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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Ethyl nitroacetate Manufacturer/High quality/Best price/In stock

Cas:626-35-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless,transparent liquid Complies Content% ≥99.90

Top purity Ethyl nitroacetate with high quality and best price cas:626-35-7

Cas:626-35-7

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethyl Nitroacetate

Cas:626-35-7

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Nitroacetic acid ethyl ester

Cas:626-35-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc.

Ethyl nitroacetate

Cas:626-35-7

Min.Order:1 Metric Ton

FOB Price: $0.6 / 1.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 626-35-7 with best price

Cas:626-35-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Acetic acid, nitro-, ethyl ester CAS No.: 626-35-7 Formula: C4H7NO4 Molecular Weight:

Ethyl nitroacetate

Cas:626-35-7

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Acetic acid, nitro-, ethyl ester 626-35-7

Cas:626-35-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Ethyl nitroacetate with competitive price CAS:626-35-7

Cas:626-35-7

Min.Order:1 Kilogram

FOB Price: $210.0 / 260.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:626-35-7

Cas:626-35-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1708.html Product Name Ethyl nitroacetate CAS No. 626-35-7

Ethyl nitroacetate

Cas:626-35-7

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

Ethyl nitroacetate CAS 626-35-7

Cas:626-35-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Tianjin Kind Pharma Co., Ltd.

Factory direct sales, accept customization. Ethyl Nitroacetate is an ester of nitrocarboxylic acid used as an intermediate in the preparation of unsubstituted amino acids. Kind Pharma has its own laboratory, we can do analytical testing for API (Ac

Ethyl Nitroacetate

Cas:626-35-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

ETHYL NITROACETATE

Cas:626-35-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

626-35-7

Cas:626-35-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Ethyl nitroacetate

Cas:626-35-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Ethylnitroacetate

Cas:626-35-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Ethyl nitroacetate Chemical Properties Boiling point 105-107 °C/25 mmHg (lit.) density 1.199 g/mL at 25 °C (lit.) refractive index n20/D 1.424(lit.) Fp 198 °F storage temp. Keep Cold pka pK1:5.85 (25°C) form

Ethyl nitroacetate

Cas:626-35-7

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Ethyl Nitroacetate cas no. 626-35-7 98%

Cas:626-35-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

Name: Ethyl nitroacetate CAS: 626-35-7 Molecular Formula: C4H7NO4 Molecular Weight: 133.103 Application:Fine chemical

Ethyl nitroacetate CAS 626-35-7

Cas:626-35-7

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Ethyl nitroacetate 25g

Cas:626-35-7

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Ethyl Nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Ethyl nitroacetate

Cas:626-35-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

propylamine
107-10-8

propylamine

diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-propylamino-3-oxopropanoate
71510-96-8

ethyl 3-propylamino-3-oxopropanoate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B 100%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-((4-methoxyphenyl)amino)-3-oxopropanoate
5382-15-0

ethyl 3-((4-methoxyphenyl)amino)-3-oxopropanoate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B 100%
methanol
67-56-1

methanol

diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl methyl malonate
6186-89-6

ethyl methyl malonate

Conditions
ConditionsYield
In chloroform at 60℃; for 24h;A n/a
B 99%
ethyl 2-nitro-3-oxobutyrate
51026-98-3

ethyl 2-nitro-3-oxobutyrate

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With sulfuric acid In methanol for 1h;97%
In ethanol at 15 - 25℃; for 10h;
ethyl chloronitroacetate
14011-27-9

ethyl chloronitroacetate

triphenylphosphine
603-35-0

triphenylphosphine

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
In methanol; benzene at 20℃; for 12h;A 71.5%
B 96%
ethanol
64-17-5

ethanol

nitroacetic acid
625-75-2

nitroacetic acid

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In tetrahydrofuran at 0℃;90%
With dicyclohexyl-carbodiimide In tetrahydrofuran at 0 - 20℃; for 24h; Inert atmosphere; Sonication;17%
With sulfuric acid
With sulfuric acid at -15 - 3℃;
With hydrogenchloride
ethyl cyanoformate
623-49-4

ethyl cyanoformate

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With acetic acid In nitromethane; dimethyl sulfoxide83%
With potassium hydroxide; nitrogen In nitromethane; dimethyl sulfoxide68%
With N2 In tetrahydrofuran; nitromethane
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

1-amino-2-propene
107-11-9

1-amino-2-propene

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-(allylamino)-3-oxopropanoate
118081-79-1

ethyl 3-(allylamino)-3-oxopropanoate

Conditions
ConditionsYield
In chloroform at 20℃; for 24h;A n/a
B 80%
ethyl-2-azidoacetate
637-81-0

ethyl-2-azidoacetate

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With HOF* CH3CN In chloroform at 0℃;75%
ethyl chloronitroacetate
14011-27-9

ethyl chloronitroacetate

propionaldehyde
123-38-6

propionaldehyde

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl α-chloro-α-nitro-β-hydroxyvalerate
84115-12-8

ethyl α-chloro-α-nitro-β-hydroxyvalerate

Conditions
ConditionsYield
With zinc; iodine In diethyl ether for 25h; Heating; reaction with other aliphatic carbonyl compounds;A n/a
B 72%
With zinc; iodine In diethyl ether 1) 5 h, reflux, 2) 20 h, r.t.;A n/a
B 72%
N-ethylethane-1,2-diamine
110-72-5

N-ethylethane-1,2-diamine

diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-[2-(ethylamino)ethylamino]-3-oxopropanoate

ethyl 3-[2-(ethylamino)ethylamino]-3-oxopropanoate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h; chemoselective reaction;A n/a
B 72%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

1,2-diaminopropan
78-90-0, 10424-38-1

1,2-diaminopropan

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-[(2-amino-2-methyl)ethylamino]-3-oxopropanoate

ethyl 3-[(2-amino-2-methyl)ethylamino]-3-oxopropanoate

Conditions
ConditionsYield
In chloroform at 20℃; for 24h; chemoselective reaction;A n/a
B 70%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

diethyl 1,2,5-oxadiazole-3,4-dicarboxylate 2-oxide
18417-40-8

diethyl 1,2,5-oxadiazole-3,4-dicarboxylate 2-oxide

Conditions
ConditionsYield
Stage #1: ethyl acetoacetate With sulfuric acid; nitric acid In dichloromethane at -5 - -3℃; Flow reactor;
Stage #2: With ethanol at 30℃; Flow reactor;
A 70%
B 22 %Spectr.
morpholine
110-91-8

morpholine

diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

3-(4-Morpholinyl)-3-oxopropansaeure-ethylester
37714-64-0

3-(4-Morpholinyl)-3-oxopropansaeure-ethylester

Conditions
ConditionsYield
In chloroform at 20℃; for 24h;A n/a
B 68%
ethyl bromoacetate
105-36-2

ethyl bromoacetate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 2-hydroxyacetate
623-50-7

ethyl 2-hydroxyacetate

Conditions
ConditionsYield
With Amberlite IRA 900 NO2- form In acetonitrile at -15℃;A 65%
B 28%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

isopropylamine
75-31-0

isopropylamine

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-isopropylamino-3-oxopropanoate
71510-97-9

ethyl 3-isopropylamino-3-oxopropanoate

Conditions
ConditionsYield
In dichloromethane at 40℃; for 24h;A n/a
B 62%
ethanol
64-17-5

ethanol

methyl 2-nitroacetate
2483-57-0

methyl 2-nitroacetate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

nitromethane
75-52-5

nitromethane

C

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
With di(n-butyl)tin oxide at 100℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere;A 61%
B n/a
C n/a
2-(N,N-dimethylamino)ethanol
108-01-0

2-(N,N-dimethylamino)ethanol

diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-(2-dimethylaminoethoxy)-3-oxo-propanoate
1010190-08-5

ethyl 3-(2-dimethylaminoethoxy)-3-oxo-propanoate

Conditions
ConditionsYield
In chloroform at 20℃;A n/a
B 60%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

isopropyl alcohol
67-63-0

isopropyl alcohol

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-isopropoxy-3-oxopropanoate
50780-97-7

ethyl 3-isopropoxy-3-oxopropanoate

Conditions
ConditionsYield
at 65℃; for 24h;A n/a
B 59%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

4-nitro-aniline
100-01-6

4-nitro-aniline

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-((4-nitrophenyl)amino)-3-oxopropanoate
10390-08-6

ethyl 3-((4-nitrophenyl)amino)-3-oxopropanoate

Conditions
ConditionsYield
In chloroform at 60℃; for 24h;A n/a
B 55%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

diethylamine
109-89-7

diethylamine

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-(diethylamino)-3-oxopropanoate
33567-70-3

ethyl 3-(diethylamino)-3-oxopropanoate

Conditions
ConditionsYield
In chloroform at 60℃; for 48h;A n/a
B 50%
ethyl chloronitroacetate
14011-27-9

ethyl chloronitroacetate

acetaldehyde
75-07-0

acetaldehyde

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl α-chloro-α-nitro-β-hydroxybutyrate
84115-11-7

ethyl α-chloro-α-nitro-β-hydroxybutyrate

Conditions
ConditionsYield
With zinc; iodine In diethyl ether 1) 5 h, reflux, 2) 1 h, r.t.;A n/a
B 47%
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

aniline
62-53-3

aniline

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-oxo-3-(phenylamino)propionate
53341-66-5

ethyl 3-oxo-3-(phenylamino)propionate

Conditions
ConditionsYield
In dichloromethane at 40℃; for 24h;A n/a
B 45%
4-nitro-5-methylisoxazole
1122-06-1

4-nitro-5-methylisoxazole

ethanol
64-17-5

ethanol

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
for 4h; Heating;A 44%
B n/a
diethyl 2-nitro-3-oxopentanedioate
1010117-23-3

diethyl 2-nitro-3-oxopentanedioate

tert-butylamine
75-64-9

tert-butylamine

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

ethyl 3-(tert-butylamino)-3-oxopropanoate
17797-87-4

ethyl 3-(tert-butylamino)-3-oxopropanoate

Conditions
ConditionsYield
In dichloromethane at 40℃; for 24h;A n/a
B 41%
ethyl chloronitroacetate
14011-27-9

ethyl chloronitroacetate

A

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

B

nitrosulfoacetic acid ethyl ester sodium salt
113689-77-3

nitrosulfoacetic acid ethyl ester sodium salt

Conditions
ConditionsYield
With sodium metabisulfite In ethanol for 0.25h; Heating;A 33%
B 29%
chloroacetic acid ethyl ester
105-39-5

chloroacetic acid ethyl ester

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With poly(vinylbenzyltriphenylphosphonium nitrite) In benzene for 24h; Ambient temperature;33%
With poly(vinylbenzyltriphenylphosphonium)*NO2(-) In benzene for 24h; Ambient temperature;33%
diethyl nitromalonate
603-67-8

diethyl nitromalonate

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Conditions
ConditionsYield
With potassium hydroxide Neutralisieren mit Salzsaeure;
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

1,3-diphenyl-propen-3-one
614-47-1

1,3-diphenyl-propen-3-one

2-nitro-5-oxo-3,5-diphenylpentanoic acid ethyl ester
24424-11-1

2-nitro-5-oxo-3,5-diphenylpentanoic acid ethyl ester

Conditions
ConditionsYield
With (S)-1-(3,5-bis(trifluoromethyl)phenyl)-3-(1-(dimethylamino)-3-methylbutan-2-yl)thiourea at 50℃; for 6h; Michael addition; neat (no solvent); optical yield given as %de;100%
With diethylamine In ethanol for 18h; Heating;87%
With sodium hydroxide; poly-L-alanine In water; toluene for 744h; Ambient temperature; the addition of ethyl nitroacetate to the chalcone in presence stereoselective catalyst;60 % Chromat.
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

benzaldehyde
100-52-7

benzaldehyde

ethyl α-nitrocinnamate
18315-80-5, 18315-86-1, 16508-09-1

ethyl α-nitrocinnamate

Conditions
ConditionsYield
With [(S)-6-((hexahydropyrrolo[1,2-a]pyrazin-2(1H)-yl)methyl)picolinaldehyde]functionalized Rh-[Zr6(μ3-O)4(μ3-OH)4(1,4-benzenedicarboxylate)6]-NH2 In toluene at 100℃; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Knoevenagel Condensation;100%
With zirconium(IV) chloride; triethylamine In tetrahydrofuran at 0℃; Reflux; Inert atmosphere; Molecular sieve;83%
With pyridine; titanium tetrachloride
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

Carbonic acid 2-ethoxy-allyl ester ethyl ester

Carbonic acid 2-ethoxy-allyl ester ethyl ester

4-Ethoxy-2-nitro-pent-4-enoic acid ethyl ester

4-Ethoxy-2-nitro-pent-4-enoic acid ethyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 45℃; for 24h;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(2R,3S,4S,5R)-1,6-dicyclohexyl-2,5-di-O-(methanesulfonyl)-2,3,4,5-hexanetetraol
216855-05-9

(2R,3S,4S,5R)-1,6-dicyclohexyl-2,5-di-O-(methanesulfonyl)-2,3,4,5-hexanetetraol

(4RS,5S)-5-cyclohexylmethyl-3-ethoxycarbonyl-4-hydroxy-2-isoxazoline 2-oxide
216855-31-1

(4RS,5S)-5-cyclohexylmethyl-3-ethoxycarbonyl-4-hydroxy-2-isoxazoline 2-oxide

Conditions
ConditionsYield
With 1H-imidazole; sodium periodate In ethanol; water at 20℃; Oxidation; Henry reaction;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

3-diethylamino-1-phenyl-propan-1-one
94-38-2

3-diethylamino-1-phenyl-propan-1-one

ethyl 2-nitro-5-oxo-5-phenylpentanoate
91958-55-3

ethyl 2-nitro-5-oxo-5-phenylpentanoate

Conditions
ConditionsYield
In toluene Condensation; Heating;100%
In toluene Heating;98%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

phenylacetylene
536-74-3

phenylacetylene

ethyl 5-phenylisoxazole-3-carboxylate
7063-99-2

ethyl 5-phenylisoxazole-3-carboxylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform at 60℃; for 40h;100%
With dmap; 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride In acetonitrile at 80℃; for 0.05h; microwave irradiation;99%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen In water at 60℃; for 4h; Reagent/catalyst; Temperature; Green chemistry;96%
norborn-2-ene
498-66-8

norborn-2-ene

nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

ethyl 3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-ene-5-carboxylate

ethyl 3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-ene-5-carboxylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform at 60℃;100%
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform at 60℃; for 40h;100%
With triethylamine; copper diacetate In chloroform at 60℃; for 20h;
With 1,4-diaza-bicyclo[2.2.2]octane In water at 60℃; for 66h;95 %Spectr.
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

norbornene
498-66-8

norbornene

3-oxa-4-aza-tricyclo[5.2.1.02,6]dec-4-ene-5-carboxylic acid ethyl ester

3-oxa-4-aza-tricyclo[5.2.1.02,6]dec-4-ene-5-carboxylic acid ethyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform at 60℃; for 40h;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

propargyl alcohol
107-19-7

propargyl alcohol

ethyl 5-(hydroxymethyl)isoxazole-3-carboxylate
123770-62-7

ethyl 5-(hydroxymethyl)isoxazole-3-carboxylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol at 80℃; for 20h;100%
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol; chloroform at 80℃; for 72h;98%
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol at 80℃; for 72h;97%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

(Z)-3-dimethylamino-2-nitroacrylic acid ethyl ester
64273-40-1

(Z)-3-dimethylamino-2-nitroacrylic acid ethyl ester

Conditions
ConditionsYield
at 20 - 100℃; for 3.5h;100%
at 20 - 90℃; for 2.25h; Inert atmosphere;
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

N,N-Dimethylacrylamide
2680-03-7

N,N-Dimethylacrylamide

ethyl 5-[(dimethylamino)carbonyl]-4,5-dihydro-isoxazole-3-carboxylate
1184832-29-8

ethyl 5-[(dimethylamino)carbonyl]-4,5-dihydro-isoxazole-3-carboxylate

Conditions
ConditionsYield
With N-methylcyclohexylamine; copper diacetate In chloroform at 60℃; for 20h;100%
With sodium hydroxide In water at 60℃; for 20h;72%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

ethyl 3-(4-fluorophenyl)-2-nitroprop-2-enoate
61924-52-5

ethyl 3-(4-fluorophenyl)-2-nitroprop-2-enoate

Conditions
ConditionsYield
With [Zr6(μ3-O)4(μ3-OH)4(4,4'-biphenyldicarboxylate)6]-NH2 In toluene at 100℃; for 24h; Knoevenagel Condensation;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

heptanal
111-71-7

heptanal

C11H19NO4

C11H19NO4

Conditions
ConditionsYield
With [Zr6(μ3-O)4(μ3-OH)4(1,4-benzenedicarboxylate)6][(S)-6-((hexahydropyrrolo[1,2-a]pyrazin-2(1H)-yl)methyl)picolinaldehyde]-NH2 In toluene at 100℃; for 24h; Reagent/catalyst; Knoevenagel Condensation;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

4-bromo-2-(ethylamino)-3-methyl-benzoic acid

4-bromo-2-(ethylamino)-3-methyl-benzoic acid

7-bromo-1-ethyl-4-hydroxy-8-methyl-3-nitro-quinolin-2-one

7-bromo-1-ethyl-4-hydroxy-8-methyl-3-nitro-quinolin-2-one

Conditions
ConditionsYield
Stage #1: 4-bromo-2-(ethylamino)-3-methyl-benzoic acid With bis(trichloromethyl) carbonate In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;
Stage #2: nitroacetic acid ethyl ester With triethylamine In tetrahydrofuran at 60℃; Inert atmosphere;
100%
Stage #1: 4-bromo-2-(ethylamino)-3-methyl-benzoic acid With bis(trichloromethyl) carbonate In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;
Stage #2: nitroacetic acid ethyl ester With triethylamine In tetrahydrofuran at 60℃; Inert atmosphere;
100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

3-methyl-4-nitro-5-(4-chlorostyryl)isoxazole
51978-97-3, 53557-97-4

3-methyl-4-nitro-5-(4-chlorostyryl)isoxazole

C16H16ClN3O7

C16H16ClN3O7

Conditions
ConditionsYield
With triethylamine In neat (no solvent) at 20℃; Reagent/catalyst; Michael Addition;100%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

3-<(dimethylamino)methyl>-4-(trimethylsilyl)indole
92012-94-7

3-<(dimethylamino)methyl>-4-(trimethylsilyl)indole

ethyl 2-nitro-3-<4-(trimethylsilyl)indol-3-yl>propanoate
92012-96-9

ethyl 2-nitro-3-<4-(trimethylsilyl)indol-3-yl>propanoate

Conditions
ConditionsYield
In acetonitrile Heating;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

4-bromo-hex-4-en-3-one
811470-76-5

4-bromo-hex-4-en-3-one

(4,5-trans)-3-(ethoxycarbonyl)-4-methyl-5-propanoyl-2-isoxazoline 2-oxide

(4,5-trans)-3-(ethoxycarbonyl)-4-methyl-5-propanoyl-2-isoxazoline 2-oxide

Conditions
ConditionsYield
With triethylamine In diethyl ether for 36h;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(E)-1,1,1-trifluoro-4-phenyl-3-buten-2-one
3108-32-5, 86571-25-7

(E)-1,1,1-trifluoro-4-phenyl-3-buten-2-one

1,1,1-trifluoro-5-nitro-4-phenyl-pentan-2-one

1,1,1-trifluoro-5-nitro-4-phenyl-pentan-2-one

Conditions
ConditionsYield
With potassium fluoride In ethanol; water99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(E)-1,1,1-trifluoro-4-phenyl-3-buten-2-one
3108-32-5, 86571-25-7

(E)-1,1,1-trifluoro-4-phenyl-3-buten-2-one

ethyl 6,6,6-trifluoro-2-nitro-5-oxo-3-phenylhexanoate

ethyl 6,6,6-trifluoro-2-nitro-5-oxo-3-phenylhexanoate

Conditions
ConditionsYield
With potassium fluoride In ethanol at 20℃; for 2h;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(E)-1,1,1,-trifluoro-4-(thophen-2-yl)but-3-en-2-one
209967-65-7

(E)-1,1,1,-trifluoro-4-(thophen-2-yl)but-3-en-2-one

1,1,1-trifluoro-5-nitro-4-(2-thienyl)pentan-2-one

1,1,1-trifluoro-5-nitro-4-(2-thienyl)pentan-2-one

Conditions
ConditionsYield
With potassium fluoride In ethanol; water99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(E)-1,1,1-trifluoro-4-(3-methoxyphenyl)but-3-en-2-one
204708-11-2

(E)-1,1,1-trifluoro-4-(3-methoxyphenyl)but-3-en-2-one

1,1,1-trifluoro-4-(3-methoxyphenyl)-5-nitropentan-2-one

1,1,1-trifluoro-4-(3-methoxyphenyl)-5-nitropentan-2-one

Conditions
ConditionsYield
With potassium fluoride In ethanol; water99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

6-methoxy 7-methyl benzo[d][1,3]dioxole-5-carbaldehyde
187040-23-9

6-methoxy 7-methyl benzo[d][1,3]dioxole-5-carbaldehyde

C14H15NO7
1003600-22-3

C14H15NO7

Conditions
ConditionsYield
With titanium tetrachloride; N-ethyl-N,N-diisopropylamine In tetrahydrofuran Knoevenagel condensation;99%
Stage #1: 6-methoxy 7-methyl benzo[d][1,3]dioxole-5-carbaldehyde With titanium tetrachloride In tetrahydrofuran at -5 - 20℃; Knoevenagel condensation;
Stage #2: nitroacetic acid ethyl ester With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at -5 - 20℃; Knoevenagel condensation;
99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(Z)-2-benzoyl-3-phenylacrylic acid ethyl ester
17451-18-2, 39626-31-8, 125105-17-1

(Z)-2-benzoyl-3-phenylacrylic acid ethyl ester

trans-3,5-diphenyl-2,3-dihydrofuran-2,4-dicarboxylic acid diethyl ester

trans-3,5-diphenyl-2,3-dihydrofuran-2,4-dicarboxylic acid diethyl ester

Conditions
ConditionsYield
With triethylamine In acetonitrile at 60℃; for 4h;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

norbornene
498-66-8

norbornene

3-oxa-4-aza-tricyclo[5.2.1.0(2,6)]dec-4-ene-5-carboxylic acid ethyl ester

3-oxa-4-aza-tricyclo[5.2.1.0(2,6)]dec-4-ene-5-carboxylic acid ethyl ester

Conditions
ConditionsYield
With N-methylcyclohexylamine; copper diacetate In chloroform at 60℃; for 20h; sealed tube;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

(E)-diphenyl-β-(trifluoromethyl)vinylsulfonium trifluoromethanesulfonate
1226574-99-7

(E)-diphenyl-β-(trifluoromethyl)vinylsulfonium trifluoromethanesulfonate

C7H8F3NO4
1330063-02-9

C7H8F3NO4

Conditions
ConditionsYield
Stage #1: nitroacetic acid ethyl ester With 1,8-diazabicyclo[5.4.0]undec-7-ene In dimethyl sulfoxide at 27℃; for 0.166667h; Inert atmosphere;
Stage #2: (E)-diphenyl-β-(trifluoromethyl)vinylsulfonium trifluoromethanesulfonate In dimethyl sulfoxide at 27℃; Inert atmosphere;
99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

hex-5-enenitrile
5048-19-1

hex-5-enenitrile

C10H14N2O3
1374526-16-5

C10H14N2O3

Conditions
ConditionsYield
With sodium hydroxide In water at 60℃; for 16h;99%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

i-propyl 2-oxo-4-phenylbut-3-enoate
111160-44-2

i-propyl 2-oxo-4-phenylbut-3-enoate

(3R)-1-ethyl 6-isopropyl 2-nitro-5-oxo-3-phenylhexanedioate

(3R)-1-ethyl 6-isopropyl 2-nitro-5-oxo-3-phenylhexanedioate

Conditions
ConditionsYield
Stage #1: nitroacetic acid ethyl ester With BF4*C8H12CuN4(1+); (S)-2-((2-(hydroxydi-p-tolylmethyl)pyrrolidin-1-yl)methyl)-6-(trifluoromethyl)phenol; lithium carbonate In toluene at 0℃; for 1h; Michael Addition; Inert atmosphere;
Stage #2: i-propyl 2-oxo-4-phenylbut-3-enoate In toluene at 0℃; Catalytic behavior; Reagent/catalyst; Temperature; Time; Michael Addition; Inert atmosphere; enantioselective reaction;
99%

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