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Nanjing Yuance Industry&Trade Co., Ltd.

Grades: 40%, 60%, 70%, 80%, 95%, 99% Excellent quality with competitive price Fast delivery Appearance:colorless liquid Storage:Store in cool dry place Package:200 kg/drum Application:Used for solvent, extraction, organic synthesis Port:Shangha

N-hexane, Hexane, CAS: 110-54-3, Normal Hexane,

Cas:110-54-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Hexane supplier in China

Cas:110-54-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless liquid Colorless liquid Water 0.01%max

Top purity N-HEXANE with high quality and best price cas:110-54-3

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Hexane CAS number 110-54-3 Assay ≥40%, ≥60%, ≥80%,≥85%,≥95%,≥97%,≥98% Appearance Colorless transparent liquid Capacity 2000mt/year

Hexane

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

N-hexane, Hexane, CAS: 110-54-3

Cas:110-54-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Hexane Anhydrous

Cas:110-54-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

EAST CHEMSOURCES LIMITED

Hexane Molecular formula: C6H14 Molecular weight: 86.18 InChI: InChI=1/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3 Molecular structure: Density: 0.659 Melting point: -95 C Boiling point: 69 degrees centigrade Flash point: -22 C Water solubility: ins

Hexane

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hexane

Cas:110-54-3

Min.Order:1

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFUCHEM 110-54-3 Hexane

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

N-hexane 97%,99%,99.9%min Identification: Chemical Name: N-hexane Synonyms: Hexane CAS No.: 110-54-3 Molecular formula: C6H14 Advantages: Full experience of large numbers containers loading in CMP Fast shipment by reputed shippin

N-hexane 99.9%min extracting agent 110-54-3

Cas:110-54-3

Min.Order:5 Metric Ton

FOB Price: $1.0

Type:Other

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Extraction solvent Hexane with CAS:110-54-3

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 4.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:110-54-3

Cas:110-54-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Hexane

Cas:110-54-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

N-hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

Analysis Item Index Result Appearance Bright & Clear accord Colour, Saybolt +28

n-Hexane

Cas:110-54-3

Min.Order:17 Metric Ton

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

N-hexane

Cas:110-54-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

N-hexane 99.9%min extracting agent 110-54-3Appearance:Colorless liquid Storage:RT Package:according to customers' requirements Application:It is mainly used for organic synthesis, solvent extraction of plant oil, extracting agent, cleaning agent, dis

N-hexane 99.9%min extracting agent 110-54-3

Cas:110-54-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

N-hexane

Cas:110-54-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

N-Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting Hexane,n-Hexane,cas:110-54-3, Please contact us by email freely. We are leading exporter in China. If you really need this cargo, pl

Hexane,n-Hexane,cas:110-54-3 from fandachem

Cas:110-54-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Hexane

Cas:110-54-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:200 kg / drum,or as per your request. Application: food additives

Hexane

Cas:110-54-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Research Peptide Biotechnology Co., Ltd.

High purity, high success rate, short cycle and moderate priceAppearance:White powder solid Storage:Negative 20 degrees Celsius Package:5mg, 10mg 100mg, 1gram Application:Applied to various scientific research

Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 110-54-3 with best price

Cas:110-54-3

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

n-Hexane

Cas:110-54-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Hexane 110-54-3

Cas:110-54-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Hexane 97%

Cas:110-54-3

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

1-hexene
592-41-6

1-hexene

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; In tetrahydrofuran at 90℃; under 5250.4 Torr; for 0.166667h; Product distribution; other olefins, other catalysts; var. temp., solv., press., and time;100%
With hydrogen; (iPrPDI)Fe(N2)2 at 20℃; under 3040 Torr; for 19h;100%
With Wilkinson's catalyst; hydrogen In dichloromethane-d2 at 45℃; under 3000.3 Torr; for 6h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere;100%
1-hexene
592-41-6

1-hexene

hydrogen
1333-74-0

hydrogen

hexane
110-54-3

hexane

Conditions
ConditionsYield
With C61H98ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 4h; Reagent/catalyst; Time;100%
With triethylsilane; ReH(NO)2(P(CH(CH3)2)3)2; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
With triethylsilane; [ReH(NO)2(P(C6H11)3)2]; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
C26H30CoN4(1+)*ClO4(1-)

C26H30CoN4(1+)*ClO4(1-)

hexane
110-54-3

hexane

Conditions
ConditionsYield
With sulfuric acid; oxygen at 60℃; under 3750.38 Torr; for 12h; Catalytic behavior; Reagent/catalyst;100%
1-hexene
592-41-6

1-hexene

A

trans-2-hexene
4050-45-7

trans-2-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With Rh complex with phosphoryl-terminated carbosilane dendrimer; hydrogen In acetone at 25℃; under 7500.75 Torr; for 2h; Product distribution; Further Variations:; Reagents;A 0.5%
B 99.5%
With hydrogen; poly-1,2,3-triazolyl ferrocenyl dendrimer-Pd nanoparticle In methanol; chloroform at 25℃; under 760.051 Torr;A 57%
B 43%
With hydrogen; Pd(salen) encapsuled in zeolite X at 25℃; under 400 Torr; for 24h; Product distribution; var. catalysts; cyclohexene;
hex-3-yne
928-49-4

hex-3-yne

A

cis-3-hexene
7642-09-3

cis-3-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 99.5%
B n/a
With bis(pentamethylcyclopentadienyl)titanium(III) hydride; hydrogen In (2)H8-toluene for 0.25h; Sealed tube;A 80%
B 20%
With silica-supported frustrated Lewis pair 3a (HBC6F5)2; (4-hydroxyphenyl)biphenylphosphine; [(SiO)2AliBuEt2O)]) In pentane at 80℃; under 30003 Torr; for 4h; Reagent/catalyst; stereoselective reaction;
1-hexene
592-41-6

1-hexene

cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

A

hexane
110-54-3

hexane

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With C24H72Ba2N4Si8 In (2)H8-toluene at 120℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;A 99%
B n/a
oenanthic acid
111-14-8

oenanthic acid

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; silica gel; palladium at 330℃; Ni/Al2O3, 180 deg C;98%
With 10-phenyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; diphenyldisulfane In 2,2,2-trifluoroethanol; ethyl acetate at 20℃; for 48h; Irradiation;40%
With barytes
Multi-step reaction with 3 steps
1: borane-d3-tetrahydrofuran / tetrahydrofuran
2: pyridinium dichlorochromate / dichloromethane
3: aldehyde deformylating oxygenase / glycerol / 0.08 h / pH 7.5
View Scheme
2-Hexyne
764-35-2

2-Hexyne

A

3-hexene
592-47-2

3-hexene

B

trans-2-hexene
4050-45-7

trans-2-hexene

C

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; palladium In ethanol at 30℃; under 15200 Torr; Product distribution;A 0.8%
B 98%
C 1.2%
n-hexan-2-one
591-78-6

n-hexan-2-one

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; K-10 montmorillonite; platinum In diethylene glycol dimethyl ether under 37503 Torr; for 20h; Reduction;98%
With hydrogen; aluminum oxide; nickel at 190℃;88%
With hydrogen at 100℃; under 750.075 Torr; for 3h;
Multi-step reaction with 2 steps
1: hydrogen / cyclohexane / 120 °C / 45004.5 Torr
2: hydrogen / cyclohexane / 120 °C / 45004.5 Torr
View Scheme
2,5-hexanedione
110-13-4

2,5-hexanedione

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; K-10 montmorillonite; platinum In diethylene glycol dimethyl ether under 37503 Torr; for 20h; Reduction;98%
Stage #1: 2,5-hexanedione With hydrogen at 120℃; under 20702.1 Torr; for 0.5h;
Stage #2: at 200℃; under 20702.1 Torr; for 5h; Reagent/catalyst;
Multi-step reaction with 2 steps
1: palladium/alumina; hydrogen / 0.5 h / 200 °C / 20702.1 Torr
2: palladium/alumina; hydrogen / 4 h / 200 °C / 20702.1 Torr
View Scheme
1-Iodohexane
638-45-9

1-Iodohexane

η3-allylbis(cyclopentadienyl)titanium(III)

η3-allylbis(cyclopentadienyl)titanium(III)

hexane
110-54-3

hexane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Product distribution;97%
2-Hexyne
764-35-2

2-Hexyne

A

cis-2-hexene
7688-21-3

cis-2-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 97%
B n/a
potassium carbonate
584-08-7

potassium carbonate

1-Bromo-2-butyne
3355-28-0

1-Bromo-2-butyne

hexane
110-54-3

hexane

Conditions
ConditionsYield
In ethyl acetate; N,N-dimethyl-formamide96.2%
1-bromo-hexane
111-25-1

1-bromo-hexane

hexane
110-54-3

hexane

Conditions
ConditionsYield
With ammonium chloride; zinc In tetrahydrofuran; water at 20℃; for 3h;95%
With lithium aluminium tetrahydride; 15-crown-5 In benzene at 80℃; for 6h;83%
Stage #1: 1-bromo-hexane With magnesium In diethyl ether
Stage #2: With ammonium chloride In water Further stages.;
37%
With tris-(trimethylsilyl)silane; oxygen at 60℃; for 6h; in sealed vial;81 % Chromat.
Conditions
ConditionsYield
With Bu3Sn4; 2,4,5,7-tetraiodo-6-hydroxy-3-fluorone Mechanism; Product distribution; Irradiation; also other halides;95%
With borohydride exchange resin; nickel diacetate In methanol for 3h; Ambient temperature;98 % Chromat.
1-hexene
592-41-6

1-hexene

benzyl alcohol
100-51-6

benzyl alcohol

A

hexane
110-54-3

hexane

B

Heptanophenone
1671-75-6

Heptanophenone

Conditions
ConditionsYield
With 5-hexyl-2,4,6-triaminopyrimidine; 5-[4-(Ph2P)benzyl]-5-ethyl-2,4,6-(1H,3H,5H)-pyrimidinetrione; substituted barbituric acid aminopyridine-containing reagent; [Rh(coe)2Cl]2; cyclohexylamine In 1,4-dioxane; phenol at 150℃; for 2h;A n/a
B 95%
5-Hydroxymethyl-5'-formyl-2,2'-bithiophene
170110-95-9

5-Hydroxymethyl-5'-formyl-2,2'-bithiophene

A

5-acetoxymethyl-5'-formyl-2,2'-bithiophene

5-acetoxymethyl-5'-formyl-2,2'-bithiophene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With pyridine; acetic anhydride In water; ethyl acetateA n/a
B 95%
With pyridine; acetic anhydride In water; ethyl acetateA n/a
B 95%
hexan-1-ol
111-27-3

hexan-1-ol

A

hexane
110-54-3

hexane

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 120℃;A 5%
B 94%
With hydrogen In n-heptane at 199.84℃; under 22502.3 Torr; Kinetics; Autoclave;
n-hexan-2-ol
626-93-7

n-hexan-2-ol

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 180℃;91%
With hydrogen In n-heptane at 119.84℃; under 51005.1 Torr; for 1h; Kinetics; Autoclave; Inert atmosphere;
With hydrogen In cyclohexane at 120℃; under 45004.5 Torr; Catalytic behavior; Reagent/catalyst;
hex-1-yne
693-02-7

hex-1-yne

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 91%
B n/a
With hydrogen; platinum In ethanol at 30℃; under 15200 Torr; Product distribution; 80 atm;A 41.7%
B 57.3%
With hydrogen; Ni(C17H35COO)2; triethylaluminum In toluene at 40℃; Kinetics; Object of study: selectivity;
3-chloropropyl dichloromethylsilane

3-chloropropyl dichloromethylsilane

vinylmagnesium chloride
3536-96-7

vinylmagnesium chloride

hexane
110-54-3

hexane

Conditions
ConditionsYield
In tetrahydrofuran91%
hex-1-yne
693-02-7

hex-1-yne

A

cis-2-hexene
7688-21-3

cis-2-hexene

B

trans-2-hexene
4050-45-7

trans-2-hexene

C

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; palladium In ethanol at 30℃; under 15200 Torr; Product distribution;A 3.8%
B 90.2%
C 6%
p-aminomethylbenzoic acid
56-91-7

p-aminomethylbenzoic acid

2,2-diphenyl ethanol
1883-32-5

2,2-diphenyl ethanol

A

4-[2,2-(diphenyl)ethoxycarbamoyl-methyl]benzoic acid

4-[2,2-(diphenyl)ethoxycarbamoyl-methyl]benzoic acid

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With CDI In tetrahydrofuran; sodium hydroxideA 90%
B n/a
pyrrolidine
123-75-1

pyrrolidine

3,3-dimethyl-D-cysteine
52-67-5

3,3-dimethyl-D-cysteine

A

4-carboxy-2,5,5-trimethylthiazolidine-2-acetopyrrolidide

4-carboxy-2,5,5-trimethylthiazolidine-2-acetopyrrolidide

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
In benzeneA 90%
B n/a
1-hexene
592-41-6

1-hexene

A

hexane
110-54-3

hexane

B

2-hexene
592-43-8

2-hexene

Conditions
ConditionsYield
With RuHCl(PPh3)((CH3OCH2CH2)2Im)(SIMes2); hydrogen at 100℃; under 3000.3 Torr; for 4h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere;A 13%
B 87%
With hydrogen; Polymer-bound Ni2-catalyst at 100℃; under 51714.8 Torr; for 3h; Product distribution; Other catalyst;A 77%
B 11%
With hydrogen In ethanol; toluene at 40℃; under 2625.26 Torr; for 2h; Catalytic behavior; Inert atmosphere;A 72%
B 28%
1-hexene
592-41-6

1-hexene

4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

A

hexane
110-54-3

hexane

B

1-(4-methoxyphenyl)-1-heptanone
69287-13-4

1-(4-methoxyphenyl)-1-heptanone

Conditions
ConditionsYield
With 5-hexyl-2,4,6-triaminopyrimidine; substituted barbituric acid aminopyridine-containing reagent; triphenylphosphine; [Rh(coe)2Cl]2; cyclohexylamine In 1,4-dioxane at 150℃;A n/a
B 87%
1-hexene
592-41-6

1-hexene

4-(trifluoromethyl)benzylic alcohol
349-95-1

4-(trifluoromethyl)benzylic alcohol

A

hexane
110-54-3

hexane

B

1-[4-(trifluoromethyl)phenyl]heptan-1-one

1-[4-(trifluoromethyl)phenyl]heptan-1-one

Conditions
ConditionsYield
With 5-hexyl-2,4,6-triaminopyrimidine; substituted barbituric acid aminopyridine-containing reagent; triphenylphosphine; [Rh(coe)2Cl]2; cyclohexylamine In 1,4-dioxane at 150℃;A n/a
B 86%
aqua{o,o'-bis((dimethylamino)methyl)phenyl}nickel(II) tetrafluoroborate

aqua{o,o'-bis((dimethylamino)methyl)phenyl}nickel(II) tetrafluoroborate

hexane
110-54-3

hexane

Ni(((CH3)2NCH2)2C6H3)(H2O)(1+)*BF4(1-)*0.167C6H14 = [Ni(C6H3(CH2N(CH3)2)2)(H2O)][BF4]*0.167C6H14

Ni(((CH3)2NCH2)2C6H3)(H2O)(1+)*BF4(1-)*0.167C6H14 = [Ni(C6H3(CH2N(CH3)2)2)(H2O)][BF4]*0.167C6H14

Conditions
ConditionsYield
In hexane; dichloromethane (N2); n-hexane added dropwise to CH2Cl2 soln. of Ni compd.; (N2); cryst. material obtained; elem. anal.;100%
hexane
110-54-3

hexane

[methyl(hydridotris(3,5-dimethylpyrazolyl)borate)(trimethylphosphine)iridium(III)(N2)][B(3,5-C6H3(CF3)2)4]*(dichloromethane)

[methyl(hydridotris(3,5-dimethylpyrazolyl)borate)(trimethylphosphine)iridium(III)(N2)][B(3,5-C6H3(CF3)2)4]*(dichloromethane)

triphenyl-arsane
603-32-7

triphenyl-arsane

[methyl(hydridotris(3,5-dimethylpyrazolyl)borate)(trimethylphosphine)iridium(III)(AsPh3)][B(3,5-C6H3(CF3)2)4]*(hexane)

[methyl(hydridotris(3,5-dimethylpyrazolyl)borate)(trimethylphosphine)iridium(III)(AsPh3)][B(3,5-C6H3(CF3)2)4]*(hexane)

Conditions
ConditionsYield
In dichloromethane byproducts: N2; CH2Cl2 soln. of AsPh3 (1 equiv.) added to CH2Cl2 soln. of Ir complex at -40°C; stirred for 12 h; filtered through glass fiber filter paper; solvent removed under reducedpressure; hexane diffused into concd. ether soln. at 22°C; elem. anal.;100%
hexane
110-54-3

hexane

(BrC6H4C3HO2H)2C2H2O2C(CH3)2

(BrC6H4C3HO2H)2C2H2O2C(CH3)2

iron(III) chloride
7705-08-0

iron(III) chloride

[(BrC6H4C3HO2)2C2H2O2C(CH3)2]3Fe2*C6H14

[(BrC6H4C3HO2)2C2H2O2C(CH3)2]3Fe2*C6H14

Conditions
ConditionsYield
In methanol in methanol; crystd.(hexane), elem. anal.;100%
hexane
110-54-3

hexane

[(cod)Ir(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Ir(cod)]BF4
881493-73-8

[(cod)Ir(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Ir(cod)]BF4

carbon monoxide
201230-82-2

carbon monoxide

[(CO)2Ir(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Ir(CO)2]BF4*0.4hexane

[(CO)2Ir(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Ir(CO)2]BF4*0.4hexane

Conditions
ConditionsYield
In dichloromethane soln. Ir-Ir complex in CH2Cl2 was stirred under CO atm. (1 atm.) for 3 hat room temp.; hexane was added, ppt. was washed with ether and dried in vacuo; elem. anal.;100%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

hexane
110-54-3

hexane

[C6H4-1,2-{NC(t-Bu)N(2,6-Me2C6H3)}2]Yb(THF)
1541157-10-1

[C6H4-1,2-{NC(t-Bu)N(2,6-Me2C6H3)}2]Yb(THF)

triphenyltin chloride
639-58-7

triphenyltin chloride

0.5C4H8O*0.25C6H14*C36H50ClN4O2Yb

0.5C4H8O*0.25C6H14*C36H50ClN4O2Yb

B

hexaphenylditin
1064-10-4

hexaphenylditin

Conditions
ConditionsYield
Stage #1: [C6H4-1,2-{NC(t-Bu)N(2,6-Me2C6H3)}2]Yb(THF); triphenyltin chloride In tetrahydrofuran for 12h; Schlenk technique;
Stage #2: 1,2-dimethoxyethane; hexane Schlenk technique;
A 75%
B 100%
hexane
110-54-3

hexane

C20H21FeN2Na*0.4C4H8O

C20H21FeN2Na*0.4C4H8O

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

C76H72Fe2N4Na2O2P2*0.5C6H14

C76H72Fe2N4Na2O2P2*0.5C6H14

Conditions
ConditionsYield
Stage #1: C20H21FeN2Na*0.4C4H8O; Triphenylphosphine oxide In toluene at 20℃; Inert atmosphere; Schlenk technique;
Stage #2: hexane In toluene at -30 - 20℃; for 24h; Inert atmosphere; Schlenk technique;
100%
hexane
110-54-3

hexane

N2SO4

N2SO4

4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

2-chloro-ethanol
107-07-3

2-chloro-ethanol

1-(4-(2-hydroxyethoxy)phenyl)ethanone
31769-45-6

1-(4-(2-hydroxyethoxy)phenyl)ethanone

Conditions
ConditionsYield
With potassium carbonate In water; ethyl acetate; N,N-dimethyl-formamide99.4%
hexane
110-54-3

hexane

([PhP(CH2SiMe2NPh)2]Ta)2(μ–η1:η2-N2)(μ-H)2

([PhP(CH2SiMe2NPh)2]Ta)2(μ–η1:η2-N2)(μ-H)2

phenylsilane
694-53-1

phenylsilane

([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Ph)(Ta[PhNSiMe2CH2)2PPh])*0.5(hexane)

([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Ph)(Ta[PhNSiMe2CH2)2PPh])*0.5(hexane)

Conditions
ConditionsYield
In toluene under N2; to a stirred soln. of Ta-contg. compd. (0.350 mmol) in toluenewas added phenylsilane (0.350 mmol) in the same solvent; stirring for 2 4 h at -40°C; solvent was removed under vac.; the residue was triturated under hexanesand left overnight; the ppt. was recovered on a glass frit; elem. anal.;99%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

hexane
110-54-3

hexane

C4H2N(C(C6F5)(C4HNHO)C(C6F5)(C4H2NH))2C(C6F5)

C4H2N(C(C6F5)(C4HNHO)C(C6F5)(C4H2NH))2C(C6F5)

(Rh(CO)2)C4H2N(C(C6F5)(C4HNO)C(C6F5)(C4H2NH))(C(C6F5)(C4HNHO)C(C6F5)(C4H2NH))C(C6F5)*1.5C6H14

(Rh(CO)2)C4H2N(C(C6F5)(C4HNO)C(C6F5)(C4H2NH))(C(C6F5)(C4HNHO)C(C6F5)(C4H2NH))C(C6F5)*1.5C6H14

Conditions
ConditionsYield
With CH3COONa In dichloromethane Rh complex and anhydrous sodium acetate added to soln. of dioxopentaphyrin in CH2Cl2, stirred under reflux for 3 h; chromy, (silica gel, CH2Cl2/hexane (4/6)), removal of solvent;99%
chloromethyl(1,5-cyclooctadiene)palladium(II)

chloromethyl(1,5-cyclooctadiene)palladium(II)

hexane
110-54-3

hexane

sodium 2,6-di((2,6-diisopropylphenyl)iminomethyl)-4-methylphenolate

sodium 2,6-di((2,6-diisopropylphenyl)iminomethyl)-4-methylphenolate

[Pd2(/mu.-Cl)Me2(2,6-di((2,6-diisopropylphenyl)iminomethyl)-4-methylphenolate)]*hexane
1156486-95-1

[Pd2(/mu.-Cl)Me2(2,6-di((2,6-diisopropylphenyl)iminomethyl)-4-methylphenolate)]*hexane

Conditions
ConditionsYield
In toluene byproducts: NaCl; (Ar, Schlenk technique); addn. of toluene soln. of 2 equiv. of palladiumcompd. to toluene soln. of phenol deriv., stirring at room temp. for 12 h; evapn., washing with hexane, elem. anal.;99%
hexane
110-54-3

hexane

dichloromethane
75-09-2

dichloromethane

[(pentamethylcyclopentadienyl)2ZrMe(2-(di-tert-butylphosphino)phenoxide)]
1309604-37-2

[(pentamethylcyclopentadienyl)2ZrMe(2-(di-tert-butylphosphino)phenoxide)]

2,6-di-tert-butylpyridininum tetrakis(pentafluorophenyl)borate
1309604-77-0

2,6-di-tert-butylpyridininum tetrakis(pentafluorophenyl)borate

(C5(CH3)5)2ZrClOC6H4P(C(CH3)3)2CH2Cl(1+)*B(C6F5)4(1-)*CH2Cl2*CH3(CH2)4CH3=ZrC35H54Cl2OPB(C6F5)4*CH2Cl2*C6H14

(C5(CH3)5)2ZrClOC6H4P(C(CH3)3)2CH2Cl(1+)*B(C6F5)4(1-)*CH2Cl2*CH3(CH2)4CH3=ZrC35H54Cl2OPB(C6F5)4*CH2Cl2*C6H14

Conditions
ConditionsYield
In dichloromethane (Ar); mixing a solns. of Zr complex and pyridinium salt in CH2Cl2, standing overnight; pouring in hexane, filtration, washing with hexanes, drying in vac., layering a soln. in CH2Cl2 with hexane; elem. anal.;99%
pyridine
110-86-1

pyridine

hexane
110-54-3

hexane

2,6-bis((S)-1-cyclohexyl-4-isopropyl-4,5-dihydro-1H-imidazol-2-yl)phenylchloroplatinum(II)

2,6-bis((S)-1-cyclohexyl-4-isopropyl-4,5-dihydro-1H-imidazol-2-yl)phenylchloroplatinum(II)

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

[(2,6-bis((S)-1-cyclohexyl-4-isopropyl-4,5-dihydro-1H-imidazol-2-yl)phenyl)Pt(pyridine)][OTf]*0.4C6H14

[(2,6-bis((S)-1-cyclohexyl-4-isopropyl-4,5-dihydro-1H-imidazol-2-yl)phenyl)Pt(pyridine)][OTf]*0.4C6H14

Conditions
ConditionsYield
In pyridine; dichloromethane byproducts: AgCl; Pt complex was reacted with Ag salt (1 equiv.) in presence of pyridine (1 equiv.) in CH2Cl2 at room temp. for 24 h; filtered through Celite; evapd.; chromd. (silica gel plates, CH2Cl2/MeOH, 10/1); elem. anal.;99%
hexane
110-54-3

hexane

C56H52N4Pd
109533-33-7

C56H52N4Pd

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

2-nitro-meso-tetramesitylporphyrinatopalladium(II) hexane 1.25-solvate

2-nitro-meso-tetramesitylporphyrinatopalladium(II) hexane 1.25-solvate

Conditions
ConditionsYield
Stage #1: C56H52N4Pd; Nitrogen dioxide In dichloromethane
Stage #2: hexane In dichloromethane
99%
bis(triphenylphosphine)(carbonyl)rhodium chloride
13938-94-8, 15318-33-9, 16353-77-8

bis(triphenylphosphine)(carbonyl)rhodium chloride

hexane
110-54-3

hexane

N,N-bis((diphenylphosphino)methyl)benzenamine
129880-59-7

N,N-bis((diphenylphosphino)methyl)benzenamine

[RhCl(CO){PhN(CH2PPh2)2}2]*0.5C6H14

[RhCl(CO){PhN(CH2PPh2)2}2]*0.5C6H14

Conditions
ConditionsYield
Stage #1: bis(triphenylphosphine)(carbonyl)rhodium chloride; N,N-bis((diphenylphosphino)methyl)benzenamine In toluene at 20 - 80℃; Inert atmosphere;
Stage #2: hexane Inert atmosphere;
99%
hexane
110-54-3

hexane

cis-[PtCl2(COD)]
12080-32-9

cis-[PtCl2(COD)]

bis(2-isocyanophenyl) phenylphosphonate
1486481-56-4

bis(2-isocyanophenyl) phenylphosphonate

C20H13Cl2N2O3PPt*0.25C6H14

C20H13Cl2N2O3PPt*0.25C6H14

Conditions
ConditionsYield
In dichloromethane for 2h; Schlenk technique; Inert atmosphere;99%
chlorobis(cyclooctene)-iridium(I) dimer

chlorobis(cyclooctene)-iridium(I) dimer

hexane
110-54-3

hexane

C40H34N2P2

C40H34N2P2

C80H68Cl2Ir2N4P4*0.15C6H14

C80H68Cl2Ir2N4P4*0.15C6H14

Conditions
ConditionsYield
Stage #1: chlorobis(cyclooctene)-iridium(I) dimer; C40H34N2P2 In benzene for 72h; Glovebox; Schlenk technique;
Stage #2: hexane Glovebox; Schlenk technique;
99%
hexane
110-54-3

hexane

(2S)-2-(2-propenyl)octanoic acid
213914-70-6

(2S)-2-(2-propenyl)octanoic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium chloride In ethyl acetate98%
hexane
110-54-3

hexane

2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

imidazolyl sodium
5587-42-8

imidazolyl sodium

2-imidazol-1-yl-benzonitrile
25373-49-3

2-imidazol-1-yl-benzonitrile

Conditions
ConditionsYield
In chloroform; acetonitrile98%
(tri(p-fluorophenyl)phosphine)3RhCl
25478-56-2

(tri(p-fluorophenyl)phosphine)3RhCl

hexane
110-54-3

hexane

[1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene
141556-42-5

[1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene

[(CN(C6H2(CH3)3)CHCHN(C6H2(CH3)3))Rh(P(C6H4F)3)2Cl]*0.5C6H14

[(CN(C6H2(CH3)3)CHCHN(C6H2(CH3)3))Rh(P(C6H4F)3)2Cl]*0.5C6H14

Conditions
ConditionsYield
In toluene byproducts: P(p-F-Ph)3; (Ar); std. Schlenk technique; ligand (1 equiv.) was added to Rh complex;toluene was added; soln. was stirred for 16 h; concd.; hexane added; cooled at -20°C for 2 h; filtered; residue washed (hexane); dried in vac. overnight;98%
hexane
110-54-3

hexane

2-mercapto-N-methylbenzamide
20054-45-9

2-mercapto-N-methylbenzamide

mercury dichloride

mercury dichloride

Hg(SC6H4CONHCH3)2*0.25C6H14

Hg(SC6H4CONHCH3)2*0.25C6H14

Conditions
ConditionsYield
In methanol (Ar); addn. of HgCl2 to a soln. of ligand in methanol at room temp., stirring for 2 h; concn., addn. of satd. aq. NaCl, filtration, washing ppt. with satd. aq.NaCl, water, recrystn. (methanol); elem. anal.;98%
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