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Cas:79-46-9
Min.Order:1 Gram
FOB Price: $1.0 / 3.0
Type:Lab/Research institutions
inquiryimg _fcksavedurl="/UserAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:79-46-9 Transportation:by air or by sea Port:Shanghai
Cas:79-46-9
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiry2-Nitropropane Basic information Product Name: 2-Nitropropane Synonyms: 2-nitro-propan;b-nitropropane;Dimethylnitromethane;i-C3H7NO2;Nipar S-20;Nipar S-20 solvent;N
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen
Cas:79-46-9
Min.Order:1 Kilogram
FOB Price: $50.0 / 80.0
Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:79-46-9
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquirySuperior quality, moderate price & quick delivery. Appearance:colourless or light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceu
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:79-46-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:79-46-9
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Cas:79-46-9
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryTech Data Relevant 1.Certificate Of Analysis (COA) 2..Material Safety Data Sheet (MSDS) 3.Technical Data Sheet(TDS) 4.Route of synthesis (ROS) 5.Nuclear Magnetic Resonance(NMR) 6.Method of Analysis(MOA) Our Service 1. Before Shipmen
Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa
Compound sourcing ServicesAgency of testing serviceFactory audit serviceFounded in Dec. 1999, Nanjing Chemlin Chemical Industrial Co.,Ltd(CHEMLIN) has been covering the business scope from trading of chemicals to custom-synthesis & Manufacturing. Co
Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int
Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys
2-Nitropropane CAS#79-46-9 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.
United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete
Propane, 2-nitro- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen
intermediateAppearance:powder Storage:Normal temperature Package:1kg/25kg/customized Application:intermediate Transportation:By Ship/Air
Conditions | Yield |
---|---|
With dihydrogen peroxide; sodium carbonate In methanol at 60℃; under 750.075 Torr; | 96.5% |
Conditions | Yield |
---|---|
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 100℃; under 3800.26 Torr; for 14h; | 65% |
With water; nitric acid at 185 - 215℃; under 46337 Torr; | |
With oxygen; nitric acid in der Gasphase; |
Conditions | Yield |
---|---|
With sodium nitrite In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Time; | 70.9% |
With poly(N-ethyl-4-vinylpyridinium)nitrite In hexane at 20℃; for 72h; | 63% |
With sodium nitrite In N,N,N,N,N,N-hexamethylphosphoric triamide at 65℃; for 5h; | 11% |
With sodium nitrite at 65℃; Product distribution; various sovents and reaction times; |
propane
A
2-nitropropane
B
acetic acid
C
1-Nitropropane
D
acetone
Conditions | Yield |
---|---|
With nitric acid; butyric acid In water at 220℃; under 73162.7 Torr; for 0.0333333h; |
Conditions | Yield |
---|---|
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; chemoselective reaction; | 88 %Chromat. |
With ammonium hydroxide; dihydrogen peroxide In methanol at 65 - 75℃; for 1h; Reagent/catalyst; Temperature; Green chemistry; |
propane
A
Nitroethane
B
2-nitropropane
C
acetic acid
D
1-Nitropropane
E
acetone
Conditions | Yield |
---|---|
With nitric acid; propionic acid In water at 235℃; under 73162.7 Torr; |
Conditions | Yield |
---|---|
With ammonia; dihydrogen peroxide at 61.84℃; for 2h; chemoselective reaction; | |
With ammonia; dihydrogen peroxide In water at 70℃; for 8h; Temperature; Molecular sieve; |
Conditions | Yield |
---|---|
With nitric acid at 400℃; | |
With Nitrogen dioxide at 250 - 795℃; | |
With Nitrogen dioxide at 250℃; | |
With nitric acid In water at 285℃; under 72402.6 Torr; Product distribution / selectivity; |
Conditions | Yield |
---|---|
With sodium nitrite at 60℃; under 0 Torr; for 48h; |
isopropylboronic acid
2-nitropropane
Conditions | Yield |
---|---|
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction; | 74% |
Conditions | Yield |
---|---|
With nitric acid In acetic acid at 15℃; for 0.5h; | 90% |
Conditions | Yield |
---|---|
With nitric acid In water at 285℃; under 72402.6 Torr; for 0.0425h; Product distribution / selectivity; | |
With nitric acid In water at 235℃; under 72402.6 Torr; for 0.0333333h; |
Conditions | Yield |
---|---|
With nitric acid; acetic acid In water at 235℃; under 88677.5 Torr; for 0.025h; Product distribution / selectivity; | |
With nitric acid; acetic acid In water at 235℃; under 73162.7 Torr; for 0.0333333h; Product distribution / selectivity; |
Conditions | Yield |
---|---|
With nitric acid In water at 235℃; under 72402.6 Torr; Product distribution / selectivity; 3 mm borosilicate glass balls packing; |
propane
A
nitromethane
B
2-nitropropane
C
1-Nitropropane
D
acetone
Conditions | Yield |
---|---|
With nitric acid; acetic acid In water at 180℃; under 72402.6 Torr; for 0.0291667h; Product distribution / selectivity; |
Conditions | Yield |
---|---|
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; Overall yield = 91 %Chromat.; chemoselective reaction; |
Conditions | Yield |
---|---|
With nitric acid at 380 - 430℃; |
Conditions | Yield |
---|---|
With silver(I) nitrite | |
With silver(I) nitrite In diethyl ether |
α-nitroisopropyl p-tolyl sulfone
A
2-nitropropane
B
2,3-dimethyl-2,3-dinitrobutane
Conditions | Yield |
---|---|
With sodium dithionite; potassium carbonate; 1,1′-dioctyl-4,4′-bipyridinium In dichloromethane; water at 35℃; for 3h; | A 65 % Spectr. B 10 % Spectr. |
propane
A
Nitroethane
B
nitromethane
C
2-nitropropane
D
2,2-dinitropropane
E
acetic acid
F
1-Nitropropane
G
acetone
Conditions | Yield |
---|---|
With nitric acid In water at 285℃; under 73496.9 Torr; for 0.0425h; Product distribution / selectivity; |
Conditions | Yield |
---|---|
With silver(I) nitrite |
Conditions | Yield |
---|---|
With silver(I) nitrite |
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene for 8h; Mechanism; Irradiation; | 66% |
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene for 19h; Mechanism; Irradiation; | 47% |
α-nitroisopropyl phenyl sulfone
2-nitropropane
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In acetonitrile for 70h; Mechanism; Irradiation; | 32% |
With N-benzyl-1,4-dihydronicotinamide In N,N-dimethyl-formamide for 6h; Ambient temperature; degassed; | 95 % Chromat. |
Conditions | Yield |
---|---|
With nitric acid at 380 - 430℃; |
Conditions | Yield |
---|---|
With nitric acid at 380 - 430℃; |
2-nitro-benzaldehyde
A
2-nitropropane
B
2,3-dimethyl-2,3-dinitrobutane
C
anthranil
Conditions | Yield |
---|---|
With 2-bromo-2-nitropropane; zinc In methanol at 50℃; for 5h; Mechanism; Product distribution; investigation of reductive cyclizations of var. 2-nitrobenzaldehydes under var. conditions; | A n/a B n/a C 37% |
Conditions | Yield |
---|---|
equil. react.; HPMS experiment at 500 K; |
Conditions | Yield |
---|---|
With diethyl ether anschliessend Behandeln mit Wassser; |
Conditions | Yield |
---|---|
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h; | 100% |
With 2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 2,8,9-tris(1-methylethyl) In various solvent(s) at 20℃; for 0.5h; Michael addition; | 99% |
With potassium carbonate In neat (no solvent) at 60℃; for 4h; Temperature; Michael Addition; | 88% |
With N-benzyl-trimethylammonium hydroxide In ethanol Heating; | |
With 2,5-dimethyl-piperazine; rac-Pro-OH In tetrahydrofuran at 20℃; Michael addition; |
1,10-phenanthroline-5,6-dione
2-nitropropane
2,2-dimethyl-1,3-dioxolo<4,5-f><1,7>phenanthroline
Conditions | Yield |
---|---|
With tetramethyl ammoniumhydroxide In acetonitrile at 59.9℃; for 24h; | 100% |
With carbonate buffer (pH 9.5) In water; acetonitrile at 55℃; for 5h; | 67% |
Conditions | Yield |
---|---|
With tetramethyl ammoniumhydroxide In acetonitrile for 24h; Heating; | 100% |
2-nitropropane
4-nitrobenzaldehdye
2-methyl-2-nitro-1-(4-nitrophenyl)propan-1-ol
Conditions | Yield |
---|---|
With polymer supported 4-DMAP at 20℃; for 0.583333h; Henry Nitro Aldol Condensation; | 100% |
With polystyryl-diphenylphosphine-ethyl acrylate complex In neat (no solvent) at 20℃; for 3h; Henry Nitro Aldol Condensation; Green chemistry; | 91% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 4h; Alkylation; | 87% |
With triethylamine In chloroform at 24.84℃; for 3h; Henry reaction; | 85% |
2-nitropropane
ethyl 4,4,4-trifluorobut-2-enoate
ethyl 3-(trifluoromethyl)-4-methyl-4-nitropentanoate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; for 6h; | 100% |
2-nitropropane
5-hydroxyiminomethylbenzofuroxan
Conditions | Yield |
---|---|
With piperidine In tetrahydrofuran at 20℃; | 100% |
tetrakis(triphenylphosphine)nickel(0)
2-nitropropane
C3H7NONi(P(C6H5)3)2
Conditions | Yield |
---|---|
In benzene Kinetics; byproducts: P(C6H5)3, OP(C6H5)3; the soln. of Ni(PPh3)4/benzene was added to the soln. of i-PrNO2/benzene with stirring at under Ar, stirred for 1 h; evapd. in vac., washed with hot hexane, dried in vac.; | 100% |
2-nitropropane
(4-hydroxyphenyl)methanol
1-nitro-1,1-dimethyl-2-(4-hydroxyphenyl]ethane
Conditions | Yield |
---|---|
With potassium tert-butylate In diethylene glycol dimethyl ether at 20 - 137℃; for 6h; | 99.6% |
With potassium tert-butylate In diethylene glycol dimethyl ether Cooling with ice; Reflux; | 83% |
With tetrabutyl ammonium fluoride at 130℃; for 15h; | 73% |
3-(Dimethylaminomethyl)indole
2-nitropropane
3-(2,2-dimethyl-2-nitroethyl)-1H-indole
Conditions | Yield |
---|---|
With tributylphosphine In acetonitrile for 4h; Heating; | 99.1% |
With sodium hydroxide at 130℃; | 93% |
With sodium hydroxide for 18h; Heating; | 70% |
With sodium hydroxide for 18h; Reflux; |
4-methyl-pent-3-en-2-one
2-nitropropane
4,4,5-trimethyl-5-nitro-2-hexanone
Conditions | Yield |
---|---|
With 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane In various solvent(s) at 20℃; for 0.33h; Michael addition; | 99% |
With N,N',N''-tris(p-tolyl)azacalix[3](2,6)(4-pyrrolidinopyridine) for 12h; Inert atmosphere; Reflux; | 88% |
With sodium In isopropyl alcohol for 336h; Reflux; | 13% |
Conditions | Yield |
---|---|
With P(i-PrNCH2CH2)3N; magnesium sulfate for 1.5h; Ambient temperature; | 99% |
With tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine In tetrahydrofuran for 0.0833333h; | 91% |
With Amberlyst A-21 for 7h; | 80% |
With methanol; sodium hydroxide |
Conditions | Yield |
---|---|
With 2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 2,8,9-tris(1-methylethyl) In various solvent(s) at 20℃; for 0.25h; Michael addition; | 99% |
With sodium methylate In methanol | 92% |
With triethylamine at 20℃; for 5h; Michael reaction; | 82% |
2-nitropropane
methacrylic acid methyl ester
methyl 2,4-dimethyl-4-nitro-pentanoate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Inert atmosphere; Large scale; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Large scale; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Inert atmosphere; Large scale; | 99% |
2-nitropropane
acrylic acid n-butyl ester
4-Methyl-4-nitro-pentanoic acid butyl ester
Conditions | Yield |
---|---|
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h; | 99% |
2-nitropropane
5-nitro-6-chloromethylimidazo<2,1-b>thiazole
5-nitro-6-isopropylidenemethylimidazo<2,1-b>thiazole
Conditions | Yield |
---|---|
With tetra(n-butyl)ammonium hydroxide In dichloromethane; water for 24h; | 99% |
[Co(cp)(η-4-C5H5)]2(μ-O-exo)
2-nitropropane
[Co(cp)(η-4-C5H5)](CMe2NO2-exo)
Conditions | Yield |
---|---|
In not given absence of oxygen and moisture; dissoln. of Co-complex in i-PrNO2 (stirring); volume reduction, crystn. on cooling to -20°C; | 99% |
1-(2-furyl)-3-phenylpropen-1-one
2-nitropropane
(S)-1-(furan-2-yl)-4-methyl-4-nitro-3-phenylpentan-1-one
Conditions | Yield |
---|---|
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 99% |
Conditions | Yield |
---|---|
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 99% |
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 96h; Michael Addition; enantioselective reaction; | 76% |
With 4-nitro-phenol; C15H23N3 In dichloromethane at 20℃; for 96h; Michael reaction; optical yield given as %ee; enantioselective reaction; | 62% |
Conditions | Yield |
---|---|
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 99% |
Conditions | Yield |
---|---|
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at 0℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 99% |
Conditions | Yield |
---|---|
With 4-nitro-phenol; C15H23N3 In dichloromethane at 20℃; for 24h; Michael reaction; optical yield given as %ee; enantioselective reaction; | 99% |
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 48h; Michael Addition; enantioselective reaction; | 96% |
Conditions | Yield |
---|---|
With 9-epi-9-amino-9-deoxyquinine; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; benzoic acid at 40℃; for 24h; Michael Addition; enantioselective reaction; | 99% |
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 48h; Michael Addition; enantioselective reaction; | 96% |
With C20H25N3O In tetrahydrofuran at 20℃; for 120h; Michael Addition; enantioselective reaction; | 49% |
2-nitropropane
d8-methyl methacrylate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 40℃; for 16h; Inert atmosphere; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h; | 99% |
2-nitropropane
methyl 2-(4-chlorophenyl)acrylate
methyl 2-(4-chlorophenyl)-4-methyl-4-nitropentanoate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; | 98.7% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; | 98.66% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; | 98.66% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; | 98.66% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; for 12h; Michael condensation; |
piperidine
formaldehyd
2-nitropropane
1,1-Dimethyl-1-nitro-2-piperidinoethan
Conditions | Yield |
---|---|
In water at 50℃; for 1h; Mannich reaction; | 98% |
With sodium hydroxide at 50℃; for 2h; Cooling with ice; | 61% |
With 1,4-dioxane; sodium hydroxide Anschliessendes Erwaermen.; |
2-nitropropane
benzalacetophenone
4-methyl-4-nitro-1,3-diphenylpentan-1-one
Conditions | Yield |
---|---|
With potassium fluoride In ethanol at 20℃; for 4h; Addition; | 98% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 12h; Ambient temperature; | 95% |
With methyl-4,6-O-benzylidene-2,3-dideoxy-α-D-glucopyranosido[2,3-h]-N-((3-(3-phenyl)thiocarbamido))propyl-1,4,7,10-tetraoxa-13-azacyclopentadecane; sodium t-butanolate In toluene at 20℃; Michael Addition; Inert atmosphere; | 10% |
With methanol; sodium methylate | |
With sodium ethanolate In ethanol |
2-nitropropane
(E)-benzalacetone
(+/-)-5-methyl-5-nitro-4-phenylhexan-2-one
Conditions | Yield |
---|---|
With 2-tert-butylimino-2-diethylamino-1,3-dimethylperhydro-1,3, 2-diazaphosphorine supported on polystyrene at 30℃; for 20h; Michael condensation; | 98% |
With Rasta resin-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene at 60℃; for 30h; Michael addition reaction; | 90% |
With potassium carbonate; 1-butyl-3-methylimidazolium Tetrafluoroborate at 30℃; for 10h; Michael reaction; ultrasonic irradiation; | 80% |
2-nitropropane
Phenyl vinyl sulfoxide
3-methyl-3-nitro-1-(phenylsulfinyl)-butane
Conditions | Yield |
---|---|
With potassium carbonate; N-benzyl-N,N,N-triethylammonium chloride at 20℃; for 1h; | 98% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 24h; Ambient temperature; | 95% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile Ambient temperature; | 95% |
2-nitropropane
3-diazo-5-phenyl-3H-1,2,4-triazole
A
benzonitrile
B
acetone oxime
Conditions | Yield |
---|---|
at 80℃; Yields of byproduct given; | A n/a B 98% |
2-nitropropane
Methyl 2-acetamidoacrylate
Conditions | Yield |
---|---|
With N-benzyl-trimethylammonium hydroxide In methanol for 0.0333333h; microwave irradiation; | 98% |
With tetrabutyl ammonium fluoride In toluene for 66h; Ambient temperature; 1.) 10 min, 2.) 40-50 deg C, overnight; | 76% |