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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or grey white crytal Storage:Store in sealed container
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inquiryAppearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:By Sea/Air/Courier Port:Qingdao
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiryProduct Name 4-Nitrobenzyl bromide CAS No 100-11-8 Quality standard Index name
Cas:100-11-8
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inquiryProduct name: 4-Nitrobenzyl Bromide CAS No.:100-11-8 Molecule Formula:C7H6BrNO2 Molecule Weight:216.03 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITE
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inquiryWe are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED
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inquiryHigh qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar
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R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou
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Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
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inquiryBest service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier
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Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
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100-11-8 Application:intermediate
Cas:100-11-8
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inquiry4-Nitrobenzyl bromideAppearance:White or Almost White crystalline powder Storage:Store in refrigerator Package:Disguised package Application:Steroids injection For Body building Transportation:By Express or By Air
Conditions | Yield |
---|---|
Stage #1: 4-nitrobenzyl chloride With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere; Stage #2: With tetrabutylammomium bromide at 20℃; Sealed tube; Inert atmosphere; | 100% |
With N-Bromosuccinimide; triphenylphosphine for 0.00555556h; microwave irradiation; | 98% |
Stage #1: 4-nitrobenzyl chloride With diisopropyl-carbodiimide; copper(II) bis(trifluoromethanesulfonate) In tetrahydrofuran at 100℃; for 0.0833333h; microwave irradiation; Stage #2: With Acetyl bromide In tetrahydrofuran at 150℃; for 0.0833333h; microwave irradiation; Further stages.; | 98% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reagent/catalyst; Reflux; | 100% |
With 2,2'-azobis(isobutyronitrile); hydrogen bromide; dihydrogen peroxide at 70 - 120℃; Reagent/catalyst; Temperature; | 99.3% |
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Reflux; | 95% |
Conditions | Yield |
---|---|
With sulfuric acid; silica gel; tetramethylammonium nitrate for 0.0333333h; | 97% |
With sulfuric acid; nitric acid at 0 - 5℃; |
2-(4-nitrobenzyloxy)tetrahydro-2H-pyran
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With 4-aminophenyl diphenylphosphinite; bromine In dichloromethane at 20℃; for 1.25h; | 95% |
4-nitrobenzyl trimethylsilyl ether
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With 4-aminophenyl diphenylphosphinite; bromine In dichloromethane at 20℃; for 0.833333h; | 95% |
4-nitro-1-[(ethoxymethoxy)methyl]benzene
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With phosphotungstic acid; tetrabutylammomium bromide at 130 - 142℃; for 0.00833333h; Microwave irradiation; Ionic liquid; chemoselective reaction; | 94% |
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0333333h; Microwave irradiation; Neat (no solvent); chemoselective reaction; | 85% |
Conditions | Yield |
---|---|
With polymethylhydrosiloxane; dimethylbromosulphonium bromide In chloroform at 20℃; for 8h; | 92% |
With Dichloromethylsilane; phosphorus tribromide; iron(III) chloride In acetonitrile for 6h; Heating; | 92% |
With isopinocampheyl-boron dibromide dimethylsulfide complex In hexane at 20℃; for 10h; Reduction; bromination; | 65% |
1-methyl-4-nitrobenzene
A
1-dibromomethyl-4-nitro-benzene
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In acetonitrile at 60℃; for 0.833333h; Time; Temperature; Flow reactor; Irradiation; | A n/a B 86% |
With N-Bromosuccinimide for 0.15h; microwave irradiation; | A 20% B 70% |
With hydrogen bromide; sodium bromide In chloroform; water at 5 - 15℃; Electrolysis; | A 50% B 50% |
With N-Bromosuccinimide In Methyl formate Product distribution; with other ten solvents; ylied (max) and selektivity was determined; | |
With N-Bromosuccinimide at 36℃; for 16h; Irradiation; neat (no solvent); |
1-((methoxymethoxy)methyl)-4-nitrobenzene
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0333333h; Microwave irradiation; Neat (no solvent); chemoselective reaction; | 86% |
Conditions | Yield |
---|---|
With triphenylphosphine In n-heptane; dichloromethane; ethyl acetate | 85% |
With triphenylphosphine In n-heptane; dichloromethane; ethyl acetate | 85% |
4-nitrobenzyl chloride
ammonium acetate
A
4-nitrobenzyl acetate
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With N-Bromosuccinimide; triphenylphosphine In acetonitrile at 20℃; for 12h; Cooling with ice; | A 80% B 10% |
N-bromo-S-(p-nitrobenzyl)-S-phenylsulfoximide
A
S-(p-nitrobenzyl)-S-phenylsulfoximide
B
S-(α-bromo-p-nitrobenzyl)-S-phenylsulfoximide
C
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
In ethanol; chloroform for 5h; Product distribution; Ambient temperature; further solvents, reaction times; | A 72.9% B 16% C n/a |
1-Amino-3-p-nitrobenzylthiopropanephosphonic acid
A
(1RS,8RS)-diamino-4,5-dithiaoctane-1,8-diphosphonic acid
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With hydrogen bromide Heating; overnight; | A 65% B n/a |
1-methyl-4-nitrobenzene
acetic anhydride
A
4-nitrobenzyl chloride
B
4-nitrobenzyl acetate
C
4-nitrobenzaldehdye
D
4-nitrobenzylidene diacetate
E
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With sulfuric acid; ozone; potassium bromide; manganese(II) In acetic acid at 10℃; for 2h; Rate constant; Product distribution; other catalysts (Co(II), Cr(III) or mixture), other times;; | A n/a B n/a C n/a D 42% E n/a |
1-methyl-4-nitrobenzene
sodium acetate
A
p-nitrobenzylidyne tribromide
B
1-dibromomethyl-4-nitro-benzene
C
4-nitrobenzyl acetate
D
1-bromomethyl-4-nitro-benzene
E
4-nitro-benzoic acid
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate; lithium bromide In acetic acid at 115℃; for 6h; Product distribution; Mechanism; benzylic oxidation, benzylic bromination-acetoxylation, other reactions conditions and other alkylbenzenes; | A n/a B 2% C 38% D 1% E n/a |
tetrachloromethane
N-Bromosuccinimide
2,2'-azobis(isobutyronitrile)
1-methyl-4-nitrobenzene
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
at 80℃; Kinetics; Irradiation; |
tetrachloromethane
N-Bromosuccinimide
1-methyl-4-nitrobenzene
1-bromomethyl-4-nitro-benzene
1-methyl-4-nitrobenzene
hexabromobenzene
A
4-nitrobenzyl chloride
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
at 200℃; Einleiten von Chlor; |
1-methyl-4-nitrobenzene
α,α,α-tribromoacetophenone
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
at 160℃; |
Conditions | Yield |
---|---|
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Equilibrium constant; Δ G; | |
With ethanol; potassium iodide; potassium bromide | |
Multi-step reaction with 2 steps 1: 66 percent / HCl / 15 h / Heating 2: conc. HBr / Heating; overnight View Scheme |
1-methyl-4-nitrobenzene
A
2-bromo-4-nitrotoluene
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With ammonium cerium(IV) nitrate; sodium bromide In water; trifluoroacetic acid for 168h; Ambient temperature; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With tributyltin bromide In pyridine at 50℃; Thermodynamic data; Δ G; | 38 % Spectr. |
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With tetrachloromethane; bromine |
4-nitrobenzyl chloride
hydrogen bromide
1-bromomethyl-4-nitro-benzene
Bromotrichloromethane
A
1,1,1-trichloro-2-(4-nitrophenyl)-ethane
B
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
With 1H-imidazole In chloroform at 70℃; for 5h; Title compound not separated from byproducts; |
4-nitrobenzyl nitrate
N-benzylpyridinium bromide
acetone
A
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
at 20℃; Kinetics; sowie bei 40grad; | |
at 20℃; sowie bei 40grad; Gleichgewicht der Reaktion; |
Conditions | Yield |
---|---|
at 150℃; UV-Licht.Irradiation; | |
at 125 - 130℃; |
tetrachloromethane
2,2'-azobis(isobutyronitrile)
1-methyl-4-nitrobenzene
bromine
1-bromomethyl-4-nitro-benzene
Conditions | Yield |
---|---|
at 80℃; Kinetics; Irradiation; |
4'-(nitrobenzyl) 4-nitrobenzoate
hydrogen bromide
A
1-bromomethyl-4-nitro-benzene
B
4-nitro-benzoic acid
picoline
1-bromomethyl-4-nitro-benzene
4-methyl-N-(4-nitrobenzyl)pyridinium bromide
Conditions | Yield |
---|---|
In acetone; benzene at 20℃; for 24h; | 100% |
In dichloromethane at 20℃; for 2h; | 46% |
Conditions | Yield |
---|---|
With sodium hydroxide In water for 0.00416667h; microwave irradiation; | 100% |
With alkaline solution |
p-cresol
1-bromomethyl-4-nitro-benzene
4-methylphenyl 4-nitrobenzyl ether
Conditions | Yield |
---|---|
With sodium hydroxide In water for 0.00277778h; microwave irradiation; | 100% |
With sodium hydroxide; Aliquat 360 In dichloromethane; water at 25℃; for 24h; | 89% |
With potassium carbonate; acetone | |
With alkaline solution |
Conditions | Yield |
---|---|
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane at 40℃; for 24h; | 100% |
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane; water at 40℃; for 24h; | 100% |
"octopus-type" calixarene 1 In dichloromethane; water at 40℃; for 24h; Product distribution; other catalysts, content of water, other carboxylates; | 100% |
With ethanol | |
5,11,17,23,29,35-hexa-....-calix<6>arene In dichloromethane at 40℃; for 24h; influence of other catalysts; |
potassium phtalimide
1-bromomethyl-4-nitro-benzene
2-(4-nitrobenzyl)-1H-isoindole-1,3(2H)-dione
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 2h; | 100% |
In N,N-dimethyl-formamide | 99% |
In N,N-dimethyl-formamide | 99% |
Conditions | Yield |
---|---|
With dipotassium hydrogenphosphate; dimethyl selenoxide In acetonitrile for 5h; Heating; | 100% |
With 2-dimethylamino-N,N-dimethylaniline N-oxide In acetonitrile at 25℃; for 24h; Oxidation; | 97% |
With potassium hydrogencarbonate; dimethyl sulfoxide for 0.0333333h; Microwave irradiation; | 97% |
triphenylphosphine
1-bromomethyl-4-nitro-benzene
(p-nitrobenzyl)triphenylphosphonium bromide
Conditions | Yield |
---|---|
With sodium hydride; m-Chlorobenzaldehyde In toluene for 12h; Reflux; | 100% |
In toluene Reflux; | 99% |
In toluene Heating; | 98.6% |
1-bromomethyl-4-nitro-benzene
p-nitrobenzyl azide
Conditions | Yield |
---|---|
With sodium azide In dimethyl sulfoxide | 100% |
With sodium azide In dimethyl sulfoxide at 20℃; | 100% |
With sodium azide In water; acetone at 20℃; for 6h; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In dimethyl sulfoxide at 90℃; for 3h; | 100% |
With sodium hydroxide In 1,4-dioxane; water at 20℃; for 0.25h; | 97% |
Stage #1: 1-bromomethyl-4-nitro-benzene With potassium carbonate In dichloromethane for 0.333333h; Cooling with ice; Inert atmosphere; Stage #2: morpholine In 1,2-dichloro-ethane at 20℃; Cooling with ice; Inert atmosphere; | 97.16% |
pyridine
1-bromomethyl-4-nitro-benzene
N-(4-nitrobenzyl)pyridinium bromide
Conditions | Yield |
---|---|
In acetone; benzene at 20℃; for 24h; | 100% |
at 20℃; for 12h; | 88% |
In nitrobenzene at 40℃; Rate constant; Mechanism; |
1,4-diaza-bicyclo[2.2.2]octane
1-bromomethyl-4-nitro-benzene
4-aza-1-p-nitrobenzylazoniabicyclo<2.2.2>octane bromide
Conditions | Yield |
---|---|
In diethyl ether for 20h; | 100% |
In diethyl ether | 97% |
Conditions | Yield |
---|---|
at 20℃; for 12h; | 100% |
In ethanol for 0.5h; Heating; | 95% |
Penicillin G potassium
1-bromomethyl-4-nitro-benzene
p-nitrobenzyl benzylpenicillinate
Conditions | Yield |
---|---|
18-crown-6 ether In acetonitrile for 24h; Ambient temperature; | 100% |
Stage #1: Penicillin G potassium; 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 42 - 45℃; for 2h; Large scale; Stage #2: With acetonyl hydroperoxide at 0 - 5℃; for 2h; Large scale; | |
Stage #1: Penicillin G potassium; 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20 - 45℃; for 2h; Large scale; Stage #2: With sulfuric acid In dichloromethane; water at -5 - 0℃; pH=< 5; Large scale; |
1-bromomethyl-4-nitro-benzene
sodium 4-nitrobenzylsulfanesulfonate
Conditions | Yield |
---|---|
With sodium thiosulfate In water; toluene | 100% |
With Sodium thiosulfate pentahydrate In methanol; water at 65℃; for 3 - 24h; |
Conditions | Yield |
---|---|
In acetone; benzene at 20℃; for 24h; | 100% |
N-tert-butyloxycarbonyl-S-trityl-L-cysteine
1-bromomethyl-4-nitro-benzene
Boc-Cys(Trt)-PNB
Conditions | Yield |
---|---|
Stage #1: N-tert-butyloxycarbonyl-S-trityl-L-cysteine With caesium carbonate In ethanol pH=10; Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; for 12h; Further stages.; | 100% |
SEC-BUTYLAMINE
1-bromomethyl-4-nitro-benzene
N-(sec-butyl)-(4-nitrobenzyl)amine
Conditions | Yield |
---|---|
In DMF (N,N-dimethyl-formamide) at 20℃; | 100% |
bis-(3-hydroxypropyl)amine
1-bromomethyl-4-nitro-benzene
N-(p-nitrobenzyl)-dipropropanolamine
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile at 55 - 60℃; for 2h; | 100% |
1-bromomethyl-4-nitro-benzene
1-methyl-3-(4-nitrobenzyl)-2,4-imidazolidinedione
Conditions | Yield |
---|---|
Stage #1: 1-methyldiazolidine-2,4-dione With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; for 0.5h; Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; | 100% |
decahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene
1-bromomethyl-4-nitro-benzene
perhydro-3a-(4-nitrobenzyl)-3a,5a,8a,10a-tetraazapyrenium bromide
Conditions | Yield |
---|---|
In acetonitrile for 48h; | 100% |
(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-5-hydroxy-4-((2-methoxyethoxy)methoxy)-2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione
1-bromomethyl-4-nitro-benzene
(1R,2R,4S)-1-((S)-1-(tert-butyldiphenylsilyloxy)ethyl)-4-((2-methoxyethoxy)methoxy)-2-methyl-5-(4-nitrobenzyloxy)-1,2,3,4-tetrahydroanthracene-9,10-dione
Conditions | Yield |
---|---|
With silver(l) oxide In N,N-dimethyl-formamide at 25℃; for 2h; Inert atmosphere; | 100% |
Cyclopentamine
1-bromomethyl-4-nitro-benzene
N,N-bis(4-nitrobenzyl)cyclopentanamine
Conditions | Yield |
---|---|
Stage #1: Cyclopentamine With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h; Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; for 2h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide |
Conditions | Yield |
---|---|
With sodium iodide In acetone at 20℃; for 18h; | 100% |
1-bromomethyl-4-nitro-benzene
(S)-3-benzyl-5-phenyl-1,3-dihydro-2H-benzo[e][1,4]diazepin-2-one
(S)-3-benzyl-1-(4-nitrobenzyl)-5-phenyl-1H-benzo[e][1,4]-diazepin-2(3H)-one
Conditions | Yield |
---|---|
Stage #1: (S)-3-benzyl-5-phenyl-1,3-dihydro-2H-benzo[e][1,4]diazepin-2-one With sodium hydride In N,N-dimethyl-formamide for 1.5h; Inert atmosphere; Stage #2: 1-bromomethyl-4-nitro-benzene In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | 100% |
1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one
1-bromomethyl-4-nitro-benzene
C26H25NO11
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 6h; | 100% |
1-bromomethyl-4-nitro-benzene
(3,5-dimethyl-1H-pyrazol-4-yl)acetic acid methyl ester
[3,5-dimethyl-1-(4-nitro-benzyl)-1H-pyrazol-4-yl]-acetic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile at 20℃; for 1h; | 100% |
With potassium carbonate In acetonitrile at 20℃; for 1h; | 100% |
With potassium carbonate In acetonitrile at 20℃; for 1h; | |
With potassium carbonate In acetonitrile at 20℃; for 1h; | 7.5 g |
1-bromomethyl-4-nitro-benzene
1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
1,3-bis(2,6-diisopropylphenyl)-2-(4-nitrobenzylidene)-2,3-dihydro-1H-imidazole
Conditions | Yield |
---|---|
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate In tetrahydrofuran at 20℃; for 8h; Inert atmosphere; Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 20℃; for 38h; Inert atmosphere; | 100% |
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate; sodium hydride In tetrahydrofuran at 25℃; for 0.25h; Schlenk technique; Inert atmosphere; Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 48℃; for 72h; Schlenk technique; Inert atmosphere; | 61% |
ethyl p-methoxyphenylacetate
1-bromomethyl-4-nitro-benzene
ethyl 2-(4-methoxyphenyl)-3-(4-nitrophenyl)propanoate
Conditions | Yield |
---|---|
Stage #1: ethyl p-methoxyphenylacetate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 25℃; for 12h; | 100% |
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