PHENYLLITHIUM supplier | CasNO.591-51-5

Name
Phenyllithium
EINECS 209-720-1
CAS No. 591-51-5
Article Data87
CAS DataBase
Density 0.835
Solubility vigorous reaction
Melting Point 160-163 °C(Solv: benzene (71-43-2))
Formula C6H5 Li
Boiling Point 140-143 ºC
Molecular Weight 84.0467
Flash Point 20 ºC
Transport Information UN 3392
Appearance Colorless transparent to yellow liquid
Safety Incompatible with air, water. Product of reaction with titanium tetraethoxide ignites spontaneously in air and reacts violently with water. When heated to decomposition it emits toxic fumes of Li₂O. See also LITHIUM COMPOUNDS and ORGANOMETALS.
Risk Codes R11;R14;R35;R52/53
Molecular Structure
Hazard Symbols
Synonyms Lithium,diphenyldi-; Phenyllithium
PSA 0.00000
LogP 1.48680

Synthetic route

: 108-86-1
bromobenzene

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With lithium In diethyl ether ultrasonic agitation;	95%
In dibutyl ether at 10 - 30℃; Reagent/catalyst; Temperature; Inert atmosphere; Large scale;	80%
With diethyl ether; lithium man erhitzt schliesslich unter Zugabe von Aether zum Sieden;

: 915703-81-0
N,N'-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3,2-diazaborole

: 75-64-9
tert-butylamine

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
In benzene at 80℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique;	84%

: 587-85-9
diphenylmercury(II)

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With lithium In diethyl ether Inert atmosphere; Schlenk technique;	74%
With lithium; benzene

: 603-33-8
triphenylbismuthane

: 7439-93-2
lithium

A: 7440-69-9
bismuth

B: 591-51-5
phenyllithium

Conditions

Conditions	Yield
In diethyl ether 20°C;	A n/a B 22%

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 108-86-1
bromobenzene

: 60-29-7
diethyl ether

: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

: 3124-01-4
hexaphenyl diplumbane

A: 27980-18-3
hexabutyldiplumbum

B: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

: 555-54-4
diphenylmagnesium

A: 1191-47-5
dibutylmagnesium

B: 591-51-5
phenyllithium

Conditions

Conditions	Yield
reversible Reaktion;

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 1132-39-4
diphenylselenide

A: 28622-61-9
butyl phenyl selenide

B: 645-96-5
Benzeneselenol

C: 591-51-5
phenyllithium

...Expand

: 60-29-7
diethyl ether

: 917-54-4
methyllithium

: 595-89-1
Tetraphenyllead

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
analoge Umsetzungen erfolgen mit Tetrakis-<4-chlor-phenyl>-zinn und mit Dibenzylquecksilber;

...Expand

: 811-49-4
ethyllithium

: 603-36-1
triphenylantimony

: 591-51-5
phenyllithium

: 811-49-4
ethyllithium

: 587-85-9
diphenylmercury(II)

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With benzene

: 811-49-4
ethyllithium

: 587-85-9
diphenylmercury(II)

A: 627-44-1
diethylmercury

B: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

: 595-90-4
tetraphenyltin(IV)

: 71-43-2
benzene

A: 1461-25-2
tetra-n-butyltin(IV)

B: 591-51-5
phenyllithium

Conditions

Conditions	Yield
anal.R.mit Tetrakis-<4-chlor-phenyl>-zinn, Tetraphenylblei, Diphenyl-di-p-tolyl-blei, Tetra-p-tolyl-blei, Triphenylblei und Tri-p-tolyl-blei;

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

: 595-89-1
Tetraphenyllead

: 71-43-2
benzene

A: 1920-90-7
tetra-n-butyl lead

B: 591-51-5
phenyllithium

...Expand

: 591-50-4
iodobenzene

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With n-butyllithium In benzene for 0.333333h; Ambient temperature;
With n-butyllithium In pentane Ambient temperature;
With tert.-butyl lithium In diethyl ether -78 deg C, 0.5 h; RT, 1 h;

: 603-32-7
triphenyl-arsane

: (14C)-Phenyllithium

A: 591-51-5
phenyllithium

B: (14)C18H15As

Conditions

Conditions	Yield
In tetrahydrofuran; benzene at 24.9℃; Rate constant; Kinetics; Thermodynamic data; var. solvents; E, ΔH(excit.), ΔS(excit.), ΔG(excit.);

...Expand

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

A: 591-51-5
phenyllithium

B: 60778-68-9
1,3-bis(lithiumphenylphosphido)propane

Conditions

Conditions	Yield
With lithium In tetrahydrofuran

: 27721-02-4
1,5-bis-(diphenylphosphino)pentane

A: 591-51-5
phenyllithium

B: 115241-59-3
1,5-Bis--pentamethylen

Conditions

Conditions	Yield
With lithium In tetrahydrofuran

: 120416-98-0
C12H10I(1-)*Li(1+)

A: 591-50-4
iodobenzene

B: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With 1-iodo-butane In tetrahydrofuran at -78℃; Equilibrium constant; solvent effect;

: 98585-81-0
bicyclo<1.1.1>pentyl phenyl sulfide

A: 2973-86-6
lithium thiophenoxide

B: 117632-98-1
C5H7Li

C: 117633-17-7
Lithium; bicyclo[1.1.1]pentane-1-thiolate

D: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With 4,4'-di-tert-butylbiphenyl; lithium at -60℃;

...Expand

: 75600-54-3, 96693-29-7
1,2-diphenyl-3,4-di-t-butyldiphosphete

A: 591-51-5
phenyllithium

B: 96693-31-1
(2-phenyl-3,4-di-tert-butyl-1,2-diphosphetenyl)lithium

Conditions

Conditions	Yield
With lithium In tetrahydrofuran Product distribution; Ambient temperature;

: 108-90-7
chlorobenzene

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With naphthalene; lithium In tetrahydrofuran at -78℃; for 0.75h; various react. cond.; diff. chloroarenes; further reaction with electrophiles;
With lithium; lithium hydride; biphenyl In dibutyl ether at 35℃; for 6h;
With lithium In tetrahydrofuran at -25℃;

: 7688-25-7
1,4-di(diphenylphosphino)-butane

A: 591-51-5
phenyllithium

B: 115241-57-1
1,4-Bis--tetramethylen

Conditions

Conditions	Yield
With lithium In tetrahydrofuran

: 109-72-8, 29786-93-4
n-butyllithium

: 587-85-9
diphenylmercury(II)

: 71-43-2
benzene

petroleum ether: petroleum ether

: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 108-86-1
bromobenzene

petroleum ether: petroleum ether

: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

diphenyl-bis-<4-chloro-phenyl>-lead: diphenyl-bis-<4-chloro-phenyl>-lead

A: 14774-78-8
4-chlorophenyl lithium

B: 591-51-5
phenyllithium

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

: 60-29-7
diethyl ether

triphenyl-<4-chloro-phenyl>-lead: triphenyl-<4-chloro-phenyl>-lead

A: 14774-78-8
4-chlorophenyl lithium

B: 591-51-5
phenyllithium

...Expand

: 594-19-4
tert.-butyl lithium

: 587-85-9
diphenylmercury(II)

: 71-43-2
benzene

petroleum ether: petroleum ether

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
mit Dibenzylquecksilber erfolgt eine analoge Umsetzung;

...Expand

: 462-06-6
fluorobenzene

: 591-51-5
phenyllithium

Conditions

Conditions	Yield
With naphthalene; lithium In tetrahydrofuran at -30℃; for 0.583333h; lithiation;

: 591-51-5
phenyllithium

: S-Phenyldibenzothiophenium

: 34884-36-1
phenyl o-terphenyl sulfide

Conditions

Conditions	Yield
Mechanism; 1.) THF, cyclohexane, ether, -100 deg C, 2.) THF, cyclohexane, ether, room temp.;	100%
Stage #1: phenyllithium With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; Stage #2: S-Phenyldibenzothiophenium In tetrahydrofuran; hexane at -78 - 23℃; for 1.5h; Inert atmosphere;	100%
In tetrahydrofuran

: 591-51-5
phenyllithium

: 68981-86-2
3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)pyridine

: 68981-78-2
3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-1,4-dihydro-4-phenylpyridine

Conditions

Conditions	Yield
In tetrahydrofuran 1.) -78 deg C, 1 h, 2.) 0 deg C, 1 h;	100%
In tetrahydrofuran at -78℃; for 0.166667h;	82%
In diethyl ether for 1h; Ambient temperature;	78.6%

: 120-75-2
2-Methylbenzothiazole

: 591-51-5
phenyllithium

: 125414-91-7
(2-Benzothiazolyl)methyllithium

Conditions

Conditions	Yield
In diethyl ether; benzene at -78℃;	100%

: 14371-10-9
(E)-3-phenylpropenal

: 75-77-4
chloro-trimethyl-silane

: 591-51-5
phenyllithium

: 94740-99-5
(E)-1,3-diphenyl-1-trimethylsilyloxy-2-propene

Conditions

Conditions	Yield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at -78℃; for 0.25h; Stage #2: chloro-trimethyl-silane In tetrahydrofuran Further stages.;	100%
1) THF, -20 deg C, 15 min; 2) THF, RT, 12 h; Yield given. Multistep reaction;

...Expand

: 13096-62-3
(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one

: 591-51-5
phenyllithium

: 118436-89-8, 118436-90-1
(2,3,4,6-tetra-O-benzyl-1-C-phenyl)-D-glucopyranose

Conditions

Conditions	Yield
at -78℃;	100%
In tetrahydrofuran 1.) -78 deg C, 2 h, 2.) from -78 deg C to room temperature, 2 h;	85.7%
In tetrahydrofuran at -78℃;

: 39163-29-6, 117780-10-6
1,4,5,6,7,7a-hexahydro-inden-2-one

: 591-51-5
phenyllithium

: 536976-47-3
2-phenyl-2,4,5,6,7,7a-hexahydro-1H-inden-2-ol

Conditions

Conditions	Yield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;	100%
With cerium(III) chloride 1.) THF, -20 deg C, 0.5 h, 2.) THF, from -78 deg C to RT; Multistep reaction;

: 25462-04-8
2-Methyl-2-(tert-butylperoxy)cyclohexanon

: 591-51-5
phenyllithium

: 109139-15-3, 109139-16-4
2-tert-Butylperoxy-2-methyl-1-phenyl-cyclohexanol

Conditions

Conditions	Yield
In diethyl ether at -78℃; for 0.666667h;	100%

: 97229-08-8
1,4-diiodocubane

: 591-51-5
phenyllithium

: 124225-33-8
1-iodo-4-phenylcubane

Conditions

Conditions	Yield
In diethyl ether; cyclohexane for 1h; Ambient temperature;	100%
In diethyl ether; pentane for 0.666667h; Ambient temperature;	88%
In diethyl ether Ambient temperature;

: 103885-03-6
dodec-1-en-2-yl triflate

: 591-51-5
phenyllithium

: 115146-99-1
1-methyleneundecylbenzene

Conditions

Conditions	Yield
With manganese chloride bis(lithium chloride) In tetrahydrofuran; diethyl ether at 25℃; for 1h;	100%

: 132402-19-8
2,2,5,5-Tetramethyl-3,6-diphenyl-2,5-dihydro-pyrazine 1,4-dioxide

: 591-51-5
phenyllithium

: 1,4-dihydroxy-3,3,6,6-tetramethyl-2,2,5,5-tetraphenyl-piperazine

Conditions

Conditions	Yield
at 20℃; for 3h;	100%
at 20℃; for 3h; PhLi excess; Yield given;

: 136964-79-9
C26H24O2S

: 591-51-5
phenyllithium

: 99222-19-2
C28H20

Conditions

Conditions	Yield
In tetrahydrofuran at 0℃;	100%

: 60211-89-4, 63616-13-7, 93424-19-2
trans-1-iodo-2-isothiocyanatocyclohexane

: 591-51-5
phenyllithium

: 77469-36-4
N-(trans-2-iodocyclohexyl)thiobenzamide

Conditions

Conditions	Yield
In diethyl ether at -78℃; for 0.416667h;	100%

: 103668-60-6
2-(dimethoxymethyl)-1-naphthaldehyde

: 591-51-5
phenyllithium

: 114469-02-2
2-(dimethoxymethyl)-α-phenyl-1-naphthalenemethanol

Conditions

Conditions	Yield
In diethyl ether; hexane at -78 - 0℃; for 3.25h;	100%

: 591-51-5
phenyllithium

: 139017-06-4
3-Methyl-1-oxa-5-sila-spiro[4.4]nonane

: 139017-23-5
2-Methyl-3-(1-phenyl-silolan-1-yl)-propan-1-ol

Conditions

Conditions	Yield
In diethyl ether; cyclohexane for 1h; Ambient temperature;	100%

: 591-51-5
phenyllithium

: 144534-06-5
(1S*,2R*,7S*,8R*,11S*)-11-Carbomethoxy-3,3-dimethyltricyclo<5.3.1.02,8>undecane

: 144534-08-7
(1S*,2R*,7S*,8R*,11S*)-3,3-Dimethyl-11-(diphenylhydroxymethyl)-tricyclo<5.3.1.02,8>undecane

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether 1) rt, 1.5 h, 2) reflux, 3 h;	100%

: 591-51-5
phenyllithium

: 157823-76-2
(4S)-3-benzyl-2-oxo-oxazolidine-4-carboxylic acid methyl ester

: 157823-78-4
(S)-4-Benzoyl-3-benzyl-oxazolidin-2-one

Conditions

Conditions	Yield
In tetrahydrofuran at -78℃; for 0.5h;	100%

: 591-51-5
phenyllithium

: 38870-61-0
4,4-dimethyl-2,5-diphenyl-4H-imidazole 1-oxide

: 155126-64-0
1-hydroxy-2,5,5-triphenyl-4,4-dimethyl-2-imidazoline

Conditions

Conditions	Yield
In diethyl ether for 0.25h;	100%
In diethyl ether for 0.25h; Yield given;

: 591-51-5
phenyllithium

: 17157-48-1
bromoacetaldehyde

: 2425-28-7
2-Bromo-1-phenylethanol

Conditions

Conditions	Yield
at -78℃; for 0.25h;	100%

: 591-51-5
phenyllithium

: 5-Phenyl-dibenzoselenophenium; bromide

: 136004-59-6
phenyl o-terphenyl selenide

Conditions

Conditions	Yield
Mechanism; 1.) THF, cyclohexane, ether, -78 deg C, 2.) THF, cyclohexane, ether, room temp.;	100%

: 591-51-5
phenyllithium

: 185121-30-6
(2S)-5-oxo-1-(9'-phenylfluoren-9'-yl)pyrrolidine-2-carboxylic acid methyl ester

: (5S)-5-benzoyl-1-(9'-phenylfluoren-9'-yl)pyrrolidin-2-one

Conditions

Conditions	Yield
In tetrahydrofuran at -78℃; for 1h;	100%

: 591-51-5
phenyllithium

: diphenyl(phenylethynyl)selenium trifluoromethanesulfonate

A: 886-66-8
1,4-diphenyl-1,3-butadiyne

B: 1132-39-4
diphenylselenide

C: 10271-65-5
2-(phenylethynyl)-1,1'-biphenyl

D: 536-74-3
phenylacetylene

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether; cyclohexane at 20℃; for 3h; Substitution; Further byproducts given;	A 2% B 100% C 4% D 60%

...Expand

: 14371-10-9
(E)-3-phenylpropenal

: 591-51-5
phenyllithium

: 75-26-3
isopropyl bromide

: 85267-90-9
(+/-)-4-methyl-1,3-diphenylpentan-1-one

Conditions

Conditions	Yield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h; Stage #2: isopropyl bromide In tetrahydrofuran Further stages.;	100%
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h; Addition; Stage #2: isopropyl bromide In tetrahydrofuran at 20℃; Alkylation;	100 % Chromat.

...Expand

: 2683-82-1
2,3,7,8,12,13,17,18-octaethyl-porphyrin

: 591-51-5
phenyllithium

: 60188-33-2
2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrine

Conditions

Conditions	Yield
Stage #1: 2,3,7,8,12,13,17,18-octaethyl-porphyrin; phenyllithium In tetrahydrofuran; cyclohexane at 40℃; for 0.25h; Addition; Stage #2: With water In tetrahydrofuran; cyclohexane Hydrolysis; Stage #3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran; dichloromethane; cyclohexane for 0.0833333h; Oxidation; Further stages.;	100%
Stage #1: 2,3,7,8,12,13,17,18-octaethyl-porphyrin; phenyllithium In tetrahydrofuran at -40 - 20℃; Stage #2: With water In tetrahydrofuran Stage #3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran Further stages.;	100%

: 14371-10-9
(E)-3-phenylpropenal

: 588-72-7
[(E)-2-bromoethenyl]benzene

: 591-51-5
phenyllithium

: 251635-75-3
trans-1,3,5-triphenylpent-4-en-1-one

Conditions

Conditions	Yield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h; Stage #2: [(E)-2-bromoethenyl]benzene In tetrahydrofuran Further stages.;	100%

...Expand

: 953-21-9
(1E,2E)-N,3-diphenylprop-2-en-1-imine

: 591-51-5
phenyllithium

: (E)-N-(1,3-diphenylallyl)aniline

Conditions

Conditions	Yield
Stage #1: (1E,2E)-N,3-diphenylprop-2-en-1-imine; phenyllithium In tetrahydrofuran; diethyl ether at -78℃; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether	100%
Stage #1: (1E,2E)-N,3-diphenylprop-2-en-1-imine; phenyllithium In tetrahydrofuran at -45℃; for 1h; Stage #2: With oxonium In tetrahydrofuran Further stages.;	92%

: 61154-46-9
bicyclo<5.3.0>-dec-1(10)-en-9-one

: 591-51-5
phenyllithium

: 536976-48-4
2-phenyl-1,2,4,5,6,7,8,8a-octahydroazulen-2-ol

Conditions

Conditions	Yield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;	100%

: 591-51-5
phenyllithium

: 225650-45-3
1,4,5,6,7,8,9,9a-octahydro-2H-cyclopenta[8]annulen-2-one

: 536976-49-5
2-phenyl-2,4,5,6,7,8,9,9a-octahydro-1H-cyclopenta[8]annulen-2-ol

Conditions

Conditions	Yield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;	100%

: 823-09-6
2-(methylsulfanyl)pyrimidine

: 591-51-5
phenyllithium

: 56734-10-2
2-(methylsulfanyl)-4-phenylpyrimidine

Conditions

Conditions	Yield
Stage #1: 2-(methylsulfanyl)pyrimidine; phenyllithium In tetrahydrofuran at 0℃; for 2h; Stage #2: With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 0.75h;	100%

: 56734-10-2
2-(methylsulfanyl)-4-phenylpyrimidine

: 591-51-5
phenyllithium

: 59807-21-5
2-(methylsulfanyl)-4,6-diphenylpyrimidine

Conditions

Conditions	Yield
Stage #1: 2-(methylsulfanyl)-4-phenylpyrimidine; phenyllithium In tetrahydrofuran at 20℃; for 4h; Stage #2: With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 0.75h;	100%

: 632-83-7
1-Bromoanthraquinone

: 591-51-5
phenyllithium

: 955123-64-5
1-bromo-9,10-diphenyl-9,10-dihydroanthracene-9,10-diol

Conditions

Conditions	Yield
In tetrahydrofuran; dibutyl ether at 20℃; for 24h;	100%

PHENYLLITHIUM Chemical Properties

Molecular Formula: C₆H₅Li
Molecular Weight: 84.04
EINECS: 209-720-1
Flash point: 20 ºC
Storage temp: 2-8°C
Boiling point: 140-143 º C
Density: 0.835 g/mL at 25 °C
Water solubility: vigorous reaction
Sensitive of Phenyllithium (591-51-5): Air & Moisture Sensitive
Synonyms: Lithiumphenyl;Phenyl-lithiu;Phenyllithium;Phenyllithium dibutyl;Phli;Phenyllithium, 1.9m solution in cyclo-hexane-ether, 70 to 30;Phenyllithium solution 20% in dibutylether;Phenyllithium sol., 1.8-2.1 m in cyclo- hexane/ether 70/30%
Product Categories: Classes of Metal Compounds;Li (Lithium) Compounds;Typical Metal Compounds
Following is the molecular structure of Phenyllithium (591-51-5):

PHENYLLITHIUM Safety Profile

Incompatible with air, water. Product of reaction with titanium tetraethoxide ignites spontaneously in air and reacts violently with water. When heated to decomposition it emits toxic fumes of Li₂O.
Safety Information of Phenyllithium (591-51-5):
Hazard Codes F,C,N
F: Highly Flammable C: Corrosive N: Dangerous for the environment
Risk Statements: 11-14-17-34-52/53-67-66-65-50/53-22-19-35
11: Highly Flammable
14: Reacts violently with water
17: Spontaneously flammable in air
34: Causes burns
52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
67: Vapors may cause drowsiness and dizziness
66: Repeated exposure may cause skin dryness or cracking
65: Harmful: May cause lung damage if swallowed
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
22: Harmful if swallowed
19: May form explosive peroxides
35: Causes severe burns
Safety Statements: 26-36/37/39-45-61-62-60-43-16-6-8
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61: Avoid release to the environment. Refer to special instructions safety data sheet
62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
60: This material and/or its container must be disposed of as hazardous waste
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
16: Keep away from sources of ignition - No smoking
6: Keep under ... (inert gas to be specified by the manufacturer)
8: Keep container dry
RIDADR: UN 3392 4.2/PG 1
WGK Germany: 2
HazardClass: 4.3
PackingGroup: II

Product Name

Phenyllithium

Synthetic route

PHENYLLITHIUM Chemical Properties

PHENYLLITHIUM Safety Profile

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