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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

3-Chlorobromobenzene

Cas:108-37-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Bromo-3-Chlorobenzene supplier in China

Cas:108-37-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Our Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)

3-Bromochlorobenzene

Cas:108-37-2

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-bromochlorobenzene

Cas:108-37-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-Bromo-3-Chlorobenzene

Cas:108-37-2

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 108-37-2 1-bromo-3-chlorobenzene Manufacturer

Cas:108-37-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

3-Bromochlorobenzene

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day

3-Bromochlorobenzene

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Bromochlorobenzene

Cas:108-37-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3-bromochlorobenzene

Cas:108-37-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

3-BROMOCHLOROBENZENE Basic information Product Name: 3-BROMOCHLOROBENZENE Synonyms: 1-bromo-3-chloro-benzen;1-Chloro-3-bromobenzene;3-Bromo-1-chlorobenzene;3-Chlorobromobenzene;3-Chlorophenyl bromide;3-ch

3-BROMOCHLOROBENZENE 108-37-2

Cas:108-37-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

1-bromo-3-chloro-benzen

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 108-37-2 with fast shipping

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFUCHEM--High purity 108-37-2 3-BROMOCHLOROBENZENE

Cas:108-37-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product Name: 3-BROMOCHLOROBENZENE Synonyms: 3-Chlorobromobenzene 98%;3-Chlorobromobenzene;3-Chlorophenyl bromide;3-chlorophenylbromide;Benzene, 1-bromo-3-chloro-;benzene,1-bromo-3-chloro-;1-bromo-3-chl

3-Bromochlorobenzene CAS:108-37-2

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:clear colorless to light yellow liquid Storage:room temperature Package:200kg/Drum Application:1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electr

3-Chlorobromobenzene with high quallity

Cas:108-37-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-3-chloro- 108-37-2

Cas:108-37-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

3-BROMOCHLOROBENZENE CAS:108-37-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

3-BROMOCHLOROBENZENE CAS:108-37-2

Cas:108-37-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-BROMOCHLOROBENZENE

Cas:108-37-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Benzene,1-bromo-3-chloro-/ LIDE PHARMA- Factory supply / Best price

Cas:108-37-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

3-Chlorobromobenzene CAS: 108-37-2 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure C.The IR spe

Factory supply 3-Chlorobromobenzene

Cas:108-37-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-bromo-3-chloro-

Cas:108-37-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1-Bromo-3-chlorobenzene

Cas:108-37-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance: CLEAR COLOURLESS TO LIGHT YELLOW LIQUID Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Interm

Benzene,1-bromo-3-chloro-

Cas:108-37-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Bromochlorobenzene

Cas:108-37-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-bromo-3-chloro-

Cas:108-37-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Bromo-3-Chlorobenzene

Cas:108-37-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-bromochlorobenzene

Cas:108-37-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Intermediate 1-Bromo-3-chlorobenzene CAS 108-37-2

Cas:108-37-2

Min.Order:1 Liter

FOB Price: $4.5 / 5.0

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

3-BROMOCHLOROBENZENE Chemical Properties Melting point -21.5 °C Boiling point 196 °C(lit.) density 1.63 g/mL at 25 °C(lit.) refractive index n20/D 1.576(lit.) Fp 177 °F storage temp. Store below +30°C. for

3-Chlorobromobenzene

Cas:108-37-2

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

Synthetic route

3-chlorobenzenediazonium tetrafluoroborate
456-39-3

3-chlorobenzenediazonium tetrafluoroborate

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination;99%
4-bromo-2-chloroiodobenzene
31928-47-9

4-bromo-2-chloroiodobenzene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With [Ir(2-phenylpyridine)-2-(4,4’-di-tert-butyl-2,2’-bipyridine)]PF6; N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 1.5h; Irradiation;92%
(3-chlorophenyl)(mesityl)iodonium trifluoromethanesulfonate
1416277-01-4

(3-chlorophenyl)(mesityl)iodonium trifluoromethanesulfonate

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 80℃; for 2h;92%
3-bromo-benzenediazonium; tetrachloro cuprate(II)

3-bromo-benzenediazonium; tetrachloro cuprate(II)

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
In dimethyl sulfoxide Ambient temperature;90%
m-chlorophenylhydrazine hydrochloride
2312-23-4

m-chlorophenylhydrazine hydrochloride

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With boron tribromide; dimethyl sulfoxide at 80℃; for 1h;90%
C6H4ClN2(1+)*C6H4NO4S2(1-)

C6H4ClN2(1+)*C6H4NO4S2(1-)

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;75%
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;71%
3-bromobenzenediazonium o-benzenedisulfonimide

3-bromobenzenediazonium o-benzenedisulfonimide

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; Substitution;74%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 81℃; for 8h;59%
chlorobenzene
108-90-7

chlorobenzene

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With bromine trifluoride; bromine at 0 - 10℃;A 25%
B 5%
2-(3-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
635305-47-4

2-(3-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With copper(ll) bromide In methanol Heating;24%
4-Bromo-2-chloro-benzoic Acid
59748-90-2

4-Bromo-2-chloro-benzoic Acid

5-bromo-3-chloro-3',5'-dimethyl-[1,1'-biphenyl]-2-carboxylic acid
1344681-59-9

5-bromo-3-chloro-3',5'-dimethyl-[1,1'-biphenyl]-2-carboxylic acid

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

3-bromo-5-chloro-3',5'-dimethyl-1,1'-biphenyl
1344681-53-3

3-bromo-5-chloro-3',5'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With silver carbonate In dimethyl sulfoxide at 120℃; for 4h;A 18%
B 5%
bromobenzene
108-86-1

bromobenzene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With thallium chloride at 100℃; durch Chlorieren;
3-chlorobenzenediazonium
17333-84-5

3-chlorobenzenediazonium

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With tetrachloromethane at 270℃;
3-chloro-aniline
108-42-9

3-chloro-aniline

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With hydrogen bromide; acetic acid at 5 - 10℃; Einleiten von N2O3 und anschliessendes Erhitzen;
Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuBr und HBr;
Stage #1: 3-chloro-aniline With hydrogen bromide; sodium nitrite In water at 0 - 5℃;
Stage #2: With hydrogen bromide; copper(I) bromide In water
Acetanilid
103-84-4

Acetanilid

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
durch sukzessive Chlorierung, Bromierung, Verseifung und Behandlung mit Aethylnitrit;
3-bromoaniline
591-19-5

3-bromoaniline

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuCl;
1-bromo-2,3-dichlorobenzene
56961-77-4

1-bromo-2,3-dichlorobenzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

Conditions
ConditionsYield
With hexane at 25℃; for 4h; Irradiation; relative rate of dehalogenation, other polyhalobenzenes;
4-chloro-2-bromoaniline
873-38-1

4-chloro-2-bromoaniline

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With tetrafluoroboric acid; N,N-dimethyl-formamide; sodium nitrite 1) water, 0 deg C, 2 h, 2) 40 deg C, 30 min; Yield given. Multistep reaction;
1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism; Product distribution;A 11.6 % Chromat.
B 3.2 % Chromat.
1,3-dibromo-5-chlorobenzene
14862-52-3

1,3-dibromo-5-chlorobenzene

benzene
71-43-2

benzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

m-chlorobiphenyl
2051-61-8

m-chlorobiphenyl

C

3-bromo-5-chloro-1,1’-biphenyl
126866-35-1

3-bromo-5-chloro-1,1’-biphenyl

D

5′-chloro-1,1′:3′,1″-terphenyl

5′-chloro-1,1′:3′,1″-terphenyl

Conditions
ConditionsYield
at 25℃; for 20h;A 1.0 % Chromat.
B 30.3 % Chromat.
C 25.2 % Chromat.
D 36.1 % Chromat.
1,4-dibromo-2-chlorobenzene
3460-24-0

1,4-dibromo-2-chlorobenzene

benzene
71-43-2

benzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

C

4-bromo-3-chloro-1,1'-biphenyl
91354-08-4

4-bromo-3-chloro-1,1'-biphenyl

D

2-chloro-4-bromobiphenyl
58775-86-3

2-chloro-4-bromobiphenyl

Conditions
ConditionsYield
at 25℃; for 20h;A 2.7 % Chromat.
B 8.2 % Chromat.
C 4.3 % Chromat.
D 17.1 % Chromat.
3-chloro-benzenecarboperoxoic acid
937-14-4

3-chloro-benzenecarboperoxoic acid

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With Bromotrichloromethane; cyclohexane In 1,2-dichloro-ethane at 65℃; for 24h; Product distribution; Mechanism;
bromine
7726-95-6

bromine

chlorobenzene
108-90-7

chlorobenzene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
at 475℃;
3-chloro-phenyl-mercury acetate

3-chloro-phenyl-mercury acetate

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With bromine; acetic acid
diazotized m-chloro-aniline

diazotized m-chloro-aniline

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With hydrogen bromide Behandlung mit CuBr;
m-bromo-benzenediazonium chloroplatinate

m-bromo-benzenediazonium chloroplatinate

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With sodium carbonate
silver-<3-chloro benzoate>

silver-<3-chloro benzoate>

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With tetrachloromethane; bromine
chlorobenzene
108-90-7

chlorobenzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

2-chloro-1-bromo-benzene; 4-chloro-1-bromo-benzene

2-chloro-1-bromo-benzene; 4-chloro-1-bromo-benzene

Conditions
ConditionsYield
With bromine at 475℃;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

carbon dioxide
124-38-9

carbon dioxide

2-bromo-6-chlorobenzoic acid
93224-85-2

2-bromo-6-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: carbon dioxide In tetrahydrofuran at -78 - 20℃; for 2h;
100%
With 2,2,6,6-tetramethyl-piperidine; n-butyllithium In tetrahydrofuran; hexane at -75℃; for 2h;94%
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexanes at -78℃; for 2h;
Stage #2: carbon dioxide In tetrahydrofuran; hexanes for 0.25h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexanes; water Product distribution / selectivity;
85%
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 1.5h;
Stage #2: carbon dioxide In tetrahydrofuran; hexane at -78℃; for 0.333333h;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; hexane
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -75℃; for 4h; Inert atmosphere;
Stage #2: carbon dioxide In tetrahydrofuran at -70 - 20℃; for 5.5h; Inert atmosphere;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

3-chloro-trans-cinnamic acid n-butyl ester
131061-13-7

3-chloro-trans-cinnamic acid n-butyl ester

Conditions
ConditionsYield
With potassium carbonate; bis(dibenzylideneacetone)-palladium(0); 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride In N,N-dimethyl acetamide at 120℃; for 5h; Heck reaction;100%
With tetrabutylammonium acetate; palladium diacetate at 100℃; for 0.5h; Heck reaction; Air atmosphere; Ionic liquid; chemoselective reaction;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

1-t-Butoxycarbonylpiperazine
57260-71-6

1-t-Butoxycarbonylpiperazine

tert-butyl 4-(3-chlorophenyl)piperazine-1-carboxylate
186790-11-4

tert-butyl 4-(3-chlorophenyl)piperazine-1-carboxylate

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene; 1-t-Butoxycarbonylpiperazine With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In xylene at 50℃;
Stage #2: With macroporous polymer-supported isocyanate In xylene at 50℃; for 24h;
100%
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃;83%
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; XPhos In 1,4-dioxane at 95℃; for 2h; Inert atmosphere;61.2%
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; DavePhos
With tris-(dibenzylideneacetone)dipalladium(0); potassium tert-butylate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 16h; Inert atmosphere; Heating;1.5 g
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

3-monochlorophenol
108-43-0

3-monochlorophenol

Conditions
ConditionsYield
With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); tert-butyl XPhos In 1,4-dioxane; water at 100℃; for 1h;99%
Multi-step reaction with 2 steps
1: copper dichloride; potassium carbonate / 20 h / 130 °C / Inert atmosphere; Schlenk technique
2: potassium hydroxide / dimethyl sulfoxide / 3 h / 100 °C / Schlenk technique
View Scheme
Multi-step reaction with 2 steps
1: fac-tris(2-phenylpyridinato-N,C2')iridium(III); tributyl-amine; water / acetonitrile / 36 h / 25 °C / Schlenk technique; Inert atmosphere; Sealed tube; Irradiation
2: air / 16 h / 25 °C / Inert atmosphere
View Scheme
With copper(l) iodide; C20H20N4O4; caesium carbonate; Benzaldoxime In dimethyl sulfoxide at 80℃; for 18h; Inert atmosphere; Glovebox;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Methyl formate
107-31-3

Methyl formate

1-chloro-3-methoxy-benzene
2845-89-8

1-chloro-3-methoxy-benzene

Conditions
ConditionsYield
With copper(I) bromide In methanol; sodium methylate99%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

3-chlorobenzoic acid tert-butyl ester
16537-17-0

3-chlorobenzoic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -10℃;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -10℃;
Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.;
99%
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -10℃; for 1h; Inert atmosphere;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -10℃; for 2h; Inert atmosphere;
99%
Stage #1: 1-bromo-3-chlorobenzene With n-hexyllithium In 2-methyltetrahydrofuran; hexane at 0℃; for 0.000194444h; Flow reactor;
Stage #2: di-tert-butyl dicarbonate In 2-methyltetrahydrofuran; hexane at 0℃; for 0.00475h; Flow reactor;
50%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

carbon monoxide
201230-82-2

carbon monoxide

aniline
62-53-3

aniline

3-chloro-N-phenylbenzamide
6832-92-4

3-chloro-N-phenylbenzamide

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 80℃; under 760.051 Torr; for 15h;99%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

C17H16N4O
1358787-39-9

C17H16N4O

C23H19ClN4O
1358787-91-3

C23H19ClN4O

Conditions
ConditionsYield
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃;99%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

carbon monoxide
201230-82-2

carbon monoxide

benzylamine
100-46-9

benzylamine

N-benzyl-(3-chloro)benzamide
82082-49-3

N-benzyl-(3-chloro)benzamide

Conditions
ConditionsYield
With triethylamine In toluene at 70℃; under 760.051 Torr; for 7h; Catalytic behavior;99%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

9H-carbazole
86-74-8

9H-carbazole

9-(3-chlorophenyl)-9H-carbazole
19222-81-2

9-(3-chlorophenyl)-9H-carbazole

Conditions
ConditionsYield
Stage #1: 9H-carbazole With methylmagnesium chloride In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 5 - 20℃; for 0.166667h; Inert atmosphere;
Stage #2: 1-bromo-3-chlorobenzene With PdCl(π-allyl)(cyclohexyl-(1-methyl-2,2-diphenylcyclopropylphophine)) In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 108 - 112℃; for 2h; Inert atmosphere;
99%
Stage #1: 9H-carbazole With methylmagnesium chloride In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 5 - 20℃; for 0.333333h; Inert atmosphere;
Stage #2: 1-bromo-3-chlorobenzene With di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 110℃; for 1h;
98.5%
With bis(di-tert-butyl(2-butenyl)phosphine)dichloropalladium; sodium t-butanolate In o-xylene at 135℃; for 9h; Reagent/catalyst; Inert atmosphere;95%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

A

chlorobenzene
108-90-7

chlorobenzene

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction;A 98%
B n/a
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

phenylboronic acid
98-80-6

phenylboronic acid

m-chlorobiphenyl
2051-61-8

m-chlorobiphenyl

Conditions
ConditionsYield
With 3,5-di-tert-butyl-2-hydroxybenzaldehyde; potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 2h; Suzuki-Miyaura Coupling;98%
With (BeDABCO)2Pd2Cl6; potassium carbonate In ethanol at 20℃; for 0.0166667h; Suzuki-Miyaura Coupling;97%
With potassium phosphate; tetraphosphine N,N,N′,N′-tetra(diphenylphosphinomethyl)-pyridine-2,6-diamine; palladium dichloride In o-xylene at 90℃; for 2h; Concentration; Time; Temperature; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;97%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

methylamine
74-89-5

methylamine

3-chloro-N-methylaniline
7006-52-2

3-chloro-N-methylaniline

Conditions
ConditionsYield
With copper In water at 100℃; for 12h; Ullmann reaction;98%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

tributylphenylstannane
960-16-7

tributylphenylstannane

m-chlorobiphenyl
2051-61-8

m-chlorobiphenyl

Conditions
ConditionsYield
With 2C13H19N2(1+)*Cl6Pd2(2+); cesium fluoride In N,N-dimethyl-formamide at 120℃; for 0.0166667h; Stille Cross Coupling; Microwave irradiation;98%
With [Pd{C6H2-(CH2CH2NH2)-(OMe)2-3,4}Br(PPh3)]; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 0.0333333h; Stille coupling; Microwave irradiation; chemoselective reaction;92%
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 0.0666667h; Stille coupling; Microwave irradiation; chemoselective reaction;90%
With dmap; palladium dichloride for 0.333333h; Stille Cross Coupling; Microwave irradiation;61%
1H-imidazole
288-32-4

1H-imidazole

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

1-(3-chlorophenyl)-1H-imidazole
51581-52-3

1-(3-chlorophenyl)-1H-imidazole

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 48h; Inert atmosphere;98%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

3-(3-bromo-5-chlorophenyl)-1,1,1,3,5,5,5-heptamethyltrisiloxane

3-(3-bromo-5-chlorophenyl)-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 2.9-dimethyl-1,10-phenanthroline In 1,4-dioxane at 100℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube; regioselective reaction;98%
styrene
292638-84-7

styrene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

benzonitrile
100-47-0

benzonitrile

6-chloro-2,4-diphenylquinoline
21923-40-0

6-chloro-2,4-diphenylquinoline

Conditions
ConditionsYield
With N-n-butyl-N-methylpiperidine bis(trifluoromethanesulfonyl)imide salt; acetylferrocene; H2SiEt2 at 60℃; for 8h; Reagent/catalyst;97.9%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

1-(3-chlorophenyl)-2,2,2-trifluoroethanone
321-31-3

1-(3-chlorophenyl)-2,2,2-trifluoroethanone

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran at -78 - -50℃; for 1h;
Stage #2: ethyl trifluoroacetate, In tetrahydrofuran at -78 - 20℃; Reagent/catalyst; Solvent; Temperature;
97.3%
Stage #1: 1-bromo-3-chlorobenzene With magnesium In diethyl ether Inert atmosphere;
Stage #2: ethyl trifluoroacetate, In diethyl ether at -78 - -50℃; for 3.5h; Inert atmosphere;
methanol
67-56-1

methanol

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

carbon monoxide
201230-82-2

carbon monoxide

methyl 3-chlorobenzoate
2905-65-9

methyl 3-chlorobenzoate

Conditions
ConditionsYield
With benzophenone; sodium methylate; cobalt(II) acetate at 40℃; under 750.075 Torr; for 15h; Irradiation;97%
With sodium methylate; C2H5OOCCH2Co(CO)4 In diethyl ether at 25 - 35℃;78%
styrene
292638-84-7

styrene

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

(E)-3-chlorostilbene
14064-43-8

(E)-3-chlorostilbene

Conditions
ConditionsYield
With potassium carbonate In methanol; water at 45℃; for 6h; Catalytic behavior; Heck Reaction; Green chemistry; stereoselective reaction;97%
With CF3O3S(1-)*C52H46NO2P2Pd(1+); potassium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; for 0.1h; Heck cross-coupling reaction; In air; Microwave irradiation; chemoselective reaction;96%
With triethylamine In N,N-dimethyl-formamide for 0.233333h; Sonication;95%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

sodium n-propoxide
6819-41-6

sodium n-propoxide

1-chloro-3-propoxybenzene
51241-31-7

1-chloro-3-propoxybenzene

Conditions
ConditionsYield
With propyl methanoate; lithium chloride; copper(I) bromide In propan-1-ol at 110℃; for 4h; Sealed tube;97%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Trimethyl borate
121-43-7

Trimethyl borate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
97%
Stage #1: 1-bromo-3-chlorobenzene With isopropylmagnesium chloride; lithium chloride; 3-butyl-1-methylimidazolium acetate In tetrahydrofuran at 5 - 10℃; for 3h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at 0℃; for 4h; Inert atmosphere;
Stage #3: With hydrogenchloride In water at 5℃; for 0.5h; Inert atmosphere;
66.43 g
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

4,6-diphenyl-2-[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,1': 2',1"-terphenyl-3-yl]-1,3,5-triazine

4,6-diphenyl-2-[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,1': 2',1"-terphenyl-3-yl]-1,3,5-triazine

2-[3-chloro-1,1': 5',1": 2",1""-quaterphenyl-3"-yl]-4,6-diphenyl-1,3,5-triazine

2-[3-chloro-1,1': 5',1": 2",1""-quaterphenyl-3"-yl]-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water for 20h; Inert atmosphere; Reflux;97%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

PCB 11
2050-67-1

PCB 11

Conditions
ConditionsYield
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; for 5h; Microwave irradiation; chemoselective reaction;96%
With [Pd{C6H2(CH2CH2NH2)-(OMe)2-2,3}(μ-Br)]2; potassium carbonate In 1-methyl-pyrrolidin-2-one at 120℃; for 0.0666667h; Microwave irradiation;96%
With [Pd(C6H4CH2NH2-κ2-CN)PPh3MOBPPY]OTf; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 0.0333333h; Microwave irradiation; chemoselective reaction;92%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Pentafluorobenzene
363-72-4

Pentafluorobenzene

3'-chloro-2,3,4,5,6-pentafluoro-1,1'-biphenyl
786-55-0

3'-chloro-2,3,4,5,6-pentafluoro-1,1'-biphenyl

Conditions
ConditionsYield
With di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; potassium carbonate; palladium diacetate In N,N-dimethyl acetamide at 120℃;96%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

2-methyl-4-(3-chlorophenyl)-3-butyn-2-ol

2-methyl-4-(3-chlorophenyl)-3-butyn-2-ol

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; Tri(p-tolyl)phosphine In tetrahydrofuran at 80℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;96%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide at 90℃; for 72h; Sonogashira Coupling;94%
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