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Chemsigma International Co.,Ltd.

1111MicrosoftInternetExplorer402DocumentNotSpecified7.8 磅Normal0

2-Nitropropane

Cas:79-46-9

Min.Order:1 Gram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

img _fcksavedurl="/UserAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:79-46-9 Transportation:by air or by sea Port:Shanghai

2-Nitropropane

Cas:79-46-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

2-Nitropropane Basic information Product Name: 2-Nitropropane Synonyms: 2-nitro-propan;b-nitropropane;Dimethylnitromethane;i-C3H7NO2;Nipar S-20;Nipar S-20 solvent;N

2-Nitropropane79-46-9

Cas:79-46-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-nitropropane

Cas:79-46-9

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Nitropropane

Cas:79-46-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2-Nitropropane

Cas:79-46-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

2-Nitropropane Alkyl hydrocarbons

Cas:79-46-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 80.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:79-46-9

Cas:79-46-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Nitropropane

Cas:79-46-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Nitropropane

Cas:79-46-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Nitropropane

Cas:79-46-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Nitropropane

Cas:79-46-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless or light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceu

Propane, 2-nitro-

Cas:79-46-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 2-Nitropropane

Cas:79-46-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Nitropropane

Cas:79-46-9

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

2-Nitropropane

Cas:79-46-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 79-46-9 with competitive price

Cas:79-46-9

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Propane, 2-nitro-

Cas:79-46-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#79-46-9;CAT#A839696

Cas:79-46-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Tech Data Relevant 1.Certificate Of Analysis (COA) 2..Material Safety Data Sheet (MSDS) 3.Technical Data Sheet(TDS) 4.Route of synthesis (ROS) 5.Nuclear Magnetic Resonance(NMR) 6.Method of Analysis(MOA) Our Service 1. Before Shipmen

79-46-9 2-Nitropropane

Cas:79-46-9

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

2-nitropropane

Cas:79-46-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Compound sourcing ServicesAgency of testing serviceFactory audit serviceFounded in Dec. 1999, Nanjing Chemlin Chemical Industrial Co.,Ltd(CHEMLIN) has been covering the business scope from trading of chemicals to custom-synthesis & Manufacturing. Co

79-46-9

Cas:79-46-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou KieRay Chem Co.,Ltd.

Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int

2-Nitropropane

Cas:79-46-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

2-Nitropropane

Cas:79-46-9

Min.Order:0

Negotiable

Type:Other

inquiry

ORCHID CHEMICAL SUPPLIES LTD

2-Nitropropane CAS#79-46-9 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

2-Nitropropane

Cas:79-46-9

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Propane, 2-nitro-

Cas:79-46-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete

Propane, 2-nitro-

Cas:79-46-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Propane, 2-nitro- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Propane, 2-nitro-

Cas:79-46-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model

Propane, 2-nitro-

Cas:79-46-9

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Petrochemical Co.,Ltd

intermediateAppearance:powder Storage:Normal temperature Package:1kg/25kg/customized Application:intermediate Transportation:By Ship/Air

79-46-9

Cas:79-46-9

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

acetone oxime
127-06-0

acetone oxime

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With dihydrogen peroxide; sodium carbonate In methanol at 60℃; under 750.075 Torr;96.5%
propane
74-98-6

propane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 100℃; under 3800.26 Torr; for 14h;65%
With water; nitric acid at 185 - 215℃; under 46337 Torr;
With oxygen; nitric acid in der Gasphase;
isopropyl bromide
75-26-3

isopropyl bromide

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With sodium nitrite In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Time;70.9%
With poly(N-ethyl-4-vinylpyridinium)nitrite In hexane at 20℃; for 72h;63%
With sodium nitrite In N,N,N,N,N,N-hexamethylphosphoric triamide at 65℃; for 5h;11%
With sodium nitrite at 65℃; Product distribution; various sovents and reaction times;
propane
74-98-6

propane

A

2-nitropropane
79-46-9

2-nitropropane

B

acetic acid
64-19-7

acetic acid

C

1-Nitropropane
108-03-2

1-Nitropropane

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With nitric acid; butyric acid In water at 220℃; under 73162.7 Torr; for 0.0333333h;
acetone
67-64-1

acetone

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; chemoselective reaction;88 %Chromat.
With ammonium hydroxide; dihydrogen peroxide In methanol at 65 - 75℃; for 1h; Reagent/catalyst; Temperature; Green chemistry;
propane
74-98-6

propane

A

Nitroethane
79-24-3

Nitroethane

B

2-nitropropane
79-46-9

2-nitropropane

C

acetic acid
64-19-7

acetic acid

D

1-Nitropropane
108-03-2

1-Nitropropane

E

acetone
67-64-1

acetone

Conditions
ConditionsYield
With nitric acid; propionic acid In water at 235℃; under 73162.7 Torr;
acetone
67-64-1

acetone

A

2-nitropropane
79-46-9

2-nitropropane

B

acetone oxime
127-06-0

acetone oxime

Conditions
ConditionsYield
With ammonia; dihydrogen peroxide at 61.84℃; for 2h; chemoselective reaction;
With ammonia; dihydrogen peroxide In water at 70℃; for 8h; Temperature; Molecular sieve;
propane
74-98-6

propane

A

2-nitropropane
79-46-9

2-nitropropane

B

1-Nitropropane
108-03-2

1-Nitropropane

Conditions
ConditionsYield
With nitric acid at 400℃;
With Nitrogen dioxide at 250 - 795℃;
With Nitrogen dioxide at 250℃;
With nitric acid In water at 285℃; under 72402.6 Torr; Product distribution / selectivity;
diisopropyl sulfate
2973-10-6

diisopropyl sulfate

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With sodium nitrite at 60℃; under 0 Torr; for 48h;
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction;74%
isopropyl alcohol
67-63-0

isopropyl alcohol

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With nitric acid In acetic acid at 15℃; for 0.5h;90%
propane
74-98-6

propane

A

2-nitropropane
79-46-9

2-nitropropane

B

acetic acid
64-19-7

acetic acid

C

1-Nitropropane
108-03-2

1-Nitropropane

Conditions
ConditionsYield
With nitric acid In water at 285℃; under 72402.6 Torr; for 0.0425h; Product distribution / selectivity;
With nitric acid In water at 235℃; under 72402.6 Torr; for 0.0333333h;
propane
74-98-6

propane

A

nitromethane
75-52-5

nitromethane

B

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With nitric acid; acetic acid In water at 235℃; under 88677.5 Torr; for 0.025h; Product distribution / selectivity;
With nitric acid; acetic acid In water at 235℃; under 73162.7 Torr; for 0.0333333h; Product distribution / selectivity;
propane
74-98-6

propane

A

2-nitropropane
79-46-9

2-nitropropane

B

2,2-dinitropropane
595-49-3

2,2-dinitropropane

C

1-Nitropropane
108-03-2

1-Nitropropane

Conditions
ConditionsYield
With nitric acid In water at 235℃; under 72402.6 Torr; Product distribution / selectivity; 3 mm borosilicate glass balls packing;
propane
74-98-6

propane

A

nitromethane
75-52-5

nitromethane

B

2-nitropropane
79-46-9

2-nitropropane

C

1-Nitropropane
108-03-2

1-Nitropropane

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With nitric acid; acetic acid In water at 180℃; under 72402.6 Torr; for 0.0291667h; Product distribution / selectivity;
acetone oxime
127-06-0

acetone oxime

A

2-nitropropane
79-46-9

2-nitropropane

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; Overall yield = 91 %Chromat.; chemoselective reaction;
2,3-dimethylbutane
79-29-8

2,3-dimethylbutane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With nitric acid at 380 - 430℃;
2-iodo-propane
75-30-9

2-iodo-propane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With silver(I) nitrite
With silver(I) nitrite In diethyl ether
α-nitroisopropyl p-tolyl sulfone
21272-86-6

α-nitroisopropyl p-tolyl sulfone

A

2-nitropropane
79-46-9

2-nitropropane

B

2,3-dimethyl-2,3-dinitrobutane
3964-18-9

2,3-dimethyl-2,3-dinitrobutane

Conditions
ConditionsYield
With sodium dithionite; potassium carbonate; 1,1′-dioctyl-4,4′-bipyridinium In dichloromethane; water at 35℃; for 3h;A 65 % Spectr.
B 10 % Spectr.
propane
74-98-6

propane

A

Nitroethane
79-24-3

Nitroethane

B

nitromethane
75-52-5

nitromethane

C

2-nitropropane
79-46-9

2-nitropropane

D

2,2-dinitropropane
595-49-3

2,2-dinitropropane

E

acetic acid
64-19-7

acetic acid

F

1-Nitropropane
108-03-2

1-Nitropropane

G

acetone
67-64-1

acetone

Conditions
ConditionsYield
With nitric acid In water at 285℃; under 73496.9 Torr; for 0.0425h; Product distribution / selectivity;
2-iodo-propane
75-30-9

2-iodo-propane

A

i-propyl nitrite
541-42-4

i-propyl nitrite

B

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With silver(I) nitrite
isopropyl bromide
75-26-3

isopropyl bromide

A

i-propyl nitrite
541-42-4

i-propyl nitrite

B

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With silver(I) nitrite
2-bromo-2-nitropropane
5447-97-2

2-bromo-2-nitropropane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene for 8h; Mechanism; Irradiation;66%
2-chloro-2-nitro-propane
594-71-8

2-chloro-2-nitro-propane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene for 19h; Mechanism; Irradiation;47%
α-nitroisopropyl phenyl sulfone
41774-06-5

α-nitroisopropyl phenyl sulfone

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In acetonitrile for 70h; Mechanism; Irradiation;32%
With N-benzyl-1,4-dihydronicotinamide In N,N-dimethyl-formamide for 6h; Ambient temperature; degassed;95 % Chromat.
Isobutane
75-28-5

Isobutane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With nitric acid at 380 - 430℃;
methylbutane
78-78-4

methylbutane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With nitric acid at 380 - 430℃;
2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

A

2-nitropropane
79-46-9

2-nitropropane

B

2,3-dimethyl-2,3-dinitrobutane
3964-18-9

2,3-dimethyl-2,3-dinitrobutane

C

anthranil
271-58-9

anthranil

Conditions
ConditionsYield
With 2-bromo-2-nitropropane; zinc In methanol at 50℃; for 5h; Mechanism; Product distribution; investigation of reductive cyclizations of var. 2-nitrobenzaldehydes under var. conditions;A n/a
B n/a
C 37%
2-nitro-propan-2-ide
20846-00-8

2-nitro-propan-2-ide

hydrogen sulfide
7783-06-4

hydrogen sulfide

A

hydrgensulfide(1-)

hydrgensulfide(1-)

B

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
equil. react.; HPMS experiment at 500 K;
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

1.1-bromonitromethane

1.1-bromonitromethane

2-nitropropane
79-46-9

2-nitropropane

Conditions
ConditionsYield
With diethyl ether anschliessend Behandeln mit Wassser;
cyclohexenone
930-68-7

cyclohexenone

2-nitropropane
79-46-9

2-nitropropane

(+/-)-3-(2-nitropropan-2-yl)cyclohexanone
4908-50-3

(+/-)-3-(2-nitropropan-2-yl)cyclohexanone

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h;100%
With 2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 2,8,9-tris(1-methylethyl) In various solvent(s) at 20℃; for 0.5h; Michael addition;99%
With potassium carbonate In neat (no solvent) at 60℃; for 4h; Temperature; Michael Addition;88%
With N-benzyl-trimethylammonium hydroxide In ethanol Heating;
With 2,5-dimethyl-piperazine; rac-Pro-OH In tetrahydrofuran at 20℃; Michael addition;
1,10-phenanthroline-5,6-dione
82701-91-5

1,10-phenanthroline-5,6-dione

2-nitropropane
79-46-9

2-nitropropane

2,2-dimethyl-1,3-dioxolo<4,5-f><1,7>phenanthroline
112881-55-7

2,2-dimethyl-1,3-dioxolo<4,5-f><1,7>phenanthroline

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide In acetonitrile at 59.9℃; for 24h;100%
With carbonate buffer (pH 9.5) In water; acetonitrile at 55℃; for 5h;67%
phanquinone
84-12-8

phanquinone

2-nitropropane
79-46-9

2-nitropropane

2,2-Dimethyl-1,3-dioxa-4,11-diaza-cyclopenta[l]phenanthrene

2,2-Dimethyl-1,3-dioxa-4,11-diaza-cyclopenta[l]phenanthrene

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide In acetonitrile for 24h; Heating;100%
2-nitropropane
79-46-9

2-nitropropane

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

2-methyl-2-nitro-1-(4-nitrophenyl)propan-1-ol
39220-93-4

2-methyl-2-nitro-1-(4-nitrophenyl)propan-1-ol

Conditions
ConditionsYield
With polymer supported 4-DMAP at 20℃; for 0.583333h; Henry Nitro Aldol Condensation;100%
With polystyryl-diphenylphosphine-ethyl acrylate complex In neat (no solvent) at 20℃; for 3h; Henry Nitro Aldol Condensation; Green chemistry;91%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 4h; Alkylation;87%
With triethylamine In chloroform at 24.84℃; for 3h; Henry reaction;85%
2-nitropropane
79-46-9

2-nitropropane

ethyl 4,4,4-trifluorobut-2-enoate
25597-16-4, 91600-34-9, 406-10-0

ethyl 4,4,4-trifluorobut-2-enoate

ethyl 3-(trifluoromethyl)-4-methyl-4-nitropentanoate
638132-91-9

ethyl 3-(trifluoromethyl)-4-methyl-4-nitropentanoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; for 6h;100%
2-nitropropane
79-46-9

2-nitropropane

5-hydroxyiminomethylbenzofuroxan
241818-88-2

5-hydroxyiminomethylbenzofuroxan

5-hydroxyiminomethyl-2,2-dimethyl-2Н-benzimidazole 1,3-dioxide

5-hydroxyiminomethyl-2,2-dimethyl-2Н-benzimidazole 1,3-dioxide

Conditions
ConditionsYield
With piperidine In tetrahydrofuran at 20℃;100%
tetrakis(triphenylphosphine)nickel(0)
15133-82-1

tetrakis(triphenylphosphine)nickel(0)

2-nitropropane
79-46-9

2-nitropropane

C3H7NONi(P(C6H5)3)2
71928-74-0

C3H7NONi(P(C6H5)3)2

Conditions
ConditionsYield
In benzene Kinetics; byproducts: P(C6H5)3, OP(C6H5)3; the soln. of Ni(PPh3)4/benzene was added to the soln. of i-PrNO2/benzene with stirring at under Ar, stirred for 1 h; evapd. in vac., washed with hot hexane, dried in vac.;100%
2-nitropropane
79-46-9

2-nitropropane

(4-hydroxyphenyl)methanol
623-05-2

(4-hydroxyphenyl)methanol

1-nitro-1,1-dimethyl-2-(4-hydroxyphenyl]ethane
16066-97-0

1-nitro-1,1-dimethyl-2-(4-hydroxyphenyl]ethane

Conditions
ConditionsYield
With potassium tert-butylate In diethylene glycol dimethyl ether at 20 - 137℃; for 6h;99.6%
With potassium tert-butylate In diethylene glycol dimethyl ether Cooling with ice; Reflux;83%
With tetrabutyl ammonium fluoride at 130℃; for 15h;73%
3-(Dimethylaminomethyl)indole
87-52-5

3-(Dimethylaminomethyl)indole

2-nitropropane
79-46-9

2-nitropropane

3-(2,2-dimethyl-2-nitroethyl)-1H-indole
835-40-5

3-(2,2-dimethyl-2-nitroethyl)-1H-indole

Conditions
ConditionsYield
With tributylphosphine In acetonitrile for 4h; Heating;99.1%
With sodium hydroxide at 130℃;93%
With sodium hydroxide for 18h; Heating;70%
With sodium hydroxide for 18h; Reflux;
4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

2-nitropropane
79-46-9

2-nitropropane

4,4,5-trimethyl-5-nitro-2-hexanone
4538-83-4

4,4,5-trimethyl-5-nitro-2-hexanone

Conditions
ConditionsYield
With 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane In various solvent(s) at 20℃; for 0.33h; Michael addition;99%
With N,N',N''-tris(p-tolyl)azacalix[3](2,6)(4-pyrrolidinopyridine) for 12h; Inert atmosphere; Reflux;88%
With sodium In isopropyl alcohol for 336h; Reflux;13%
heptanal
111-71-7

heptanal

2-nitropropane
79-46-9

2-nitropropane

2-methyl-2-nitro-3-nonanol
80379-17-5

2-methyl-2-nitro-3-nonanol

Conditions
ConditionsYield
With P(i-PrNCH2CH2)3N; magnesium sulfate for 1.5h; Ambient temperature;99%
With tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine In tetrahydrofuran for 0.0833333h;91%
With Amberlyst A-21 for 7h;80%
With methanol; sodium hydroxide
2-nitropropane
79-46-9

2-nitropropane

methyl vinyl ketone
78-94-4

methyl vinyl ketone

5-methyl-5-nitrohexan-2-one
4604-49-3

5-methyl-5-nitrohexan-2-one

Conditions
ConditionsYield
With 2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 2,8,9-tris(1-methylethyl) In various solvent(s) at 20℃; for 0.25h; Michael addition;99%
With sodium methylate In methanol92%
With triethylamine at 20℃; for 5h; Michael reaction;82%
2-nitropropane
79-46-9

2-nitropropane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

methyl 2,4-dimethyl-4-nitro-pentanoate
5762-40-3

methyl 2,4-dimethyl-4-nitro-pentanoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Inert atmosphere; Large scale;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Large scale;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; for 22.66h; Inert atmosphere; Large scale;99%
2-nitropropane
79-46-9

2-nitropropane

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

4-Methyl-4-nitro-pentanoic acid butyl ester
91017-54-8

4-Methyl-4-nitro-pentanoic acid butyl ester

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h;99%
2-nitropropane
79-46-9

2-nitropropane

5-nitro-6-chloromethylimidazo<2,1-b>thiazole
139029-62-2

5-nitro-6-chloromethylimidazo<2,1-b>thiazole

5-nitro-6-isopropylidenemethylimidazo<2,1-b>thiazole
139029-63-3

5-nitro-6-isopropylidenemethylimidazo<2,1-b>thiazole

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In dichloromethane; water for 24h;99%
[Co(cp)(η-4-C5H5)]2(μ-O-exo)
158369-38-1

[Co(cp)(η-4-C5H5)]2(μ-O-exo)

2-nitropropane
79-46-9

2-nitropropane

[Co(cp)(η-4-C5H5)](CMe2NO2-exo)
158369-40-5

[Co(cp)(η-4-C5H5)](CMe2NO2-exo)

Conditions
ConditionsYield
In not given absence of oxygen and moisture; dissoln. of Co-complex in i-PrNO2 (stirring); volume reduction, crystn. on cooling to -20°C;99%
1-(2-furyl)-3-phenylpropen-1-one
3988-74-7, 42811-81-4, 69656-34-4

1-(2-furyl)-3-phenylpropen-1-one

2-nitropropane
79-46-9

2-nitropropane

(S)-1-(furan-2-yl)-4-methyl-4-nitro-3-phenylpentan-1-one
403706-60-5

(S)-1-(furan-2-yl)-4-methyl-4-nitro-3-phenylpentan-1-one

Conditions
ConditionsYield
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
2-nitropropane
79-46-9

2-nitropropane

benzalacetophenone
94-41-7

benzalacetophenone

3-(S)-4-methyl-4-nitro-1,3-diphenylpentan-1-one

3-(S)-4-methyl-4-nitro-1,3-diphenylpentan-1-one

Conditions
ConditionsYield
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 96h; Michael Addition; enantioselective reaction;76%
With 4-nitro-phenol; C15H23N3 In dichloromethane at 20℃; for 96h; Michael reaction; optical yield given as %ee; enantioselective reaction;62%
2-nitropropane
79-46-9

2-nitropropane

4'-chlorochalcone
956-02-5

4'-chlorochalcone

(S)-1-(4-chlorophenyl)-4-methyl-4-nitro-3-phenylpentan-1-one

(S)-1-(4-chlorophenyl)-4-methyl-4-nitro-3-phenylpentan-1-one

Conditions
ConditionsYield
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at -20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
2-nitropropane
79-46-9

2-nitropropane

4'-methoxychalcone
959-23-9

4'-methoxychalcone

(S)-1-(4-methoxyphenyl)-4-methyl-4-nitro-3-phenylpentan-1-one

(S)-1-(4-methoxyphenyl)-4-methyl-4-nitro-3-phenylpentan-1-one

Conditions
ConditionsYield
With 2Br(1-)*C90H68F24N2(2+); potassium carbonate In toluene at 0℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
4-(4-chlorophenyl)-3-buten-2-one
3160-40-5

4-(4-chlorophenyl)-3-buten-2-one

2-nitropropane
79-46-9

2-nitropropane

(S)-4-(4-chlorophenyl)-5-methyl-5-nitrohexan-2-one

(S)-4-(4-chlorophenyl)-5-methyl-5-nitrohexan-2-one

Conditions
ConditionsYield
With 4-nitro-phenol; C15H23N3 In dichloromethane at 20℃; for 24h; Michael reaction; optical yield given as %ee; enantioselective reaction;99%
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 48h; Michael Addition; enantioselective reaction;96%
2-nitropropane
79-46-9

2-nitropropane

1-Phenylbut-1-en-3-one
122-57-6

1-Phenylbut-1-en-3-one

(S)-5-methyl-5-nitro-4-phenylhexan-2-one

(S)-5-methyl-5-nitro-4-phenylhexan-2-one

Conditions
ConditionsYield
With 9-epi-9-amino-9-deoxyquinine; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; benzoic acid at 40℃; for 24h; Michael Addition; enantioselective reaction;99%
With C19H30N2; N-tert-butoxycarbonyl-L-phenylalanine In chloroform at 25℃; for 48h; Michael Addition; enantioselective reaction;96%
With C20H25N3O In tetrahydrofuran at 20℃; for 120h; Michael Addition; enantioselective reaction;49%
2-nitropropane
79-46-9

2-nitropropane

d8-methyl methacrylate
35233-69-3

d8-methyl methacrylate

methyl-d3 4-methyl-2-(methyl-d3)-4-nitropentanoate-3,3-d2

methyl-d3 4-methyl-2-(methyl-d3)-4-nitropentanoate-3,3-d2

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 40℃; for 16h; Inert atmosphere;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20 - 80℃; for 20h;99%
2-nitropropane
79-46-9

2-nitropropane

methyl 2-(4-chlorophenyl)acrylate
50415-59-3

methyl 2-(4-chlorophenyl)acrylate

methyl 2-(4-chlorophenyl)-4-methyl-4-nitropentanoate
1001123-94-9

methyl 2-(4-chlorophenyl)-4-methyl-4-nitropentanoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃;98.7%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃;98.66%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃;98.66%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃;98.66%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; for 12h; Michael condensation;
piperidine
110-89-4

piperidine

formaldehyd
50-00-0

formaldehyd

2-nitropropane
79-46-9

2-nitropropane

1,1-Dimethyl-1-nitro-2-piperidinoethan
17697-46-0

1,1-Dimethyl-1-nitro-2-piperidinoethan

Conditions
ConditionsYield
In water at 50℃; for 1h; Mannich reaction;98%
With sodium hydroxide at 50℃; for 2h; Cooling with ice;61%
With 1,4-dioxane; sodium hydroxide Anschliessendes Erwaermen.;
2-nitropropane
79-46-9

2-nitropropane

benzalacetophenone
94-41-7

benzalacetophenone

4-methyl-4-nitro-1,3-diphenylpentan-1-one
20894-11-5

4-methyl-4-nitro-1,3-diphenylpentan-1-one

Conditions
ConditionsYield
With potassium fluoride In ethanol at 20℃; for 4h; Addition;98%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 12h; Ambient temperature;95%
With methyl-4,6-O-benzylidene-2,3-dideoxy-α-D-glucopyranosido[2,3-h]-N-((3-(3-phenyl)thiocarbamido))propyl-1,4,7,10-tetraoxa-13-azacyclopentadecane; sodium t-butanolate In toluene at 20℃; Michael Addition; Inert atmosphere;10%
With methanol; sodium methylate
With sodium ethanolate In ethanol
2-nitropropane
79-46-9

2-nitropropane

(E)-benzalacetone
1896-62-4

(E)-benzalacetone

(+/-)-5-methyl-5-nitro-4-phenylhexan-2-one
20894-13-7

(+/-)-5-methyl-5-nitro-4-phenylhexan-2-one

Conditions
ConditionsYield
With 2-tert-butylimino-2-diethylamino-1,3-dimethylperhydro-1,3, 2-diazaphosphorine supported on polystyrene at 30℃; for 20h; Michael condensation;98%
With Rasta resin-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene at 60℃; for 30h; Michael addition reaction;90%
With potassium carbonate; 1-butyl-3-methylimidazolium Tetrafluoroborate at 30℃; for 10h; Michael reaction; ultrasonic irradiation;80%
2-nitropropane
79-46-9

2-nitropropane

Phenyl vinyl sulfoxide
20451-53-0

Phenyl vinyl sulfoxide

3-methyl-3-nitro-1-(phenylsulfinyl)-butane
61174-01-4

3-methyl-3-nitro-1-(phenylsulfinyl)-butane

Conditions
ConditionsYield
With potassium carbonate; N-benzyl-N,N,N-triethylammonium chloride at 20℃; for 1h;98%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 24h; Ambient temperature;95%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile Ambient temperature;95%
2-nitropropane
79-46-9

2-nitropropane

3-diazo-5-phenyl-3H-1,2,4-triazole
80670-36-6

3-diazo-5-phenyl-3H-1,2,4-triazole

A

benzonitrile
100-47-0

benzonitrile

B

acetone oxime
127-06-0

acetone oxime

Conditions
ConditionsYield
at 80℃; Yields of byproduct given;A n/a
B 98%
2-nitropropane
79-46-9

2-nitropropane

Methyl 2-acetamidoacrylate
35356-70-8

Methyl 2-acetamidoacrylate

methyl 2-acetylamino-4-methyl-4-nitropentanoate

methyl 2-acetylamino-4-methyl-4-nitropentanoate

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide In methanol for 0.0333333h; microwave irradiation;98%
With tetrabutyl ammonium fluoride In toluene for 66h; Ambient temperature; 1.) 10 min, 2.) 40-50 deg C, overnight;76%
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