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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride Manufacturer/High quality/Best price/In stock

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,3-Bis(2,6-Diisopropylphenyl)Imidazolium Chloride with high purity

Cas:250285-32-6

Min.Order:1 Kilogram

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Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,3-Bis(2,6-Diisopropylphenyl)Imidazolium Chloride

Cas:250285-32-6

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant produc

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3-Bis-[2,6-bis-(1-methylethyl)-phenyl]-1H-imidazolium chloride

Cas:250285-32-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details CAS: 250285-32-6 MF: C27H37ClN2 MW: 425.05 EINECS: 627-434-9 Product Categories: organic amine;Achiral Nitrogen;Imidazolium Compounds;Lig

China Largest factory Manufacturer Supply 1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride CAS 250285-32-6

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE Basic information Product Name: 1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE Synonyms: 1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOLIUM

250285-32-6

Cas:250285-32-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride CAS:250285-32-6

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $2.0 / 5.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Hot product CAS 250285-32-6 with high-quality service

Cas:250285-32-6

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE CAS Number 250285-32-6 Synonyms 1,3-Bis(2,6-diisopropylphenyl)imidazoliumchloride,97%;1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLI&;1,3-BIS[2,6-BIS

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $32.0 / 40.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride CAS:250285-32-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, speciali

1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride CAS:250285-32-6

Cas:250285-32-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:250285-32-6

Cas:250285-32-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1,3-Bis(2,6-Diisopropylphenyl)Imidazolium Chloride

Cas:250285-32-6

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride

Cas:250285-32-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE

Cas:250285-32-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE

Cas:250285-32-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride

Cas:250285-32-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE

Cas:250285-32-6

Min.Order:1 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,3-bis(2,6-di-i-propylphenyl)iMidazoliuM chloride/High quality/Best price

Cas:250285-32-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride CAS NO.250285-32-6

Cas:250285-32-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE

Cas:250285-32-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUMCHLORIDE

Cas:250285-32-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIUM CHLORIDE Chemical Properties Melting point 278 °C (dec.)(lit.) form Powder color White, off-white or tan Water Solubility Slightly soluble in water. Sensitive Hygroscopic InChIKey A

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:200 Kilogram

FOB Price: $64.0

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride

Cas:250285-32-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

Cas:250285-32-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride

Cas:250285-32-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Synthetic route

C34H50Cl2N4Pd
1207373-09-8

C34H50Cl2N4Pd

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform-d1 at 20℃; for 12h; Inert atmosphere;100%
formaldehyd
50-00-0

formaldehyd

1,2-bis(2,6-diisopropylphenylimino)ethane
74663-75-5

1,2-bis(2,6-diisopropylphenylimino)ethane

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2h;97%
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2h; Inert atmosphere; Glovebox;87%
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2.75h; Inert atmosphere;86%
1,2-bis(2,6-diisopropylphenylimino)ethane
74663-75-5

1,2-bis(2,6-diisopropylphenylimino)ethane

ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h; Molecular sieve; Inert atmosphere;94%
With air In tetrahydrofuran; water at 40℃; for 16h; Solvent;65%
With water In tetrahydrofuran at 40℃; for 16h; Condensation;47%
formaldehyd
50-00-0

formaldehyd

(1E,2E)-N1,N2-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine
74663-75-5

(1E,2E)-N1,N2-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2h;90%
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2h;89%
With hydrogenchloride In 1,4-dioxane; ethyl acetate at 20℃; for 17h;86%
Stage #1: formaldehyd; (1E,2E)-N1,N2-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine In toluene at 100℃; Formylation;
Stage #2: With hydrogenchloride In 1,4-dioxane; toluene at 70℃; for 5h; chloridation;
47%
With hydrogenchloride In 1,4-dioxane; ethyl acetate at 20℃; Heating;41%
formaldehyd
50-00-0

formaldehyd

Glyoxal
131543-46-9

Glyoxal

2,6-diisopropylbenzenamine
24544-04-5

2,6-diisopropylbenzenamine

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With hydrogenchloride In methanol for 36h; Reflux;84.6%
chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I)
578743-87-0

chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I)

A

1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-one
1060651-05-9

1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-one

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With air In dimethylsulfoxide-d6 at 150℃; for 155h;A 16%
B 81%
With water; oxygen In dimethylsulfoxide-d6 at 150℃; for 155h; Kinetics; Sealed tube;A 16 %Spectr.
B 81 %Spectr.
methanol
67-56-1

methanol

1,2-bis(2,6-diisopropylphenylimino)ethane
74663-75-5

1,2-bis(2,6-diisopropylphenylimino)ethane

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Stage #1: methanol; 1,2-bis(2,6-diisopropylphenylimino)ethane With sodium tetrahydroborate In tetrahydrofuran at 0 - 20℃; for 3h;
Stage #2: With ammonium chloride In tetrahydrofuran
80%
1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene
244187-81-3

1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene

A

SiCl2*NHC

SiCl2*NHC

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With trichlorosilane In toluene at 25℃; for 12h; Inert atmosphere;A 79%
B n/a
1,2-bis(2,6-diisopropylphenylimino)ethane
74663-75-5

1,2-bis(2,6-diisopropylphenylimino)ethane

paracetaldehyde
123-63-7

paracetaldehyde

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With chloro-trimethyl-silane In ethyl acetate at 70℃; for 2.75h;76%
formaldehyd
50-00-0

formaldehyd

1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene

1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; 1,4-dioxane at 40℃; for 72h;58%
{1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(pyridine)palladium

{1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(pyridine)palladium

triethylamine
121-44-8

triethylamine

A

{1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(N-ethylethanamine)palladium

{1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(N-ethylethanamine)palladium

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 140℃; for 20h; Inert atmosphere; Schlenk technique; Sealed tube;A n/a
B 54%
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1,2-bis(2,6-diisopropylphenylimino)ethane
74663-75-5

1,2-bis(2,6-diisopropylphenylimino)ethane

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
at 40℃; for 16h; Sealed tube;52%
at 40℃; for 16h; Sealed tube;52%
2,6-diisopropylbenzenamine
24544-04-5

2,6-diisopropylbenzenamine

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 77.5 percent / formic acid / ethanol; H2O / 48 h
2.1: toluene / 100 °C
2.2: 47 percent / HCl / toluene; dioxane / 5 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1: 90 percent / propan-1-ol; H2O / 1 h / 70 °C
2: 47 percent / water / tetrahydrofuran / 16 h / 40 °C
View Scheme
Multi-step reaction with 2 steps
1: ethanol / 12 h / 20 °C
2: tetrahydrofuran / 18 h / 40 °C / Inert atmosphere
View Scheme
Glyoxal
131543-46-9

Glyoxal

2,6-diisopropylbenzenamine
24544-04-5

2,6-diisopropylbenzenamine

ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Inert atmosphere;
trans-[PdCl2(1,3-diethylimidazole)(1,3-(2,6-(i-Pr)2C6H3)2C3H2N2)]

trans-[PdCl2(1,3-diethylimidazole)(1,3-(2,6-(i-Pr)2C6H3)2C3H2N2)]

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Stage #1: trans-[PdCl2(1,3-diethylimidazole)(1,3-(2,6-(i-Pr)2C6H3)2C3H2N2)] With silver tetrafluoroborate In [D3]acetonitrile at 80℃; for 48h; Inert atmosphere;
Stage #2: With lithium chloride In [D3]acetonitrile Inert atmosphere;
C27H36Cl3N2P
1080030-15-4

C27H36Cl3N2P

1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene
244187-81-3

1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene

A

C54H72Cl2N4P(1+)*Cl(1-)

C54H72Cl2N4P(1+)*Cl(1-)

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
at -30 - 20℃; for 50h; Inert atmosphere;
1,3-bis(2,6-diisopropylphenyl)imidazolium fluoride

1,3-bis(2,6-diisopropylphenyl)imidazolium fluoride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With chloroform
1-(2,6-diisopropylphenyl)-1H-imidazole
25364-47-0

1-(2,6-diisopropylphenyl)-1H-imidazole

2-chloro-1,3-bis(1-methylethyl)benzene

2-chloro-1,3-bis(1-methylethyl)benzene

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In acetonitrile for 36h; Reflux; Inert atmosphere; Schlenk technique;
Glyoxal
131543-46-9

Glyoxal

2,6-diisopropylbenzenamine
24544-04-5

2,6-diisopropylbenzenamine

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With chloro-trimethyl-silane In formic acid
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 140℃; for 21h; Inert atmosphere; Schlenk technique; Sealed tube;21 %Chromat.
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(1-propylamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(1-propylamine)palladium

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 140℃; for 21h; Inert atmosphere; Schlenk technique; Sealed tube;18 %Chromat.
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N,N-diethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N,N-diethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 100℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;A 49 %Chromat.
B 41 %Chromat.
In N,N-dimethyl-formamide at 140℃; for 21h; Inert atmosphere; Schlenk technique; Sealed tube;A 32 %Chromat.
B 56 %Chromat.
Multi-step reaction with 2 steps
1: chloroform-d1 / 24 h / 40 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: N,N-dimethyl-formamide / 1 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N,N-diethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N,N-diethylethanamine)palladium

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 2 steps
1: triethylamine / chloroform-d1 / 60 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 3 steps
1: chloroform-d1 / 24 h / 40 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: 1,4-dioxane / 0.5 h / 50 °C / Inert atmosphere; Schlenk technique
3: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 3 steps
1: chloroform-d1 / 24 h / 40 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: 1,4-dioxane / 0.5 h / 50 °C / Inert atmosphere; Schlenk technique
3: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 3 steps
1: chloroform-d1 / 24 h / 40 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: N,N-dimethyl-formamide / 1 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
3: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(pyridine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(pyridine)palladium

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1,4-dioxane / 0.5 h / 50 °C / Inert atmosphere; Schlenk technique
2: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 2 steps
1: 1,4-dioxane / 0.5 h / 50 °C / Inert atmosphere; Schlenk technique
2: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide / 1 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: N,N-dimethyl-formamide / 21 h / 140 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(pyridine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(pyridine)palladium

triethylamine
121-44-8

triethylamine

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

{1,3-bis[2,6-di(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(dichloro)(N-ethylethanamine)palladium

B

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;A 33 %Chromat.
B 38 %Chromat.
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis(2,6-diisopropylphenyl)-2-(4-nitrobenzylidene)-2,3-dihydro-1H-imidazole
1357448-32-8

1,3-bis(2,6-diisopropylphenyl)-2-(4-nitrobenzylidene)-2,3-dihydro-1H-imidazole

Conditions
ConditionsYield
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate In tetrahydrofuran at 20℃; for 8h; Inert atmosphere;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 20℃; for 38h; Inert atmosphere;
100%
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate; sodium hydride In tetrahydrofuran at 25℃; for 0.25h; Schlenk technique; Inert atmosphere;
Stage #2: 1-bromomethyl-4-nitro-benzene In tetrahydrofuran at 48℃; for 72h; Schlenk technique; Inert atmosphere;
61%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

sodium cyclopentadienide

sodium cyclopentadienide

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

CpPd(IPr)Cl

CpPd(IPr)Cl

Conditions
ConditionsYield
With KO(tBu) In tetrahydrofuran Ar; Pd compd.(2.5 mmol), ligand (2.5 mmol), and KO(tBu) (2.5 mmol) in THF, stirred at room temp. for 12 h, THF soln. of NaCp (5 mmol) added, mixt. stirred overnight at room temp.; chromd.;99%
1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis(2,6-diisopropylphenyl)-1H-imidazole-2(3H)-thione
1311297-12-7

1,3-bis(2,6-diisopropylphenyl)-1H-imidazole-2(3H)-thione

Conditions
ConditionsYield
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With sulfur In acetone at 40℃; for 0.25h;
Stage #2: With triethylamine In acetone at 60℃;
99%
With potassium carbonate; sulfur In acetone at 60℃; for 16h; Reagent/catalyst;99%
With potassium tert-butylate; sulfur In tetrahydrofuran at 20℃;87%
2-Picolinic acid
98-98-6

2-Picolinic acid

palladium dichloride

palladium dichloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

C33H40ClN3O2Pd

C33H40ClN3O2Pd

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran for 12h; Inert atmosphere; Reflux;99%
With caesium carbonate In 1,4-dioxane at 80℃; for 20h; Schlenk technique; Inert atmosphere;65%
bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-cinnamyl)Cl2]

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-cinnamyl)Cl2]

Conditions
ConditionsYield
In acetone at 60℃; for 1h;99%
In neat (no solvent) for 0.0833333h; Solvent; Green chemistry;99%
In acetone at 60℃; for 1h;99%
bis(η3-allyl-μ-chloropalladium(II))

bis(η3-allyl-μ-chloropalladium(II))

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[IPrH][Pd(η3-allyl)Cl2]

[IPrH][Pd(η3-allyl)Cl2]

Conditions
ConditionsYield
In acetone at 60℃; for 1h;99%
In acetone at 60℃; for 1h;99%
(2-methylallyl)palladium-chloride dimer

(2-methylallyl)palladium-chloride dimer

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-2-Me-allyl)Cl2]

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-2-Me-allyl)Cl2]

Conditions
ConditionsYield
In neat (no solvent) for 0.0833333h; Green chemistry;99%
bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II)

bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II)

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-crotyl)Cl2]

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-crotyl)Cl2]

Conditions
ConditionsYield
In neat (no solvent) for 0.0833333h; Green chemistry;99%
[Pd(η3-tBu-indenyl)(μ-Cl)]2

[Pd(η3-tBu-indenyl)(μ-Cl)]2

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-tBu-indenyl)Cl2]

[N,N'-bis-[2,6-(di-iso-propyl)phenyl]imidazol-2-ylidene·H][Pd(η3-tBu-indenyl)Cl2]

Conditions
ConditionsYield
In neat (no solvent) for 0.0833333h; Green chemistry;99%
7,8-benzoquinoline
230-27-3

7,8-benzoquinoline

palladium dichloride

palladium dichloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

C40H44ClN3Pd

C40H44ClN3Pd

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 50℃; for 18h; Inert atmosphere;99%
bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II)

bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II)

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[IPr*·H][Pd(η3-crotyl)Cl2]

[IPr*·H][Pd(η3-crotyl)Cl2]

Conditions
ConditionsYield
for 0.0833333h;99%
(2-methylallyl)palladium-chloride dimer

(2-methylallyl)palladium-chloride dimer

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[IPr*·H][Pd(η3-2-Me-allyl)Cl2]

[IPr*·H][Pd(η3-2-Me-allyl)Cl2]

Conditions
ConditionsYield
for 0.0833333h;99%
bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][Pd(η3-cin)Cl2]

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][Pd(η3-cin)Cl2]

Conditions
ConditionsYield
for 0.0833333h;99%
copper dichloride

copper dichloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][CuCl3]

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][CuCl3]

Conditions
ConditionsYield
Milling;99%
palladium dichloride

palladium dichloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][PdCl3]

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][PdCl3]

Conditions
ConditionsYield
Milling;99%
acetic acid
64-19-7

acetic acid

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis(2,6-diisopropylphenyl)imidazolium acetate

1,3-bis(2,6-diisopropylphenyl)imidazolium acetate

Conditions
ConditionsYield
With Amberlyst A26 hydroxide In methanol; water at 70℃;98.9%
3-Chloropyridine
626-60-8

3-Chloropyridine

palladium dichloride

palladium dichloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropiridyl)palladium(II) dichloride

[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropiridyl)palladium(II) dichloride

Conditions
ConditionsYield
With sodium carbonate at 80℃; for 16h; Product distribution / selectivity;98%
With caesium carbonate at 80℃; for 16h; Reactivity;93%
With potassium carbonate at 80℃; for 16h; Product distribution / selectivity;80%
chloroacetonitrile
107-14-2

chloroacetonitrile

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]acetonitrile
1225274-70-3

[1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]acetonitrile

Conditions
ConditionsYield
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere; Sonication;
Stage #2: chloroacetonitrile In tetrahydrofuran at 20℃; for 72h; Inert atmosphere;
98%
With potassium tert-butylate In tetrahydrofuran-d8 at 20℃; anaerobic conditions; ultrasonification;
1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis-(2,6-diisopropylphenyl)imidazolium hexafluorophosphate

1,3-bis-(2,6-diisopropylphenyl)imidazolium hexafluorophosphate

Conditions
ConditionsYield
With ammonium hexafluorophosphate In water at 20℃; for 0.166667h; Inert atmosphere;98%
With potassium hexafluorophosphate In water at 20℃; Inert atmosphere; Glovebox;
bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

((1,3-bis(2,6-di-isopropylphenyl)-4,5-dihydroimidazol-2-ylidene)chloro)(3-phenylallyl)palladium (2)

((1,3-bis(2,6-di-isopropylphenyl)-4,5-dihydroimidazol-2-ylidene)chloro)(3-phenylallyl)palladium (2)

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃; for 5h;98%
With potassium carbonate In ethanol at 60℃; for 5h; Green chemistry;98%
Stage #1: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In acetone at 60℃;
Stage #2: With triethylamine In acetone at 60℃;
77%
1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

N,N'-1,3-bis(2,6-diisopropylphenyl)-2-iodoimidazolium chloride

N,N'-1,3-bis(2,6-diisopropylphenyl)-2-iodoimidazolium chloride

Conditions
ConditionsYield
With N-iodo-succinimide In dichloromethane at 40℃; for 3h; Sealed tube;98%
vinyl acetate
108-05-4

vinyl acetate

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

2-(1-acetoxy-1-ethyl)-1,3-bis(2,6-diisopropylphenyl)imidazolium chloride
1134205-18-7

2-(1-acetoxy-1-ethyl)-1,3-bis(2,6-diisopropylphenyl)imidazolium chloride

Conditions
ConditionsYield
Stage #1: 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride With potassium tert-butylate In tetrahydrofuran for 0.166667h;
Stage #2: vinyl acetate In tetrahydrofuran
97%
1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I)

chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I)

Conditions
ConditionsYield
With dimethylsulfide gold(I) chloride; potassium carbonate In acetone at 60℃; for 1h; Reagent/catalyst; Solvent; Temperature; Time;97%
Multi-step reaction with 2 steps
1: dichloromethane / 0.25 h
2: potassium carbonate / dichloromethane / 1.5 h
View Scheme
Multi-step reaction with 2 steps
1: dimethyl sulfoxide; methanol / Schlenk technique; Inert atmosphere
2: dimethyl sulfoxide; methanol / 4 h / 20 °C / Schlenk technique; Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: dichloromethane / Darkness
2: dichloromethane
View Scheme
Multi-step reaction with 2 steps
1: acetone / 0.17 h / 60 °C
2: sodium acetate / acetone / 0.83 h / 60 °C
View Scheme
copper(l) chloride

copper(l) chloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][CuCl2]

[1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium][CuCl2]

Conditions
ConditionsYield
Milling;97%
In neat (no solvent, solid phase) for 0.166667h; Milling;
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

bis(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)copper hexafluorophosphate

bis(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)copper hexafluorophosphate

Conditions
ConditionsYield
With sodium t-butanolate In tetrahydrofuran (Ar); glovebox; mixt. of Cu complex, ligand and NaO-t-Bu in THF was stirred for 6 h; filtered through Celite (THF); filtrate mixed with hexane; filtered; elem. anal.;96%
lithium tetrakis(tetrahydrofuran)bis(3,3',5,5'-tetra-tert-butyl-2,2'-diphenolato)aluminate(III)

lithium tetrakis(tetrahydrofuran)bis(3,3',5,5'-tetra-tert-butyl-2,2'-diphenolato)aluminate(III)

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

(1,3-bis(2,6-diisopropylphenyl)imidazolinium)bis(3,3',5,5'-tetra-tert-butyl-2,2'-diphenolato)aluminate(III)

(1,3-bis(2,6-diisopropylphenyl)imidazolinium)bis(3,3',5,5'-tetra-tert-butyl-2,2'-diphenolato)aluminate(III)

Conditions
ConditionsYield
In dichloromethane byproducts: LiCl; under inert gas, imidazolinium-compd. dissolved in CH2Cl2, aluminate-compd. in CH2Cl2 added whilst stirring; filtered through Celite, washed with CH2Cl2, solv. removed, elem. anal.;96%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium dichloroaurate(I)
1439915-35-1

1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium dichloroaurate(I)

Conditions
ConditionsYield
In dichloromethane for 0.25h;96%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

potassium carbonate
584-08-7

potassium carbonate

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
250285-32-6

1,3-bis[2,6-diisopropylphenyl]imidazolium chloride

(η5-pentamethylcyclopentadienyl)(κ2-CO3)(N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)iridium(III) hydrate

(η5-pentamethylcyclopentadienyl)(κ2-CO3)(N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)iridium(III) hydrate

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 24 - 60℃; for 34h; Inert atmosphere;96%

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