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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accre

Pharmaceutical intermediate 2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:170 Kilogram

FOB Price: $6.5

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 96-47-9 2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

2-Methyltetrahydrofuran CAS No: 96-47-9 Molecular Structure: Specifications: Item Details

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--96-47-9--2-Methyltetrahydrofuran factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business

TIANFUCHEM--96-47-9--2-Methyltetrahydrofuran factory price

Cas:96-47-9

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Pharmaceutical intermediate 2-Methyltetrahydrofuran / LIDE PHARMA- Factory supply / Best price

Cas:96-47-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

2-Methyltetrahydrofuran Basic information Product Name: 2-Methyltetrahydrofuran Synonyms: 2-Methyltetrahydrofuran,For Grignard reaction,anhydrous, stabilized;2-Methyltetrahydrofuran,99+%,Extra Dry,Stabilized;2-Methyltetrahydrofuran,99+%,Extra D

Factory Supply methyl-THF

Cas:96-47-9

Min.Order:1 Gram

Negotiable

Type:Other

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 96-47-9 with best quality

Cas:96-47-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 2-Methyltetrahydrofuran Synonyms 2-Methylfuranidine;2-Methyloxolane;Furan, 2-methyl-tetrahydro-;Tetrahydrofuran, 2-methyl-;Tetrahydrosylvan;TETRAHYDROSILVAN;

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Methyltetrahydrofuran 96-47-9

Cas:96-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

2-Methyltetrahydrofuran /CAS:96-47-9

Cas:96-47-9

Min.Order:1 Kilogram

FOB Price: $54.0 / 70.0

Type:Trading Company

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Pharmaceutical intermediate 2-Methyltetrahydrofuran CAS NO.96-47-9

Cas:96-47-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

2-Methyltetrahydrofuran cas:96-47-9

Cas:96-47-9

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Hangzhou ZeErRui Chemical Co., Ltd.

Product Name 2-Methyl tetrahydrofuran CAS No 96-47-9 Structure Molecular formula C5H1

2-Methyltetrahydrofuran manufacture

Cas:96-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

2-Methyltetrahydrofuran / METHFAppearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermedia

2-Methyltetrahydrofuran / METHF

Cas:96-47-9

Min.Order:1 Gram

Negotiable

Type:Other

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

2-Methyltetrahydrofuran CAS NO.: 96-47-9

Cas:96-47-9

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Methyltetrahydrofuran Synonyms: 2-Methyltetrahydrofuran,For Grignard reaction,anhydrous, stabilized;2-Methyltetrahydrofuran,99+%,Extra Dry,Stabilized;2-Methyltetrahydrofuran,99+%,Extra Dry over Molecular Sieve,Stabilized;2-Methy

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 2-Methyltetrahydrofuran CAS No.: 96-47-9 Molecule Formula:C5H10O Molecule Weight:86.13 Purity: 99.0% Package: 200kg/drum Description:Colorless clear liquid Manufacture Standards:Enterprise Standard

High Purity 2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:Colorless to light yellow liquid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Methyltetrahydrofuran cas no. 96-47-9 98%

Cas:96-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

Best price 2-Methyltetrahydrofuran 96-47-9

Cas:96-47-9

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

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Wuxi TAA Chemical Industry Co.,LTD.

1.Factory supply with good quality and price.2.Regular order with good quality and price .3.ISO,Halal Koshert Certificate. 4.One biggest supplly in China.99.Factory offer.Appearance:colorless liquid Storage:store in a well-closed container away from

High quality 2-Methyltetrahydrofuran for hot sale

Cas:96-47-9

Min.Order:0

Negotiable

Type:Other

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-Methyltetrahydrofuran 96-47-9

Cas:96-47-9

Min.Order:0

Negotiable

Type:Trading Company

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Afine Chemicals Limited

excellent quality and reliable supplierAppearance:COA mentioned Storage:COA mentioned Package:Standard or custom package Application:pharmaceutical raw materails Transportation:sea/air /courier Port:China main port

2-METHYLTETRAHYDROFURAN

Cas:96-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#96-47-9;CAT#A845598

Cas:96-47-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and

2-furan

Cas:96-47-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Zibo Kunran Enterprises Co. LTD

1. Factory steady offer directly; 2. More than 10 years of production and process improved experience; 3. Professional hazard chemical Logistics; 4. Reliable quality assurance 5. Punctual delivery time Appearance:Clear colorless Liquid Sto

Supply 99.5%min 2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

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Henan Wising Chem Co., Ltd

Henan Wising Chem specialize in sourcing the chemicals in China. We are associated with many trusted manufacturers each having different area of expertise required for meeting the needs of our local as well as overseas buyers . We have access t

2-Methyltetrahydrofuran

Cas:96-47-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zouping Mingxing Chemical Co.,Ltd.

Appearance: colorless liquid Purity: 99.5% Water: 0.05%max Packing: 170kg per drum. Production Capacity: 1400kg per day. Payment terms: TT after BL date; L/C; 20%TT in advance and balance against copy of BL. Lead time: 3-10days after th

Produce 2-Methyltetrahydrofuran 96-47-9 C5H10O

Cas:96-47-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Synthetic route

2-methylfuran
534-22-5

2-methylfuran

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With 3% Pd/C; hydrogen In isopropyl alcohol at 219.84℃; under 25858.1 Torr; for 5h; Inert atmosphere;100%
With palladium-aluminum at 150℃; Hydrogenation;
With osmium at 80℃; Hydrogenation;
1,4-Pentanediol
626-95-9

1,4-Pentanediol

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol under 30003 Torr; for 5h; Reagent/catalyst; Autoclave;99%
Trichlorbutylstannan for 0.24h;96%
Nafion-H at 135℃; for 5h;90%
4-oxopentanoic acid ethyl ester
539-88-8

4-oxopentanoic acid ethyl ester

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With hydrogen In hexane at 180℃; for 4h; Temperature; Reagent/catalyst; Solvent; Autoclave;98%
Multi-step reaction with 2 steps
1: hydrogen / 1,4-dioxane / 2 h / 190 °C / 30003 Torr / Autoclave
2: hydrogen / 1,4-dioxane / 5 h / 190 °C / 30003 Torr / Autoclave
View Scheme
Multi-step reaction with 2 steps
1: hydrogen / 1,4-dioxane / 2 h / 190 °C / 30003 Torr / Autoclave
2: hydrogen / 1,4-dioxane / 5 h / 190 °C / 30003 Torr / Autoclave
View Scheme
furfural
98-01-1

furfural

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With palladium on silica; copper phyllosilicate; hydrogen at 180℃; Reagent/catalyst; Inert atmosphere;97.1%
Stage #1: furfural With hydrogen at 200℃; under 760.051 Torr; Flow reactor;
Stage #2: With hydrogen at 120℃; under 760.051 Torr; Temperature; Flow reactor;
96.3%
With hydrogen; 5% palladium over charcoal; copper chromite catalyst E 403-TU at 175℃; under 760.051 Torr; Product distribution / selectivity; In the presence of quartz glass rings (as an evaporation zone);
5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With tris(2,4-pentanedionato)ruthenium(III); N-butyl-N'-(4-sulfobutyl)-imidazolium p-toluenesulfonate; hydrogen; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] at 160℃; under 75007.5 Torr; for 18h; Inert atmosphere; Autoclave; Ionic liquid;95%
Multi-step reaction with 2 steps
1: sodium; alcohol
2: hydrochloric acid; alcohol / 150 °C / im Druckrohr
View Scheme
Multi-step reaction with 2 steps
1: sodium; xylene
2: HI / auf dem Wasserbad und folgenden Reduzieren mit Zinkstaub und Eisessig
View Scheme
levulinic acid
123-76-2

levulinic acid

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With bromopentacarbonylmanganese(I); phenylsilane In toluene at 100℃; for 24h; Catalytic behavior; Time; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique;95%
With Cu/SiO2 at 220℃; under 22502.3 Torr; Temperature;93%
With ammonium hexafluorophosphate; Λ(+)-tris(pentane-2,5-dionato)ruthenium; N-butyl-N'-(4-sulfobutyl)-imidazolium p-toluenesulfonate; hydrogen; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] at 160℃; under 75007.5 Torr; for 18h; Inert atmosphere;92%
pentan-1-ol
71-41-0

pentan-1-ol

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

1-iodo-butane
542-69-8

1-iodo-butane

C

pentanal
110-62-3

pentanal

Conditions
ConditionsYield
With N-iodo-succinimide In chlorobenzene for 2h; Irradiation;A 94%
B 1%
C n/a
With N-iodo-succinimide In chlorobenzene for 2h; Product distribution; Irradiation; var. irradiat. times, temps. and light cond.;A 94%
B 1%
C n/a
(C4H9)3SnOCH(CH3)CH2CH2CH2Cl
41968-76-7

(C4H9)3SnOCH(CH3)CH2CH2CH2Cl

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

tributyltin chloride
1461-22-9

tributyltin chloride

Conditions
ConditionsYield
decompn. of the crude compound at 120°C (0.5 h);A 93%
B n/a
decompn. of the crude compound at 120°C (0.5 h);A 93%
B n/a
n-Pent-4-enyl alcohol
821-09-0

n-Pent-4-enyl alcohol

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With Nd magnetically supported catalyst In dichloromethane at 83℃; for 24h; Schlenk technique; Inert atmosphere;91%
With aluminium(III) triflate In nitromethane at 101℃; for 1h;87%
With ytterbium(III) triflate at 120℃; Inert atmosphere; Ionic liquid;78%
tetrahydrofuran-2-carbaldehyde
7681-84-7

tetrahydrofuran-2-carbaldehyde

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With hydrogen In para-xylene at 180℃; under 30003 Torr; for 48h; Glovebox; Sealed tube; chemoselective reaction;90%
pentan-1-ol
71-41-0

pentan-1-ol

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; iodine Irradiation;89%
furfural
98-01-1

furfural

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

2-methylfuran
534-22-5

2-methylfuran

C

(+/-)-2-pentanol
6032-29-7

(+/-)-2-pentanol

D

2-Pentanone
107-87-9

2-Pentanone

Conditions
ConditionsYield
With hydrogen; Cu-based catalyst at 212℃; Product distribution; Further Variations:; Temperatures; reaction in vapour phase, fixed bed reactor;A 3.3%
B 88.6%
C 4.8%
D 2.7%
5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

pentan-1-ol
71-41-0

pentan-1-ol

Conditions
ConditionsYield
With 30% Cu/SiO2 In methanol at 190℃; under 60006 Torr; for 10h; Reagent/catalyst; Solvent; Temperature; Autoclave;A 16.3%
B 82.9%
2-methylfuran
534-22-5

2-methylfuran

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

Conditions
ConditionsYield
With carbon dioxide; 5% Pd(II)/C(eggshell); hydrogen at 300℃; under 112511 Torr; Supercritical conditions;A 82%
B 6%
N-(4-Pentenyl-1-oxy)pyridine-2(1H)-thione
114720-43-3

N-(4-Pentenyl-1-oxy)pyridine-2(1H)-thione

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 80℃; for 0.333333h; Product distribution; Mechanism;80%
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

Conditions
ConditionsYield
With hydrogen In water at 130℃; for 4h; Reagent/catalyst; Solvent; Autoclave;A 17%
B 80%
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 20%
B 79%
With hydrogen In water at 130℃; for 24h; Reagent/catalyst; Autoclave;A 77%
B 12%
5-Hydroxy-2-pentanone
1071-73-4

5-Hydroxy-2-pentanone

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Conditions
ConditionsYield
With triethylsilane; trifluorormethanesulfonic acid In dichloromethane-d2 at 20℃; for 24h; NMR tube;80%
With hydrogen In neat (no solvent) at 90℃; under 15001.5 Torr; for 5h;> 99 %Chromat.
furfural
98-01-1

furfural

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

2-methylfuran
534-22-5

2-methylfuran

Conditions
ConditionsYield
Stage #1: furfural With hydrogen at 200℃; under 760.051 Torr; Flow reactor;
Stage #2: With hydrogen at 100℃; under 760.051 Torr; Temperature; Flow reactor;
A 79.3%
B 20%
With hydrogen In isopropyl alcohol at 229.84℃; under 30003 Torr; for 2h;A 10%
B 57%
With carbon dioxide; palladium on activated charcoal; hydrogen In water at 80℃; for 0.333333h;
furfural
98-01-1

furfural

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

Conditions
ConditionsYield
Stage #1: furfural With hydrogen at 160℃; under 760.051 Torr; Flow reactor;
Stage #2: With hydrogen at 130℃; under 760.051 Torr; Flow reactor;
A 13.7%
B 78.2%
With hydrogen In 1,4-dioxane; isopropyl alcohol at 200℃; under 48754.9 Torr; for 6h; Reagent/catalyst;A 36%
B 45%
Multi-step reaction with 2 steps
1: isopropyl alcohol; 10% Pd/C / 7.5 h / 150 °C / Inert atmosphere
2: isopropyl alcohol; 10% Pd/C / 7.5 h / 180 °C / Inert atmosphere
View Scheme
5-ketohexanoic acid
3128-06-1

5-ketohexanoic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol at 250℃; under 52505.3 Torr; for 24h; Temperature; Reagent/catalyst;A 75%
B 8%
With hydrogen In isopropyl alcohol at 250℃; under 52505.3 Torr; for 5h; Temperature; Reagent/catalyst;A 22.7%
B 64.5%
phenylthio-4-pentenol
111341-49-2

phenylthio-4-pentenol

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

n-Pent-4-enyl alcohol
821-09-0

n-Pent-4-enyl alcohol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In various solvent(s) at 80℃; for 0.5h; Rate constant; Mechanism; Bu3Sn. effect in SH2 displacement of alkoxy radicals from sulphur, exo cyclization;A 73%
B 26%
furfural
98-01-1

furfural

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

C

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
Stage #1: furfural With hydrogen at 160℃; under 760.051 Torr; Flow reactor;
Stage #2: With hydrogen at 120℃; under 760.051 Torr; Flow reactor;
A 13.1%
B 70%
C 9.1%
With Ni3Sn2; hydrogen In isopropyl alcohol at 20 - 179.84℃; for 12h; Autoclave;A 5 %Chromat.
B 5 %Chromat.
C 91 %Chromat.
With hydrogen In isopropyl alcohol at 50℃; under 3750.38 Torr; Autoclave;
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

pentan-1-ol
71-41-0

pentan-1-ol

C

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 68%
B 7%
C 11%
With hydrogen; CuO0.95Co0.05/SiO2 In 1,4-dioxane at 265℃; under 18751.9 Torr;
With hydrogen; CuO(80)SiO2(20) In 1,4-dioxane at 265℃; under 19135 Torr; Product distribution / selectivity; Inert atmosphere;
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

1,4-Pentanediol
626-95-9

1,4-Pentanediol

C

(+/-)-2-pentanol
6032-29-7

(+/-)-2-pentanol

D

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

Conditions
ConditionsYield
With hydrogen In water at 150℃; for 4h; Reagent/catalyst; Autoclave;A 67%
B n/a
C 9%
D 14%
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

pentan-1-ol
71-41-0

pentan-1-ol

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 64%
B 6%
With hydrogen In 1,4-dioxane at 330℃; Product distribution / selectivity;
With hydrogen In 1,4-dioxane at 265℃; under 15001.5 Torr; Product distribution / selectivity;
With hydrogen; CuO(80)SiO2(20) In 1,4-dioxane at 290℃; under 19135 Torr; Product distribution / selectivity; Inert atmosphere;
With hydrogen; CuO(80)SiO2(20) In 1,4-dioxane at 265℃; under 15001.5 Torr; Product distribution / selectivity; Inert atmosphere;
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

(+/-)-2-pentanol
6032-29-7

(+/-)-2-pentanol

C

pentan-1-ol
71-41-0

pentan-1-ol

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 63%
B 18%
C 10%
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

(+/-)-2-pentanol
6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 60%
B 18%
Multi-step reaction with 2 steps
1: ruthenium-carbon composite; hydrogen / 1,4-dioxane / 5 h / 30003 Torr / Autoclave
2: ruthenium-carbon composite; hydrogen / isopropyl alcohol / 5 h / 30003 Torr / Autoclave
View Scheme
Multi-step reaction with 2 steps
1: hydrogen / water / 100 °C / 30003 Torr / Flow reactor; Green chemistry
2: hydrogen / water / 70 °C / 30003 Torr / Flow reactor; Green chemistry
View Scheme
levulinic acid
123-76-2

levulinic acid

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

1,4-Pentanediol
626-95-9

1,4-Pentanediol

C

(+/-)-2-pentanol
6032-29-7

(+/-)-2-pentanol

D

pentan-1-ol
71-41-0

pentan-1-ol

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 60%
B 10%
C 23%
D 6%
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;A 25%
B 27%
C 34%
D 7%
With hydrogen In water at 150℃; under 37503.8 Torr; for 4h; Autoclave;
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

C

2-methylfuran
534-22-5

2-methylfuran

Conditions
ConditionsYield
With hydrogen In methanol at 25℃; for 1h; Reagent/catalyst; Sealed tube; Green chemistry;A 8%
B 52%
C 25%
With Ni/Al2O3; hydrogen at 180℃; under 7500.75 Torr; Reagent/catalyst; Flow reactor;
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

Conditions
ConditionsYield
With hydrogen In methanol at 25℃; under 750.075 Torr; for 1h; Reagent/catalyst; Sealed tube; Green chemistry;A 25%
B 52%
With water; hydrogen at 199.84℃; under 60006 Torr; for 3h; Autoclave;
With hydrogen In ethanol at 60℃; under 2250.23 Torr; for 2h;
With hydrogen at 200℃; under 760.051 Torr; Flow reactor;A 5.3 %Chromat.
B 94.5 %Chromat.
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

rac-5-iodopentan-2-ol
90397-87-8

rac-5-iodopentan-2-ol

Conditions
ConditionsYield
With aluminium trichloride; sodium iodide In acetonitrile at 0℃; for 2h; regioselective ring opening of var. 2 subst. tetrahydrofurans;100%
With aluminium trichloride; sodium iodide In acetonitrile at 0℃; for 2h;100%
With aluminum (III) chloride; sodium iodide In acetonitrile at 0 - 20℃; for 5h; Inert atmosphere; Schlenk technique;58%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

aniline
62-53-3

aniline

(+/-)-2-methyl-1-phenylpyrrolidine
33342-99-3, 160751-58-6, 160751-59-7

(+/-)-2-methyl-1-phenylpyrrolidine

Conditions
ConditionsYield
With carbon dioxide; alumina In toluene at 237℃; under 108011 Torr; Flow reactor; Supercritical conditions;100%
Stage #1: aniline With 1,8-diazabicyclo[5.4.0]undec-7-ene; trichlorophosphate In 5,5-dimethyl-1,3-cyclohexadiene at 90℃; for 0.25h;
Stage #2: 2-methyltetrahydrofuran In 5,5-dimethyl-1,3-cyclohexadiene at 110℃; for 15h; Sealed tube;
93%
With trimethylaluminum In toluene at 20 - 110℃; for 16h;78%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

1,5,9-trimesityldipyrromethene
1114543-34-8

1,5,9-trimesityldipyrromethene

dibutylmagnesium
1191-47-5

dibutylmagnesium

C45H56MgN2O

C45H56MgN2O

Conditions
ConditionsYield
Stage #1: 1,5,9-trimesityldipyrromethene; dibutylmagnesium In toluene for 0.25h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: 2-methyltetrahydrofuran In toluene Inert atmosphere; Schlenk technique; Glovebox;
100%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

acetyl chloride
75-36-5

acetyl chloride

1-acetoxy-4-chloropentane
36978-15-1

1-acetoxy-4-chloropentane

Conditions
ConditionsYield
With [(IPr=S)BiCl3]*CHCl3 In dichloromethane at 20℃; for 2h; Reagent/catalyst; regioselective reaction;98%
K[Pt(C2H4)Cl3] In 2-methyltetrahydrofuran for 24h; Ambient temperature;70%
With zinc
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

1,4-Diiodopentane
55930-45-5

1,4-Diiodopentane

Conditions
ConditionsYield
With O-phenyl phosphorodichloridate; sodium iodide for 24h; Heating;98%
With N,N-diethyl-1,1,1-trimethylsilanamine; methyl iodide In toluene at 80 - 90℃; for 103h; Ring cleavage; iodination; diiodation; diiodination;51%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

2,2-Dimethylpropanoyl iodide
61915-52-4

2,2-Dimethylpropanoyl iodide

4-pivaloyloxy-1-iodopentane
82131-08-6

4-pivaloyloxy-1-iodopentane

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Green chemistry;98%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Phenoxyacetyl iodide
79929-43-4

Phenoxyacetyl iodide

C13H17IO3

C13H17IO3

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Green chemistry;97%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

benzoyl chloride
98-88-4

benzoyl chloride

4-chloro-1-pentyl benzoate
36978-17-3

4-chloro-1-pentyl benzoate

Conditions
ConditionsYield
With molybdenum(V) chloride In 1,2-dichloro-ethane at 50℃; for 3h;96%
With zinc(II) oxide In neat (no solvent) at 0 - 20℃; Green chemistry;94%
With iron In 1,2-dichloro-ethane at 70℃; for 8h; Time; Schlenk technique; Inert atmosphere; regioselective reaction;91%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

(S)-2-acetoxypropanoyl chloride
36394-75-9

(S)-2-acetoxypropanoyl chloride

4-chloropentyl (S)-(-)-2-acetoxypropionate

4-chloropentyl (S)-(-)-2-acetoxypropionate

Conditions
ConditionsYield
With bismuth(III) chloride In dichloromethane at 20℃;96%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

acetic anhydride
108-24-7

acetic anhydride

Conditions
ConditionsYield
With aminosulfonic acid In acetic acid at 60℃; for 4h;95%
With sulfuric acid at 20℃; for 20h;70%
With ytterbium(III) triflate Heating;47%
at 170 - 180℃;
at 240℃;
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

4-chloropentyl 4-methoxybenzoate
27749-09-3

4-chloropentyl 4-methoxybenzoate

Conditions
ConditionsYield
With zinc(II) oxide In neat (no solvent) at 0 - 20℃; for 2.5h; Green chemistry; regioselective reaction;95%
With iron In 1,2-dichloro-ethane at 70℃; Schlenk technique; Inert atmosphere; regioselective reaction;93%
With iron pentacarbonyl Heating;
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Benzoyl bromide
618-32-6

Benzoyl bromide

4-bromopentyl benzoate

4-bromopentyl benzoate

Conditions
ConditionsYield
With bismuth(III) bromide In dichloromethane at 20℃; for 4h;95%
With palladium diacetate at 100℃; for 2h; Microwave irradiation;81.9%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

2-Fluoro-benzoyl iodide
79929-48-9

2-Fluoro-benzoyl iodide

C12H14FIO2

C12H14FIO2

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Green chemistry;95%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

dimethylcarbamoyl iodide
13358-75-3

dimethylcarbamoyl iodide

C8H16INO2

C8H16INO2

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Green chemistry;95%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

ethyl iodoacetate
598-40-3

ethyl iodoacetate

Propionic acid 4-iodo-1-methyl-butyl ester
149741-97-9

Propionic acid 4-iodo-1-methyl-butyl ester

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Green chemistry;95%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Acetyl bromide
506-96-7

Acetyl bromide

A

1-acetoxy-4-bromopentane
26923-92-2

1-acetoxy-4-bromopentane

B

acetic acid-(4-bromo-1-methyl-butyl ester)
26923-93-3

acetic acid-(4-bromo-1-methyl-butyl ester)

Conditions
ConditionsYield
With zinc(II) chloride 1.) 21 deg C, 0.5 h, 2.) reflux, 2.5 h; Yields of byproduct given. Title compound not separated from byproducts;A 93%
B n/a
With zinc(II) chloride 1.) 21 deg C, 0.5 h, 2.) reflux, 2.5 h; Yield given. Title compound not separated from byproducts;A 93%
B n/a
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

2-methyl-1-(m-tolyl)pyrrolidine

2-methyl-1-(m-tolyl)pyrrolidine

Conditions
ConditionsYield
Stage #1: 1-amino-3-methylbenzene With 1,8-diazabicyclo[5.4.0]undec-7-ene; trichlorophosphate at 90℃; for 0.25h;
Stage #2: 2-methyltetrahydrofuran at 110℃; for 10h; Sealed tube;
93%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

Phenoxyacetyl chloride
701-99-5

Phenoxyacetyl chloride

4-chloropentyl phenoxyacetate

4-chloropentyl phenoxyacetate

Conditions
ConditionsYield
With bismuth(III) chloride In dichloromethane at 20℃;92%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

4-chloropentyl-4-methylbenzoate

4-chloropentyl-4-methylbenzoate

Conditions
ConditionsYield
With iron In 1,2-dichloro-ethane at 70℃; Schlenk technique; Inert atmosphere; regioselective reaction;92%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

4-fluorobenzoyl chloride
403-43-0

4-fluorobenzoyl chloride

4-chloropentyl 4-fluorobenzoate

4-chloropentyl 4-fluorobenzoate

Conditions
ConditionsYield
With zinc(II) oxide In neat (no solvent) at 0 - 20℃; for 2h; Green chemistry; regioselective reaction;92%
With iron In 1,2-dichloro-ethane at 70℃; Schlenk technique; Inert atmosphere; regioselective reaction;88%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

silver hexafluoroantimonate

silver hexafluoroantimonate

C36H52ClInN2O2

C36H52ClInN2O2

C46H72InN2O4(1+)*F6Sb(1-)

C46H72InN2O4(1+)*F6Sb(1-)

Conditions
ConditionsYield
at -30 - 20℃; for 0.333333h; Darkness;92%
2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

3,5-dimethyl-N-ethylaniline
13342-22-8

3,5-dimethyl-N-ethylaniline

1-(3,5-dimethylphenyl)-2-methylpyrrolidine

1-(3,5-dimethylphenyl)-2-methylpyrrolidine

Conditions
ConditionsYield
With titanium tetrachloride; 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane; o-xylene at 120℃; for 14h; Sealed tube;92%
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