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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Nitrobenzyl Bromide supplier in China

Cas:100-11-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply α-bromo-4-nitrotoluene

Cas:100-11-8

Min.Order:1

Negotiable

Type:Other

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

100-11-8 4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or grey white crytal Storage:Store in sealed container

High-purity 4-Nitrobenzyl bromide CAS 100-11-8 with best price

Cas:100-11-8

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:By Sea/Air/Courier Port:Qingdao

4-Nitrobenzyl bromide 100-11-8

Cas:100-11-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality P-Nitrobenzyl Bromide

Cas:100-11-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

Product Name 4-Nitrobenzyl bromide CAS No 100-11-8 Quality standard Index name

high purity 4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:50 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 4-Nitrobenzyl Bromide CAS No.:100-11-8 Molecule Formula:C7H6BrNO2 Molecule Weight:216.03 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITE

Best Quality 4-Nitrobenzyl Bromide

Cas:100-11-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

Benzene,1-(bromomethyl)-4-nitro-CAS NO.: 100-11-8

Cas:100-11-8

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Benzene,1-(bromomethyl)-4-nitro-

Cas:100-11-8

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white to light yellow crystal powde Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:as per your request Application:Used as Pharmaceutical Intermed

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO Factory/Good qualityAppearance:off white Storage:dry and cool place Package:10G/BAG; 1KG/BAG ;25KG/DRUM Application:Active pharaceutical ingredients Transportation:BY SEA,AIR,EXPRESS Port:SHANGHAI;BEIJING

1-(Bromomethyl)-4-nitrobenzene

Cas:100-11-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-(BroMoMethyl)-4-nitrobenzene

Cas:100-11-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

P-Nitrobenzyl Bromide

Cas:100-11-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Nitrobenzyl broMide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

P-Nitrobenzyl Bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-Nitrobenzyl broMide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

4-Nitrobenzyl Bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

SAGECHEM LIMITED

100-11-8 Application:intermediate

Benzene, 1-(bromomethyl)-4-nitro-

Cas:100-11-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Koning Pharmchem Co., Ltd.

4-Nitrobenzyl bromideAppearance:White or Almost White crystalline powder Storage:Store in refrigerator Package:Disguised package Application:Steroids injection For Body building Transportation:By Express or By Air

4-Nitrobenzyl bromide

Cas:100-11-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
Stage #1: 4-nitrobenzyl chloride With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: With tetrabutylammomium bromide at 20℃; Sealed tube; Inert atmosphere;
100%
With N-Bromosuccinimide; triphenylphosphine for 0.00555556h; microwave irradiation;98%
Stage #1: 4-nitrobenzyl chloride With diisopropyl-carbodiimide; copper(II) bis(trifluoromethanesulfonate) In tetrahydrofuran at 100℃; for 0.0833333h; microwave irradiation;
Stage #2: With Acetyl bromide In tetrahydrofuran at 150℃; for 0.0833333h; microwave irradiation; Further stages.;
98%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reagent/catalyst; Reflux;100%
With 2,2'-azobis(isobutyronitrile); hydrogen bromide; dihydrogen peroxide at 70 - 120℃; Reagent/catalyst; Temperature;99.3%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Reflux;95%
benzyl bromide
100-39-0

benzyl bromide

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With sulfuric acid; silica gel; tetramethylammonium nitrate for 0.0333333h;97%
With sulfuric acid; nitric acid at 0 - 5℃;
2-(4-nitrobenzyloxy)tetrahydro-2H-pyran
18483-99-3

2-(4-nitrobenzyloxy)tetrahydro-2H-pyran

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With 4-aminophenyl diphenylphosphinite; bromine In dichloromethane at 20℃; for 1.25h;95%
4-nitrobenzyl trimethylsilyl ether
14856-73-6

4-nitrobenzyl trimethylsilyl ether

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With 4-aminophenyl diphenylphosphinite; bromine In dichloromethane at 20℃; for 0.833333h;95%
4-nitro-1-[(ethoxymethoxy)methyl]benzene
1058649-42-5

4-nitro-1-[(ethoxymethoxy)methyl]benzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With phosphotungstic acid; tetrabutylammomium bromide at 130 - 142℃; for 0.00833333h; Microwave irradiation; Ionic liquid; chemoselective reaction;94%
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0333333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;85%
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With polymethylhydrosiloxane; dimethylbromosulphonium bromide In chloroform at 20℃; for 8h;92%
With Dichloromethylsilane; phosphorus tribromide; iron(III) chloride In acetonitrile for 6h; Heating;92%
With isopinocampheyl-boron dibromide dimethylsulfide complex In hexane at 20℃; for 10h; Reduction; bromination;65%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

A

1-dibromomethyl-4-nitro-benzene
619-75-0

1-dibromomethyl-4-nitro-benzene

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 60℃; for 0.833333h; Time; Temperature; Flow reactor; Irradiation;A n/a
B 86%
With N-Bromosuccinimide for 0.15h; microwave irradiation;A 20%
B 70%
With hydrogen bromide; sodium bromide In chloroform; water at 5 - 15℃; Electrolysis;A 50%
B 50%
With N-Bromosuccinimide In Methyl formate Product distribution; with other ten solvents; ylied (max) and selektivity was determined;
With N-Bromosuccinimide at 36℃; for 16h; Irradiation; neat (no solvent);
1-((methoxymethoxy)methyl)-4-nitrobenzene
139884-17-6

1-((methoxymethoxy)methyl)-4-nitrobenzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0333333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;86%
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

carbon tetrabromide
558-13-4

carbon tetrabromide

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With triphenylphosphine In n-heptane; dichloromethane; ethyl acetate85%
With triphenylphosphine In n-heptane; dichloromethane; ethyl acetate85%
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

ammonium acetate
631-61-8

ammonium acetate

A

4-nitrobenzyl acetate
619-90-9

4-nitrobenzyl acetate

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With N-Bromosuccinimide; triphenylphosphine In acetonitrile at 20℃; for 12h; Cooling with ice;A 80%
B 10%
N-bromo-S-(p-nitrobenzyl)-S-phenylsulfoximide
85313-81-1

N-bromo-S-(p-nitrobenzyl)-S-phenylsulfoximide

A

S-(p-nitrobenzyl)-S-phenylsulfoximide
85313-79-7

S-(p-nitrobenzyl)-S-phenylsulfoximide

B

S-(α-bromo-p-nitrobenzyl)-S-phenylsulfoximide
85313-84-4

S-(α-bromo-p-nitrobenzyl)-S-phenylsulfoximide

C

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
In ethanol; chloroform for 5h; Product distribution; Ambient temperature; further solvents, reaction times;A 72.9%
B 16%
C n/a
1-Amino-3-p-nitrobenzylthiopropanephosphonic acid
81979-40-0

1-Amino-3-p-nitrobenzylthiopropanephosphonic acid

A

(1RS,8RS)-diamino-4,5-dithiaoctane-1,8-diphosphonic acid
77275-39-9

(1RS,8RS)-diamino-4,5-dithiaoctane-1,8-diphosphonic acid

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With hydrogen bromide Heating; overnight;A 65%
B n/a
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

acetic anhydride
108-24-7

acetic anhydride

A

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

B

4-nitrobenzyl acetate
619-90-9

4-nitrobenzyl acetate

C

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

D

4-nitrobenzylidene diacetate
2929-91-1

4-nitrobenzylidene diacetate

E

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With sulfuric acid; ozone; potassium bromide; manganese(II) In acetic acid at 10℃; for 2h; Rate constant; Product distribution; other catalysts (Co(II), Cr(III) or mixture), other times;;A n/a
B n/a
C n/a
D 42%
E n/a
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

sodium acetate
127-09-3

sodium acetate

A

p-nitrobenzylidyne tribromide
14505-17-0

p-nitrobenzylidyne tribromide

B

1-dibromomethyl-4-nitro-benzene
619-75-0

1-dibromomethyl-4-nitro-benzene

C

4-nitrobenzyl acetate
619-90-9

4-nitrobenzyl acetate

D

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

E

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

Conditions
ConditionsYield
With dipotassium peroxodisulfate; lithium bromide In acetic acid at 115℃; for 6h; Product distribution; Mechanism; benzylic oxidation, benzylic bromination-acetoxylation, other reactions conditions and other alkylbenzenes;A n/a
B 2%
C 38%
D 1%
E n/a
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

2,2'-azobis(isobutyronitrile)
78-67-1

2,2'-azobis(isobutyronitrile)

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
at 80℃; Kinetics; Irradiation;
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

hexabromobenzene
87-82-1

hexabromobenzene

A

4-nitrobenzyl chloride
100-14-1

4-nitrobenzyl chloride

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
at 200℃; Einleiten von Chlor;
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

α,α,α-tribromoacetophenone
7402-45-1

α,α,α-tribromoacetophenone

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
at 160℃;
4-nitrobenzyl chloride
100-14-1

4-nitrobenzyl chloride

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Equilibrium constant; Δ G;
With ethanol; potassium iodide; potassium bromide
Multi-step reaction with 2 steps
1: 66 percent / HCl / 15 h / Heating
2: conc. HBr / Heating; overnight
View Scheme
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

A

2-bromo-4-nitrotoluene
7745-93-9

2-bromo-4-nitrotoluene

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; sodium bromide In water; trifluoroacetic acid for 168h; Ambient temperature; Yield given. Yields of byproduct given;
4-nitrobenzyl iodide
3145-86-6

4-nitrobenzyl iodide

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With tributyltin bromide In pyridine at 50℃; Thermodynamic data; Δ G;38 % Spectr.
silver-salt of/the/ <4-nitro-phenyl>-acetic acid

silver-salt of/the/ <4-nitro-phenyl>-acetic acid

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With tetrachloromethane; bromine
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Bromotrichloromethane
75-62-7

Bromotrichloromethane

<4-NO2C6H4CH2Co(dmgH)2Py>

<4-NO2C6H4CH2Co(dmgH)2Py>

A

1,1,1-trichloro-2-(4-nitrophenyl)-ethane
2201-11-8

1,1,1-trichloro-2-(4-nitrophenyl)-ethane

B

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With 1H-imidazole In chloroform at 70℃; for 5h; Title compound not separated from byproducts;
4-nitrobenzyl nitrate
15539-77-2

4-nitrobenzyl nitrate

N-benzylpyridinium bromide
2589-31-3

N-benzylpyridinium bromide

acetone
67-64-1

acetone

A

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

B

1-benzyl-pyridinium nitrate

1-benzyl-pyridinium nitrate

Conditions
ConditionsYield
at 20℃; Kinetics; sowie bei 40grad;
at 20℃; sowie bei 40grad; Gleichgewicht der Reaktion;
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

bromine
7726-95-6

bromine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
at 150℃; UV-Licht.Irradiation;
at 125 - 130℃;
tetrachloromethane
56-23-5

tetrachloromethane

2,2'-azobis(isobutyronitrile)
78-67-1

2,2'-azobis(isobutyronitrile)

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

bromine
7726-95-6

bromine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
at 80℃; Kinetics; Irradiation;
4'-(nitrobenzyl) 4-nitrobenzoate
3481-11-6

4'-(nitrobenzyl) 4-nitrobenzoate

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

A

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

B

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

picoline
108-89-4

picoline

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-methyl-N-(4-nitrobenzyl)pyridinium bromide
57042-61-2

4-methyl-N-(4-nitrobenzyl)pyridinium bromide

Conditions
ConditionsYield
In acetone; benzene at 20℃; for 24h;100%
In dichloromethane at 20℃; for 2h;46%
3-methyl-phenol
108-39-4

3-methyl-phenol

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

(4-nitro-benzyl)-m-tolyl ether

(4-nitro-benzyl)-m-tolyl ether

Conditions
ConditionsYield
With sodium hydroxide In water for 0.00416667h; microwave irradiation;100%
With alkaline solution
p-cresol
106-44-5

p-cresol

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-methylphenyl 4-nitrobenzyl ether
67565-47-3

4-methylphenyl 4-nitrobenzyl ether

Conditions
ConditionsYield
With sodium hydroxide In water for 0.00277778h; microwave irradiation;100%
With sodium hydroxide; Aliquat 360 In dichloromethane; water at 25℃; for 24h;89%
With potassium carbonate; acetone
With alkaline solution
potassium acetate
127-08-2

potassium acetate

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-nitrobenzyl acetate
619-90-9

4-nitrobenzyl acetate

Conditions
ConditionsYield
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane at 40℃; for 24h;100%
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane; water at 40℃; for 24h;100%
"octopus-type" calixarene 1 In dichloromethane; water at 40℃; for 24h; Product distribution; other catalysts, content of water, other carboxylates;100%
With ethanol
5,11,17,23,29,35-hexa-....-calix<6>arene In dichloromethane at 40℃; for 24h; influence of other catalysts;
potassium phtalimide
1074-82-4

potassium phtalimide

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

2-(4-nitrobenzyl)-1H-isoindole-1,3(2H)-dione
62133-07-7

2-(4-nitrobenzyl)-1H-isoindole-1,3(2H)-dione

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;100%
In N,N-dimethyl-formamide99%
In N,N-dimethyl-formamide99%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; dimethyl selenoxide In acetonitrile for 5h; Heating;100%
With 2-dimethylamino-N,N-dimethylaniline N-oxide In acetonitrile at 25℃; for 24h; Oxidation;97%
With potassium hydrogencarbonate; dimethyl sulfoxide for 0.0333333h; Microwave irradiation;97%
triphenylphosphine
603-35-0

triphenylphosphine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

(p-nitrobenzyl)triphenylphosphonium bromide
2767-70-6

(p-nitrobenzyl)triphenylphosphonium bromide

Conditions
ConditionsYield
With sodium hydride; m-Chlorobenzaldehyde In toluene for 12h; Reflux;100%
In toluene Reflux;99%
In toluene Heating;98.6%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

p-nitrobenzyl azide
17271-88-4

p-nitrobenzyl azide

Conditions
ConditionsYield
With sodium azide In dimethyl sulfoxide100%
With sodium azide In dimethyl sulfoxide at 20℃;100%
With sodium azide In water; acetone at 20℃; for 6h;99%
morpholine
110-91-8

morpholine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-(4-nitrobenzyl)morpholine
6425-46-3

4-(4-nitrobenzyl)morpholine

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 3h;100%
With sodium hydroxide In 1,4-dioxane; water at 20℃; for 0.25h;97%
Stage #1: 1-bromomethyl-4-nitro-benzene With potassium carbonate In dichloromethane for 0.333333h; Cooling with ice; Inert atmosphere;
Stage #2: morpholine In 1,2-dichloro-ethane at 20℃; Cooling with ice; Inert atmosphere;
97.16%
pyridine
110-86-1

pyridine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

N-(4-nitrobenzyl)pyridinium bromide
4329-73-1

N-(4-nitrobenzyl)pyridinium bromide

Conditions
ConditionsYield
In acetone; benzene at 20℃; for 24h;100%
at 20℃; for 12h;88%
In nitrobenzene at 40℃; Rate constant; Mechanism;
1,4-diaza-bicyclo[2.2.2]octane
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-aza-1-p-nitrobenzylazoniabicyclo<2.2.2>octane bromide
136497-64-8

4-aza-1-p-nitrobenzylazoniabicyclo<2.2.2>octane bromide

Conditions
ConditionsYield
In diethyl ether for 20h;100%
In diethyl ether97%
1,1,3,3-tetramethyl-2-thiourea
2782-91-4

1,1,3,3-tetramethyl-2-thiourea

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1,1,3,3-tetramethyl-2-(4-nitrobenzyl)thiouronium bromide

1,1,3,3-tetramethyl-2-(4-nitrobenzyl)thiouronium bromide

Conditions
ConditionsYield
at 20℃; for 12h;100%
In ethanol for 0.5h; Heating;95%
Penicillin G potassium
113-98-4

Penicillin G potassium

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

p-nitrobenzyl benzylpenicillinate
27487-21-4

p-nitrobenzyl benzylpenicillinate

Conditions
ConditionsYield
18-crown-6 ether In acetonitrile for 24h; Ambient temperature;100%
Stage #1: Penicillin G potassium; 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 42 - 45℃; for 2h; Large scale;
Stage #2: With acetonyl hydroperoxide at 0 - 5℃; for 2h; Large scale;
Stage #1: Penicillin G potassium; 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20 - 45℃; for 2h; Large scale;
Stage #2: With sulfuric acid In dichloromethane; water at -5 - 0℃; pH=< 5; Large scale;
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

sodium 4-nitrobenzylsulfanesulfonate
94039-56-2

sodium 4-nitrobenzylsulfanesulfonate

Conditions
ConditionsYield
With sodium thiosulfate In water; toluene100%
With Sodium thiosulfate pentahydrate In methanol; water at 65℃; for 3 - 24h;
isonicotinic acid ethylester
1570-45-2

isonicotinic acid ethylester

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

4-ethoxycarbonyl-N-(4-nitrobenzyl)pyridinium bromide

4-ethoxycarbonyl-N-(4-nitrobenzyl)pyridinium bromide

Conditions
ConditionsYield
In acetone; benzene at 20℃; for 24h;100%
N-tert-butyloxycarbonyl-S-trityl-L-cysteine
21947-98-8, 87494-13-1

N-tert-butyloxycarbonyl-S-trityl-L-cysteine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Boc-Cys(Trt)-PNB
566916-29-8

Boc-Cys(Trt)-PNB

Conditions
ConditionsYield
Stage #1: N-tert-butyloxycarbonyl-S-trityl-L-cysteine With caesium carbonate In ethanol pH=10;
Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; for 12h; Further stages.;
100%
SEC-BUTYLAMINE
33966-50-6

SEC-BUTYLAMINE

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

N-(sec-butyl)-(4-nitrobenzyl)amine
838824-14-9

N-(sec-butyl)-(4-nitrobenzyl)amine

Conditions
ConditionsYield
In DMF (N,N-dimethyl-formamide) at 20℃;100%
bis-(3-hydroxypropyl)amine
14002-33-6

bis-(3-hydroxypropyl)amine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

N-(p-nitrobenzyl)-dipropropanolamine
881169-78-4

N-(p-nitrobenzyl)-dipropropanolamine

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 55 - 60℃; for 2h;100%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1-methyl-3-(4-nitrobenzyl)-2,4-imidazolidinedione
873537-31-6

1-methyl-3-(4-nitrobenzyl)-2,4-imidazolidinedione

Conditions
ConditionsYield
Stage #1: 1-methyldiazolidine-2,4-dione With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; for 0.5h;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran; N,N-dimethyl-formamide at 20℃;
100%
decahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene
72738-47-7

decahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

perhydro-3a-(4-nitrobenzyl)-3a,5a,8a,10a-tetraazapyrenium bromide
1021925-74-5

perhydro-3a-(4-nitrobenzyl)-3a,5a,8a,10a-tetraazapyrenium bromide

Conditions
ConditionsYield
In acetonitrile for 48h;100%
(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-5-hydroxy-4-((2-methoxyethoxy)methoxy)-2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione
1192030-70-8

(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-5-hydroxy-4-((2-methoxyethoxy)methoxy)-2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-4-((2-methoxyethoxy)methoxy)-2-methyl-5-(4-nitrobenzyloxy)-1,2,3,4-tetrahydroanthracene-9,10-dione
1192030-84-4

(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-4-((2-methoxyethoxy)methoxy)-2-methyl-5-(4-nitrobenzyloxy)-1,2,3,4-tetrahydroanthracene-9,10-dione

Conditions
ConditionsYield
With silver(l) oxide In N,N-dimethyl-formamide at 25℃; for 2h; Inert atmosphere;100%
Cyclopentamine
1003-03-8

Cyclopentamine

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

N,N-bis(4-nitrobenzyl)cyclopentanamine
1252601-24-3

N,N-bis(4-nitrobenzyl)cyclopentanamine

Conditions
ConditionsYield
Stage #1: Cyclopentamine With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h;
Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; for 2h;
100%
With potassium carbonate In N,N-dimethyl-formamide
C19H20N2
946415-03-8

C19H20N2

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

C26H26N3O2(1+)*I(1-)
1255528-55-2

C26H26N3O2(1+)*I(1-)

Conditions
ConditionsYield
With sodium iodide In acetone at 20℃; for 18h;100%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

(S)-3-benzyl-5-phenyl-1,3-dihydro-2H-benzo[e][1,4]diazepin-2-one
884492-66-4

(S)-3-benzyl-5-phenyl-1,3-dihydro-2H-benzo[e][1,4]diazepin-2-one

(S)-3-benzyl-1-(4-nitrobenzyl)-5-phenyl-1H-benzo[e][1,4]-diazepin-2(3H)-one
1289116-75-1

(S)-3-benzyl-1-(4-nitrobenzyl)-5-phenyl-1H-benzo[e][1,4]-diazepin-2(3H)-one

Conditions
ConditionsYield
Stage #1: (S)-3-benzyl-5-phenyl-1,3-dihydro-2H-benzo[e][1,4]diazepin-2-one With sodium hydride In N,N-dimethyl-formamide for 1.5h; Inert atmosphere;
Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; Inert atmosphere;
100%
1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one
1314917-55-9

1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

C26H25NO11
1314917-90-2

C26H25NO11

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 6h;100%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

(3,5-dimethyl-1H-pyrazol-4-yl)acetic acid methyl ester
56699-23-1

(3,5-dimethyl-1H-pyrazol-4-yl)acetic acid methyl ester

[3,5-dimethyl-1-(4-nitro-benzyl)-1H-pyrazol-4-yl]-acetic acid methyl ester
1322081-35-5

[3,5-dimethyl-1-(4-nitro-benzyl)-1H-pyrazol-4-yl]-acetic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃; for 1h;100%
With potassium carbonate In acetonitrile at 20℃; for 1h;100%
With potassium carbonate In acetonitrile at 20℃; for 1h;
With potassium carbonate In acetonitrile at 20℃; for 1h;7.5 g
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis(2,6-diisopropylphenyl)-2-(4-nitrobenzylidene)-2,3-dihydro-1H-imidazole
1357448-32-8

1,3-bis(2,6-diisopropylphenyl)-2-(4-nitrobenzylidene)-2,3-dihydro-1H-imidazole

Conditions
ConditionsYield
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate In tetrahydrofuran at 20℃; for 8h; Inert atmosphere;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 20℃; for 38h; Inert atmosphere;
100%
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate; sodium hydride In tetrahydrofuran at 25℃; for 0.25h; Schlenk technique; Inert atmosphere;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 48℃; for 72h; Schlenk technique; Inert atmosphere;
61%
ethyl p-methoxyphenylacetate
14062-18-1

ethyl p-methoxyphenylacetate

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

ethyl 2-(4-methoxyphenyl)-3-(4-nitrophenyl)propanoate
1428333-35-0

ethyl 2-(4-methoxyphenyl)-3-(4-nitrophenyl)propanoate

Conditions
ConditionsYield
Stage #1: ethyl p-methoxyphenylacetate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 25℃; for 12h;
100%

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