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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Methylphenylacetic acid Manufacturer/High quality/Best price/In stock

Cas:644-36-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality O-Tolylacetic Acid supplier in China

Cas:644-36-0

Min.Order:1 Kilogram

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Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Methylphenylacetic acid CAS number 644-36-0 Assay ≥99% Appearance White crystal Capacity 200mt/year Application Organic synthesis intermed

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Hot selling 2-Methylphenylacetic acid CAS 644-36-0 with good quality Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed

Hot selling 2-Methylphenylacetic acid CAS 644-36-0 with good quality

Cas:644-36-0

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:1 Kilogram

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EAST CHEMSOURCES LIMITED

o-Tolylacetic acid CAS N.O: 644-36-0 Molecular Formula: C9H10O2 Molecular Weight: 150.176 EINECS N.O: 211-416-9 Assay ≥ 99%

o-Tolylacetic acid

Cas:644-36-0

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:1 Kilogram

FOB Price: $5.0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory supply O-Tolylacetic Acid

Cas:644-36-0

Min.Order:1

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Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Methylphenylacetic Acid

Cas:644-36-0

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

o-Tolylacetic acid

Cas:644-36-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-(2-methylphenyl)acetic Acid

Cas:644-36-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Good quantity Dichlorophenylphosphine Basic information Product Name: Dichlorophenylphosphine Synonyms: benzenephosphorusdichloride[qr];dichlorophenyl-phosphin;Phenylphosphine dichlori

TIANFU-CHEM 2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New arrivalCAS 644-36-0 with best price

Cas:644-36-0

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

CAS: 644-36-0 MF: C9H10O2 MW: 150.17 EINECS: 211-416-9 Product Categories: Mol File: 644-36-0.mol Appear

2-Methylphenylacetic acid CAS: 644-36-0

Cas:644-36-0

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzeneacetic acid,2-methyl- 644-36-0

Cas:644-36-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

2-Methylphenylacetic acid CAS:644-36-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2-Methylphenylacetic acid CAS:644-36-0

Cas:644-36-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzeneacetic acid,2-methyl-

Cas:644-36-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:644-36-0

Cas:644-36-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

o-Tolylacetic acid cas:644-36-0

Cas:644-36-0

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 644-36-0 ,2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

O-Tolylacetic Acid

Cas:644-36-0

Min.Order:0

Negotiable

Type:Manufacturers

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

o-Tolylacetic acid

Cas:644-36-0

Min.Order:1 Kilogram

FOB Price: $30.0 / 40.0

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 644-36-0 2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

Top supplier 2-Methylphenylacetic acid 644-36-0 in China

Cas:644-36-0

Min.Order:1 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Methylphenylacetic acid Manufacturer

Cas:644-36-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Methylphenylacetic acid

Cas:644-36-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: O-Tolylacetic Acid CAS No.:644-36-0 Molecule Formula:C9H10O2 Molecule Weight:150.18 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING ITEMS

Best Quality O-Tolylacetic Acid with good supplier

Cas:644-36-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Synthetic route

Ru((+)-BINAP)(O2 CCH3)2

Ru((+)-BINAP)(O2 CCH3)2

2-methylenephenylacetic acid

2-methylenephenylacetic acid

argon

argon

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
In methanol100%
2-o-tolylethanol
19819-98-8

2-o-tolylethanol

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With periodic acid; pyridinium chlorochromate In acetonitrile98%
With periodic acid; tripropylammonium fluorochromate (VI) In acetonitrile at 0℃;98%
isochroman-3-one
4385-35-7

isochroman-3-one

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With palladium 10% on activated carbon; W(OTf)6; hydrogen; acetic acid at 50℃; under 760.051 Torr; for 12h;98%
With palladium on activated carbon; W(OTf)6; hydrogen In acetic acid at 50℃; under 760.051 Torr; for 12h;97%
ethyl 2-(2-methylphenyl)acetate
40291-39-2

ethyl 2-(2-methylphenyl)acetate

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With water; sodium hydroxide In 1,4-dioxane at 60℃; for 2h; pH=10 - 14;97%
With potassium hydroxide In ethanol at 20℃; for 15h;0.33 g
2-tolylmethylnitrile
22364-68-7

2-tolylmethylnitrile

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium hydrogen sulfate; water at 60 - 65℃; for 1.25h; Green chemistry;94%
With sulfuric acid; acetic acid
With potassium hydroxide; dihydrogen peroxide Behandlung mit Salzsaeure;
1-(pyrrolidin-1-yl)-2-(o-tolyl)ethan-1-one
512787-29-0

1-(pyrrolidin-1-yl)-2-(o-tolyl)ethan-1-one

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane for 41h; Heating;91%
2-indanone
615-13-4

2-indanone

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With potassium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene Reflux;90%
carbon monoxide
201230-82-2

carbon monoxide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With cobalt(II) pyridine-2-carboxylate; palladium diacetate; sodium hydroxide In methanol at 150℃; under 11251.1 Torr; for 6h; Autoclave;89%
With palladium hydroxide, 20 wt% on carbon; tetrabutylammomium bromide; water In tetrahydrofuran at 110℃; under 7500.75 Torr; for 4h; Sealed tube; Autoclave;65%
carbon monoxide
201230-82-2

carbon monoxide

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
Stage #1: carbon monoxide With C28H22CoN4O6 In butan-1-ol at 60℃; under 760.051 Torr; for 2h; Glovebox; High pressure; Green chemistry;
Stage #2: 1-chloromethyl-2-methylbenzene With tetra-(n-butyl)ammonium iodide; sodium hydroxide In butan-1-ol at 60℃; under 760.051 Torr; for 22h; Glovebox; High pressure; Green chemistry; regioselective reaction;
88%
With bis-triphenylphosphine-palladium(II) chloride; tetraethylammonium chloride; sodium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene at 80℃; under 11251.1 Torr; for 20h; Autoclave; regioselective reaction;83%
With sodium hydroxide; cerium(III) chloride; cetyltrimethylammonim bromide; nickel cyanide In toluene at 85 - 95℃; under 1 Torr; for 7.25h;55%
carbon monoxide
201230-82-2

carbon monoxide

phthalyl alcohol
612-14-6

phthalyl alcohol

A

isochroman-3-one
4385-35-7

isochroman-3-one

B

o-xylene
95-47-6

o-xylene

C

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In acetone at 90℃; under 68400 Torr; for 42h; Carbonylation; reduction;A 88%
B n/a
C 9%
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 120℃; under 68400 Torr; for 42h; Carbonylation; reduction;A 13%
B n/a
C 52%
carbon monoxide
201230-82-2

carbon monoxide

Triethyl-(2-methyl-benzyl)-ammonium; chloride
85267-32-9

Triethyl-(2-methyl-benzyl)-ammonium; chloride

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With sodium hydroxide; dicobalt octacarbonyl at 65℃; Irradiation;85%
carbon monoxide
201230-82-2

carbon monoxide

Triethyl-(2-methyl-benzyl)-ammonium; bromide
85267-31-8

Triethyl-(2-methyl-benzyl)-ammonium; bromide

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With sodium hydroxide; dicobalt octacarbonyl at 65℃; Irradiation;85%
carbon dioxide
124-38-9

carbon dioxide

N,N,N-trimethyl-1-(o-tolyl)methanaminium iodide
117867-97-7

N,N,N-trimethyl-1-(o-tolyl)methanaminium iodide

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
Stage #1: carbon dioxide; N,N,N-trimethyl-1-(o-tolyl)methanaminium iodide With manganese; 2,9-dibutyl-4,7-dimethyl-1,10-phenanthroline; nickel(II) bromide 2-methoxyethyl ether complex In N,N-dimethyl-formamide at 90℃; under 760.051 Torr; for 72h; Schlenk technique;
Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 20℃; Schlenk technique;
82%
formic acid
64-18-6

formic acid

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; α,α′-bis(2-pyridyl(tert-butyl)phosphino)-o-xylene; palladium diacetate In N,N-dimethyl-formamide at 115℃; for 12h; Inert atmosphere;80%
carbon monoxide
201230-82-2

carbon monoxide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

B

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

C

1,3-bis(2-methylphenyl)-2-propanone
23592-92-9

1,3-bis(2-methylphenyl)-2-propanone

D

o-Tolyl-acetic acid 2-methyl-benzyl ester
80720-85-0

o-Tolyl-acetic acid 2-methyl-benzyl ester

Conditions
ConditionsYield
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; dichloromethane at 25℃; under 760 Torr; for 24h;A 69%
B 10%
C 7%
D 18%
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; dichloromethane at 25℃; under 760 Torr; for 24h;A 69%
B 10%
C 7%
D 18%
carbon monoxide
201230-82-2

carbon monoxide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

1,3-bis(3,4-methylphenyl)acetone

1,3-bis(3,4-methylphenyl)acetone

Conditions
ConditionsYield
With sodium hydroxide; cobalt tricarbonyl nitrosyl; trimethyldodecylammonium chloride In benzene under 760 Torr; Ambient temperature;A 4%
B 68%
C 12%
D 10%
2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

1,3-bis(3,4-methylphenyl)acetone

1,3-bis(3,4-methylphenyl)acetone

Conditions
ConditionsYield
With sodium hydroxide; cobalt tricarbonyl nitrosyl; carbon monoxide; trimethyldodecylammonium chloride In benzene under 760 Torr; Ambient temperature;A 4%
B 68%
C 12%
D 10%
carbon monoxide
201230-82-2

carbon monoxide

α,α-dibromo-o-xylene
79985-01-6

α,α-dibromo-o-xylene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With potassium hydroxide; dicobalt octacarbonyl; N-benzyl-N,N,N-triethylammonium chloride In benzene under 760 Torr; for 12h; Ambient temperature;67%
carbon monoxide
201230-82-2

carbon monoxide

phthalyl alcohol
612-14-6

phthalyl alcohol

A

isochroman-3-one
4385-35-7

isochroman-3-one

B

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); hydrogen iodide In acetone at 90℃; under 68400 Torr; for 42h;A 56%
B 9 % Spectr.
o-xylene
95-47-6

o-xylene

carbon dioxide
124-38-9

carbon dioxide

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With bis(2-pyridyl)methane; xanth-9-one; nickel(II) chloride hexahydrate; potassium tert-butylate In benzene at 20℃; under 760.051 Torr; for 4h; Reagent/catalyst; Irradiation; Schlenk technique;55%
1,1-dibromo-2-(2-methylphenyl)ethene
104464-03-1

1,1-dibromo-2-(2-methylphenyl)ethene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With PEG-400; sodium hydroxide; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) In dichloromethane at 60 - 65℃; for 17h;51%
Multi-step reaction with 2 steps
1: 99 percent / H2O / ethyl acetate / 12 h / 20 °C
2: 91 percent / aq. HCl / dioxane / 41 h / Heating
View Scheme
sodium cyanide
143-33-9

sodium cyanide

2-methylphenyl aldehyde
529-20-4

2-methylphenyl aldehyde

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
Stage #1: sodium cyanide; 2-methylphenyl aldehyde With sodium disulfite In water
Stage #2: With hydrogenchloride at 20℃; for 12h;
38%
carbon monoxide
201230-82-2

carbon monoxide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

B

o-Tolyl-acetic acid 2-methyl-benzyl ester
80720-85-0

o-Tolyl-acetic acid 2-methyl-benzyl ester

Conditions
ConditionsYield
With sodium hydroxide; η6-C6H6BPh3-Rh(COD)+; tetra-n-hexylammonium hydrogen sulfate In dichloromethane at 40℃; under 760 Torr;A 35%
B 20%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

acetic acid
64-19-7

acetic acid

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With silver(I) acetate; sodium acetate; palladium dichloride at 130℃; for 24h; Schlenk technique; Inert atmosphere;18%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With diethyl ether Eintragen einer Loesung des Reaktionsprodukts in Dioxan in eine warme Suspension von Silberoxid in Natriumthiosulfat enthaltender wss. Natriumcarbonat-Loesung;
1-methyl-2-(2-propenyl)-benzene
1587-04-8

1-methyl-2-(2-propenyl)-benzene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With potassium permanganate; acetic acid at 0℃;
o-xylene
95-47-6

o-xylene

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With sodium; diethylmercury Durchleiten von Kohlendioxyd;
Multi-step reaction with 3 steps
1: bromine
2: alcohol
3: hydrogen peroxide; potassium hydroxide / Behandlung mit Salzsaeure
View Scheme
Multi-step reaction with 2 steps
1: dichloro[4,5-bis(diphenylphosphino)-9,9’-dimethylxanthene]palladium(II); di-tert-butyl peroxide / 16 h / 120 °C / 7600.51 Torr
2: water; sodium hydroxide / 1,4-dioxane / 2 h / 60 °C / pH 10 - 14
View Scheme
Multi-step reaction with 4 steps
1: chlorine / 4 h / 95 °C / Photolysis
2: iron(III) chloride; N-benzyl-N,N,N-triethylammonium chloride; boric acid / water / 1 h / 30 °C
3: sodium hydroxide / 6 h / 95 °C
4: hydrogenchloride; water / 20 °C
View Scheme
2-tolylmethylnitrile
22364-68-7

2-tolylmethylnitrile

A

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

B

2-methylphenethylamine
55755-16-3

2-methylphenethylamine

Conditions
ConditionsYield
With ethanol; sodium
homophthalic anhydride
703-59-3

homophthalic anhydride

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With hydrogen; palladium In ethyl acetate
methanol
67-56-1

methanol

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With sulfuric acid at 0℃; for 8h; Reflux; Inert atmosphere;100%
With sulfuric acid for 6.5h; Inert atmosphere; Reflux;99%
With sulfuric acid at 28℃; for 12h;98%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

ethyl acrylate
140-88-5

ethyl acrylate

C14H16O4
1251864-79-5

C14H16O4

Conditions
ConditionsYield
With N-(tert-butyloxycarbonyl)-L-isoleucine; oxygen; palladium diacetate; p-benzoquinone In tert-Amyl alcohol at 85℃; under 760.051 Torr; for 48h; regioselective reaction;100%
With (2S,3S)-N-acetyl-2-amino-3-methylpentanoic acid; oxygen; palladium diacetate; potassium hydrogencarbonate In tert-Amyl alcohol at 90℃; under 760.051 Torr; for 2h;97%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

N-cyclohexyl-cyclohexanamine
101-83-7

N-cyclohexyl-cyclohexanamine

C9H10O2*C12H23N

C9H10O2*C12H23N

Conditions
ConditionsYield
In methanol at 20℃;100%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

N-hydroxy-2-o-tolylacetamide
2594-02-7

N-hydroxy-2-o-tolylacetamide

Conditions
ConditionsYield
Stage #1: o-methylphenylacetic acid With 1,1'-carbonyldiimidazole In tetrahydrofuran for 1h;
Stage #2: With hydroxylamine hydrochloride In tetrahydrofuran; water for 16h;
99%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C7H7BF3*K(1+)

C7H7BF3*K(1+)

2-(3,4'-dimethylbiphenyl-2-yl)acetic acid
1342343-93-4

2-(3,4'-dimethylbiphenyl-2-yl)acetic acid

Conditions
ConditionsYield
With palladium diacetate; potassium hydrogencarbonate; N-acetyl-L-isoleucine; silver carbonate; p-benzoquinone In tert-Amyl alcohol for 2h; Heating;99%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

O-(2,3-dimethylbut-2-enyl)hydroxylamine hydrochloride
1426580-46-2

O-(2,3-dimethylbut-2-enyl)hydroxylamine hydrochloride

N-(2,3-dimethylbut-2-enyloxy)-2-o-tolylacetamide
1426580-47-3

N-(2,3-dimethylbut-2-enyloxy)-2-o-tolylacetamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 12h;99%
octanol
111-87-5

octanol

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C17H26O2
1435489-74-9

C17H26O2

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 80℃; for 18h; Reagent/catalyst; Sealed tube;99%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

N-(3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)-2-hydroxyacetamide

N-(3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)-2-hydroxyacetamide

2-((3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)amino)-2-oxoethyl 2-(o-tolyl)acetate

2-((3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)amino)-2-oxoethyl 2-(o-tolyl)acetate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 6h;99%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With sulfuric acid In methanol98%
With sulfuric acid In methanol98%
With sulfuric acid In formic acid for 6h; Reflux;
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

(1R,2R)-pseudoephedrine
321-97-1

(1R,2R)-pseudoephedrine

N-((1R,2R)-1-hydroxy-1-phenylpropan-2-yl)-N-methyl-2-o-tolylacetamide
1101876-22-5

N-((1R,2R)-1-hydroxy-1-phenylpropan-2-yl)-N-methyl-2-o-tolylacetamide

Conditions
ConditionsYield
With dmap; diisopropyl-carbodiimide In dichloromethane at 0 - 20℃; Inert atmosphere;98%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C6H4BF4*K(1+)

C6H4BF4*K(1+)

2-(4'-fluoro-3-methylbiphenyl-2-yl)acetic acid
1342343-98-9

2-(4'-fluoro-3-methylbiphenyl-2-yl)acetic acid

Conditions
ConditionsYield
With palladium diacetate; potassium hydrogencarbonate; N-acetyl-L-isoleucine; silver carbonate; p-benzoquinone In tert-Amyl alcohol for 2h; Heating;98%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

2-o-tolylethanol
19819-98-8

2-o-tolylethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether97%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 3h; Inert atmosphere; Schlenk technique; Reflux;88%
With hydrogen In neat (no solvent) at 160℃; under 37503.8 Torr; for 24h;84%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

2-chloromethylphenylacetic acid
95335-46-9

2-chloromethylphenylacetic acid

chlorobenzene
108-90-7

chlorobenzene

phenylacetic acid
103-82-2

phenylacetic acid

Conditions
ConditionsYield
With sulfuryl dichloride96.8%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

N,O-dimethylhydroxylamine*hydrochloride
6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

N-methoxy-N-methyl-2-(2-methylphenyl)acetamide
918417-27-3

N-methoxy-N-methyl-2-(2-methylphenyl)acetamide

Conditions
ConditionsYield
Stage #1: o-methylphenylacetic acid; N,O-dimethylhydroxylamine*hydrochloride In chloroform for 0.166667h; Cooling with ice;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In chloroform for 0.166667h;
Stage #3: With triethylamine In chloroform for 3.16667h;
96%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; Inert atmosphere;94%
Stage #1: o-methylphenylacetic acid With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 0℃; for 0.25h;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride With triethylamine In dichloromethane at 20℃; for 1h; chemoselective reaction;
80%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

ethyl acrylate
140-88-5

ethyl acrylate

(E)-2-(2-(3-ethoxy-3-oxoprop-1-en-1-yl)-6-methylphenyl)acetic acid
1215037-90-3

(E)-2-(2-(3-ethoxy-3-oxoprop-1-en-1-yl)-6-methylphenyl)acetic acid

Conditions
ConditionsYield
With (2S,3S)-N-acetyl-2-amino-3-methylpentanoic acid; oxygen; palladium diacetate; potassium hydrogencarbonate In tert-Amyl alcohol at 90℃; under 760.051 Torr; for 2h; Kinetics; Mechanism; Reagent/catalyst;96%
With (S)-acetamidoalanine; palladium diacetate; potassium hydrogencarbonate In tert-Amyl alcohol at 90℃; for 2h;54%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

3-(o-tolyl)propanenitrile
26016-32-0

3-(o-tolyl)propanenitrile

Conditions
ConditionsYield
Stage #1: o-methylphenylacetic acid With indium(III) bromide; 1,1,3,3-Tetramethyldisiloxane; iodine In chloroform at 60℃; Inert atmosphere;
Stage #2: trimethylsilyl cyanide With tetrabutyl ammonium fluoride In tetrahydrofuran; chloroform at 60℃; for 5h; Reagent/catalyst; Inert atmosphere; chemoselective reaction;
96%
Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C14H18O3

C14H18O3

Conditions
ConditionsYield
With β-cyclodextrin-SO3H In neat (no solvent) at 70℃; for 3h;96%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

o-Tolylacetic acid 4-nitro-benzyl ester
866785-40-2

o-Tolylacetic acid 4-nitro-benzyl ester

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzene at 50℃; for 20h;95%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C6H4BClF3*K(1+)

C6H4BClF3*K(1+)

2-(4'-chloro-3-methyl-[1,1'-biphenyl]-2-yl)acetic acid
1342343-95-6

2-(4'-chloro-3-methyl-[1,1'-biphenyl]-2-yl)acetic acid

Conditions
ConditionsYield
With palladium diacetate; potassium hydrogencarbonate; N-acetyl-L-isoleucine; silver carbonate; p-benzoquinone In tert-Amyl alcohol for 2h; Heating;95%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

3,5-bis(trifluoromethyl)iodobenzene
328-73-4

3,5-bis(trifluoromethyl)iodobenzene

2-(4-methyl-3',5'-bis(trifluoromethyl)-[1,1'-biphenyl]-3-yl)acetic acid

2-(4-methyl-3',5'-bis(trifluoromethyl)-[1,1'-biphenyl]-3-yl)acetic acid

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate; (3r,5r,7r)-N-(2-hydroxy-5-(trifluoromethyl)pyridin-3-yl)adamantane-1-carboxamide; palladium diacetate; silver carbonate at 100℃; for 24h;95%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

2-(1-cyclohexenyl)ethylamine
3399-73-3

2-(1-cyclohexenyl)ethylamine

N-[2-(cyclohex-1-en-1-yl)ethyl]-2-(o-tolyl)acetamide

N-[2-(cyclohex-1-en-1-yl)ethyl]-2-(o-tolyl)acetamide

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; Inert atmosphere;95%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

propargyl alcohol
107-19-7

propargyl alcohol

C12H12O2
90705-93-4

C12H12O2

Conditions
ConditionsYield
With β-cyclodextrin-SO3H In neat (no solvent) at 70℃; for 4h;94%
With toluene-4-sulfonic acid at 80℃;
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

3,5-dimethylphenyl iodide
22445-41-6

3,5-dimethylphenyl iodide

2-(3',4,5'-trimethyl-[1,1'-biphenyl]-3-yl)acetic acid

2-(3',4,5'-trimethyl-[1,1'-biphenyl]-3-yl)acetic acid

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate; (3r,5r,7r)-N-(2-hydroxy-5-(trifluoromethyl)pyridin-3-yl)adamantane-1-carboxamide; palladium diacetate; silver carbonate at 100℃; for 24h;94%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl iodide
74-88-4

methyl iodide

methyl 2-[2-(bromomethyl)phenyl]acetate
13737-37-6

methyl 2-[2-(bromomethyl)phenyl]acetate

Conditions
ConditionsYield
Stage #1: o-methylphenylacetic acid; methyl iodide With sodium hydrogencarbonate In N,N-dimethyl-formamide at 20℃; for 12h;
Stage #2: With N-Bromosuccinimide In acetonitrile at 80℃; for 2h;
94%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl iodide
74-88-4

methyl iodide

(rac)-2-(2-methylphenyl)propanoic acid
137144-15-1, 144789-13-9, 62835-95-4

(rac)-2-(2-methylphenyl)propanoic acid

Conditions
ConditionsYield
Stage #1: o-methylphenylacetic acid With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
93%
Stage #1: o-methylphenylacetic acid With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
82%
Stage #1: o-methylphenylacetic acid With n-butyllithium; lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
59%

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