
With copper(II) acetate monohydrate In ethyl acetate at 20℃; for 8h; | 98% |
With zinc(II) acetate dihydrate In acetonitrile at 20℃; for 16h; | 88% |
Conditions | Yield |
---|---|
With [Zr6(μ3-O)4(μ3-OH)4(1,4-benzenedicarboxylate)6][(S)-6-((hexahydropyrrolo[1,2-a]pyrazin-2(1H)-yl)methyl)picolinaldehyde]-NH2 In toluene at 100℃; for 24h; Reagent/catalyst; Knoevenagel Condensation; | 100% |
Conditions | Yield |
---|---|
With [(R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclo-hexanediaminato(2-)]Mn(II)sulfophenyl-L-sodum lactose templated helical silica supported In dichloromethane at 0℃; for 6h; Reagent/catalyst; Diels-Alder Cycloaddition; Ionic liquid; Molecular sieve; enantioselective reaction; | 100% |
Conditions | Yield |
---|---|
In ethanol at 20℃; | 100% |
Conditions | Yield |
---|---|
With K[(H2O)4(3-picolinic acid)2Ce][(H2O)5(3-picolinic acid)2Ce][PW10Ti2O40]·11H2O at 49.84℃; for 4h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; | 99.8% |
Conditions | Yield |
---|---|
With P(i-PrNCH2CH2)3N; magnesium sulfate for 0.666667h; Ambient temperature; | 99% |
With triethylamine; lithium bromide at 80℃; for 0.05h; Henry reaction; microwave irradiation; | 96% |
With acrylic acid methyl ester; triphenylphosphine In ethanol at 20℃; for 2h; Henry reaction; | 96% |
Conditions | Yield |
---|---|
With P(i-PrNCH2CH2)3N; magnesium sulfate for 1.5h; Ambient temperature; | 99% |
With tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine In tetrahydrofuran for 0.0833333h; | 91% |
With Amberlyst A-21 for 7h; | 80% |
With methanol; sodium hydroxide |
Conditions | Yield |
---|---|
With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 8h; Green chemistry; | 99% |
With water; oxygen at 100℃; for 24h; | 98% |
With periodic acid; pyridinium chlorochromate In acetonitrile for 1.5h; | 97% |
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