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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3',4'-(Methylenedioxy)-acetophenone

Cas:3162-29-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

CAS 3162-29-6 3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 3162-29-6 with best quality

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: 3',4'-(Methylenedioxy)acetophenone Synonyms: 1-(1,3-Benzodioxol-5-yl)ethanone CAS: 3162-29-6 MF: C9H8O3 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Organic

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanone,1-(1,3-benzodioxol-5-yl)-

Cas:3162-29-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

intermediate 3,4-Methylenedioxyacetophenone/CAS:3162-29-6

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $43.0 / 50.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanone,1-(1,3-benzodioxol-5-yl)-

Cas:3162-29-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3162-29-6

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1-(Benzo[d][1,3]dioxol-5-yl)ethanone

Cas:3162-29-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

3,4-Methylenedioxyacetophenone Basic information Product Name: 3,4-Methylenedioxyacetophenone Synonyms: 1-(1,3-Benzodioxol-5-yl)ethanone;3,4-Methylen-dioxy-acetophenon;Methyl (1,3-benzodioxole-5-yl) ketone;Moskachan A;3,4-Methylenedioxyacetophe

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

1-(benzo[d][1,3]dioxol-5-yl)ethanone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

3',4'-(Methylenedioxy)acetophenone cas no. 3162-29-6 98%

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Ethanone,1-(1,3-benzodioxol-5-yl)-

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 3',4'-(Methylenedioxy)acetophenone 100g

Cas:3162-29-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

1-(Benzo[d][1,3]dioxol-5-yl)ethanone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

3',4'-(Methylenedioxy)acetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethanone,1-(1,3-benzodioxol-5-yl)-

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

3,4-Methylenedioxyacetophenone Application:3,4-Methylenedioxyacetophenone

3,4-Methylenedioxyacetophenone

Cas:3162-29-6

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

acetic anhydride
108-24-7

acetic anhydride

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 1.5h; Friedel-Crafts Acylation;98%
at 120℃; Friedel-Crafts Acylation;90%
With diatomite-solid acid catalyst In 1,2-dichloro-ethane at 80℃; for 6h; Time; Friedel-Crafts Acylation;90.3%
Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

acetic acid
64-19-7

acetic acid

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
In nitrobenzene at 80℃; Friedel-Crafts Acylation;96%
1-benzo[1,3]dioxol-5-yl-ethanol
6329-73-3, 91613-73-9, 120523-14-0

1-benzo[1,3]dioxol-5-yl-ethanol

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With 2,2'-bipyridinium chlorochromate In dichloromethane for 3.5h;95%
With Dess-Martin periodane In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;84%
With potassium phosphate; copper(l) iodide; 1,10-Phenanthroline In 1,4-dioxane at 80℃; Solvent; Time; Schlenk technique;81%
1-benzo[1,3]dioxol-5-yl-ethylamine
121734-64-3

1-benzo[1,3]dioxol-5-yl-ethylamine

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With 4-phenylnaphthalene-1,2-dione In acetonitrile at 80℃; for 36h;95%
Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

acetyl chloride
75-36-5

acetyl chloride

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With indium(III) tosylate In dodecane; nitromethane for 2.5h; Friedel-Crafts Acylation; Schlenk technique; Reflux;94%
With 10percent AlCl3 on polystyrene In dichloromethane at 45℃; Friedel-Crafts Acylation;94%
With diatomite-solid acid catalyst In 1,2-dichloro-ethane at 80℃; for 6h; Friedel-Crafts Acylation;71.5%
With carbon disulfide; aluminium trichloride at -15℃;
With aluminum (III) chloride In dichloromethane at -50℃; for 2h; Friedel-Crafts Acylation; Sealed tube; Inert atmosphere;
methyl magnesium (1+); bromide

methyl magnesium (1+); bromide

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide
147030-72-6

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere;93%
isosafrole
120-58-1

isosafrole

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
Stage #1: isosafrole With N-iodo-succinimide; cetyltrimethylammonim bromide In 1,4-dioxane; water at 115℃; for 0.25h; Microwave irradiation;
Stage #2: With dipyridinium dichromate; acetic acid In 1,4-dioxane; water at 115℃; for 0.25h; Microwave irradiation;
86%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide
147030-72-6

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With benzotriazol-1-ol In tetrahydrofuran; diethyl ether at 0℃; for 1h;85%
piperonal
120-57-0

piperonal

methylmagnesium bromide
75-16-1

methylmagnesium bromide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
Stage #1: piperonal; methylmagnesium bromide In tetrahydrofuran at 0℃; Green chemistry;
Stage #2: With [bis(acetoxy)iodo]benzene at 0 - 20℃; Green chemistry;
80%
Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

Acetyl bromide
506-96-7

Acetyl bromide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With diatomite-solid acid catalyst In 1,2-dichloro-ethane at 80℃; for 6h; Friedel-Crafts Acylation;76%
1-(benzo[d][1,3]dioxol-5-yl)-2,2-dibromoethan-1-one
783321-45-9

1-(benzo[d][1,3]dioxol-5-yl)-2,2-dibromoethan-1-one

A

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B

1-(benzo[1,3]dioxol-5-yl)-2-bromoethanone
40288-65-1

1-(benzo[1,3]dioxol-5-yl)-2-bromoethanone

Conditions
ConditionsYield
With water; 1-methyl-3-pentyl-1H-imidazolium tetrafluoroborate at 125℃; under 2585.74 Torr; for 0.0416667h; microwave irradiation;A n/a
B 75%
S-2-(tert-butylcarbamoyl)phenyl ethanethioate
69672-52-2

S-2-(tert-butylcarbamoyl)phenyl ethanethioate

3,4-(methylenedioxy)-benzeneboronic acid
94839-07-3

3,4-(methylenedioxy)-benzeneboronic acid

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With air; Cu(I)-3-methylsalicylate In N,N-dimethyl-formamide at 50℃; Miyaura-Suzuki reaction;75%
1-(benzo[d][1,3]dioxol-5-yl)-2,2-dibromoethan-1-one
783321-45-9

1-(benzo[d][1,3]dioxol-5-yl)-2,2-dibromoethan-1-one

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With water; 1-methyl-3-pentyl-1H-imidazolium tetrafluoroborate at 125℃; under 2585.74 Torr; for 0.116667h; microwave irradiation;70%
5-(2,2-dibromovinyl)-1,3-benzodioxol
92449-54-2

5-(2,2-dibromovinyl)-1,3-benzodioxol

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With water; zinc at 275℃; for 4h;66%
diiodomethane
75-11-6

diiodomethane

1-(3,4-dihydroxyphenyl)ethan-1-one
1197-09-7

1-(3,4-dihydroxyphenyl)ethan-1-one

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide Inert atmosphere;65%
1-(2′-bromo-4′,5′-methylenedioxyphenyl)ethan-1-one
71095-26-6

1-(2′-bromo-4′,5′-methylenedioxyphenyl)ethan-1-one

A

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B

1-(6'-Acetyl-[5,5']bi[benzo[1,3]dioxolyl]-6-yl)-ethanone
79422-58-5

1-(6'-Acetyl-[5,5']bi[benzo[1,3]dioxolyl]-6-yl)-ethanone

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In N,N-dimethyl-formamide 1.) - 78 deg C, 2.) 25 deg C, 10 min, 3.) 35 deg C, 12 h;A 39%
B 61%
4-(3,4-methylenedioxyphenyl)-4-oxo-2-(3,4,5-trimethoxyphenyl)butyramide
88775-41-1

4-(3,4-methylenedioxyphenyl)-4-oxo-2-(3,4,5-trimethoxyphenyl)butyramide

A

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B

(Z)-2-(3,4,5-trimethoxyphenyl)-4-(3,4-methylenedioxyphenyl)-4-oxo-2-butenoic acid
88775-49-9

(Z)-2-(3,4,5-trimethoxyphenyl)-4-(3,4-methylenedioxyphenyl)-4-oxo-2-butenoic acid

C

4-(3,4-methylenedioxyphenyl)-4-oxo-2-(3,4,5-trimethoxyphenyl)butyric acid
88775-29-5

4-(3,4-methylenedioxyphenyl)-4-oxo-2-(3,4,5-trimethoxyphenyl)butyric acid

D

Eudesmic acid
118-41-2

Eudesmic acid

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 10h; Product distribution; Heating; var. condition;A 16%
B 18.5%
C 44.7%
D 13.6%
With sodium hydroxide In ethanol for 10h; Heating;A 0.227 g
B n/a
C n/a
D n/a
With sodium hydroxide In ethanol for 6h; Heating;A 0.021 g
B 0.056 g
C 0.14 g
D 0.023 g
piperonal
120-57-0

piperonal

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

A

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B

safrole 2',3'-oxide
7470-44-2

safrole 2',3'-oxide

C

1-(1,3-benzodioxol-5-yl)-2-propanone
4676-39-5

1-(1,3-benzodioxol-5-yl)-2-propanone

Conditions
ConditionsYield
With triethylamine In methanol; diethyl ether for 24h; Ambient temperature;A 19%
B 9%
C 37%
With triethylamine In methanol; dichloromethane for 24h; Ambient temperature;A 17%
B 14%
C 34%
2-azido-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one
102831-07-2

2-azido-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one

A

piperonal
120-57-0

piperonal

B

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

C

benzo[1,3]dioxole-5-carboxylic acid (2-benzo[1,3]dioxol-5-yl-2-oxo-ethyl)amide

benzo[1,3]dioxole-5-carboxylic acid (2-benzo[1,3]dioxol-5-yl-2-oxo-ethyl)amide

Conditions
ConditionsYield
In toluene Photolysis;A 19%
B 7%
C 30%
piperonal
120-57-0

piperonal

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With diethyl ether
3,4-(methylenedioxy)benzoyl chloride
25054-53-9

3,4-(methylenedioxy)benzoyl chloride

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With dimethylcadmium; benzene
(E)-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one oxime
62681-68-9

(E)-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one oxime

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With sulfuric acid
ethyl 3-(benzo[d][1,3]dioxol-5-yl)-3-oxopropanoate
81581-27-3

ethyl 3-(benzo[d][1,3]dioxol-5-yl)-3-oxopropanoate

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With potassium hydroxide
With sulfuric acid
Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

acetyl chloride
75-36-5

acetyl chloride

A

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B

diiodomethane
75-11-6

diiodomethane

C

dimethyl phthalate
635-67-6

dimethyl phthalate

D

3,4-diacetoxyacetophenone
72712-21-1

3,4-diacetoxyacetophenone

Conditions
ConditionsYield
With sodium iodide In acetonitrile for 6h; Product distribution; Ambient temperature;A n/a
B 40 % Chromat.
C 43 % Chromat.
D n/a
4-acetoxy-3-methoxycarbonyl-4-(3,4-methylenedioxyphenyl)but-3-ene-2-one
104548-23-4

4-acetoxy-3-methoxycarbonyl-4-(3,4-methylenedioxyphenyl)but-3-ene-2-one

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With hydrogenchloride In methanol for 2h; Heating;
With sodium hydroxide In methanol for 2h; Heating;
With piperidine In methanol for 1h; Heating; further reagents: morpholine, piperazine;
methyllithium
917-54-4

methyllithium

piperonylonitrile
4421-09-4

piperonylonitrile

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -78 - 20℃; for 2.5h;
piperonal
120-57-0

piperonal

methyl iodide
74-88-4

methyl iodide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With N-chloro-succinimide; magnesium 1.) C6H6, THF, 10 min, 2.) C6H6, THF, a) 0 deg C, 5 min, b) RT, 25 min; Yield given. Multistep reaction;
methylmagnesium chloride
676-58-4

methylmagnesium chloride

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide
147030-72-6

benzo[1,3]dioxole-5-carboxylic acid methoxymethylamide

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
In tetrahydrofuran Substitution;
12-bromo-11-oxy-3.4-methylenedioxy-1-propyl-benzene

12-bromo-11-oxy-3.4-methylenedioxy-1-propyl-benzene

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Conditions
ConditionsYield
With chromium(III) oxide; sulfuric acid
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one oxime
62681-68-9

1-(benzo[d][1,3]dioxol-5-yl)ethan-1-one oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; triethylamine In ethanol for 25h;100%
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃;100%
With sodium hydroxide; hydroxylamine hydrochloride In ethanol; water at 25 - 80℃; Inert atmosphere;87%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(R)-2-methylpropane-2-sulfinamide
196929-78-9

(R)-2-methylpropane-2-sulfinamide

(R)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfinamide

(R)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 20℃; for 30h; Time; Reflux;100%
With titanium(IV) tetraethanolate In tetrahydrofuran for 35.5h; Reflux;
With titanium (IV) ethoxide In tetrahydrofuran at 20℃; for 35.5h; Reflux;
With titanium(IV) tetraethanolate In tetrahydrofuran at 65℃; for 6h; Inert atmosphere;
3-thiophene carboxaldehyde
498-62-4

3-thiophene carboxaldehyde

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(E)-1-benzo[1,3]dioxol-5-yl-3-thiophen-3-ylpropenone

(E)-1-benzo[1,3]dioxol-5-yl-3-thiophen-3-ylpropenone

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With lithium hydroxide In ethanol at 20℃; for 0.166667h; Large scale;
Stage #2: 3-thiophene carboxaldehyde In ethanol at 20℃; Large scale;
99%
With sodium hydroxide In ethanol; water
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(R)-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-ol
120523-14-0

(R)-1-(benzo[d][1,3]dioxol-5-yl)ethan-1-ol

Conditions
ConditionsYield
With dimethylsulfide; dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole In dichloromethane; toluene at 20℃; for 5h; Corey-Bakshi-Shibata reduction;99%
With 1,1,1,3',3',3'-hexafluoro-propanol; C32H39BrMnN2O2P; potassium tert-butylate; hydrogen In methanol at 20℃; under 22502.3 Torr; for 16h; Glovebox; Autoclave; enantioselective reaction;99%
With bromopentacarbonylmanganese(I); hydrogen; C45H43FeNP2; potassium hydroxide In methanol; toluene at 20℃; for 36h; enantioselective reaction;99%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(S)-1-[3,4-(methylenedioxy)phenyl]-1-ethanol
179237-91-3

(S)-1-[3,4-(methylenedioxy)phenyl]-1-ethanol

Conditions
ConditionsYield
With dimethylsulfide; dimethylsulfide borane complex; (R)-2-methyl-(CBS)-oxazaborolidine In dichloromethane; toluene at 20℃; for 5h;99%
With dimethylsulfide; dimethylsulfide borane complex; (R)-2-methyl-CBS-oxaborolidine In dichloromethane; toluene at 20℃; for 5h; Corey-Bakshi-Shibata reduction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C53H73FeN2O2PS; hydrogen; lithium tert-butoxide In isopropyl alcohol at 25 - 30℃; under 22801.5 Torr; for 12h; Autoclave; enantioselective reaction;99%
With Lactobacillus fermentum P1 whole cells at 26.44℃; for 30.39h; pH=6.2; pH-value; Temperature;n/a
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

5-(2-nitrophenyl)-2-furaldehyde
20000-96-8

5-(2-nitrophenyl)-2-furaldehyde

(2E)-1-(1',3'-benzodioxol-5-yl)-3-[5-(2-nitrophenyl)-furan-2-yl]-2-propen-1-one.
1352444-90-6

(2E)-1-(1',3'-benzodioxol-5-yl)-3-[5-(2-nitrophenyl)-furan-2-yl]-2-propen-1-one.

Conditions
ConditionsYield
With potassium hydroxide In methanol at 20℃; for 24h; Aldol condensation;99%
With potassium hydroxide In methanol; water at 20℃; for 24h; Aldol condensation;99%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

3,4-(methylenedioxy)phenyl methyl ketone-d6

3,4-(methylenedioxy)phenyl methyl ketone-d6

Conditions
ConditionsYield
With 10% Pt/activated carbon; water-d2 In cyclohexane; isopropyl alcohol at 80℃; for 24h; Inert atmosphere;99%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

2-amino-1-benzylamine
4403-69-4

2-amino-1-benzylamine

Dubamine
6808-65-7

Dubamine

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate); toluene-4-sulfonic acid In toluene at 100℃; for 36h; Schlenk technique; Sealed tube;99%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

ethylene glycol
107-21-1

ethylene glycol

C11H12O4

C11H12O4

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene; benzene at 110℃; for 20h; Dean-Stark;99%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

1-(3,4-methylenedioxyphenyl)-2-iodoethanone

1-(3,4-methylenedioxyphenyl)-2-iodoethanone

Conditions
ConditionsYield
With iodine; copper(II) oxide In methanol for 1h; Heating;98%
With iodine; Selectfluor In methanol at 22℃; for 26h;75%
With iodine; copper(II) oxide In ethanol at 78℃;
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

1-(benzo[d][1,3]dioxol-5-yl)-3-(4-nitrophenyl)prop-2-en-1-one

1-(benzo[d][1,3]dioxol-5-yl)-3-(4-nitrophenyl)prop-2-en-1-one

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With lithium hydroxide monohydrate In methanol at 20℃; for 1h;
Stage #2: 4-nitrobenzaldehdye In methanol at 20℃; for 3h;
97.9%
With potassium hydroxide In methanol; water at 20℃;79%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

thiosemicarbazide
79-19-6

thiosemicarbazide

1-(1,3-benzodioxol-5-yl)ethan-1-one thiosemicarbazone
18087-38-2

1-(1,3-benzodioxol-5-yl)ethan-1-one thiosemicarbazone

Conditions
ConditionsYield
In ethanol for 4h; Reflux;97%
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With acetic acid In methanol for 0.25h; Reflux;
Stage #2: thiosemicarbazide In methanol Reflux;
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

piperonal
120-57-0

piperonal

Conditions
ConditionsYield
With oxygen; copper(l) chloride In dimethyl sulfoxide at 120℃; under 60006 Torr;97%
2-Aminobenzyl alcohol
5344-90-1

2-Aminobenzyl alcohol

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

Dubamine
6808-65-7

Dubamine

Conditions
ConditionsYield
With iron(III) oxide; potassium tert-butylate In toluene for 15h; Inert atmosphere; Sealed tube;97%
With potassium tert-butylate; oxygen In toluene at 130℃; for 24h; Friedlaender Quinoline Synthesis; Green chemistry;91%
With [(p-cymene)Ru(BiBzImH2)Cl][Cl]; caesium carbonate In tert-Amyl alcohol at 125℃; for 12h;81%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

2-iodobenzaldehyde
26260-02-6

2-iodobenzaldehyde

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2-iodophenyl)prop-2-en-1-one

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2-iodophenyl)prop-2-en-1-one

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With sodium hydroxide In ethanol; water at 0℃; for 0.0833333h;
Stage #2: 2-iodobenzaldehyde In ethanol; water at 0 - 10℃;
97%
5-bromo-2-furancarboxaldehyde
1899-24-7

5-bromo-2-furancarboxaldehyde

1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(5-bromofuran-2-yl)prop-2-en-1-one

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(5-bromofuran-2-yl)prop-2-en-1-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 20℃; for 16h; Claisen-Schmidt Condensation; Inert atmosphere; Microwave irradiation;97%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

B-2-(2-methylallyl)-1,3,2-dioxaborinane
1433220-26-8

B-2-(2-methylallyl)-1,3,2-dioxaborinane

2-(benzo[d][1,3]dioxol-5-yl)-4-methylpent-4-en-2-ol
1433220-29-1

2-(benzo[d][1,3]dioxol-5-yl)-4-methylpent-4-en-2-ol

Conditions
ConditionsYield
With tert-Amyl alcohol In neat (no solvent) at 23℃; Inert atmosphere;96%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
72824-04-5

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(S)-2-(benzo[d][1,3]dioxol-5-yl)pent-4-en-2-ol

(S)-2-(benzo[d][1,3]dioxol-5-yl)pent-4-en-2-ol

Conditions
ConditionsYield
Stage #1: 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With (S)-2-((2-hydroxy-3-(triphenylsilyl)benzyl)amino)-3-methyl-1-(pyrrolidin-1-yl)butan-1-one; sodium t-butanolate In tetrahydrofuran; methanol; toluene at -30℃; for 0.5h; Inert atmosphere;
Stage #2: 1-(benzo[d][1,3]dioxol-6-yl)ethanone In tetrahydrofuran; methanol; toluene at -30℃; for 8h; Inert atmosphere; enantioselective reaction;
96%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

(S)-2-methylpropane-2-sulfinamide
343338-28-3

(S)-2-methylpropane-2-sulfinamide

(E)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfonamide

(E)-N-(1-(benzo[d][1,3]dioxol-5-yl)ethylidene)-2-methylpropane-2-sulfonamide

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone; (S)-2-methylpropane-2-sulfinamide With titanium(IV) tetraethanolate In tetrahydrofuran Inert atmosphere; Reflux;
Stage #2: With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 0.166667h; Inert atmosphere;
96%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

chloranil
118-75-2

chloranil

5-acetyl-2-(4-hydroxy-2,3,5,6-tetrachlorophenoxy)-1,3-benzodioxole

5-acetyl-2-(4-hydroxy-2,3,5,6-tetrachlorophenoxy)-1,3-benzodioxole

Conditions
ConditionsYield
In benzene for 3h; Irradiation;95%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

1-benzo[1,3]dioxol-5-yl-ethanol
6329-73-3, 91613-73-9, 120523-14-0

1-benzo[1,3]dioxol-5-yl-ethanol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol; dichloromethane at 0℃; for 0.5h;95%
With sodium tetrahydroborate; nickel(II) phthalocyanine In PEG-400 at 20℃; for 0.75h; chemoselective reaction;95%
With C28H35ClCoN5(1+)*Cl(1-); potassium tert-butylate; hydrogen In tetrahydrofuran at 20℃; under 22502.3 Torr; for 16h; Autoclave;92%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

1-benzo[1,3]dioxol-5-yl-ethylamine
121734-64-3

1-benzo[1,3]dioxol-5-yl-ethylamine

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With aluminium(III) triflate; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; 1,2-bis-(diphenylphosphino)ethane In dodecane; toluene at -5℃; under 4500.45 Torr; for 0.5h; Autoclave;
Stage #2: With hydrogen In dodecane; toluene at 140℃; under 30003 Torr; for 16h; Acidic conditions; chemoselective reaction;
95%
With 4-methoxy-N-(1-(naphthalen-2-yl)ethylidene)aniline; ammonium formate In methanol at 80℃; for 12h; Inert atmosphere; chemoselective reaction;92%
With ammonia; hydrogen In tetrahydrofuran at 120℃; for 15h;89%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

2-chloro-6-methoxyquinolin-3-carboxaldehyde
73568-29-3

2-chloro-6-methoxyquinolin-3-carboxaldehyde

(2E)-1-(1',3'-benzodioxol-5-yl)-3-(2-chloro-6-methoxyquinolin-3-yl)-2-propen-1-one
1352444-88-2

(2E)-1-(1',3'-benzodioxol-5-yl)-3-(2-chloro-6-methoxyquinolin-3-yl)-2-propen-1-one

Conditions
ConditionsYield
With potassium hydroxide In methanol at 20℃; for 24h; Aldol condensation;95%
With potassium hydroxide In methanol; water at 20℃; for 24h; Aldol condensation;95%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

2,6-dimethoxybenzaldehyde
3392-97-0

2,6-dimethoxybenzaldehyde

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,6-dimethoxyphenyl)prop-2-en-1-one
1352444-80-4

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,6-dimethoxyphenyl)prop-2-en-1-one

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone With sodium hydroxide In ethanol; water at 20℃; for 0.0833333h; Claisen-Schmidt Condensation;
Stage #2: 2,6-dimethoxybenzaldehyde at 20℃; Claisen-Schmidt Condensation;
95%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

[bromo(difluoro)methyl](trimethyl)silane
115262-01-6

[bromo(difluoro)methyl](trimethyl)silane

1-(benzo[d][1,3]dioxol-5-yl)-2-fluoroprop-2-en-1-one

1-(benzo[d][1,3]dioxol-5-yl)-2-fluoroprop-2-en-1-one

Conditions
ConditionsYield
Stage #1: 1-(benzo[d][1,3]dioxol-6-yl)ethanone; [bromo(difluoro)methyl]-trimethyl-silane With tetrabutylammomium bromide In toluene at 110℃; for 6h; Sealed tube;
Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran; toluene at 20℃; for 3h; Sealed tube;
95%
1-(benzo[d][1,3]dioxol-6-yl)ethanone
3162-29-6

1-(benzo[d][1,3]dioxol-6-yl)ethanone

4-methoxymethoxy-benzaldehyde
6515-21-5

4-methoxymethoxy-benzaldehyde

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(4-(methoxymethoxy)phenyl)prop-2-en-1-one

(E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(4-(methoxymethoxy)phenyl)prop-2-en-1-one

Conditions
ConditionsYield
With sodium hydroxide In methanol; water at 20℃; Claisen-Schmidt Condensation;95%

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