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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 5-Chloro-1,3-Xylene with high purity

Cas:556-97-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

5-Chloro-1,3-xylene Manufacturer/High quality/Best price/In stock

Cas:556-97-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5-Chloro-m-xylene

Cas:556-97-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1-chloro-3,5-dimethylbenzene

Cas:556-97-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 556-97-8 with best quality

Cas:556-97-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-chloro-3,5-dimethyl- 556-97-8

Cas:556-97-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 5-Chloro-1,3-xylene Synonyms: 5-CHLORO-M-XYLENE;1-CHLORO-3,5-DIMETHYLBENZENE;1-chloro-3,5-xylene;3,5-dimethylchlorobenzene;3,5-dimethylphenylchloride;5-chloro-1,3-xylene;5-chloro-m-xylen;1,3-Dimethyl-5-chlorobenzene CAS: 556-97

3,5-Dimethylchlorobenzene 556-97-8 C8H9Cl

Cas:556-97-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

5-Chloro-1,3-xylene CAS:556-97-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

5-Chloro-1,3-xylene CAS:556-97-8

Cas:556-97-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-chloro-3,5-dimethyl-

Cas:556-97-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-chloro-3,5-dimethyl-

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

5-Chloro-1,3-Xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used in organic synthesis Transportation:as per your request Po

Benzene,1-chloro-3,5-dimethyl-

Cas:556-97-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-chloro-3,5-dimethyl-

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 5-Chloro-1,3-Xylene

Cas:556-97-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

5-Chloro-m-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/3,5-Dimethylchlorobenzene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

3,5-Dimethylchlorobenzene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1-Chloro-3,5-dimethylbenzene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-Chloro-3,5-diMethylbenzene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 5-Chloro-m-xylene 25g

Cas:556-97-8

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

5-Chloro-1,3-Xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzene,1-chloro-3,5-dimethyl-

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

3,5-Dimethylchlorobenzene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:off-white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as prima

5-Chloro-1,3-xylene

Cas:556-97-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

<(3,5-Dimethylphenyl)azo>pyrrolidine

<(3,5-Dimethylphenyl)azo>pyrrolidine

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride; copper(l) chloride54%
With hydrogenchloride; copper(l) chloride Product distribution; triazene moiety as protecting group for aromatic amines; var. triazenes;
3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuCl;
dibromide of 5-chloro-1.3-dimethyl-cyclohexadiene

dibromide of 5-chloro-1.3-dimethyl-cyclohexadiene

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

Conditions
ConditionsYield
With quinoline
o-xylene
95-47-6

o-xylene

A

2,4-dimethylchlorobenzene
95-66-9

2,4-dimethylchlorobenzene

B

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

C

2-chloro-1,4-dimethyl-benzene
95-72-7

2-chloro-1,4-dimethyl-benzene

D

2,6-dimethyl-1-chlorobenzene
6781-98-2

2,6-dimethyl-1-chlorobenzene

E

4-chloro-1,2-dimethylbenzene
615-60-1

4-chloro-1,2-dimethylbenzene

F

3-chloro-o-xylene
608-23-1

3-chloro-o-xylene

G

1,2-dichloro-4,5-dimethyl-benzene
20824-80-0

1,2-dichloro-4,5-dimethyl-benzene

H

1,2-dichloro-3,4-dimethyl-benzene
68266-67-1

1,2-dichloro-3,4-dimethyl-benzene

I

2-methyl-5-chlorobenzyl chloride
34060-72-5

2-methyl-5-chlorobenzyl chloride

J

1,4-dichloro-2,3-dimethyl-benzene
52331-02-9

1,4-dichloro-2,3-dimethyl-benzene

K

3,5-dichloro-o-xylene
70172-92-8

3,5-dichloro-o-xylene

L

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

M

alpha,2-dichloro-6-methyltoluene
55676-90-9

alpha,2-dichloro-6-methyltoluene

Conditions
ConditionsYield
With chlorine; the fluorine-containing K-L-type zeolite In 1,2-dichloro-ethane at 80℃; for 1.75 - 3.66667h; Product distribution / selectivity;
With chlorine; a K-L-type zeolite In 1,4-dioxane; 1,2-dichloro-ethane at 80℃; for 6.75h;
copper(I) chloride
7758-89-6

copper(I) chloride

3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite In water
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

A

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

B

phenylboronic acid
98-80-6

phenylboronic acid

Conditions
ConditionsYield
With cesium fluoride; Pd(dba)2 In tolueneA n/a
B 99%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

Conditions
ConditionsYield
With ammonium hydroxide; potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;99%
Multi-step reaction with 2 steps
1.1: sulfuric acid; nitric acid / 30 °C / Cooling with ice
2.1: palladium on activated charcoal / ethanol / 0.5 h / 50 °C / Autoclave
2.2: 0.83 h / 65 °C / 2250.23 Torr / Autoclave
View Scheme
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

benzylamine
100-46-9

benzylamine

N-benzyl-3,5-dimethylaniline
124043-95-4

N-benzyl-3,5-dimethylaniline

Conditions
ConditionsYield
With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;99%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

phenylboronic acid
98-80-6

phenylboronic acid

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With cesium fluoride; Pd(dba)2 In toluene98%
With potassium phosphate; C75H58Cl2N4Pd In water; isopropyl alcohol at 25℃; for 4.5h; Reagent/catalyst; Suzuki-Miyaura Coupling; Schlenk technique;98%
With potassium phosphate; C20H28Br2N2Pd In water; isopropyl alcohol at 25℃; for 7.5h; Reagent/catalyst; Suzuki-Miyaura Coupling;95%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

4-amino-3-methylphenol
2835-99-6

4-amino-3-methylphenol

4-(3,5-dimethylphenylamino)-3-methyl-phenol
1198117-98-4

4-(3,5-dimethylphenylamino)-3-methyl-phenol

Conditions
ConditionsYield
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 110℃; for 3h; Inert atmosphere;97%
furan-2-ylmethanamine
617-89-0

furan-2-ylmethanamine

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-(furan-2-yl-methyl)-3,5-dimethylaniline
416887-98-4

N-(furan-2-yl-methyl)-3,5-dimethylaniline

Conditions
ConditionsYield
With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;97%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-methylheptylamine
36343-05-2

N-methylheptylamine

(3,5-dimethyl-phenyl)-heptyl-methyl-amine

(3,5-dimethyl-phenyl)-heptyl-methyl-amine

Conditions
ConditionsYield
With sodium t-butanolate; 3-dioxolane; Pd(dba)2*2-(2'-dicyclohexylphosphinophenyl)-2-methyl-1 In toluene at 105℃; for 1h;95%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

4-amino-2-methylphenol
2835-96-3

4-amino-2-methylphenol

4-[(3,5-dimethylphenyl)amino]-2-methylphenol
1198117-78-0

4-[(3,5-dimethylphenyl)amino]-2-methylphenol

Conditions
ConditionsYield
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 110℃; for 1.33333h; Inert atmosphere;94%
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

3-(3,5-dimethylbenzyl)-5,5-dimethylcyclohex-2-enone

3-(3,5-dimethylbenzyl)-5,5-dimethylcyclohex-2-enone

Conditions
ConditionsYield
With 2-(2,6-dimethoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole; palladium diacetate; lithium tert-butoxide In 1,4-dioxane at 100℃; for 1h; Schlenk technique; Inert atmosphere;94%
morpholine
110-91-8

morpholine

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N (dimethyl-3,5-phenyl-1) morpholine
16800-77-4

N (dimethyl-3,5-phenyl-1) morpholine

Conditions
ConditionsYield
With sodium t-butanolate; 3-dioxolane; Pd(dba)2*2-(2'-dicyclohexylphosphinophenyl)-2-methyl-1 In toluene at 105℃; for 1h;92%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

tributylphenylstannane
960-16-7

tributylphenylstannane

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With potassium fluoride; tetrabutylammomium bromide; tris-(o-tolyl)phosphine; copper(I) oxide at 125 - 130℃; for 72h; Stille cross-coupling;92%
With palladium diacetate; orotic acid; cesium fluoride In 1,4-dioxane at 100℃; for 22h; Stille Cross Coupling; Sealed tube; Inert atmosphere; Schlenk technique;44%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

butylcarbamic acid benzyl ester
13105-53-8

butylcarbamic acid benzyl ester

benzyl butyl(3,5-dimethylphenyl)carbamate
1198294-06-2

benzyl butyl(3,5-dimethylphenyl)carbamate

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); bis(3,5-bis(trifluoromethyl)phenyl)(2’,4’,6’-triisopropyl-3,6-dimethoxy-[1,1’-biphenyl]-2-yl)phosphine; caesium carbonate In toluene at 130℃; for 17h; Inert atmosphere; Molecular sieve;92%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-methylaniline
100-61-8

N-methylaniline

N,3,5-trimethyl-N-phenylaniline
474352-69-7

N,3,5-trimethyl-N-phenylaniline

Conditions
ConditionsYield
Stage #1: 1-chloro-3,5-dimethylbenzene; N-methylaniline With palladium diacetate; sodium sulfate; sodium t-butanolate; XPhos for 1h; Buchwald-Hartwig Coupling; Milling;
Stage #2: In water; ethyl acetate for 0.0333333h; Buchwald-Hartwig Coupling; Milling;
90%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

(Ra)-2,2'-bis(methoxy-methyloxy)-1,1'-binaphthalene

(Ra)-2,2'-bis(methoxy-methyloxy)-1,1'-binaphthalene

(R)-3,3′-bis(3,5-dimethylphenyl)-2,2′-dihydroxy-1,1′-dinaphthyl

(R)-3,3′-bis(3,5-dimethylphenyl)-2,2′-dihydroxy-1,1′-dinaphthyl

Conditions
ConditionsYield
Stage #1: 1-chloro-3,5-dimethylbenzene; (Ra)-2,2'-bis(methoxy-methyloxy)-1,1'-binaphthalene With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; tert.-butyl lithium In n-heptane at 20℃; for 0.166667h; Schlenk technique;
Stage #2: In n-heptane Schlenk technique; Acidic conditions;
88%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
325142-93-6

2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With p-phenylpyridine; sodium methylate In acetonitrile at 20℃; for 12h; Sealed tube; Inert atmosphere; Irradiation;88%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(dibenzylideneacetone)-palladium(0) In toluene at 105℃; for 18h; Sealed tube; Inert atmosphere;80%
With [1,3-bis(cyclohexyl)imidazol-2-ylidene]copper(I) chloride; potassium tert-butylate In methyl cyclohexane at 90℃; for 42h; Inert atmosphere; Glovebox;68%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

triethoxy(o-tolyl)silane
18412-55-0

triethoxy(o-tolyl)silane

2,3′,5′-trimethyl-1,1′-biphenyl
76708-77-5

2,3′,5′-trimethyl-1,1′-biphenyl

Conditions
ConditionsYield
With Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); tetrabutylammomium bromide; sodium hydroxide In water at 60℃; for 10h; Hiyama coupling; Inert atmosphere;87%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

(2-tolyl)tributyltin
68971-87-9

(2-tolyl)tributyltin

2,3′,5′-trimethyl-1,1′-biphenyl
76708-77-5

2,3′,5′-trimethyl-1,1′-biphenyl

Conditions
ConditionsYield
With Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); cesium fluoride In tetrahydrofuran at 50℃; for 8h; Stille Cross Coupling;87%
hexan-1-amine
111-26-2

hexan-1-amine

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-n-hexyl-3,5-dimethylbenzenamine

N-n-hexyl-3,5-dimethylbenzenamine

Conditions
ConditionsYield
With copper(l) iodide; C14H16N2O; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; Sealed tube;87%
With copper(l) iodide; C14H16N2O; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Sealed tube; Inert atmosphere;87%
4-sulfanylphenol
637-89-8

4-sulfanylphenol

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

4-(3,5-dimethylphenyl)sulfanylphenol

4-(3,5-dimethylphenyl)sulfanylphenol

Conditions
ConditionsYield
With C40H30Cl2N2NiO2S2; sodium hydroxide In N,N-dimethyl-formamide at 70℃; for 3h;86%
carbon dioxide
124-38-9

carbon dioxide

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

3,5-dimethylbenzoic acid
499-06-9

3,5-dimethylbenzoic acid

Conditions
ConditionsYield
With manganese; 2,9-dibutyl-4,7-dimethyl-1,10-phenanthroline; tetraethylammonium iodide; lithium acetate; cobalt(II) bromide In N,N-dimethyl acetamide at 100℃; under 760.051 Torr; for 12h; Inert atmosphere; Schlenk technique;84%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

hexanal
66-25-1

hexanal

(2Z)-2-butyl-4-(3,5-dimethylphenyl)-2-octenal
959706-71-9

(2Z)-2-butyl-4-(3,5-dimethylphenyl)-2-octenal

Conditions
ConditionsYield
With caesium carbonate; palladium diacetate In N,N-dimethyl-formamide at 80℃; for 12h;82%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-(2-pyridyl)indole
3419-91-8

N-(2-pyridyl)indole

2-(3,5-dimethylphenyl)-1-(pyridin-2-yl)-1H-indole

2-(3,5-dimethylphenyl)-1-(pyridin-2-yl)-1H-indole

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; nickel diacetate; lithium hexamethyldisilazane In neat (no solvent) at 80℃; for 16h; Sealed tube; Glovebox; Inert atmosphere; regioselective reaction;82%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

1-(bromomethyl)-3-chloro-5-methylbenzene
62358-81-0

1-(bromomethyl)-3-chloro-5-methylbenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; azobisisobutyronitrile In tetrachloromethane80%
With N-Bromosuccinimide In tetrachloromethane for 3h; Heating / reflux; UV-irradiation;68%
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 0.333333h; Heating / reflux;60%
3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione
58-08-2

3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione

1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

8-(3,5-dimethylphenyl)-1,3,7-trimethyl-1H-purine-3,7-dihydro-2,6-dione

8-(3,5-dimethylphenyl)-1,3,7-trimethyl-1H-purine-3,7-dihydro-2,6-dione

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate In 1-methyl-pyrrolidin-2-one at 125℃; for 24h;77%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

thiophenol
108-98-5

thiophenol

3,5-dimethylphenyl phenyl sulfide

3,5-dimethylphenyl phenyl sulfide

Conditions
ConditionsYield
With potassium hydroxide In water for 8h; Reflux;77%
With C40H30Cl2N2NiO2S2; sodium hydroxide In N,N-dimethyl-formamide at 70℃; for 3h;77%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

N-(2-(methylthio)phenyl)ferrocene-1-carboxamide

N-(2-(methylthio)phenyl)ferrocene-1-carboxamide

2,5-bis(3,4-dimethylphenyl)-N-(quinolin-8-yl)ferrocenecarboxamide

2,5-bis(3,4-dimethylphenyl)-N-(quinolin-8-yl)ferrocenecarboxamide

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos; Trimethylacetic acid In o-xylene at 190℃; for 21h; Schlenk technique; Inert atmosphere;77%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

4-methoxy-phenol
150-76-5

4-methoxy-phenol

1-(4-methoxyphenoxy)-3,5-dimethylbenzene
120957-65-5

1-(4-methoxyphenoxy)-3,5-dimethylbenzene

Conditions
ConditionsYield
With 2-acetonylpyridine; caesium carbonate; copper(I) bromide In dimethyl sulfoxide at 150℃; for 24h; Inert atmosphere; chemoselective reaction;70%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane
5123-13-7

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With potassium tert-butylate; cobalt(II) chloride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 60℃; for 24h; Suzuki Coupling;69%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

Acetanilid
103-84-4

Acetanilid

N-(3,5-dimethylphenyl)-N-phenylacetamide
51786-48-2

N-(3,5-dimethylphenyl)-N-phenylacetamide

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); bis(3,5-bis(trifluoromethyl)phenyl)(2’,4’,6’-triisopropyl-3,6-dimethoxy-[1,1’-biphenyl]-2-yl)phosphine; caesium carbonate In toluene at 130℃; for 17h; Inert atmosphere; Molecular sieve;68%
1-chloro-3,5-dimethylbenzene
556-97-8

1-chloro-3,5-dimethylbenzene

2-Biphenylcarboxylic acid
947-84-2

2-Biphenylcarboxylic acid

2-(3,5-dimethylphenyl)-6-phenylbenzoic acid

2-(3,5-dimethylphenyl)-6-phenylbenzoic acid

Conditions
ConditionsYield
With 3 A molecular sieve; caesium carbonate; palladium diacetate In N,N-dimethyl-formamide at 20 - 145℃; for 26h;67%

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