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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity (R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Senova Pharma

Multi-target purpose intermediate with wide usage Commercial production from grams to tons, with technical documents package support, and audit and inspection support. With high purity and optimized and stable process. Self Innovation Appe

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

(R)-(+)-2-Methyl-2-propanesulfinamide Manufacturer/High quality/Best price/In stock

Cas:196929-78-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality (R)-(+)-2-Methyl-2-Propanesulfinamide supplier in China

Cas:196929-78-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White to off-white crystals conforms purity 99%min

High purity (R)-(+)-2-Methyl-2-propanesulfinamide CAS:196929-78-9

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (R)-2-methylpropane-2-sulfinamide

Cas:196929-78-9

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price API 99% (R)-(+)-2-Methyl-2-propanesulfinamide 196929-78-9 GMP Manufacturer

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

CHemwill -- (R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1875.html Product Name (R)-(+)-2-Methyl-2-propanesulfinamide CAS No.

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

(R)-(+)-2-Methyl-2-propanesulfinamide Basic information Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable busin

best offer (R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 196929-78-9 with best quality

Cas:196929-78-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

(R)-(+)-2-Methyl-2-propanesulfinamide/ LIDE PHARMA- Factory supply / Best price

Cas:196929-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product Name: (R)-(+)-2-Methyl-2-propanesulfinamide Synonyms: R- tert butyl sulfenaMide;(R)-(+)-TERT-BUTANESULFINAMIDE;(R)-TERT-BUTANESULFINAMIDE;(R)-(+)-T-BUTANESULFINAMIDE;(R)-(+)-T-BUTYLMETHYLSULFINAMIDE

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing ways;

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

(R)-(+)-2-Methyl-2-propanesulfinamide 196929-78-9

Cas:196929-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

(R)-(+)-2-Methyl-2-propanesulfinamide Chemical Properties Melting point 103-107 °C(lit.) alpha 4 º (c=1, CHCl3 + amylenes) Boiling point 220.0±23.0 °C(Predicted) density 0.903 g/mL at 25 °C refractive index

(R)-(+)-2-Methyl-2-propanesulfinamide.

Cas:196929-78-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

(R)-(+)-2-Methyl-2-propanesulfinamide CAS:196929-78-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qu

(R)-(+)-2-Methyl-2-propanesulfinamide CAS:196929-78-9

Cas:196929-78-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

(R)-(+)-2-Methyl-2-Propanesulfinamide

Cas:196929-78-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

(R)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $29.0

Type:Trading Company

inquiry

Triumph International Development Limilted

(R)-(+)-tert-Butylsulfinamide,196929-78-9 Appearance:white or off -white power Storage:kept in a cool, dry and ventilated place Package:As customer request Application:Pharmaceutical Intermediates Transportation:By Sea,by Air,By cou

top quality tbe best price (R)-(+)-2-Methyl-2-propanesulfinamide supplier

Cas:196929-78-9

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $1.0 / 100000.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

(R)-(+)-Tert-butane sulfinamide

Cas:196929-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(R)-2-methylpropane-2-sulfinamide

Cas:196929-78-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Hope Chem Co., Ltd

1. Product advantages: exquisite appearance and unique functions. 2. Product Advantages: Our products are the best,fast speed ,in large stock 3. High-quality products and thoughtful service are your greatest satisfaction. 4. The product

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

(R)-(+)-2-Methyl-2-propanesulfinamide

Cas:196929-78-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Synthetic route

(RS,S)-N-(3-hydroxy-1,3-diphenylpropylidene)-tert-butanesulfinamide
441788-45-0

(RS,S)-N-(3-hydroxy-1,3-diphenylpropylidene)-tert-butanesulfinamide

A

(S)-3-hydroxy-1,3-diphenyl-propan-1-one
42052-51-7, 69897-46-7, 72237-27-5, 93059-59-7

(S)-3-hydroxy-1,3-diphenyl-propan-1-one

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With acetic acid In methanol at 40℃; for 20h;A 99%
B n/a
(RS,S)-N-(3-hydroxy-4-methyl-1-phenylpentylidene)-tert-butanesulfinamide
441788-43-8

(RS,S)-N-(3-hydroxy-4-methyl-1-phenylpentylidene)-tert-butanesulfinamide

A

(3S)-3-hydroxy-4-methyl-1-phenylpentan-4-one

(3S)-3-hydroxy-4-methyl-1-phenylpentan-4-one

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With acetic acid In methanol at 40℃; for 20h;A 98%
B n/a
(R)-4-chloro-2-((R)-1-(4-methylphenylsulfonamido)ethyl)phenyl 2-methylpropane-2-sulfinate

(R)-4-chloro-2-((R)-1-(4-methylphenylsulfonamido)ethyl)phenyl 2-methylpropane-2-sulfinate

A

(R)-N-(1-(5-chloro-2-hydroxyphenyl)ethyl)-4-methylbenzenesulfonamide
1421840-44-9

(R)-N-(1-(5-chloro-2-hydroxyphenyl)ethyl)-4-methylbenzenesulfonamide

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at -10℃; for 2.5h; Concentration; Temperature; Time; Inert atmosphere;A 94%
B 85%
(R)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl tert-butanesulfinate
159263-57-7

(R)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl tert-butanesulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
Stage #1: (R)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl tert-butanesulfinate With lithium hexamethyldisilazane In tetrahydrofuran at 0℃; for 48h; Inert atmosphere;
Stage #2: With silica gel In tetrahydrofuran; methanol for 0.25h; Inert atmosphere;
92%
With aluminum oxide; potassium fluoride; lithium hexamethyldisilazane 1.) THF, from -78 deg C to RT, overnight, 2.) THF, 0 deg C, 1 h; Yield given. Multistep reaction;
2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester
861821-86-5

2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With ammonia; lithium; ferric nitrate In tetrahydrofuran at -78℃; for 0.5h;90%
2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester
446021-65-4

2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium amide; ammonia In tetrahydrofuran at -78℃;90%
(4S,5R)-3-((S)-2-Methyl-propane-2-sulfinyl)-4,5-diphenyl-oxazolidin-2-one
813459-77-7

(4S,5R)-3-((S)-2-Methyl-propane-2-sulfinyl)-4,5-diphenyl-oxazolidin-2-one

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With ammonia; lithium; ferric nitrate at -78℃; for 0.5h;89%
(R)-tert-butylsulfinyl hydrazide

(R)-tert-butylsulfinyl hydrazide

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With acetic acid; zinc In dichloromethane at 35 - 42℃; for 16h; Green chemistry;83%
With acetic acid; zinc In dichloromethane at 35 - 42℃; for 16h;83%
With acetic acid; zinc In dichloromethane at 35 - 42℃; for 16h;83%
(RS)-N-benzyl-2-methylpropane-2-sulfinamide
212378-92-2

(RS)-N-benzyl-2-methylpropane-2-sulfinamide

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With ammonia; lithium; ammonium chloride at -40℃; for 0.5h;82%
(R)-DAG tert-butylsulfinate

(R)-DAG tert-butylsulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 48h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;80%
(R)-tert-butyl tert-butanethiosulfinate
67734-35-4

(R)-tert-butyl tert-butanethiosulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With n-butyllithium; ammonia at -50 - 0℃; for 1h; Temperature; Concentration; Solvent;79%
With lithium amide; ammonia at -78℃; for 0.25h;77%
With Iron(III) nitrate nonahydrate; lithium amide; ammonia at -78℃;48%
With lithium amide; ammonia In tetrahydrofuran at -78℃; Yield given;
(1S)-(6-methoxyquinolin-4-yl)(5-vinylquinuclidin-2-yl)methyl-(R)-2-tert-butylsulfinate

(1S)-(6-methoxyquinolin-4-yl)(5-vinylquinuclidin-2-yl)methyl-(R)-2-tert-butylsulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With ammonia; lithium; ferric nitrate In tetrahydrofuran at -78℃; for 0.75h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;79%
quinine

quinine

tert-butylmagnesium chloride
677-22-5

tert-butylmagnesium chloride

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
Stage #1: quinine With thionyl chloride; triethylamine at -78 - -37℃; for 1h;
Stage #2: tert-butylmagnesium chloride at -78 - 75℃; for 2h;
Stage #3: With lithium hexamethyldisilazane
70%
2-fluoro-1-(2-fluorophenyl)ethan-1-one
1402412-84-3

2-fluoro-1-(2-fluorophenyl)ethan-1-one

A

(R)-2-methyl-propane-2-sulfinic acid [2-fluoro-1-(2-fluoro-phenyl)-eth-(E)-ylidene]-amide
1415914-97-4

(R)-2-methyl-propane-2-sulfinic acid [2-fluoro-1-(2-fluoro-phenyl)-eth-(E)-ylidene]-amide

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
A 62%
B n/a
di-tert-butyl disulfide
110-06-5

di-tert-butyl disulfide

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
Stage #1: di-tert-butyl disulfide With bis(acetylacetonate)oxovanadium; (1S,2R)-1-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)-2,3-dihydro-1H-inden-2-ol; dihydrogen peroxide In acetone at 0℃;
Stage #2: With ammonia; lithium; ferric nitrate In tetrahydrofuran at -78℃;
60%
2-propyl tert-butanesulfinate
102101-45-1

2-propyl tert-butanesulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate; ammonia; lithium In 2-methyltetrahydrofuran at -65 - -50℃; Inert atmosphere;60%
2-Methyl-propane-2-sulfinic acid ((R)-3-[1,3]dioxan-2-yl-1-phenyl-propyl)-amide
860640-13-7

2-Methyl-propane-2-sulfinic acid ((R)-3-[1,3]dioxan-2-yl-1-phenyl-propyl)-amide

A

2-phenyl-3,4-dihydro-2H-pyrrole

2-phenyl-3,4-dihydro-2H-pyrrole

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

C

trimethyleneglycol
504-63-2

trimethyleneglycol

Conditions
ConditionsYield
With trifluoroacetic acid-d1 In water-d2 for 0.25h;
2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester
861821-86-5

2-Methyl-propane-2-sulfinic acid (1R,2S)-1-(2,4,6-trimethyl-benzenesulfonylamino)-indan-2-yl ester

A

N-((1R,2S)-2-Hydroxy-indan-1-yl)-2,4,6-trimethyl-benzenesulfonamide
175848-32-5

N-((1R,2S)-2-Hydroxy-indan-1-yl)-2,4,6-trimethyl-benzenesulfonamide

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium amide; ammonia at -78℃;
ethyl tert-butanesulfinate
120424-96-6

ethyl tert-butanesulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With ammonia; sodium; ferric nitrate In cyclopentyl methyl ether at -48 - 20℃; Inert atmosphere; optical yield given as %ee;6.47 g
C21H29NO4S2
1310105-98-6

C21H29NO4S2

A

C17H21NO3S
620627-46-5

C17H21NO3S

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium amide; ammonia at -60 - 20℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
phenyl 2-methylpropane-2-sulfinate

phenyl 2-methylpropane-2-sulfinate

A

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 1.5h; Inert atmosphere;
phenyl 2-methylpropane-2-sulfinate

phenyl 2-methylpropane-2-sulfinate

A

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

B

(S)-2-methylpropane-2-sulfinamide
343338-28-3

(S)-2-methylpropane-2-sulfinamide

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 1.5h; Inert atmosphere;A n/a
B n/a
C n/a
4-chlorophenyl 2-methylpropane-2-sulfinate

4-chlorophenyl 2-methylpropane-2-sulfinate

A

4-chloro-phenol
106-48-9

4-chloro-phenol

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere;
4-methoxyphenyl 2-methylpropane-2-sulfinate

4-methoxyphenyl 2-methylpropane-2-sulfinate

A

4-methoxy-phenol
150-76-5

4-methoxy-phenol

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
2,2,2-trifluoro-1-phenylethyl 2-methylpropane-2-sulfinate

2,2,2-trifluoro-1-phenylethyl 2-methylpropane-2-sulfinate

A

1-phenyl-2,2,2-trifluoromethylethanol
340-04-5, 340-05-6

1-phenyl-2,2,2-trifluoromethylethanol

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 10h; Inert atmosphere;
1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl 2-methylpropane-2-sulfinate

1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl 2-methylpropane-2-sulfinate

A

1,1,1,3,3,3-hexafluoro-2-(p-tolyl)propan-2-ol
2010-61-9

1,1,1,3,3,3-hexafluoro-2-(p-tolyl)propan-2-ol

B

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 3h; Inert atmosphere;
tert-butyl tert-butanethiosulfinate
31562-40-0

tert-butyl tert-butanethiosulfinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
Stage #1: tert-butyl tert-butanethiosulfinate With Iron(III) nitrate nonahydrate; ammonia; lithium In tetrahydrofuran at -78 - 20℃; for 16.75h; Inert atmosphere;
Stage #2: With water; chloroacetic acid In tetrahydrofuran at 20℃; for 12.3333h; Inert atmosphere; Cooling with ice;
(+)-(S)-n-Propyl t-butylsulphinate
102101-42-8

(+)-(S)-n-Propyl t-butylsulphinate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate; ammonia; sodium In tert-butyl methyl ether at -75 - -55℃; Inert atmosphere;14.5 g
propionaldehyde
123-38-6

propionaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-(-)-N-(propylidene)-2-methylpropane-2-sulfinamide
221375-47-9

(R)-(-)-N-(propylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 3h; Condensation;100%
With magnesium sulfate In dichloromethane96%
With copper(II) sulfate In dichloromethane for 20h; Inert atmosphere;54%
With titanium(IV) isopropylate In tetrahydrofuran at 50℃;
3-methyl-butan-2-one
563-80-4

3-methyl-butan-2-one

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(3-methylbutan-2-ylidene)-2-methylpropane-2-sulfinamide
866993-51-3

(R)-N-(3-methylbutan-2-ylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 75℃;100%
With titanium(IV) tetraethanolate In tetrahydrofuran Reflux;75%
With titanium(IV) tetraethanolate In tetrahydrofuran at 60 - 75℃; Condensation;
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(RS,E)-(-)-N-(3-phenylpropyl)idene-tert-butanesulfinamide
336105-29-4

(RS,E)-(-)-N-(3-phenylpropyl)idene-tert-butanesulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In dichloromethane at 20℃; for 1.5h;100%
With titanium(IV) tetraethanolate In tetrahydrofuran; isopropyl alcohol for 5h;91%
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃; for 24h;90%
butyraldehyde
123-72-8

butyraldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(RS,E)-N-butylidene-2-methylpropane-2-sulfinamide
479480-49-4

(RS,E)-N-butylidene-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With molecular sieve; copper(II) sulfate In dichloromethane at 20℃;100%
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃; for 24h;87%
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃; for 20h;85%
4-(4-fluoro-6-formyl-phenyl)-piperazine-1-carboxylic acid tert-butyl ester
697305-53-6

4-(4-fluoro-6-formyl-phenyl)-piperazine-1-carboxylic acid tert-butyl ester

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

4-{4-fluoro-2-[((RS)-2-methyl-propane-2-sulfinylimino)-methyl]-phenyl}-piperazine-1-carboxylic acid tert-butyl ester
869478-21-7

4-{4-fluoro-2-[((RS)-2-methyl-propane-2-sulfinylimino)-methyl]-phenyl}-piperazine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran; ethanol at 20℃; for 7h;100%
4-(2-chloro-6-formyl-phenyl)-piperazine-1-carboxylic acid tert-butyl ester
869478-15-9

4-(2-chloro-6-formyl-phenyl)-piperazine-1-carboxylic acid tert-butyl ester

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

4-{2-chloro-6-[((RS)-2-methyl-propane-2-sulfinylimino)-methyl]-phenyl}-piperazine-1-carboxylic acid tert-butyl ester

4-{2-chloro-6-[((RS)-2-methyl-propane-2-sulfinylimino)-methyl]-phenyl}-piperazine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran; ethanol at 20℃; for 24h;100%
N-(4-acetyl-2,5-difluorophenyl)methanesulfonamide
910487-21-7

N-(4-acetyl-2,5-difluorophenyl)methanesulfonamide

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

N-[4-((1R)-1-{[(R)-tert-butylsulfinyl]amino}ethyl)-2,5-difluorophenyl]methanesulfonamide
910487-22-8

N-[4-((1R)-1-{[(R)-tert-butylsulfinyl]amino}ethyl)-2,5-difluorophenyl]methanesulfonamide

Conditions
ConditionsYield
Stage #1: N-(4-acetyl-2,5-difluorophenyl)methanesulfonamide; (R)-2-methylpropane-2-sulfinamide With titanium(IV) tetraethanolate In tetrahydrofuran at 70℃; for 30h;
Stage #2: With sodium tetrahydroborate In tetrahydrofuran at 0 - 20℃; for 18h;
Stage #3: With methanol; water In tetrahydrofuran
100%
N-(4-acetyl-2,6-difluorophenyl)methanesulfonamide
956901-21-6

N-(4-acetyl-2,6-difluorophenyl)methanesulfonamide

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

N-[4-[(1R)-1-[[(R)-(1,1-dimethylethyl)sulfinyl]amino]ethyl]-2,6-difluorophenyl]methanesulfonamide
956901-22-7

N-[4-[(1R)-1-[[(R)-(1,1-dimethylethyl)sulfinyl]amino]ethyl]-2,6-difluorophenyl]methanesulfonamide

Conditions
ConditionsYield
Stage #1: N-(4-acetyl-2,6-difluorophenyl)methanesulfonamide; (R)-2-methylpropane-2-sulfinamide With titanium(IV) tetraethanolate In tetrahydrofuran at 70℃; for 18h;
Stage #2: With sodium tetrahydroborate In tetrahydrofuran at -20 - 20℃; for 16h;
Stage #3: With methanol; water In tetrahydrofuran
100%
Stage #1: N-(4-acetyl-2,6-difluorophenyl)methanesulfonamide; (R)-2-methylpropane-2-sulfinamide With titanium(IV) tetraethanolate In tetrahydrofuran at 70℃; for 18h;
Stage #2: With sodium tetrahydroborate In tetrahydrofuran at -20 - 20℃; for 16h;
100%
ethyl 5-formyl-4-methyl-3-(pent-4-enyloxy)-1H-pyrrole-2-carboxylate
1020414-47-4

ethyl 5-formyl-4-methyl-3-(pent-4-enyloxy)-1H-pyrrole-2-carboxylate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-ethyl 4-methyl-5-[(2-methylpropan-2-ylsulfinyl)iminomethyl]-3-pent-4-enyloxy-1H-pyrrole-2-carboxylate
1020414-52-1

(R)-ethyl 4-methyl-5-[(2-methylpropan-2-ylsulfinyl)iminomethyl]-3-pent-4-enyloxy-1H-pyrrole-2-carboxylate

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In dichloromethane at 35℃; for 48h;100%
(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

Cyclopropanecarboxaldehyde
1489-69-6

Cyclopropanecarboxaldehyde

[N(E),R(S)]-N-(cyclopropylmethylene)-2-methyl-2-propanesulfinamide
736947-01-6

[N(E),R(S)]-N-(cyclopropylmethylene)-2-methyl-2-propanesulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 17h;100%
With copper(II) sulfate In dichloromethane at 20℃; Inert atmosphere;100%
With titanium(IV) tetraethanolate In tetrahydrofuran at 75℃; for 2h;90%
isobutyraldehyde
78-84-2

isobutyraldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(tert-butanesulfinyl)-N-(2-methylpropyliden)amine
196929-86-9

(R)-N-(tert-butanesulfinyl)-N-(2-methylpropyliden)amine

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;100%
With titanium(IV) tetraethanolate In tetrahydrofuran at 23℃; for 12h; Inert atmosphere;82%
With titanium(IV) tetraethanolate at 70℃; for 0.166667h; Neat (no solvent); Microwave irradiation; Inert atmosphere;53%
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide

(R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) isopropylate In tetrahydrofuran at 20℃; for 16.0833h;100%
With p-toluenesulfonic acid on sillica gel; water In neat (no solvent) for 0.5h; Sonication; Green chemistry;95%
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 16h; Inert atmosphere;
(3aS,6S,6aS)-2,2-dimethyl-6-vinyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol

(3aS,6S,6aS)-2,2-dimethyl-6-vinyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-((3aS,4R,6S,6aS)-2,2-dimethyl-6-vinyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)-2-methylpropane-2-sulfinamide
1359756-29-8

(R)-N-((3aS,4R,6S,6aS)-2,2-dimethyl-6-vinyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane for 3h; Reflux; Inert atmosphere; stereospecific reaction;100%
4-chloro-3-fluoro-2-formylpyridine
1260878-78-1

4-chloro-3-fluoro-2-formylpyridine

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(S,E)-N-((4-chloro-3-fluoropyridin-2-yl)methylene)-2-methylpropane-2-sulfinamide
1422510-26-6

(S,E)-N-((4-chloro-3-fluoropyridin-2-yl)methylene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 1h;100%
4-cyanobenzaldehyde
105-07-7

4-cyanobenzaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide
935263-24-4

(R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane for 1h; Reflux;100%
With p-toluenesulfonic acid on sillica gel In neat (no solvent) for 0.5h; Sonication; Green chemistry;95%
With tetrafluoroboric acid diethyl ether; magnesium sulfate In dichloromethane at 20℃; for 2h;91%
5-bromopyridine-3-carbaldehyde
113118-81-3

5-bromopyridine-3-carbaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-[(1E)-(5-chloropyridin-3-yl)methylidene]-2-methylpropane-2-sulfinamide

(R)-N-[(1E)-(5-chloropyridin-3-yl)methylidene]-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃;100%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfinamide

(R)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 30h; Time; Reflux;100%
With titanium(IV) tetraethanolate In tetrahydrofuran for 35.5h; Reflux;
With titanium (IV) ethoxide In tetrahydrofuran at 20℃; for 35.5h; Reflux;
With titanium(IV) tetraethanolate In tetrahydrofuran at 65℃; for 6h; Inert atmosphere;
6-chloro-7-fluoro-2-oxo-1,2-dihydroquinoline-3-carbaldehyde

6-chloro-7-fluoro-2-oxo-1,2-dihydroquinoline-3-carbaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R,E)-N-((6-chloro-7-fluoro-2-oxo-1,2-dihydroquinolin-3-yl)methylene)-2-methylpropane-2-sulfinamide

(R,E)-N-((6-chloro-7-fluoro-2-oxo-1,2-dihydroquinolin-3-yl)methylene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) isopropylate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;100%
1-tert-butoxycarbonyl-3-formylindole
57476-50-3

1-tert-butoxycarbonyl-3-formylindole

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R,E)-tert-butyl 3-(((tert-butylsulfinyl)imino)methyl)-1H-indole-1-carboxylate

(R,E)-tert-butyl 3-(((tert-butylsulfinyl)imino)methyl)-1H-indole-1-carboxylate

Conditions
ConditionsYield
With titanium(IV) tetraethanolate at 20℃; for 12h; Inert atmosphere;100%
With titanium (IV) ethoxide In tetrahydrofuran at 20℃; for 12h;89%
allyl-N-methyl-N-(3-oxopropyl)carbamate

allyl-N-methyl-N-(3-oxopropyl)carbamate

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(E)-allyl (3-((tert-butylsulfinyl)imino)propyl)(methyl)carbamate

(E)-allyl (3-((tert-butylsulfinyl)imino)propyl)(methyl)carbamate

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃;100%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(RS,E,E)-(-)-N-(3-phenylpropenyl)idene-tert-butanesulfinamide
364364-07-8

(RS,E,E)-(-)-N-(3-phenylpropenyl)idene-tert-butanesulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; Inert atmosphere;100%
isoquinoline-8-carboxaldehyde
787615-01-4

isoquinoline-8-carboxaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(isoquinolin-8-ylmethylene)-2-methylpropane-2-sulfinamide

(R)-N-(isoquinolin-8-ylmethylene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 4h;100%
2-chloro-6-fluorobenzaldehyde
387-45-1

2-chloro-6-fluorobenzaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R,E)-N-(2-chloro-6-fluorobenzylidene)-2-methylpropane-2-sulfinamide

(R,E)-N-(2-chloro-6-fluorobenzylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 17h;100%
(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

C15H21NOS

C15H21NOS

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 75℃;100%
4-chloro-3-fluoro-2-formylpyridine
1260878-78-1

4-chloro-3-fluoro-2-formylpyridine

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(±)-(E)-N-((4-chloro-3-fluoropyridin-2-yl)methylene)-2-methylpropane-2-sulfinamide

(±)-(E)-N-((4-chloro-3-fluoropyridin-2-yl)methylene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 1h;100%
(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

3-(cyclopropylmethoxy)-4-(difluoromethoxy)-benzaldehyde
151103-09-2

3-(cyclopropylmethoxy)-4-(difluoromethoxy)-benzaldehyde

(R)-2-methyl-2-propanesulfinic acid 3-cyclopropylmethoxy-4-(difluoromethoxy)benzylideneamide
1367625-78-2

(R)-2-methyl-2-propanesulfinic acid 3-cyclopropylmethoxy-4-(difluoromethoxy)benzylideneamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 12h;99.8%
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-(-)-N-[(1E)-(4-chlorophenyl)methylene]-2-methyl-2-propanesulfinamide
336105-23-8

(R)-(-)-N-[(1E)-(4-chlorophenyl)methylene]-2-methyl-2-propanesulfinamide

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃;99%
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; Ellmann's method;95%
With titanium(IV) tetraethanolate In tetrahydrofuran at 22℃;90%
With titanium(IV) tetraethanolate In dichloromethane at 20℃;
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃;
1-naphthaldehyde
66-77-3

1-naphthaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-(-)-2-methyl-N-[(1E)-1-naphthalenylmethylene]-2-propanesulfinamide
451503-13-2

(R)-(-)-2-methyl-N-[(1E)-1-naphthalenylmethylene]-2-propanesulfinamide

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate; magnesium sulfate In dichloromethane at 20℃;99%
benzaldehyde
100-52-7

benzaldehyde

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-benzylidene-2-methylpropane-2-sulfinamide
196929-85-8

(R)-N-benzylidene-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate at 70℃; for 0.166667h; Neat (no solvent); Microwave irradiation; Inert atmosphere;99%
With copper(II) sulfate In dichloromethane at 20℃;99%
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;99%
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