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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Heptyne supplier in China

Cas:628-71-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hept-1-yne

Cas:628-71-7

Min.Order:1

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1-Heptyne

Cas:628-71-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Heptyne

Cas:628-71-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 1-Heptyne Synonyms: Amylacetylene;hept-1-yne;n-C5H11CequivCH;N-AMYLACETYLENE;1-HEPTYNE;HEPTYNE(1-);1-Heptyne99%;1-Heptyne 99% CAS: 628-71-7 MF: C7H12 MW: 96.17 EINECS: 211-051-5 Product Categ

628-71-7 1-Heptyne

Cas:628-71-7

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:628-71-7

Cas:628-71-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Heptyne

Cas:628-71-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Name: 1-Heptyne. Synonym:Amylacetylene;1-HEPTYNE,98%1-HEPTYNE,98%1-HEPTYNE,98%1-HEPTYNE,98%;hept-1-yne;n-C5H11CequivCH;N-AMYLACETYLENE;1-HEPTYNE;1-heptanone;n-pentylacetylene CAS No.: 628-71-7. Molecular formula: C7H12. Molecular weight: 96

1-Heptyne

Cas:628-71-7

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

hept-1-yne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 628-71-7 with competitive price

Cas:628-71-7

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Other

inquiry

SAGECHEM LIMITED

628-71-7 Application:intermediate

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1-HEPTYNE 628-71-7

Cas:628-71-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HWRK Chem

in store Package:50g Application:Organic Chemicals

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Yurui(Shanghai)Chemical Co.,Ltd

How May We Serve You We can Supply HPLC\HMMR\MS report for you ,pls feel free to contact us! Capability on chemical synthesis ● Shanghai High-Tech Enterprises ● Strong R&D Team from USA, Japan, Korea ● 65000M2+ Factory, 300+ reac

1-Heptyne

Cas:628-71-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#628-71-7;CAT#A834053

Cas:628-71-7

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Zouping Mingxing Chemical Co.,Ltd.

Melting point - 81 ° C The boiling point of 99-100 ° C (lit.) Density of 0.733 g/mL at 25 ° C (lit.) 93.1 mm Hg vapour pressure (37.7 ° C) Refractive index n20/D 1.408(lit.) Flash point 28 ° F Storage conditions Li

1-Heptyne

Cas:628-71-7

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

HENAN SUNLAKE ENTERPRISE CORPORATION Our company advantages: 1、The highest quality with the competitive price. 2、Professional human services. 3、The fastest and safest delivery service. 4、The faster and safest delivery service. 5、The hig

1-Heptyne

Cas:628-71-7

Min.Order:1 Liter

Negotiable

Type:Trading Company

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

National Research Platform ISO 9001 628-71-7

Cas:628-71-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

hept-1-yne

Cas:628-71-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Sigma Chemical Co., Ltd.

Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

High Quality 1-Heptyne

Cas:628-71-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

Hot Sale 1-Heptyne

Cas:628-71-7

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Shanghai Life Bio-Tech Co., LTD.

Our company is composed of skilled technicians and practiced sales team. We closely cooperate and communicate with East China University of Science and Technology, China Pharmaceutical University and other universities.Our company owns perfect experi

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1-Heptyne

Cas:628-71-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

1-Heptyne

Cas:628-71-7

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

oct-2-ynoic acid
5663-96-7

oct-2-ynoic acid

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0)100%
1,2-dibromoheptane
42474-21-5

1,2-dibromoheptane

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 60℃; for 2h;98%
With tetrabutyl-ammonium chloride; potassium hydroxide In water at 140℃; for 4h;86.4%
With potassium hydroxide; 2,5-dimethyl-2,5-hexanediol; tetraoctyl ammonium bromide at 80 - 90℃; for 0.25h;85%
With potassium hydroxide; mineral oil at 250℃;
With tetralin; anion-exchanger at 160℃;
1,2-Heptadiene
2384-90-9

1,2-Heptadiene

A

1-Heptyne
628-71-7

1-Heptyne

B

hept-2-yne
1119-65-9

hept-2-yne

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate at 70℃; for 2h;A 2%
B 93%
1,2-dichloro-heptane
10575-87-8

1,2-dichloro-heptane

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 80℃; for 8h;86%
With potassium hydroxide; mineral oil at 250℃;
1-Bromopentane
110-53-2

1-Bromopentane

acetylene
74-86-2

acetylene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia; sodium at -40 - 20℃;80%
1-(benzotriazol-1-yl)-2-heptanone p-tosylhydrazone
189343-56-4

1-(benzotriazol-1-yl)-2-heptanone p-tosylhydrazone

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With n-butyllithium In diethyl ether 1) -78 deg C, 0.5 h; 2) rt, 48 h;73%
heptanal
111-71-7

heptanal

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With Nonafluorobutanesulfonyl fluoride; tert-butylimino-tri(pyrrolidino)phosphorane In N,N-dimethyl-formamide at -10 - 20℃;66%
With phosphorus pentachloride
Multi-step reaction with 2 steps
1: PCl5
2: alcoholic potash / 150 °C
View Scheme
1-heptynyl chloride
51556-10-6

1-heptynyl chloride

butyl magnesium bromide
693-04-9

butyl magnesium bromide

A

1-Heptyne
628-71-7

1-Heptyne

B

tetradeca-6,8-diyne
16387-72-7

tetradeca-6,8-diyne

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; copper dichloride In tetrahydrofuran at 0℃; for 1.25h; Inert atmosphere;A 55%
B 35%
chloroacetic acid
79-11-8

chloroacetic acid

(Z)-1-methylthio-2-triphenylstannylhept-1-ene
351500-79-3

(Z)-1-methylthio-2-triphenylstannylhept-1-ene

A

methylthiol
74-93-1

methylthiol

B

diphenyltin di(monochloroacetate)
30250-06-7

diphenyltin di(monochloroacetate)

C

1-Heptyne
628-71-7

1-Heptyne

D

benzene
71-43-2

benzene

Conditions
ConditionsYield
In not givenA 0%
B 30%
C 5%
D n/a
1-Chloropentane
543-59-9

1-Chloropentane

1-Bromopentane
110-53-2

1-Bromopentane

sodium acetylide
1066-26-8

sodium acetylide

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia
1-Chloropentane
543-59-9

1-Chloropentane

sodium acetylide
1066-26-8

sodium acetylide

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia
1,1-dichloroheptane
821-25-0

1,1-dichloroheptane

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With potassium carbonate at 150℃;
With potassium hydroxide; mineral oil at 250℃;
With soda lime at 420℃; Zersetzen der erhaltenen Produkte mit Wasser;
4-chloro-hept-3-ene
2431-24-5

4-chloro-hept-3-ene

A

hept-3-yne
2586-89-2

hept-3-yne

B

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With sodium amide; xylene at 130℃;
With 1,2,4-Trimethylbenzene; sodium amide at 140℃;
sulfuric acid dibutyl ester
625-22-9

sulfuric acid dibutyl ester

propargyl magnesium bromide
18295-60-8

propargyl magnesium bromide

A

1-Heptyne
628-71-7

1-Heptyne

B

1,2-Heptadiene
2384-90-9

1,2-Heptadiene

(E)/(Z)-1-bromo-1-heptene
89942-12-1

(E)/(Z)-1-bromo-1-heptene

sodium ethanolate
141-52-6

sodium ethanolate

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
mixture of cis-and trans-1-bromo-heptene-(1);
(E)/(Z)-1-bromo-1-heptene
89942-12-1

(E)/(Z)-1-bromo-1-heptene

A

1-Heptene
592-76-7

1-Heptene

B

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With sodium; xylene at 25℃;
(E)/(Z)-1-bromo-1-heptene
89942-12-1

(E)/(Z)-1-bromo-1-heptene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With potassium hydroxide; mineral oil at 250℃;
1-Bromopentane
110-53-2

1-Bromopentane

sodium acetylide
1066-26-8

sodium acetylide

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia
With tetrahydrofuran; N,N-dimethyl-formamide
In ammonia at -60℃;
With ammonia
amyl iodide
628-17-1

amyl iodide

sodium acetylide
1066-26-8

sodium acetylide

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia at 20℃; man verwandelt das Reaktionsprodukt mit Natriumammonium in die Natriumverbindung und zersetzt diese durch Wasser;
hept-3-yne
2586-89-2

hept-3-yne

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With 1,2,4-Trimethylbenzene; sodium amide at 170℃;
1,2-Heptadiene
2384-90-9

1,2-Heptadiene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With sodium amide; paraffin oil at 140℃;
1-chloro-hept-1-ene
2384-75-0

1-chloro-hept-1-ene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With potassium hydroxide; mineral oil at 250℃;
With sodium amide; paraffin oil at 150 - 155℃; und zersetzt man das Reaktionsprodukt mit Wasser;
With sodium amide; toluene at 100 - 130℃; und zersetzt man das Reaktionsprodukt mit Wasser;
With sodium amide; xylene at 100 - 130℃; und zersetzt man das Reaktionsprodukt mit Wasser;
3-bromo-hept-1-yne
61996-78-9

3-bromo-hept-1-yne

A

1-Heptyne
628-71-7

1-Heptyne

B

1,2-Heptadiene
2384-90-9

1,2-Heptadiene

Conditions
ConditionsYield
With ethanol; coppered zinc
With lithium aluminium tetrahydride; diethyl ether
With amalgamated magnesium; diethyl ether anschliessend mit wss.Ammoniumchlorid;
1,1,-dichloro-1-heptene
32363-95-4

1,1,-dichloro-1-heptene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With diethyl ether; sodium
1,1-dibromohept-1-ene
32363-96-5

1,1-dibromohept-1-ene

sodium ethanolate
141-52-6

sodium ethanolate

1-Heptyne
628-71-7

1-Heptyne

1,1-dibromohept-1-ene
32363-96-5

1,1-dibromohept-1-ene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With potassium hydroxide; mineral oil at 250℃;
With sodium ethanolate
(Z)-1,2-dibromohept-1-ene

(Z)-1,2-dibromohept-1-ene

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
With ammonia; sodium amide anschliessendes Zersetzen mit Ammoniumnitrat;
n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

diethyl ether
60-29-7

diethyl ether

propargyl bromide
106-96-7

propargyl bromide

A

1-Heptyne
628-71-7

1-Heptyne

B

1,2-Heptadiene
2384-90-9

1,2-Heptadiene

Conditions
ConditionsYield
at -15℃; analoge Reaktionen mit Alkyl-, Alkenyl-, Alkinyl- und Arylmagnesiumbromiden und Einfluss von Temp. und Loesungsm. (Ae. oder Tetrahydrofuran);
(E)/(Z)-1-bromo-1-heptene
89942-12-1

(E)/(Z)-1-bromo-1-heptene

aniline
62-53-3

aniline

1-Heptyne
628-71-7

1-Heptyne

Conditions
ConditionsYield
mixture of cis-and trans-1-bromo-heptene-(1);
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

1-Heptyne
628-71-7

1-Heptyne

1-(hept-1-ynyl)-4-nitrobenzene
64146-60-7

1-(hept-1-ynyl)-4-nitrobenzene

Conditions
ConditionsYield
With copper(l) iodide; iodophenylbis(triphenylphosphine)palladium; triethylamine In chloroform at 60℃; for 1h;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tributyl-amine; potassium carbonate In water at 20℃; for 4h;95%
With piperidine; 1,3-bis(5-ferrocenylisoxazoline-3-yl)benzene; tetrabutylammomium bromide; palladium diacetate In water; N,N-dimethyl-formamide at 40℃; for 3h; Sonogashira Cross-Coupling;94%
1-Heptyne
628-71-7

1-Heptyne

4-bromobenzenecarbonitrile
623-00-7

4-bromobenzenecarbonitrile

4-(1-hept-1-ynyl)benzonitrile
64146-59-4

4-(1-hept-1-ynyl)benzonitrile

Conditions
ConditionsYield
With copper(I) bromide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 90℃; for 0.166667h;100%
With nickel(II) ferrite; potassium carbonate In water at 100℃; for 2.25h; Sonogashira Cross-Coupling;87%
With copper(I) bromide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 20℃; Rate constant;
1-Heptyne
628-71-7

1-Heptyne

tetradeca-6,8-diyne
16387-72-7

tetradeca-6,8-diyne

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; air; palladium diacetate; copper(l) iodide In acetonitrile at 20℃; for 2h;100%
With copper(l) iodide; triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride In acetonitrile at 25℃; for 24h;96%
With copper(I) oxide In dimethyl sulfoxide at 110℃; for 2h;96%
1-Heptyne
628-71-7

1-Heptyne

carbon monoxide
201230-82-2

carbon monoxide

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

(3aR,4S,7R,7aR)-2-Pentyl-3a,4,7,7a-tetrahydro-4,7-methano-inden-1-one
85806-43-5, 85806-49-1, 122422-23-5, 122422-24-6

(3aR,4S,7R,7aR)-2-Pentyl-3a,4,7,7a-tetrahydro-4,7-methano-inden-1-one

Conditions
ConditionsYield
dodecacarbonyl tetracobalt In dichloromethane at 150℃; under 7600 Torr; for 6h;100%
Co/C In tetrahydrofuran at 130℃; under 22800 Torr; for 18h; Pauson-Khand reaction;98%
Pauson-Khand reaction;64%
1-Heptyne
628-71-7

1-Heptyne

trans-1-heptenylboronic acid
57404-76-9

trans-1-heptenylboronic acid

Conditions
ConditionsYield
With benzo[1,3,2]dioxaborole In tetrahydrofuran Heating;100%
Stage #1: 1-Heptyne With dibromoborane dimethylsulfide In dichloromethane at 0℃;
Stage #2: With sodium hydroxide In dichloromethane
Stage #3: With ammonium chloride In dichloromethane Further stages.;
78%
Stage #1: 1-Heptyne With dibromoborane-methyl sulfide complex In dichloromethane at 20℃; for 4h;
Stage #2: With water In diethyl ether; dichloromethane at 20℃; for 0.25h;
74%
2-bromo-6-methylpyridine
5315-25-3

2-bromo-6-methylpyridine

1-Heptyne
628-71-7

1-Heptyne

2-(hept-1-yn-1-yl)-6-methylpyridine
334026-55-0

2-(hept-1-yn-1-yl)-6-methylpyridine

Conditions
ConditionsYield
With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride at 60℃; for 1.5h;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 60℃; Inert atmosphere;100%
1-Heptyne
628-71-7

1-Heptyne

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

(E)-2,2′-(hept-1-ene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

(E)-2,2′-(hept-1-ene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

Conditions
ConditionsYield
With tris(bicyclo[2.2.1]heptene)palladium; triphenylphosphine at 20℃; for 12h;100%
With gold nanoparticles supported on titanium dioxide at 65℃; for 2h; chemoselective reaction;91%
With methanol; potassium carbonate In diethyl ether at 40℃; for 12h; Inert atmosphere; chemoselective reaction;72%
1-Heptyne
628-71-7

1-Heptyne

tert-butyl-(1-decyl-4-iodo-but-3-enyloxy)-dimethyl-silane
502150-94-9

tert-butyl-(1-decyl-4-iodo-but-3-enyloxy)-dimethyl-silane

tert-butyl-(1-decyl-undec-3-en-5-ynyloxy)-dimethyl-silane
502150-95-0

tert-butyl-(1-decyl-undec-3-en-5-ynyloxy)-dimethyl-silane

Conditions
ConditionsYield
With piperidine; copper(l) iodide; dichloro bis(acetonitrile) palladium(II) at 20℃; Sonogashira coupling;100%
1-Heptyne
628-71-7

1-Heptyne

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

1-(4-methoxyphenyl)oct-1-yn-1-ol
371256-71-2

1-(4-methoxyphenyl)oct-1-yn-1-ol

Conditions
ConditionsYield
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; for 3h; Inert atmosphere;
100%
Stage #1: 1-Heptyne With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; n-butyllithium In tetrahydrofuran; hexane at -30℃; for 2h;
Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran; hexane at -10℃; Further stages.;
96%
With ethylmagnesium bromide
1-Heptyne
628-71-7

1-Heptyne

4-methoxy-2-(trifluoro-methanesulfonyloxy)-benzoic acid methyl ester
216768-18-2

4-methoxy-2-(trifluoro-methanesulfonyloxy)-benzoic acid methyl ester

methyl 2-(1-heptyn-1-yl)-4-(methyloxy)benzoate
872549-78-5

methyl 2-(1-heptyn-1-yl)-4-(methyloxy)benzoate

Conditions
ConditionsYield
With copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride Sonogashira Coupling;100%
{4-(4-iodobenzoyloxy)butyl}trimethylammonium bistrifluoromethanesulfonimidate
827027-40-7

{4-(4-iodobenzoyloxy)butyl}trimethylammonium bistrifluoromethanesulfonimidate

1-Heptyne
628-71-7

1-Heptyne

C2F6NO4S2(1-)*C21H32NO2(1+)
827027-80-5

C2F6NO4S2(1-)*C21H32NO2(1+)

Conditions
ConditionsYield
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In N,N-dimethyl-formamide at 40℃; for 1h; Product distribution / selectivity; Sonogashira Coupling;100%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In dichloromethane at 40℃; for 1h; Product distribution / selectivity; Sonogashira Coupling;100%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In 1,4-dioxane at 40℃; for 1h; Product distribution / selectivity; Sonogashira Coupling;100%
1-Heptyne
628-71-7

1-Heptyne

(1R,2R,3S,4R)-4-azido-1-<((tert-butyldiphenylsilyl)oxy)methyl>-2,3-(isopropylidenedioxy)cyclopentane
112543-78-9

(1R,2R,3S,4R)-4-azido-1-<((tert-butyldiphenylsilyl)oxy)methyl>-2,3-(isopropylidenedioxy)cyclopentane

(1R,2S,3R,4R)-4-[(tert-butyldiphenylsilyloxy)methyl]-2,3-isopropylidenedioxy-1-[4-pentyl-1H-1,2,3-triazol-1-yl]cyclopentane
1161113-44-5

(1R,2S,3R,4R)-4-[(tert-butyldiphenylsilyloxy)methyl]-2,3-isopropylidenedioxy-1-[4-pentyl-1H-1,2,3-triazol-1-yl]cyclopentane

Conditions
ConditionsYield
With copper; copper(II) sulfate In water; tert-butyl alcohol at 125℃; for 0.25h; Microwave irradiation;100%
1-Heptyne
628-71-7

1-Heptyne

trifluoro-methanesulfonic acid 3-methoxy-2-methyl-6-nitro-phenyl ester
835883-30-2

trifluoro-methanesulfonic acid 3-methoxy-2-methyl-6-nitro-phenyl ester

C15H19NO3
1148008-97-2

C15H19NO3

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetra-(n-butyl)ammonium iodide In triethylamine; acetonitrile Sonogashira-Hagihara coupling; Reflux;100%
1-Heptyne
628-71-7

1-Heptyne

2-Methoxybenzoyl chloride
21615-34-9

2-Methoxybenzoyl chloride

(E)-3-chloro-1-(2-hydroxyphenyl)oct-2-en-1-one

(E)-3-chloro-1-(2-hydroxyphenyl)oct-2-en-1-one

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 23℃; for 4h; Inert atmosphere;100%
formaldehyd
50-00-0

formaldehyd

1-Heptyne
628-71-7

1-Heptyne

2-octyn-1-ol
20739-58-6

2-octyn-1-ol

Conditions
ConditionsYield
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: formaldehyd In tetrahydrofuran at -78 - 20℃; for 26h;
99%
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: formaldehyd In tetrahydrofuran; hexane at -78 - 20℃; for 5h;
94%
Stage #1: 1-Heptyne With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; hexane at -30℃; for 1h;
Stage #2: formaldehyd In tetrahydrofuran; hexane at -30℃; for 2h; Further stages.;
90%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

1-Heptyne
628-71-7

1-Heptyne

2-(hept-1-yn-1-yl)pyridine
49836-16-0

2-(hept-1-yn-1-yl)pyridine

Conditions
ConditionsYield
With copper(l) iodide; diisopropylamine; triphenylphosphine; palladium dichloride In N,N-dimethyl-formamide at 75℃; for 12h; Inert atmosphere;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 1h; Sonogashira Cross-Coupling; Inert atmosphere;92%
With copper(I) bromide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 90℃; for 0.333333h;81%
With palladium 10% on activated carbon; potassium carbonate; triphenylphosphine In ethanol for 48h; Reflux; Green chemistry;77%
1-Heptyne
628-71-7

1-Heptyne

cyclohexanone
108-94-1

cyclohexanone

1-(1-heptynyl)cyclopentan-1-ol
37828-64-1

1-(1-heptynyl)cyclopentan-1-ol

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane 0 deg C, 75 min then rt., 3.5 h;99%
With sodium aluminum diethyl dihydride 1.) toluene, r.t., 3 h, 2.) toluene, 0 deg C, 1 h; Yield given. Multistep reaction;
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran
Stage #2: cyclohexanone In water
1-Heptyne
628-71-7

1-Heptyne

benzoyl chloride
98-88-4

benzoyl chloride

1-phenyloct-2-yn-1-one
27259-10-5

1-phenyloct-2-yn-1-one

Conditions
ConditionsYield
With triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) for 15h; Ambient temperature;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Sonogashira Cross-Coupling; Sealed tube; Inert atmosphere;99%
With copper(l) iodide; di-μ-chlorobis{hydrogen bis(diphenylphosphito)(1-)-P,P'}dipalladium; triethylamine In toluene at 80℃; for 18h; Inert atmosphere;93%
1-Heptyne
628-71-7

1-Heptyne

9-(3-iodo-benzyl)-9H-purin-6-ylamine
220582-68-3

9-(3-iodo-benzyl)-9H-purin-6-ylamine

9-<3-(1-heptynyl)benzyl>-9H-6-purinamine
220582-73-0

9-<3-(1-heptynyl)benzyl>-9H-6-purinamine

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triphenylphosphine In various solvent(s) for 0.75h; Heating;99%
1-Heptyne
628-71-7

1-Heptyne

2-iodophenylamine
615-43-0

2-iodophenylamine

2-(hept-1-ynyl)benzeneamine
118476-12-3

2-(hept-1-ynyl)benzeneamine

Conditions
ConditionsYield
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide at 20℃; for 2h; Sonogashira coupling reaction;99%
With copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride In diethylamine at 30℃; for 24h;98%
Stage #1: 2-iodophenylamine With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 30℃; for 0.166667h; Inert atmosphere;
Stage #2: 1-Heptyne at 30℃; for 24h; Inert atmosphere;
98%
1-Heptyne
628-71-7

1-Heptyne

4-acetoxyiodobenzene
33527-94-5

4-acetoxyiodobenzene

acetic acid 4-hept-1-ynyl-phenyl ester

acetic acid 4-hept-1-ynyl-phenyl ester

Conditions
ConditionsYield
With copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 20℃; for 3h;99%
piperidine
110-89-4

piperidine

1-Heptyne
628-71-7

1-Heptyne

benzaldehyde
100-52-7

benzaldehyde

1-(1-phenyloct-2-yn-1-yl)piperidine

1-(1-phenyloct-2-yn-1-yl)piperidine

Conditions
ConditionsYield
With [copper(I)]2[(2-picolyliminomethyl)pyrrole]2 In toluene at 110℃; for 2h; Inert atmosphere;99%
With zinc diacetate In toluene for 7h; Heating;89%
With [bmim]PF6 at 120℃; for 2h;83 % Chromat.
With nano Co3O4 In toluene at 130℃; for 15h; Sealed tube;10 %Chromat.
1-Heptyne
628-71-7

1-Heptyne

4-iodo-2-nitrotoluene
41252-97-5

4-iodo-2-nitrotoluene

1-(4-methyl-3-nitrophenyl)hept-1-yne

1-(4-methyl-3-nitrophenyl)hept-1-yne

Conditions
ConditionsYield
With copper(l) iodide; diisopropylamine; triphenylphosphine; palladium on activated charcoal In N,N-dimethyl-formamide at 100℃; for 16h; Sonogashira reaction;99%
1-Heptyne
628-71-7

1-Heptyne

benzyl azide
622-79-7

benzyl azide

4-pentyl-1-(phenylmethyl)-1H-1,2,3-triazole
1033749-58-4

4-pentyl-1-(phenylmethyl)-1H-1,2,3-triazole

Conditions
ConditionsYield
With Cu98Mn2 nanoporous catalyst In toluene at 65℃; for 6h; Huisgen cycloaddition; regioselective reaction;99%
With copper(ll) sulfate pentahydrate; sodium L-ascorbate In dichloromethane; water at 20℃; for 24h;99%
With copper-supported ionic liquid catalyst In ethanol; water at 20℃; for 1.5h; Huisgen cycloaddition;98%
1-Heptyne
628-71-7

1-Heptyne

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-(hept-1-yn-1-yl)benzaldehyde

2-(hept-1-yn-1-yl)benzaldehyde

Conditions
ConditionsYield
With copper(l) iodide; bis(triphenylylphosphine)palladium(II) dichloride; triethylamine at 50℃; for 5h;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 50℃; for 4h; Sonogashira coupling; Inert atmosphere;91%
Stage #1: 1-Heptyne; ortho-bromobenzaldehyde With bis-triphenylphosphine-palladium(II) chloride; triethylamine at 20℃; for 0.25h; Sonogashira coupling; Inert atmosphere;
Stage #2: With copper(l) iodide at 50℃; for 4h; Sonogashira coupling; Inert atmosphere;
91%
1-Heptyne
628-71-7

1-Heptyne

benzyl bromide
100-39-0

benzyl bromide

4-pentyl-1-(phenylmethyl)-1H-1,2,3-triazole
1033749-58-4

4-pentyl-1-(phenylmethyl)-1H-1,2,3-triazole

Conditions
ConditionsYield
With sodium azide In water at 20℃; for 1.5h; Huisgen Cycloaddition; Green chemistry;99%
With sodium azide; sodium L-ascorbate In water; tert-butyl alcohol for 4h; Heating; Green chemistry;96%
With sodium azide; sodium L-ascorbate In water; tert-butyl alcohol at 55℃; for 4h; Huisgen Cycloaddition; Green chemistry; regioselective reaction;95%
paraformaldehyde-d2
1664-98-8

paraformaldehyde-d2

1-Heptyne
628-71-7

1-Heptyne

1,1-[2H2]-oct-2-yn-1-ol
144401-62-7

1,1-[2H2]-oct-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: 1-Heptyne With ethyl bromide; magnesium In tetrahydrofuran Inert atmosphere;
Stage #2: paraformaldehyde-d2 In tetrahydrofuran for 2h; Reflux;
Stage #3: With sulfuric acid In tetrahydrofuran; water Cooling with ice;
99%
Stage #1: 1-Heptyne With ethylmagnesium bromide In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: paraformaldehyde-d2 In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
40%
Stage #1: 1-Heptyne With ethylmagnesium bromide In tetrahydrofuran Inert atmosphere;
Stage #2: paraformaldehyde-d2 In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran; hexane at -20℃; for 1h;
Stage #2: paraformaldehyde-d2 In tetrahydrofuran; water at -20 - 20℃; for 18h;
1-Heptyne
628-71-7

1-Heptyne

4β-azido-4-deoxy-4′-demethylepipodophyllotoxin
117604-05-4

4β-azido-4-deoxy-4′-demethylepipodophyllotoxin

4'-O-demethyl-4β-[(4-pentyl)-1,2,3-triazol-1-yl]-4-desoxypodophyllotoxin
1310548-40-3

4'-O-demethyl-4β-[(4-pentyl)-1,2,3-triazol-1-yl]-4-desoxypodophyllotoxin

Conditions
ConditionsYield
With copper(ll) sulfate pentahydrate; L-ascorbic acid sodium salt In water; tert-butyl alcohol at 20℃; for 8h;99%
2-amino-5-iodopyrimidine
1445-39-2

2-amino-5-iodopyrimidine

1-Heptyne
628-71-7

1-Heptyne

5-(hept-1-ynyl)pyrimidin-2-amine
1361537-65-6

5-(hept-1-ynyl)pyrimidin-2-amine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira coupling; Inert atmosphere; Reflux;99%

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