1-Bromoadamantane supplier

Name
1-Bromoadamantane
EINECS 212-200-7
CAS No. 768-90-1
Article Data124
CAS DataBase
Density 1.448 g/cm³
Solubility insoluble in water
Melting Point 116-118 °C
Formula C₁₀H₁₅Br
Boiling Point 240.5 °C at 760 mmHg
Molecular Weight 215.133
Flash Point 96.4 °C
Transport Information
Appearance white to almost white crystals or cryst. powder
Safety 22-24/25-36-26
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms 1-Adamantyl bromide;1-Bromotricyclo(3.3.1.13,7)decane;Tricyclo[3.3.1.13, 7]decane, 1-bromo-;Adamantane, 1-bromo-;Adamantyl bromide;1-Bromo adamantane;1-Bromotricyclo[3.3.1.13,7]decane;
PSA 0.00000
LogP 3.35010

Synthetic route

: 935-56-8
1-chloroadamantane

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere;	99%
With hydrogen bromide at 130℃; for 2h;	90%
With boron tribromide for 0.5h;	86%

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 876-53-9
1,3-dibromoadamantane

Conditions

Conditions	Yield
With iron(III)-acetylacetonate; carbon tetrabromide Reagent/catalyst; Sealed tube; Inert atmosphere;	A 99% B 23%
With bromine; iron at 0 - 50℃; for 3h;	A n/a B 93%
With iodine(I) bromide In tetrachloromethane for 3h; Heating;	A 75 % Chromat. B 25 % Chromat.
With iodine(I) bromide In tetrachloromethane for 3h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 768-95-6
1-adamanthanol

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With oxygen; 1,2-dibromomethane for 10h; Reflux;	99%
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere;	99%
With dibromo sulfoxide In toluene for 22h;	96%

: 281-23-2
adamantane

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With bromine; Nitrogen dioxide In trifluoroacetic acid at 20℃; for 0.5h;	98%
With water; bromine for 0.166667h;	93%
With bromine at 85 - 110℃; Temperature;	93%

: 2094-72-6
1-Adamantanecarbonyl chloride

A: 768-90-1
1-Adamantyl bromide

B: 66832-24-4
2-<(trichloromethyl)thio>pyridine

Conditions

Conditions	Yield
With Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; dmap at 105℃; for 0.5h;	A 98% B n/a

: 1-adamantyl n-butyl ether

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With bromine In tetrachloromethane at 20℃; for 12h;	97%

: 34913-44-5
1-(Dibromoamino)adamantane

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
In acetone at 250 - 260℃;	94%
In acetone at 250 - 260℃; also at 250 deg C, 6 Torr, without solvent;	94%

: 768-92-3
1-adamantyl fluoride

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With hydrogen bromide at 105℃; for 0.5h;	92%
With boron tribromide In hexane at 0℃; for 0.0833333h;	90%

: 74131-25-2
4-(1-adamantyl)benzene-1,3-diol

A: 768-90-1
1-Adamantyl bromide

B: 2437-49-2
2,4,6-tribromoresorcinol

C: 74131-27-4
2,6-Dibromo-4-(1-adamantyl)resorcinol

Conditions

Conditions	Yield
With bromine In methanol; acetic acid for 1h; Ambient temperature;	A n/a B n/a C 91.5%

...Expand

: 75-62-7
Bromotrichloromethane

: 281-23-2
adamantane

: 75-05-8
acetonitrile

A: 768-90-1
1-Adamantyl bromide

B: 67-66-3
chloroform

C: 880-52-4
N-(1-adamantyl)acetamide

Conditions

Conditions	Yield
With water; molybdenum hexacarbonyl at 140℃; for 2h;	A n/a B n/a C 90%

...Expand

: 828-51-3
1-Adamantanecarboxylic acid

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With Ag(Phen)2OTf; dibromoisocyanuric acid In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;	89%
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; caesium carbonate; Diethyl 2-bromomalonate In ethyl acetate at 20℃; for 4h; Solvent; Inert atmosphere; Irradiation;	70%
With Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; dmap 2.) reflux; Yield given. Multistep reaction;
Multi-step reaction with 2 steps 1: (COBr)2 2: Fe / 1 h / Ambient temperature View Scheme

: 32314-61-7
1-nitroxyadamantane

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With sulfuric acid; potassium bromide for 1h;	89%

: 281-23-2
adamantane

: 75-05-8
acetonitrile

A: 768-90-1
1-Adamantyl bromide

B: 75-25-2
Bromoform

C: 23074-42-2
1-adamantanecarbonitrile

Conditions

Conditions	Yield
With carbon tetrabromide; molybdenum hexacarbonyl at 140 - 160℃; for 6h; Reactivity; Mechanism; Reagent/catalyst;	A 15% B n/a C 85%

...Expand

: 281-23-2
adamantane

: 98-88-4
benzoyl chloride

A: 768-90-1
1-Adamantyl bromide

B: 7314-85-4
2-adamantyl bromide

C: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With aluminum tri-bromide In various solvent(s) at 20℃; for 2h;	A 70% B 3% C 82%
With aluminum tri-bromide In various solvent(s) at 20℃; for 2h;	A 70% B 3% C 82%

...Expand

: 62133-11-3
1-(1-adamantyl)-3,4-dimethylbenzene

A: 768-90-1
1-Adamantyl bromide

B: 876-53-9
1,3-dibromoadamantane

C: 2810-69-7
1,2,3,4-tetrabromo-5,6-dimethylbenzene

Conditions

Conditions	Yield
With bromine; iron for 3.5h; Product distribution; Ambient temperature;	A n/a B n/a C 82%

...Expand

: 935-56-8
1-chloroadamantane

A: 768-90-1
1-Adamantyl bromide

B: 7314-85-4
2-adamantyl bromide

C: 281-23-2
adamantane

D: 876-53-9
1,3-dibromoadamantane

Conditions

Conditions	Yield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.3h;	A 78% B 3% C 9% D 9 % Chromat.
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.3h;	A 78% B 3% C 9% D 3 % Chromat.

...Expand

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 700-58-3
2-Adamantanone

C: 935-56-8
1-chloroadamantane

D: 7314-85-4
2-adamantyl bromide

E: 768-95-6
1-adamanthanol

F: 700-57-2
1-adamantanol

Conditions

Conditions	Yield
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone at 20℃; Product distribution; Mechanism;	A 12.2% B 1.8% C 0.7% D 2.3% E 77.2% F 1.1%
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone for 1h; Mechanism; Product distribution; Ambient temperature; concentration depending investigated;

...Expand

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 935-56-8
1-chloroadamantane

C: 7314-85-4
2-adamantyl bromide

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; Bromotrichloromethane; iron(III) chloride In pyridine; acetic acid at 60℃; for 18h;	A 69.2% B 4.1% C 26.7%
With tert.-butylhydroperoxide; Bromotrichloromethane; iron(III) chloride In pyridine; acetic acid at 60℃; for 18h; Product distribution; Mechanism; various conditions;	A 69.2% B 4.1% C 26.7%

...Expand

: 88459-01-2
(1s,3s)-adamantan-1-yl(phenyl)sulfide

: 768-90-1
1-Adamantyl bromide

Conditions

Conditions	Yield
With bromine In dichloromethane at 20℃; for 1h;	68%

: 34913-44-5
1-(Dibromoamino)adamantane

A: 768-90-1
1-Adamantyl bromide

B: 876-53-9
1,3-dibromoadamantane

Conditions

Conditions	Yield
at 95 - 250℃; under 6 Torr; for 1h;	A 65% B n/a

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: (1s,3s,5s,7s)-1,3-dibromoadamantane

Conditions

Conditions	Yield
Stage #1: adamantane With [2,2]bipyridinyl; N-Bromosuccinimide; manganese(II) acetate for 0.0833333h; Inert atmosphere; Stage #2: With trimethylsilylazide at 60℃; for 0.5h; Inert atmosphere; Sealed tube; regioselective reaction;	A 62% B 15%
Stage #1: adamantane With [2,2]bipyridinyl; N-Bromosuccinimide; manganese(II) acetate for 0.0833333h; Inert atmosphere; Stage #2: With trimethylsilylazide at 60℃; for 18h; Inert atmosphere; Sealed tube; regioselective reaction;	A 16% B 62%

: 52044-18-5
C10H15Ge(CH3)3

A: 768-90-1
1-Adamantyl bromide

B: 100203-98-3
1-adamantyldimethylbromogermane

Conditions

Conditions	Yield
With bromine In tetrachloromethane soln. of Br2 added to soln. of 1-AdGeMe3; boiled (18 h, 78°C); solvent removed; recrystd. (hexane); elem.anal.;	A 54.7% B 28.7%

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 7314-85-4
2-adamantyl bromide

Conditions

Conditions	Yield
With dihydrogen peroxide; bromine In water; 1,2-dichloro-ethane for 4h;	A 48.7% B 51.3%
With Li2MnO3; bromine; oxygen at 100℃; under 760.051 Torr; for 24h; Photolysis;	A 42% B 5%
With hydrogenchloride; oxygen; potassium bromide; sodium nitrite In chloroform; water at 20 - 30℃; under 760.051 Torr; for 24h; Sealed tube; Irradiation;	A 20% B 17%

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 768-95-6
1-adamanthanol

Conditions

Conditions	Yield
With [(hydrotris(3,5-diphenyl-pyrazol-1-yl)borate)FeII(benzilate)]; tetrabutylammomium bromide; oxygen; pyridinium perchlorate In acetonitrile at 20℃;	A 7% B 48%
With ruthenium hydroxide trichloride; carbon tetrabromide; water at 160℃; for 9h; Inert atmosphere; regioselective reaction;	A 30% B 30%

: 281-23-2
adamantane

A: 768-90-1
1-Adamantyl bromide

B: 935-56-8
1-chloroadamantane

C: 7314-85-4
2-adamantyl bromide

D: 768-95-6
1-adamanthanol

E: 700-57-2
1-adamantanol

F: 7346-41-0
2-chloroadamantane

Conditions

Conditions	Yield
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone at 20℃; for 3.5h; Rate constant; Product distribution; Kinetics;	A 42.3% B 9.2% C 10.5% D 33% E 2% F 2.5%

...Expand

: 5511-20-6
1-(Bromoamino)adamantane

A: 768-90-1
1-Adamantyl bromide

B: 768-94-5
1-Adamantanamine

Conditions

Conditions	Yield
In dichloromethane at 250 - 260℃; 15-30percent SE-30 on Chromosorb W;	A 30% B n/a

: 1643-19-2
tetrabutylammomium bromide

: 937-14-4
3-chloro-benzenecarboperoxoic acid

A: 768-90-1
1-Adamantyl bromide

B: 7314-85-4
2-adamantyl bromide

C: 63987-54-2
n-butyl 3-chlorobenzoate

Conditions

Conditions	Yield
With adamantane In acetonitrile at 20℃; for 1h; Yields of byproduct given;	A n/a B n/a C 24%

...Expand

: 64-20-0
tetramethylammonium bromide

: 937-14-4
3-chloro-benzenecarboperoxoic acid

A: 768-90-1
1-Adamantyl bromide

B: 7314-85-4
2-adamantyl bromide

C: 2905-65-9
methyl 3-chlorobenzoate

Conditions

Conditions	Yield
With adamantane In acetonitrile at 20℃; for 1h; Yields of byproduct given;	A n/a B n/a C 19%

...Expand

: 506-96-7
Acetyl bromide

: 935-56-8
1-chloroadamantane

A: 768-90-1
1-Adamantyl bromide

B: 75-36-5
acetyl chloride

Conditions

Conditions	Yield
With iron(III) chloride at 25℃; for 168h; Equilibrium constant; Thermodynamic data; ΔG;
With iron(III) chloride In chloroform at 25℃; for 168h; Equilibrium constant; Thermodynamic data; ΔG;

...Expand

: 768-90-1
1-Adamantyl bromide

: 100-66-3
methoxybenzene

: 726-94-3
1-(4-methoxyphenyl)adamantane

Conditions

Conditions	Yield
With molybdenum hexacarbonyl Sealed tube; regioselective reaction;	100%
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;	91%
With palladium 10% on activated carbon; potassium carbonate for 20h; Heating;	82.65%

: 768-90-1
1-Adamantyl bromide

: 281-23-2
adamantane

Conditions

Conditions	Yield
With triethylsilane; dilauryl peroxide; 1-dodecylthiol at 70℃; for 1h;	100%
With triethylsilane; dilauryl peroxide; 1-dodecylthiol In cyclohexane at 80℃; for 1h;	100%
With sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); cPS-SnBu2Cl In 1,2-dimethoxyethane at 80℃; for 0.5h;	100%

: 768-90-1
1-Adamantyl bromide

: 64-19-7
acetic acid

: 22635-62-7
1-acetyloxyadamantane

Conditions

Conditions	Yield
With iron(III)-acetylacetonate Heating;	100%
With bromine for 0.05h;	90%

: 768-90-1
1-Adamantyl bromide

: 149814-40-4
(2S,4R)-1-(tert-butoxycarbonyl)-4-((tert-butyldimethylsilyl)oxy)pyrrolidine-2-carboxylic acid

: 400724-37-0
1-adamantyl (2S,4R)-1-(tert-butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)pyrrolidine-2-carboxylate

Conditions

Conditions	Yield
With silver(l) oxide In diethyl ether at 20℃; for 30h;	100%

: 768-90-1
1-Adamantyl bromide

: 107-19-7
propargyl alcohol

: 119728-80-2
1-adamantyl propargyl ether

Conditions

Conditions	Yield
With triethylamine	100%

: 1,4-bis(3-phenyl-1,2,4-triazol-4-yl)benzene

: 768-90-1
1-Adamantyl bromide

: 4,4'-(1,4-phenylene)bis[1-(1-adamantyl)-3-phenyl-1,2,4-triazolium] dibromide

Conditions

Conditions	Yield
In acetic acid Heating;	100%

: 768-90-1
1-Adamantyl bromide

: 108-88-3
toluene

: 1459-55-8
4-(1-adamantyl)toluene

Conditions

Conditions	Yield
With molybdenum hexacarbonyl at 100℃; for 2h; Catalytic behavior; Reagent/catalyst; Temperature; Time; Sealed tube; regioselective reaction;	99%
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;	97%
With iron pentacarbonyl; Bromotrichloromethane at 80℃; for 5h; Friedel-Crafts Alkylation;	95%

: 768-90-1
1-Adamantyl bromide

: 75-16-1
methylmagnesium bromide

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
In dibutyl ether at 85℃; for 1h;	99%
In dibutyl ether at 105℃; for 4.5h;	80%
In dibutyl ether at 70 - 90℃; Rate constant; Thermodynamic data; ΔE;

: 768-90-1
1-Adamantyl bromide

: 95-48-7
ortho-cresol

: 53799-14-7
4-((3r,5r,7r)-adamantan-1-yl)-2-methylphenol

Conditions

Conditions	Yield
With molybdenum hexacarbonyl at 120℃; for 0.5h; Sealed tube; regioselective reaction;	99%

: 768-90-1
1-Adamantyl bromide

: 768-95-6
1-adamanthanol

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In acetic anhydride; acetic acid; N,N-dimethyl-formamide at 0 - 10℃; for 4h; Substitution; Electrochemical reaction;	98%
With water; bromine for 1h;	95.5%
With hydrogenchloride In N,N-dimethyl-formamide at 105℃; for 0.5h;	95%

: 768-90-1
1-Adamantyl bromide

: 143671-61-8
4-methylquinoline trifluoroacetate

: 77492-66-1
4-methyl-2-(tricyclo[3.3.1.13,7]dec-1-yl)quinolone

Conditions

Conditions	Yield
With {Au(dppm)}2Cl2 In methanol Inert atmosphere; UV-irradiation;	98%
With 2,2'-azobis(isobutyronitrile); 1,1,2,2-tetraphenyldisilane In ethanol for 24h; Product distribution; Heating; other reagents;	93%
With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane In benzene for 14h; Heating;	90%
With tetrakis(trimethylsilyl)silane In dichloromethane at 30℃; for 14h; Irradiation;	83%

: 768-90-1
1-Adamantyl bromide

: 768-93-4
1-iodoadamantane

Conditions

Conditions	Yield
With hydrogen iodide; cetyltributylphosphonium bromide at 105℃; for 1.75h;	98%
With hydrogen iodide at 105℃; for 0.5h;	90%
Stage #1: 1-Adamantyl bromide With zinc In tetrahydrofuran for 2h; Reflux; Stage #2: With iodine In tetrahydrofuran at 20℃;	79%
With potassium iodide at 19.9℃; under 45003600 Torr; under shear deformation (360 deg);	19%

: 768-90-1
1-Adamantyl bromide

: 553-26-4
4,4'-bipyridine

: 112671-78-0
1-Adamantan-1-yl-[4,4']bipyridinyl-1-ium; bromide

Conditions

Conditions	Yield
With water at 180℃; for 4h;	98%

: 292638-84-7
styrene

: 768-90-1
1-Adamantyl bromide

: 70624-80-5
1-[(1E)-2-phenylethenyl]-tricyclo[3.3.1.13,7]decane

Conditions

Conditions	Yield
Stage #1: 1-Adamantyl bromide With palladium diacetate; heptakis(6-amino-6-deoxy)-β-cyclodextrin In water; N,N-dimethyl-formamide for 0.5h; Stage #2: styrene With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 8h;	98%
With (trimethylsilyl)methylmagnesium chloride; Co(1,3-bis(diphenylphosphino)hexane)Cl2 In diethyl ether at 20℃; for 8h; Heck reaction;	87%
With Co(1,3-bis(diphenylphosphino)hexane)Cl2; (trimethylsilyl)methylmagnesium chloride In diethyl ether at 20℃; for 8h; Heck reaction;	87%
With potassium carbonate; palladium on activated charcoal In N,N-dimethyl-formamide at 100 - 120℃;	41%

: 768-90-1
1-Adamantyl bromide

: 95-47-6
o-xylene

: 62133-11-3
1-(1-adamantyl)-3,4-dimethylbenzene

Conditions

Conditions	Yield
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;	98%
With zinc(II) chloride Substitution; Heating;	92%
With zinc(II) chloride for 10h; Heating;	90%
With molybdenum hexacarbonyl at 120℃; for 2h; Sealed tube; regioselective reaction;	72%

: 768-90-1
1-Adamantyl bromide

: 112-60-7
Tetraethylene glycol

: 2-(2-(2-(2-(((3s,5s,7s)-adamantan-1-yl)oxy)ethoxy)ethoxy)ethoxy)ethan-1-ol

Conditions

Conditions	Yield
With triethylamine at 180℃; for 23h;	98%
With triethylamine	93%
With triethylamine In dichloromethane at 180℃;	91%

: 768-90-1
1-Adamantyl bromide

: 58521-27-0
pentafluorophenyl potassium carboxylate

: 74867-23-5
1-(perfluorophenyl)adamantane

Conditions

Conditions	Yield
With copper(l) iodide In diethylene glycol dimethyl ether at 130℃; for 24h; Inert atmosphere;	98%

: 110-86-1
pyridine

: 768-90-1
1-Adamantyl bromide

: 19984-57-7
1-(adamantan-1-yl)pyridinium bromide

Conditions

Conditions	Yield
With water at 180℃; for 6h;	97%
at 180℃; for 6h;	97%
at 180℃; for 24h;	12%

: 768-90-1
1-Adamantyl bromide

: 768-92-3
1-adamantyl fluoride

Conditions

Conditions	Yield
With sodium nitrate; (HF)x*C5H5N In dichloromethane for 5h; Ambient temperature;	97%
With nitronium tetrafluoborate; pyridine polyhydrogen fluoride In dichloromethane for 3h; Ambient temperature;	96%
With n-Bu4PF at 150℃; for 5h;	91%

: 768-90-1
1-Adamantyl bromide

: 237394-19-3
2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester

: 237394-33-1
2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester

Conditions

Conditions	Yield
With silver(l) oxide In chloroform for 0.5h; Heating;	97%

: 768-90-1
1-Adamantyl bromide

: 237394-20-6
2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester

: 237394-34-2
2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester

Conditions

Conditions	Yield
With silver(l) oxide In chloroform for 0.5h; Heating;	97%

: 768-90-1
1-Adamantyl bromide

: 71665-89-9
silver(I)-di(4-methylbenzolsulfonyl)amide

: N,N-bis(p-toluenesulfonyl)-1-adamantylamine

Conditions

Conditions	Yield
In benzene at 20℃; for 96h; Substitution;	97%

: 768-90-1
1-Adamantyl bromide

: 504-63-2
trimethyleneglycol

: 359827-31-9
3-(adamantane-1-yloxy)propan-1-ol

Conditions

Conditions	Yield
With triethylamine Heating;	97%

: 768-90-1
1-Adamantyl bromide

: 937785-33-6
(R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)phosphinic acid) propanoic acid allyl ester

: (R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)adamantyloxyphosphinyl) propanoic acid allyl ester

Conditions

Conditions	Yield
With silver(l) oxide In chloroform for 2h; Heating;	97%
With silver(l) oxide In chloroform for 2.83333h; Heating / reflux;	97%

: 768-90-1
1-Adamantyl bromide

: 1631-73-8
trimethylstannane

A: 281-23-2
adamantane

B: 1527-99-7
n-butyltrimethyltin

Conditions

Conditions	Yield
With n-butyllithium In hexane 1-bromoadamantane (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 15 min, quenched with water; analyzed by GC;	A 97% B 95%

...Expand

1-Bromoadamantane Chemical Properties

IUPAC Name: 1-Bromoadamantane
Canonical SMILES: C1C2CC3CC1CC(C2)(C3)Br
InChI: InChI=1S/C10H15Br/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2
InChIKey: VQHPRVYDKRESCL-UHFFFAOYSA-N
Molecular Weight: 215.1301 [g/mol]
Molecular Formula: C₁₀H₁₅Br
XLogP3: 3.6
H-Bond Donor: 0
H-Bond Acceptor: 0
EINECS: 212-200-7
Melting Point: 116-118 °C(lit.)
Index of Refraction: 1.586
Molar Refractivity: 49.9 cm³
Molar Volume: 148.5 cm³
Surface Tension: 45.1 dyne/cm
Density: 1.448 g/cm³
Flash Point: 96.4 °C
Enthalpy of Vaporization: 45.8 kJ/mol
Boiling Point: 240.5 °C at 760 mmHg
Vapour Pressure: 0.0587 mmHg at 25 °C
Product Categories: Adamantanes
Sensitive: Moisture Sensitive
Appearance of 1-Bromoadamantane (CAS NO.768-90-1): white to almost white crystals or cryst. powder

1-Bromoadamantane Safety Profile

Hazard Codes : Harmful Xn
Risk Statements :
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements :
S22: Do not breathe dust
S24/25: Avoid contact with skin and eyes
S36: Wear suitable protective clothing
S26: In case of contact with eyes, rinse immediately with plenty of WATER and seek medical advice
WGK Germany of 1-Bromoadamantane (CAS NO.768-90-1): 3

1-Bromoadamantane Specification

1-Bromoadamantane (CAS NO.768-90-1), its Synonyms are 1-Bromotricyclo(3.3.1.13,7)decane ; 3-Amino-1-adamantanol ; Tricyclo[3.3.1.13, 7]decane, 1-bromo- ; 1-Adamantyl bromide ; Adamantane, 1-bromo- ; Adamantyl bromide .

Product Name

1-Bromoadamantane

Synthetic route

1-Bromoadamantane Chemical Properties

1-Bromoadamantane Safety Profile

1-Bromoadamantane Specification

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