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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

METHYL O-TOLYLACETATE CAS 40851-62-5

Cas:40851-62-5

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

Methyl o-tolylacetate

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl o-tolylacetate

Cas:40851-62-5

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

Methyl o-tolylacetate

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

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Antimex Chemical Limied

hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

Benzeneaceticacid,2-methyl-,methylester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

40851-62-5

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jinan Liheng Biological Technology Co., Ltd.

In stock, the process is mature and stable, and can be customized according to customer needs.Appearance:Colorless to yellow liquid Storage:Store at room temperature, airtight, shading, separate by category Package:0.1kg/0.5kg/1kg/25kg Application:Sy

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

Methyl o-tolylacetate

Cas:40851-62-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zouping Sanhao Chemical Co., Ltd .

Yellow liquid Application:organic chemicals

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the METHYL O-TOLYLACETATE, CAS:40851-62-5 with the most competitive price and the best qu

METHYL O-TOLYLACETATE

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Co.Ltd

Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

2-Methyl-benzeneacetic acid methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

CHEMSWORTH

Benzeneacetic acid,2-methyl-, methyl ester

Cas:40851-62-5

Min.Order:0

Negotiable

Type:

inquiry

Synthetic route

methanol
67-56-1

methanol

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With sulfuric acid at 0℃; for 8h; Reflux; Inert atmosphere;100%
With sulfuric acid for 6.5h; Inert atmosphere; Reflux;99%
With sulfuric acid at 28℃; for 12h;98%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With sulfuric acid In methanol98%
With sulfuric acid In methanol98%
With sulfuric acid In formic acid for 6h; Reflux;
1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
94%
methanol
67-56-1

methanol

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With sulfuric acid; trimethyl orthoformate at 20℃; for 0.333333h;91%
methanol
67-56-1

methanol

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

trimethyl orthoformate
149-73-5

trimethyl orthoformate

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With iodine; silver nitrate for 5h; Heating;90%
1-methoxycarbonylmethyl-2-methyl-2,5-cyclohexadiene-1-carboxylic acid
1202873-25-3

1-methoxycarbonylmethyl-2-methyl-2,5-cyclohexadiene-1-carboxylic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;87%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

2-methyl-benzyl alcohol
89-95-2

2-methyl-benzyl alcohol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; 1,3-bis-(diphenylphosphino)propane at 135℃; under 15001.5 Torr; for 24h; Autoclave; Green chemistry;81%
methanol
67-56-1

methanol

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

A

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

B

2-methoxy-1-(2-methylphenyl)ethanone
97728-46-6

2-methoxy-1-(2-methylphenyl)ethanone

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene at 60℃; for 1h;A 62%
B 13%
o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
In diethyl ether
o-(methoxycarbonylmethyl)benzoic acid
14736-50-6

o-(methoxycarbonylmethyl)benzoic acid

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
(i) furan-2-carbonyl chloride, Et3N, (ii) H2, Pd(OH)2-BaSO4; Multistep reaction;
3-methylbenzocyclobutenone
62708-44-5

3-methylbenzocyclobutenone

sodium methylate
124-41-4

sodium methylate

A

methyl 2,3-dimethylbenzoate
15012-36-9

methyl 2,3-dimethylbenzoate

B

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
In methanol at 65℃; for 2h; Yield given. Yields of byproduct given;
2-tolylmethylnitrile
22364-68-7

2-tolylmethylnitrile

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

2-(methoxymethoxy)-2-(2-methylbenzyl)malononitrile

2-(methoxymethoxy)-2-(2-methylbenzyl)malononitrile

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: (R)-10-camphorsulfonic acid; acetic acid / 1,2-dimethoxyethane / 5 h / 60 °C / Sealed tube; Inert atmosphere
2: triethylamine / 1,2-dimethoxyethane / -40 - 0 °C / Inert atmosphere
View Scheme
2-methyl-benzyl alcohol
89-95-2

2-methyl-benzyl alcohol

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 41 h / 0 - 23 °C / Inert atmosphere
2: (R)-10-camphorsulfonic acid; acetic acid / 1,2-dimethoxyethane / 5 h / 60 °C / Sealed tube; Inert atmosphere
3: triethylamine / 1,2-dimethoxyethane / -40 - 0 °C / Inert atmosphere
View Scheme
methanol
67-56-1

methanol

C11H10N2O

C11H10N2O

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

Conditions
ConditionsYield
With triethylamine In 1,2-dimethoxyethane at -40 - 0℃; Mitsunobu Displacement; Inert atmosphere;14 mg
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 2-[2-(bromomethyl)phenyl]acetate
13737-37-6

methyl 2-[2-(bromomethyl)phenyl]acetate

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane100%
With N-Bromosuccinimide In acetonitrile Irradiation;70%
With bromine Irradiation;
Methyl formate
107-31-3

Methyl formate

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 3-oxo-2-o-tolylpropanoate

methyl 3-oxo-2-o-tolylpropanoate

Conditions
ConditionsYield
With sodium hydride In toluene at 0 - 28℃; for 13h; Inert atmosphere;98%
Methyl formate
107-31-3

Methyl formate

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 2-(2-methyl phenyl)-3-hydroxy-2-propenoate
139191-69-8

methyl 2-(2-methyl phenyl)-3-hydroxy-2-propenoate

Conditions
ConditionsYield
Stage #1: methyl o-tolylacetate With sodium methylate In toluene
Stage #2: Methyl formate In toluene at 0 - 20℃;
Stage #3: With hydrogenchloride In water pH=4 - 5;
95%
Stage #1: Methyl formate; methyl o-tolylacetate In toluene at 10 - 20℃;
Stage #2: With hydrogenchloride In water pH=4 - 5;
95%
With sodium hydroxide
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

2-o-tolylethanol
19819-98-8

2-o-tolylethanol

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride In tetrahydrofuran; hexane; water at 0 - 20℃; pH=1; Inert atmosphere;92%
Stage #1: methyl o-tolylacetate With [CpFe(CO)2(PCy3)][BF4]; phenylsilane at 100℃; for 24h; Irradiation; Neat (no solvent); Inert atmosphere;
Stage #2: With hydrogenchloride; water In tetrahydrofuran at 20℃; for 1h;
73%
With diisobutylaluminium hydride In tetrahydrofuran; toluene at 20℃;
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

propionyl chloride
79-03-8

propionyl chloride

C13H16O3
364374-63-0

C13H16O3

Conditions
ConditionsYield
aluminum (III) chloride In carbon disulfide at 0℃; for 4h; Heating / reflux;91%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl α-(2-methylphenyl)-α-diazoacetate

methyl α-(2-methylphenyl)-α-diazoacetate

Conditions
ConditionsYield
With 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; Inert atmosphere;89%
With 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃;81%
With 4-acetamidobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; Inert atmosphere;70%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

5-amino-1-[1-(1-hydroxyethyl)-2-phenylethyl]-1H-imidazole-4-carboxamide

5-amino-1-[1-(1-hydroxyethyl)-2-phenylethyl]-1H-imidazole-4-carboxamide

9-(1-benzyl-2-hydroxypropyl)-2-(2-methylbenzyl)-1,9-dihydropurin-6-one

9-(1-benzyl-2-hydroxypropyl)-2-(2-methylbenzyl)-1,9-dihydropurin-6-one

Conditions
ConditionsYield
With sodium methylate In methanol Reflux;88%
1-bromo-4-butene
5162-44-7

1-bromo-4-butene

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 2-(o-tolyl)hex-5-enoate

methyl 2-(o-tolyl)hex-5-enoate

Conditions
ConditionsYield
Stage #1: methyl o-tolylacetate With n-butyllithium; diisopropylamine In tetrahydrofuran; diethyl ether for 0.5h; Inert atmosphere;
Stage #2: 1-bromo-4-butene With N,N,N,N,N,N-hexamethylphosphoric triamide In tetrahydrofuran; diethyl ether Inert atmosphere;
87%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

benzaldehyde
100-52-7

benzaldehyde

syn-methyl 3-hydroxy-3-phenyl-2-o-tolylpropanoate

syn-methyl 3-hydroxy-3-phenyl-2-o-tolylpropanoate

anti-methyl 3-hydroxy-3-phenyl-2-o-tolylpropanoate

anti-methyl 3-hydroxy-3-phenyl-2-o-tolylpropanoate

Conditions
ConditionsYield
Stage #1: methyl o-tolylacetate With triethylamine; dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane In dichloromethane at -78℃; for 2h; Inert atmosphere;
Stage #2: benzaldehyde In dichloromethane at -78℃; for 3h; Aldol Condensation; Inert atmosphere; Overall yield = 90percent; diastereoselective reaction;
A n/a
B 84%
Stage #1: methyl o-tolylacetate With di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: benzaldehyde In dichloromethane at 20℃; for 3h; Aldol Condensation; Inert atmosphere; Overall yield = 84percent; diastereoselective reaction;
A 77%
B n/a
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

C10H12(2)H2O2

C10H12(2)H2O2

Conditions
ConditionsYield
With C29H46IrN3P(1+)*C32H12BF24(1-); deuterium In chlorobenzene at 20℃; under 760.051 Torr; for 2h; Sealed tube;82%
formaldehyd
50-00-0

formaldehyd

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 2-(2-methylphenyl)acrylate
127560-52-5

methyl 2-(2-methylphenyl)acrylate

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate In toluene at 80℃; for 12h;80%
With potassium carbonate; calcium oxide In N,N-dimethyl-formamide at 40℃; for 16h;75%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In toluene at 20 - 50℃;56%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl 1-hydroxycyclohexanecarboxylate
6149-50-4

methyl 1-hydroxycyclohexanecarboxylate

4-hydroxy-3-o-tolyl-1-oxaspiro[4.5]dec-3-en-2-one

4-hydroxy-3-o-tolyl-1-oxaspiro[4.5]dec-3-en-2-one

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran Inert atmosphere; Reflux;78%
With potassium tert-butylate In tetrahydrofuran Dieckmann Condensation; Reflux;
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

C14H21NO2S

C14H21NO2S

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 103℃; Inert atmosphere; Schlenk technique;78%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

2, 4-dichloro-5-(iodomethyl)pyrimidine
7627-44-3

2, 4-dichloro-5-(iodomethyl)pyrimidine

3-(2,4-Dichloro-pyrimidin-5-yl)-2-O-tolyl-propionic acid methyl ester
710324-40-6

3-(2,4-Dichloro-pyrimidin-5-yl)-2-O-tolyl-propionic acid methyl ester

Conditions
ConditionsYield
Stage #1: methyl o-tolylacetate With n-butyllithium; N-cyclohexylisopropylamine In tetrahydrofuran; hexanes at -78℃; for 1h;
Stage #2: 2, 4-dichloro-5-(iodomethyl)pyrimidine In tetrahydrofuran at -78 - -30℃; for 1.16667h;
77.2%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

dimethyl sulfate
77-78-1

dimethyl sulfate

trimethyl orthoformate
149-73-5

trimethyl orthoformate

(E)-methyl 3-methoxy-2-(2-methylphenyl)propenoate
103455-45-4

(E)-methyl 3-methoxy-2-(2-methylphenyl)propenoate

Conditions
ConditionsYield
Stage #1: trimethyl orthoformate With titanium tetrachloride In 1,2-dichloro-ethane at 10 - 20℃; for 1h; Inert atmosphere;
Stage #2: methyl o-tolylacetate In 1,2-dichloro-ethane at 0 - 20℃; for 2h; Inert atmosphere;
Stage #3: dimethyl sulfate Further stages;
75.1%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

1-(2-iodoethyl)-2-methylbenzene
178685-03-5

1-(2-iodoethyl)-2-methylbenzene

Conditions
ConditionsYield
With indium(III) bromide; methyldiphenylsilane; iodine In chloroform at 60℃; for 3h; Inert atmosphere; Sealed tube;75%
triethylsilane
617-86-7

triethylsilane

methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

C16H28O2Si

C16H28O2Si

Conditions
ConditionsYield
With decacarbonyldirhenium(0) In toluene at 30℃; for 9h; Reagent/catalyst; Inert atmosphere; UV-irradiation; Schlenk technique;75%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

methyl thioisocyanate
556-61-6

methyl thioisocyanate

C12H15NO2S
1262547-26-1

C12H15NO2S

Conditions
ConditionsYield
Stage #1: methyl o-tolylacetate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h;
Stage #2: methyl thioisocyanate In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h;
74%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

o-nitrobenzonitrile
612-24-8

o-nitrobenzonitrile

C17H14N2O4

C17H14N2O4

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide at 20℃; for 0.5h; regioselective reaction;74%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

5-amino-1-(4-phenylbutyl)-1H-imidazole-4-carboxamide

5-amino-1-(4-phenylbutyl)-1H-imidazole-4-carboxamide

2-(2-methylbenzyl)-9-(4-phenylbutyl)-1,9-dihydro-purin-6-one

2-(2-methylbenzyl)-9-(4-phenylbutyl)-1,9-dihydro-purin-6-one

Conditions
ConditionsYield
In methanol Reflux;62%
methyl o-tolylacetate
40851-62-5

methyl o-tolylacetate

5-amino-1-(3-phenylpropyl)-1H-imidazole-4-carboxamide

5-amino-1-(3-phenylpropyl)-1H-imidazole-4-carboxamide

2-(2-methylbenzyl)-9-(3-phenylpropyl)-1,9-dihydropurin-6-one

2-(2-methylbenzyl)-9-(3-phenylpropyl)-1,9-dihydropurin-6-one

Conditions
ConditionsYield
With sodium methylate In methanol Reflux;57%

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