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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Cyclohexene, 1-methyl-

Cas:591-49-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

1-Methyl-1-cyclohexene CAS: 591-49-1 Molecular Formula: C7H12 Home Product Category Organic raw materials Hydrocarbons 591-49-1 591-49-1 - Names and Identifiers Name 1-Methyl-1-cyclohexene Synonyms 1-methyl-cyclohe

Factory high quality 1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:1 Kilogram

FOB Price: $159.0 / 170.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Methyl-1-cyclohexene

Cas:591-49-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

tianfu-chem_591-49-1// 1-Methyl-1-cyclohexene, stabilized, 98+%

Cas:591-49-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

1-METHYL-1-CYCLOHEXENE Basic information Product Name: 1-METHYL-1-CYCLOHEXENE Synonyms: 1-methyl-cyclohexen;1-Methylcyclohexene-1;alpha-Methylcyclohexene;cyclohexene,1-methyl-;1-METHYL-1-CYCLOHEXENE;1-METHYLCYCLOHEXENE;1-METHYLCYCLOHEX-1-ENE;2,

Factory Supply 1-methyl-cyclohexen

Cas:591-49-1

Min.Order:1 Gram

Negotiable

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

1-METHYL-1-CYCLOHEXENE 591-49-1

Cas:591-49-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

UPS Standard CAS 591-49-1 with high-quality service

Cas:591-49-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Cyclohexene, 1-methyl-

Cas:591-49-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High quality 1-METHYL-1-CYCLOHEXENE CAS 591-49-1 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in

High quality 1-METHYL-1-CYCLOHEXENE CAS 591-49-1

Cas:591-49-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Cyclohexene, 1-methyl-

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kunshan Push Trading Co.,LTD

1-methyl-1-cyclohexane 591-49-1 ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good and

1-methyl-1-cyclohexane 591-49-1

Cas:591-49-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1-(METHYL)-1-CYCLOHEXENE cas no.591-49-1 0.98

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methylcyclohex-1-ene

Cas:591-49-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Cyclohexene, 1-methyl-

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1-methyl-1-cyclohexene

Cas:591-49-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

product best price 1-METHYL-1-CYCLOHEXENEAppearance:colourless liquid Storage:Store at 2-8℃ Package:according to customers' requirements Application:medicine Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...)

product best price 1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:1 Gram

Negotiable

Type:Other

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1-Methyl-1-cyclohexene Manufacturer/High quality/Best price/In stock

Cas:591-49-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

product best price 1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1-Methyl-1-Cyclohexene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1-Methyl-1-cyclohexene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1-METHYL-1-CYCLOHEXENE 100g

Cas:591-49-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-Methyl-1-cyclohexene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Methyl-1-cyclohexene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

Cyclohexene, 1-methyl- cas 591-49-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Cyclohexene, 1-methyl- cas 591-49-1

Cas:591-49-1

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:colourless liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

1-Methyl-1-cyclohexene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Methylcyclohex-1-ene

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

591-49-1 Application:intermediate

1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1-METHYL-1-CYCLOHEXENE 591-49-1

Cas:591-49-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1-METHYL-1-CYCLOHEXENE

Cas:591-49-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methylenecyclohexane
1192-37-6

methylenecyclohexane

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
In water Ambient temperature;99%
With Grotjahn’s catalyst In [(2)H6]acetone at 70℃; for 1h; Reagent/catalyst; Inert atmosphere; Glovebox;98%
With (μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2 In dichloromethane at 20℃; for 3h;79%
cis-methyl-2 phenylacetoxy cyclohexane
42288-78-8, 42288-79-9

cis-methyl-2 phenylacetoxy cyclohexane

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

carbon dioxide
124-38-9

carbon dioxide

D

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
In pentane Irradiation; Further byproducts given;A 1.4%
B 13%
C 97%
D 6.7%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

cyclohexanone
108-94-1

cyclohexanone

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
Stage #1: methyl magnesium iodide; cyclohexanone In diethyl ether
Stage #2: With iodine In toluene Heating;
95%
Yield given. Multistep reaction;
2) dehydration; Yield given. Multistep reaction;
methylmagnesium chloride
676-58-4

methylmagnesium chloride

cyclohexanone
108-94-1

cyclohexanone

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
Stage #1: methylmagnesium chloride; cyclohexanone In tetrahydrofuran at -10 - 0℃; for 0.5h; Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In 1,2-dichloro-ethane Reflux;
92%
1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With phosphoric acid at 110 - 120℃;91%
With aluminum(III) sulfate; iodine
With aluminum(III) sulfate; toluene-4-sulfonic acid
1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

acetic anhydride
108-24-7

acetic anhydride

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1-acetoxy-1-methyl-cyclohexane
16737-30-7

1-acetoxy-1-methyl-cyclohexane

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In acetonitrile at -20℃; for 5h;A 9%
B 91%
1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1-acetoxy-1-methyl-cyclohexane
16737-30-7

1-acetoxy-1-methyl-cyclohexane

Conditions
ConditionsYield
With acetic anhydride; scandium tris(trifluoromethanesulfonate) In acetonitrile at -20℃; for 5h;A 9%
B 91%
methylenecyclohexane
1192-37-6

methylenecyclohexane

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With ammonium hypophosphorous acid; palladium on activated charcoal In benzene for 3h;A n/a
B 87%
2-methyl-1,7-octadiene
13151-07-0

2-methyl-1,7-octadiene

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With trans-dichlorobis(2,6-dibromphenoxy)oxotungsten(VI); tetraethyllead(IV) In various solvent(s) at 90℃; for 2h;84%
1-(N,N-Dichloroamino)-1-methylcyclohexane
57337-77-6

1-(N,N-Dichloroamino)-1-methylcyclohexane

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

methylenecyclohexane
1192-37-6

methylenecyclohexane

Conditions
ConditionsYield
In neat (no solvent) at 210℃; Product distribution; var. reactor materials;A 80%
B 20%
all-cis-1,3-bis(methansulfonyloxy)-2-methylcyclohexan

all-cis-1,3-bis(methansulfonyloxy)-2-methylcyclohexan

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With tetra-n-propylammonium bromide In N,N-dimethyl-formamide electrochemical reduction (Pt-electrode);73%
1,2-epoxy-1-methylcyclohexane
1713-33-3

1,2-epoxy-1-methylcyclohexane

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); diethylzinc In tetrahydrofuran; hexane Inert atmosphere;72%
With trifluoroacetic acid; selenobenzamide In dichloromethane at 0℃; for 0.0833333h; Mechanism; With other reagents are dicussed.;51 % Chromat.
With trifluoroacetic acid; selenobenzamide In dichloromethane at 0℃; for 0.0833333h; With other reagents are discussed.;51 % Chromat.
3-methylcyclohex-2-en-1-ol
21378-21-2

3-methylcyclohex-2-en-1-ol

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With methanol; toluene-4-sulfonic acid at 25℃; for 18h; Inert atmosphere; Sealed tube; UV-irradiation;71%
2,5-dihydrotoluene
4313-57-9

2,5-dihydrotoluene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

D

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; for 8h; Yields of byproduct given;A 67%
B n/a
C n/a
D 2%
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; under 760 Torr; for 8h; Product distribution; Mechanism; different 1,4-cyclohexadienes and reaction times;A 67%
B n/a
C n/a
D 2%
toluene
108-88-3

toluene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

2,5-dihydrotoluene
4313-57-9

2,5-dihydrotoluene

C

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

Conditions
ConditionsYield
With lithium; ethylenediamine; isopropyl alcohol at 85 - 95℃; for 0.333333h;A n/a
B 67%
C n/a
4-methyl-1,2-diazaspiro<2.5>oct-1-ene
14359-89-8

4-methyl-1,2-diazaspiro<2.5>oct-1-ene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

Conditions
ConditionsYield
With β‐cyclodextrin for 2h; Irradiation;A 66%
B 34 % Chromat.
With alpha cyclodextrin for 2h; Irradiation;A 72 % Chromat.
B 28 % Chromat.
1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1-acetoxy-1-methyl-cyclohexane
16737-30-7

1-acetoxy-1-methyl-cyclohexane

C

1'-methylcyclohexyl 3-oxobutanoate
91328-33-5

1'-methylcyclohexyl 3-oxobutanoate

D

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
ConditionsYield
With acetic anhydride; cobalt(II) chloride In acetonitrile at 80℃; for 12h;A 10%
B 65%
C 19%
D n/a
1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

acetic anhydride
108-24-7

acetic anhydride

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1-acetoxy-1-methyl-cyclohexane
16737-30-7

1-acetoxy-1-methyl-cyclohexane

C

1'-methylcyclohexyl 3-oxobutanoate
91328-33-5

1'-methylcyclohexyl 3-oxobutanoate

D

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
ConditionsYield
With cobalt(II) chloride In acetonitrile at 80℃; for 12h;A 10%
B 65%
C 19%
D n/a
4-methyl-N'-(2-methylcyclohexylidene)benzenesulfonohydrazide
52826-41-2

4-methyl-N'-(2-methylcyclohexylidene)benzenesulfonohydrazide

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With tetraethylammonium bromide In N,N-dimethyl-formamide at 20℃;54%
With tetrabutylammonium perchlorate; oxygen In dimethyl sulfoxide for 12h; Ambient temperature; electrolysis;46.6%
carbon monoxide
201230-82-2

carbon monoxide

2-methyl-1-cyclohexenyl triflate
32363-21-6

2-methyl-1-cyclohexenyl triflate

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

2-methylcyclohex-1-ene-1-carbaldehyde
54625-15-9

2-methylcyclohex-1-ene-1-carbaldehyde

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; lithium chloride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 50℃;A 8 % Chromat.
B 53%
1-chloroacetophenone
532-27-4

1-chloroacetophenone

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

4a-methyl-1,2,3,4,4a,9,10,10aβ-octahydro-9-phenanthrone
60795-74-6, 60795-83-7, 84711-03-5, 84711-04-6, 134930-34-0

4a-methyl-1,2,3,4,4a,9,10,10aβ-octahydro-9-phenanthrone

Conditions
ConditionsYield
With silver trifluoromethanesulfonate In acetonitrile for 1h; Irradiation;A n/a
B 45%
1-methoxy-5-methyl-cyclohexa-1,4-diene
13697-84-2

1-methoxy-5-methyl-cyclohexa-1,4-diene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

1-methoxy-5-methyl-bicyclo<3.1.0>hexane
88739-07-5

1-methoxy-5-methyl-bicyclo<3.1.0>hexane

Conditions
ConditionsYield
With hydrogenchloride; amalgamated zinc In diethyl ether at -35℃;A n/a
B n/a
C 40%
With hydrogenchloride; amalgamated zinc In diethyl ether at -35℃;
cis-trans-1,3-bis(methansulfonyloxy)-2-methylcyclohexan

cis-trans-1,3-bis(methansulfonyloxy)-2-methylcyclohexan

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

endo-6-Methylbicyclo<3.1.0>hexan
90271-67-3

endo-6-Methylbicyclo<3.1.0>hexan

Conditions
ConditionsYield
With tetra-n-propylammonium bromide In N,N-dimethyl-formamide electrochemical reduction (Pt-electrode);A 40%
B 9%
bicyclo[4.1.0]heptane
286-08-8

bicyclo[4.1.0]heptane

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

Cycloheptene
628-92-2

Cycloheptene

Conditions
ConditionsYield
With iodine In dichloromethane for 8h; Irradiation;A 7%
B 39%
C 0.2%
With iodine In dichloromethane for 8h; Product distribution; Quantum yield; Irradiation; different reaction circumstances;
4-methyl-cyclohex-3-enecarbaldehyde
7560-64-7

4-methyl-cyclohex-3-enecarbaldehyde

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

para-xylene
106-42-3

para-xylene

C

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

D

toluene
108-88-3

toluene

Conditions
ConditionsYield
With palladium on carbon at 300℃; under 760.051 Torr; Inert atmosphere;A n/a
B n/a
C 22%
D 27%
1-methyl-4,5-threo-bis(benzenesulphonyl)cyclohexene

1-methyl-4,5-threo-bis(benzenesulphonyl)cyclohexene

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

Conditions
ConditionsYield
With ammonia; lithium23%
methanol
67-56-1

methanol

2-methyl-1-iodo-1-cyclohexene
40648-08-6

2-methyl-1-iodo-1-cyclohexene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1-chloro-2-methylcyclohexene
16642-49-2

1-chloro-2-methylcyclohexene

Conditions
ConditionsYield
at 40℃; for 10h; Irradiation;A 12%
B 21%
C7H12Pt(Cl)4
108296-73-7

C7H12Pt(Cl)4

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

Cycloheptene
628-92-2

Cycloheptene

D

4-methylcyclohexene
591-47-9

4-methylcyclohexene

E

methylenecyclohexane
1192-37-6

methylenecyclohexane

Conditions
ConditionsYield
With potassium cyanide In diethyl ether Refluxing in ether for 1 h, evapn. of ether in vac., treating of residue with aq. KCN.; Extg. with CHCl3, NMR, MS. Further products.;A 13.6%
B 10%
C 2.8%
D 4.3%
E 9.8%
cis-methyl-2 phenylacetoxy cyclohexane
42288-78-8, 42288-79-9

cis-methyl-2 phenylacetoxy cyclohexane

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

methyl cyclohexane
82166-21-0

methyl cyclohexane

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
In pentane Irradiation; Further byproducts given;A 1.4%
B 13%
C 6.7%
D 2.7%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

1,2-epoxy-1-methylcyclohexane
1713-33-3

1,2-epoxy-1-methylcyclohexane

Conditions
ConditionsYield
With tris(1,4-dihydro-2-methyl-4-oxo-1-(2-phenylethyl)-3-pyridinolato)iron(III); oxygen; isobutyraldehyde In 1,2-dichloro-ethane at 60℃; for 22h;100%
With tert.-butylhydroperoxide; C14H25Cl2MoO6P In 2,2,4-trimethylpentane; dichloromethane at 19.9℃; for 24h;100%
With sodium persulfate; water at 20℃; for 12h; Reagent/catalyst;100%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With hydrogen In neat (no solvent) at 70℃; for 5h; Catalytic behavior; Flow reactor;100%
With C40H56N2RuSi4; hydrogen In toluene at 25℃; under 760.051 Torr; for 3h; Schlenk technique;99%
With C40H56FeN2Si4(2-); hydrogen In 1,2-dimethoxyethane at 80℃; under 7600.51 Torr; for 2h; Schlenk technique; Autoclave;99%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

propionaldehyde
123-38-6

propionaldehyde

(methyl-2' cyclohexyl)-1 propanone-1
85995-78-4

(methyl-2' cyclohexyl)-1 propanone-1

Conditions
ConditionsYield
With dibenzoyl peroxide at 90℃; for 10h;100%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

propargyl alcohol
107-19-7

propargyl alcohol

2-Bromo-1-methyl-1-prop-2-ynyloxy-cyclohexane
118616-30-1

2-Bromo-1-methyl-1-prop-2-ynyloxy-cyclohexane

Conditions
ConditionsYield
With N-Bromosuccinimide at 0℃; for 1h;100%
triethylsilane
617-86-7

triethylsilane

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

triethyl(cis-2-methylcyclohexyl)silane

triethyl(cis-2-methylcyclohexyl)silane

Conditions
ConditionsYield
With C14H26B22Cl22Zn at 20℃; for 0.25h; Inert atmosphere; Glovebox;100%
With fluorotris(pentafluorophenyl)phosphonium tetrakis(pentafluorophenyl)borate In dichloromethane at 20℃; for 1h; Inert atmosphere;96%
With C33H36F5N2Zn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 14h;
With C29H42AlN2(1+)*C24BF20(1-) In chlorobenzene at 20℃; for 0.166667h;82 %Spectr.
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

1-bromo-1-methylcyclohexane
931-77-1

1-bromo-1-methylcyclohexane

Conditions
ConditionsYield
With (R)-2,6-di([1,1'-biphenyl]-4-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine-4-oxide; boron tribromide In dichloromethane-d2 at 20℃; for 1h;99%
With hydrogen bromide In water at 45℃; for 48h;68.7%
With hydrogen bromide; acetic acid; diphenylamine
With hydrogen bromide; acetic acid
With hydrogen bromide; silica gel In water at 0 - 20℃; for 48h; Reagent/catalyst;98 %Spectr.
ammonia borane complex
10043-11-5

ammonia borane complex

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

aminodi-2-methylcyclohexylborane

aminodi-2-methylcyclohexylborane

Conditions
ConditionsYield
In tetrahydrofuran Reflux; Inert atmosphere;97%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

2-methoxy-1,4-benzoquinone
2880-58-2

2-methoxy-1,4-benzoquinone

3-Methoxy-5a-methyl-5a,6,7,8-tetrahydro-dibenzofuran-2-ol
137123-26-3

3-Methoxy-5a-methyl-5a,6,7,8-tetrahydro-dibenzofuran-2-ol

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane 1.) -78 deg C, 1 h, 2.) -78 deg C to r.t., 12 h;96.6%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

6-oxoheptanoic acid
3128-07-2

6-oxoheptanoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; 12-tungstophosphoric acid/Al/C In tert-butyl alcohol at 60℃; for 24h;96%
With tris(cetylpyridinium) 12-tungstophosphate; dihydrogen peroxide In tert-butyl alcohol for 24h; Heating;90%
With tert.-butylhydroperoxide; indium(III) chloride In water at 90℃; for 8.2h;84%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

[Chloro-(3,4-dichloro-phenylsulfanyl)-methyl]-trimethyl-silane
114124-63-9

[Chloro-(3,4-dichloro-phenylsulfanyl)-methyl]-trimethyl-silane

1,2-Dichloro-4-[2-methyl-cyclohex-(E)-ylidenemethylsulfanyl]-benzene

1,2-Dichloro-4-[2-methyl-cyclohex-(E)-ylidenemethylsulfanyl]-benzene

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at -20℃; for 0.5h;96%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

n-octanoic acid chloride
111-64-8

n-octanoic acid chloride

1-(2-methyl-2-cyclohexen-1-yl)octan-1-one

1-(2-methyl-2-cyclohexen-1-yl)octan-1-one

Conditions
ConditionsYield
With 2,6-Dibromopyridine; aluminum (III) chloride In dichloromethane at 20℃; for 3h; Inert atmosphere;96%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

1,2-dibromo-1-methylcyclohexane
56860-91-4

1,2-dibromo-1-methylcyclohexane

Conditions
ConditionsYield
With bromine In dichloromethane at 0 - 20℃; for 0.5h;95%
With chloroform; bromine
With 4DABCO*6HBr*4Br2 In chloroform for 0.5h;95 % Chromat.
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

acetic anhydride
108-24-7

acetic anhydride

1-(2-methyl-cyclohex-2-enyl)-ethanone
15564-32-6

1-(2-methyl-cyclohex-2-enyl)-ethanone

Conditions
ConditionsYield
With hydrogenchloride; silver hexafluoroantimonate In acetic acid for 12h; Ambient temperature;95%
ethylaluminum dichloride In dichloromethane at 25℃; for 1h;55%
With tin(IV) chloride
With zinc(II) chloride
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

N-(4-methylphenylaminothio)phthalimide
118622-94-9

N-(4-methylphenylaminothio)phthalimide

N-(4-methylphenyl)-2-methylenecyclohexane-1-sulfenamide

N-(4-methylphenyl)-2-methylenecyclohexane-1-sulfenamide

Conditions
ConditionsYield
With triethylamine In acetone at 20℃;95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

cis-2-acetoxy-1-methylcyclohexanol

cis-2-acetoxy-1-methylcyclohexanol

Conditions
ConditionsYield
With water; iodine In acetic acid at 90℃; for 2.5h;95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

(1RS,2SR)-2-bromo-1-fluoro-1-methylcyclohexene
122540-68-5, 130721-14-1, 141038-94-0

(1RS,2SR)-2-bromo-1-fluoro-1-methylcyclohexene

Conditions
ConditionsYield
With N-Bromosuccinimide; 1-ethyl-3-methylimidazolium oligo hydrogenfluoride In dichloromethane at 20℃; for 1h;95%
With N-Bromosuccinimide; 3-ethyl-1-methyl-imidazorium oligo hydrogen fluoride In dichloromethane at 20℃; for 1h;95%
With N-Bromosuccinimide; 3-ethyl-1-methylimidazolium oligo hydrogen fluoride In dichloromethane at 20℃; for 1h;95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

p-methylphenacyl chloride
4209-24-9

p-methylphenacyl chloride

4a,6-Dimethyl-2,3,4,4a,10,10a-hexahydro-1H-phenanthren-9-one
145474-36-8

4a,6-Dimethyl-2,3,4,4a,10,10a-hexahydro-1H-phenanthren-9-one

Conditions
ConditionsYield
With silver trifluoromethanesulfonate In benzene for 1h; Irradiation;95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate

4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate

2-methylene-1-[4-acetamido(2,2,6,6-tetramethylpiperidin-1-yl)oxy]cyclohexane

2-methylene-1-[4-acetamido(2,2,6,6-tetramethylpiperidin-1-yl)oxy]cyclohexane

Conditions
ConditionsYield
Stage #1: 1-methylcyclohex-1-ene; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 20℃; for 1.5h;
Stage #2: With sodium carbonate
95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

trans-2-bromo-1-methylcyclohexanol

trans-2-bromo-1-methylcyclohexanol

Conditions
ConditionsYield
With water In acetone at 20℃; for 0.0833333h;95%
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

1,2-dichloro-1-methylcyclohexane
69954-99-0

1,2-dichloro-1-methylcyclohexane

Conditions
ConditionsYield
With manganese(IV) oxide; acetyl chloride; manganese(ll) chloride In N,N-dimethyl-formamide at 30℃; for 2h;94%
With ; calcium chloride In acetic acid Heating;74%
With diethyl ether; chlorine
With molybdenum(V) chloride In dichloromethane at -78℃;
With 1-nitrocyclohexene; titanium tetrachloride In dichloromethane at 25℃; for 0.5h;21 % Chromat.
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