CAS No.75-52-5,Nitromethane Suppliers,MSDS download

: 75-17-2
formaldoxime

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With dihydrogen peroxide; triethylamine In tert-butyl alcohol at 60℃; under 6000.6 Torr;	96.5%

: 77-78-1
dimethyl sulfate

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With sodium carbonate; sodium nitrite In water at 30℃; for 3h; Reagent/catalyst; Temperature;	84%
With sodium nitrite In water at 60℃;	75%
With water; sodium carbonate; sodium nitrite zuletzt bei 120grad;

: 75-76-3
tetramethylsilane

A: 75-52-5
nitromethane

B: 420-56-4
trimethylsilyl fluoride

Conditions

Conditions	Yield
With nitronium tetrafluoborate In sulfolane at 80℃; for 2h; Product distribution; Mechanism; other alkyl- and allylsilanes; other temperature, var. solvents;	A 80% B n/a

: 2009-83-8
6-chloro-1-hexanol

: 2483-57-0
methyl 2-nitroacetate

A: 75-52-5
nitromethane

B: 124-38-9
carbon dioxide

C: 6-chlorohexyl 2-nitroacetate

Conditions

Conditions	Yield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Sealed tube; Inert atmosphere;	A n/a B n/a C 76%

...Expand

: 111-87-5
octanol

: 2483-57-0
methyl 2-nitroacetate

A: 75-52-5
nitromethane

B: 124-38-9
carbon dioxide

C: octyl 2-nitroacetate

Conditions

Conditions	Yield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere;	A n/a B n/a C 69%

...Expand

: 74-88-4
methyl iodide

A: 75-52-5
nitromethane

B: 624-91-9
methyl nitrite

Conditions

Conditions	Yield
With tetrabutylammonium nitrite In chloroform-d1 at 20℃;	A 67% B 28 % Spectr.
With silver(I) nitrite
With silver nitrate

: 6032-29-7
(+/-)-2-pentanol

: 2483-57-0
methyl 2-nitroacetate

A: 75-52-5
nitromethane

B: 124-38-9
carbon dioxide

C: s-pentyl 2-nitroacetate

Conditions

Conditions	Yield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Sealed tube; Inert atmosphere;	A n/a B n/a C 66%

...Expand

: 2483-57-0
methyl 2-nitroacetate

: 107-18-6
allyl alcohol

A: 75-52-5
nitromethane

B: 124-38-9
carbon dioxide

C: 221116-46-7
allyl 2-nitroacetate

Conditions

Conditions	Yield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Sealed tube; Inert atmosphere;	A n/a B n/a C 66%

...Expand

: 64-17-5
ethanol

: 2483-57-0
methyl 2-nitroacetate

A: 626-35-7
nitroacetic acid ethyl ester

B: 75-52-5
nitromethane

C: 124-38-9
carbon dioxide

Conditions

Conditions	Yield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere;	A 61% B n/a C n/a

...Expand

: 66-27-3
Methyl methanesulfonate

A: 75-52-5
nitromethane

B: 624-91-9
methyl nitrite

Conditions

Conditions	Yield
With tetrabutylammonium nitrite In chloroform-d1 at 20℃;	A 60% B 29 % Spectr.

: 22755-24-4
sodium salt of nitromethane

A: 75-52-5
nitromethane

B: 1493-05-6
difluoro-nitro-methane

C: 21824-10-2
fluorotrinitromethane

Conditions

Conditions	Yield
With calcium fluoride; fluorine at -70 - -65℃;	A 24% B 20% C 45%

...Expand

: 420-37-1
trimethoxonium tetrafluoroborate

A: 75-52-5
nitromethane

B: 624-91-9
methyl nitrite

Conditions

Conditions	Yield
With tetrabutylammonium nitrite In chloroform-d1 at 20℃;	A 41% B 41 % Spectr.

: 333-27-7
methyl trifluoromethanesulfonate

A: 75-52-5
nitromethane

B: 624-91-9
methyl nitrite

Conditions

Conditions	Yield
With tetrabutylammonium nitrite In chloroform-d1 at 20℃;	A 38% B 56 % Spectr.

: sodium aci-nitroethane

A: 75-52-5
nitromethane

B: 1493-05-6
difluoro-nitro-methane

C: 17003-27-9
1-fluoro-1-nitro-ethane

Conditions

Conditions	Yield
With calcium fluoride; fluorine at -80 - -75℃;	A 24% B 20% C 23%

...Expand

: 67-56-1
methanol

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With Cu(MeNO2)2+ Thermodynamic data; free energie for exchange of both ligands;
With water; sodium hydrogencarbonate; iron(II) sulfate; sodium nitrite
With sulfuric acid; sodium nitrite

: 74-83-9
methyl bromide

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With sodium nitrite bei pH 6-10;

: 74-87-3
methylene chloride

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With sodium nitrite bei pH 6-10;

: 60-29-7
diethyl ether

A: 75-52-5
nitromethane

B: 31890-52-5
1-ethoxy-2-nitroethane

Conditions

Conditions	Yield
With nitric acid at 400℃; Nebenprod.2:Nitroaethan;

: 624-91-9
methyl nitrite

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With magnesium hydrosilicate at 120 - 130℃;

: 625-58-1
ethyl nitrate

A: 75-52-5
nitromethane

B: 624-91-9
methyl nitrite

C: 109-95-5
ethyl nitrite

Conditions

Conditions	Yield
at 160 - 219℃; Kinetics; unter vermindertem Druck.Pyrolysis;

...Expand

: 625-58-1
ethyl nitrate

A: 50-00-0
formaldehyd

B: 75-52-5
nitromethane

C: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
at 95℃; unter vermindertem Druck.Photolysis;

...Expand

: 34557-54-5
methane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
With nitric acid at 475℃;
With nitric acid
With oxygen; nitric acid

: 74-84-0
ethane

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

Conditions

Conditions	Yield
at 420℃; beim Nitrieren in der Dampfphase;

: 74-84-0
ethane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
bei der Nitrierung;

: 74-98-6
propane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
bei der Nitrierung;
With nitric acid
With oxygen; nitric acid
With nitric acid; acetic acid In water at 235℃; under 72402.6 Torr; for 0.05h;

: 75-28-5
Isobutane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
bei der Nitrierung;

: 78-78-4
methylbutane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
bei der Nitrierung;

: 79-29-8
2,3-dimethylbutane

: 75-52-5
nitromethane

Conditions

Conditions	Yield
bei der Nitrierung;

: 5447-98-3
2-methyl-1-nitro-2-propanol

A: 75-52-5
nitromethane

B: 67-64-1
acetone

Conditions

Conditions	Yield
With water at 130 - 150℃;
at 245.6℃; under 55 Torr; Kinetics; Further Variations:; Pressures; Temperatures; also in the presence of free radical inhibitors;

: 625-75-2
nitroacetic acid

A: 75-52-5
nitromethane

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

Conditions

Conditions	Yield
at 25℃; Geschwindigkeit in saurer Loesung bei verschiedenen pH und Einfluss von verschiedenen anorganischen und organischen Salzen;
at 15℃; Geschwindigkeit in saurer Loesung bei verschiedenen pH und Einfluss von verschiedenen anorganischen und organischen Salzen;
at 15℃; Geschwindigkeit in saurer Loesung bei verschiedenen pH und Einfluss von Glucose und Rohrzucker;

: 4397-53-9
p-benzyloxybenzaldehyde

: 75-52-5
nitromethane

: 2982-55-0
(E)-1-(benzyloxy)-4-(2-nitrovinyl)benzene

Conditions

Conditions	Yield
Stage #1: p-benzyloxybenzaldehyde; nitromethane With sodium methylate In methanol at 0 - 20℃; for 0.166667h; Stage #2: With hydrogenchloride; water In methanol at 0 - 20℃; for 0.25h;	100%
Stage #1: p-benzyloxybenzaldehyde; nitromethane With sodium methylate In methanol at 0 - 20℃; for 0.166667h; Stage #2: With hydrogenchloride In methanol; water at 0 - 20℃; for 0.25h;	100%
Stage #1: p-benzyloxybenzaldehyde; nitromethane With sodium methylate In methanol at 0 - 20℃; Stage #2: With hydrogenchloride In methanol; water at 0 - 20℃;	100%

: 75-52-5
nitromethane

: 623-43-8
crotonic acid methyl ester

: 16507-06-5
methyl 3-methyl-4-nitro-butyrate

Conditions

Conditions	Yield
With N,N,N',N'-tetramethylguanidine at 20℃; for 576h;	100%
With DBN In methanol at 60℃; for 6h; Inert atmosphere;	71.44%
With methanol; potassium carbonate
With N-benzyl-trimethylammonium hydroxide In methanol
With 1,8-diazabicyclo[5.4.0]undec-7-ene In methanol Michael addition;

: 75-52-5
nitromethane

: 124-13-0
Octanal

: 4013-87-0
2-hydroxy-1-nitrononane

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran; butan-1-ol at 23℃; Inert atmosphere;	100%
With silica gel; triethylamine at 20℃; for 3h; Henry Nitro Aldol Condensation;	95%
With potassium tert-butylate In tetrahydrofuran; tert-butyl alcohol at 20℃; for 18.5h; Henry reaction;	94%

: 75-52-5
nitromethane

: 5417-17-4
2-chloro-3,4-dimethoxybenzaldehyde

: 41122-35-4
(E)-2-chloro-3,4-dimethoxy-1-(2-nitrovinyl)benzene

Conditions

Conditions	Yield
With ammonium acetate; acetic acid for 4h; Inert atmosphere; Reflux;	100%
With ammonium acetate In acetic acid for 3h; Heating;	95%
With ammonium acetate; acetic acid

: 75-52-5
nitromethane

: 104-87-0
4-methyl-benzaldehyde

: 7559-36-6
4-methyl-β-nitrostyrene

Conditions

Conditions	Yield
With C62H54N2O2; copper diacetate In ethanol at 10℃; for 48h; Henry Nitro Aldol Condensation; enantioselective reaction;	100%
With C62H48CuN2O2; copper diacetate; benzaldehyde In ethanol at 10℃; for 48h; Reagent/catalyst; Henry Nitro Aldol Condensation;	100%
With (2-hydroxyethyl)ammonium formate at 20℃; for 0.8h; Knoevenagel condensation; Ionic liquid;	95%

: 75-52-5
nitromethane

: 104-88-1
4-chlorobenzaldehyde

: 706-07-0
1-chloro-4-(2-nitrovinyl)benzene

Conditions

Conditions	Yield
With copper(II) ferrite In dimethyl sulfoxide at 120℃; for 0.0333333h; Microwave irradiation;	100%
With bridged diamino-functionalized periodic mesoporous organosilicas with high nitrogen contents at 90℃; for 5h; Henry Nitro Aldol Condensation;	99%
With acetic acid; benzylamine at 78 - 80℃; for 3.5h; Product distribution / selectivity;	97.1%

: 75-52-5
nitromethane

: 104-88-1
4-chlorobenzaldehyde

: 89979-04-4
1-(4-chlorophenyl)-2-nitroethanol

Conditions

Conditions	Yield
With polymer supported 4-DMAP at 20℃; for 0.416667h; Reagent/catalyst; Henry Nitro Aldol Condensation;	100%
With triethylamine at 80℃; for 0.0166667h; Henry reaction; microwave irradiation;	99%
With Musca acuminata (banana) peel ash In neat (no solvent) at 20℃; for 0.333333h; Henry Nitro Aldol Condensation; Green chemistry;	98%

: 75-52-5
nitromethane

: 555-16-8
4-nitrobenzaldehdye

: 18731-47-0
1-(4-nitrophenyl)-2-nitroethanol

Conditions

Conditions	Yield
With C57H78N12; copper(II) acetate monohydrate In methanol; dichloromethane for 72h; Henry reaction; Inert atmosphere;	100%
With polymer supported 4-DMAP at 20℃; for 0.333333h; Reagent/catalyst; Henry Nitro Aldol Condensation;	100%
With P(i-PrNCH2CH2)3N; magnesium sulfate for 0.0833333h; Ambient temperature;	99%

: 75-52-5
nitromethane

: 100-52-7
benzaldehyde

: 141377-54-0, 145920-96-3, 149495-00-1, 15990-45-1
2-nitro-1-phenylethan-1-ol

Conditions

Conditions	Yield
palladium/alumina at 60℃; for 1h;	100%
With 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane hydroxide In neat (no solvent) at 20℃; for 0.166667h; Reagent/catalyst; Henry Nitro Aldol Condensation; Green chemistry;	99%
With 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane hydroxide In neat (no solvent) at 20℃; for 0.166667h; Catalytic behavior; Reagent/catalyst; Henry Nitro Aldol Condensation; Ionic liquid; Green chemistry;	99%

: 75-52-5
nitromethane

: 123-72-8
butyraldehyde

: 2224-37-5
1-nitropentan-2-ol

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water at 0℃; for 0.166667h; Addition; Henry reaction;	100%
With P(i-PrNCH2CH2)3N; magnesium sulfate for 0.666667h; Ambient temperature;	98%
With rac-1',2',3',4'-tetrahydro-1,1'-bisisoquinoline In tetrahydrofuran at 20℃; for 24h; Henry Nitro Aldol Condensation;	98%

: 75-52-5
nitromethane

: 66-25-1
hexanal

: 6302-74-5
1-nitroheptan-2-ol

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran; tert-butyl alcohol at 0 - 20℃; for 24h; Henry reaction;	100%
With potassium tert-butylate In tetrahydrofuran; tert-butyl alcohol Addition;	99%
With (S,S)-1,2-diaminocyclohexane; copper(II) acetate monohydrate In ethanol at 20℃; for 12h; Henry reaction; Inert atmosphere; enantioselective reaction;	99%

: 75-52-5
nitromethane

: 94-41-7
benzalacetophenone

: 6277-67-4
4-nitro-1,3-diphenyl-butan-1-one

Conditions

Conditions	Yield
With potassium carbonate In ethanol Michael condensation; Reflux;	100%
With alkaline hydroxide In ethanol at 60℃; for 12h; Michael addition;	100%
With potassium fluoride In ethanol at 20℃; for 2h; Addition;	98%

: 75-52-5
nitromethane

: 119-67-5
o-carboxybenzaldehyde

: 3598-68-3
3-(nitromethyl)-isobenzofuran-1-(3H)-one

Conditions

Conditions	Yield
With sodium hydroxide In methanol at 15 - 30℃; for 1h;	100%
With alkaline solution

: 75-52-5
nitromethane

: 2043-61-0
cyclohexanecarbaldehyde

: 141377-56-2, 141434-99-3, 149559-83-1, 50598-90-8
1-cyclohexyl-2-nitroethanol

Conditions

Conditions	Yield
tris(bis(trimethylsilyl)amido)samarium(III) In tetrahydrofuran for 25h; Ambient temperature;	100%
With potassium fluoride In isopropyl alcohol at 0 - 20℃; for 24h; Inert atmosphere;	100%
With calcium oxide at 50℃; for 12h;	99%

: 75-52-5
nitromethane

: 108-94-1
cyclohexanone

: 100-53-8
phenylmethanethiol

: 335458-24-7
1-benzylthio-1-nitromethylcyclohexane

Conditions

Conditions	Yield
With piperidine In benzene	100%
With piperidine In acetonitrile for 4h; Heating;	96%
With piperidine In acetonitrile for 4h; Heating / reflux;	22%
With piperidine In benzene Heating;

...Expand

: 75-52-5
nitromethane

: 120-92-3
cyclopentanone

: 100-53-8
phenylmethanethiol

: 335458-23-6
1-benzylthio-1-nitromethylcyclopentane

Conditions

Conditions	Yield
With piperidine In benzene	100%
With piperidine In acetonitrile for 4h; Heating;	94%
With piperidine In benzene Heating;

...Expand

: 104-53-0
3-phenyl-propionaldehyde

: 75-52-5
nitromethane

: 141377-53-9, 141434-97-1, 149494-99-5, 85290-51-3
1-nitro-4-phenylbutan-2-ol

Conditions

Conditions	Yield
(anthracenebisresorcinol(4-):2La(3+))polymer In benzene at 20℃; for 0.333333h; Addition; nitroaldol reaction;	100%
With potassium fluoride In isopropyl alcohol at 0 - 20℃; for 24h; Inert atmosphere;	100%
With silica gel; triethylamine at 20℃; for 2h; Catalytic behavior; Reagent/catalyst; Henry Nitro Aldol Condensation;	99%

: 75-52-5
nitromethane

: 133157-50-3
2-Formyl-2,3-dihydronaphtho<1,8-bc>pyran

: 133157-51-4
1-(1-Hydroxy-2-nitroethyl)-2,3-dihydronaphtho<1,8-bc>pyran

Conditions

Conditions	Yield
With triethylamine 1) 15 min, cooling 2) 2 h, r.t.;	100%

: 75-52-5
nitromethane

: 127181-13-9
(+)-(4S,5S,6R)-6-acetamido-N-(benzyloxycarbonyl)-4,5-(isopropylidenedioxy)-3-piperidinone

: 141781-97-7
(-)-(2R,3S,4S,5R)-2-acetamido-N-(benzyloxycarbonyl)-3,4-O-isopropylidene-5-(nitromethyl)-3,4,5-piperidinetriol

Conditions

Conditions	Yield
With sodium hydride In 1,2-dimethoxyethane for 2h; Ambient temperature;	100%

: 75-52-5
nitromethane

: 94-41-7
benzalacetophenone

A: 6277-67-4, 68047-61-0, 122348-60-1, 77670-36-1
(R)-1,3-diphenyl-4-nitrobutane-1-one

B: 6277-67-4, 77670-36-1, 122348-60-1, 68047-61-0
(S)-4-nitro-1,3-diphenylbutan-1-one

Conditions

Conditions	Yield
With (+)-quinidine-acrylonitrile copolymer In toluene under 661957 Torr; for 5h;	A n/a B 100%
With 1-[3,5-bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2-(dimethylamino)cyclohexyl]thiourea In toluene at 20℃; for 192h; Kinetics; Reagent/catalyst; Michael addition; enantioselective reaction;
Stage #1: nitromethane With (1R,1'R,2S,2'S)-1,1'-(propane-1,3-diyl)bis(2-((2,6-diisopropylphenyl)carbamoyl)pyrrolidine-1-oxide); ytterbium(III) triflate In tetrahydrofuran at 30℃; for 0.5h; Asymmetric Michael addition; Inert atmosphere; Stage #2: benzalacetophenone With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 30℃; for 48h; Asymmetric Michael addition; Inert atmosphere; optical yield given as %ee; enantioselective reaction;

...Expand

: 75-52-5
nitromethane

: 529-20-4
2-methylphenyl aldehyde

: 28638-59-7, 34222-71-4
methyl-2 β-nitrostyrene

Conditions

Conditions	Yield
ammonium acetate at 90℃; for 2h;	100%
With sodium hydroxide

: 75-52-5
nitromethane

: 100-53-8
phenylmethanethiol

: 67-64-1
acetone

: 105780-12-9
benzyl(2-methyl-1-nitropropan-2-yl)sulfane

Conditions

Conditions	Yield
With piperidine In benzene	100%
With piperidine In tetrahydrofuran for 12h; Heating;	96%
With piperidine for 15h; Heating;	49%
In benzene at 100℃; for 22h; Dean-Stark;	23%
With piperidine In benzene for 10h; Reflux; Inert atmosphere;

...Expand

: 75-52-5
nitromethane

: 122-57-6
1-Phenylbut-1-en-3-one

: 122348-55-4, 122348-59-8, 142232-08-4, 1574-86-3
5-nitro-4-phenylpentan-2-one

Conditions

Conditions	Yield
With hydrotalcite for 0.1h; Michael addition; Microwave irradiation;	100%
With potassium fluoride; 18-crown-6 ether In acetonitrile for 168h; Heating;	93%
With C10H20NaO5*HO(1-); water In methanol at 25℃; for 0.833333h; Michael addition;	90%

: 75-52-5
nitromethane

: 33985-40-9, 58056-24-9, 63029-10-7, 105368-48-7, 141610-28-8, 141724-46-1
1-O-methyl-2,3-O-isopropylidene-α-D-mannopentoaldo-1,4-furanose

: 85339-08-8, 85339-09-9, 118205-71-3, 118205-72-4, 124648-90-4, 129443-53-4
6-Deoxy-2,3-O-isopropylidene-6-nitro-α-D-lyxo-hexofuranoside

Conditions

Conditions	Yield
With sodium methylate In methanol at 0℃; for 2h;	100%
With sodium methylate In methanol at 0℃; for 2h;

: 75-52-5
nitromethane

: 60656-87-3
benzyloxyacetoaldehyde

: 169139-89-3
(+/-)-3-benzyloxy-1-nitropropan-2-ol

Conditions

Conditions	Yield
With potassium fluoride In isopropyl alcohol at 20℃; for 15h; Addition; Henry reaction;	100%
With aluminum oxide at 21℃; for 24h;	98%
With potassium hydroxide In methanol at 20℃; for 1.5h;	88%

: 75-52-5
nitromethane

: 201684-34-6
Toluene-4-sulfonic acid 5-bromo-3-formyl-1H-indol-7-yl ester

: 126260-59-1
(E)-5-bromo-3-nitrovinyl-7-(p-toluenesulfonyloxy)indole

Conditions

Conditions	Yield
With ammonium acetate for 3h; Heating;	100%

: 75-52-5
nitromethane

: 2700-22-3
Benzylidenemalononitrile

: 3-nitro-2-phenylpropane-1,1-dicarbonitrile

Conditions

Conditions	Yield
aluminum oxide at 90℃; for 0.15h;	100%
With piperazine-grafted reduced graphene oxide (rGO-NH) In ethanol at 60℃; for 8h; Reagent/catalyst; Michael Addition;	72%
With aluminum oxide at 20 - 90℃; for 0.2h; microwave irradiation;	63%
at 60℃; for 4h; Michael Addition;
With quinidine In toluene at 20℃;