Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryOur Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)
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inquiryhigh quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryCangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi
DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
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inquiry3-BROMOCHLOROBENZENE Basic information Product Name: 3-BROMOCHLOROBENZENE Synonyms: 1-bromo-3-chloro-benzen;1-Chloro-3-bromobenzene;3-Bromo-1-chlorobenzene;3-Chlorobromobenzene;3-Chlorophenyl bromide;3-ch
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inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryProduct Name: 3-BROMOCHLOROBENZENE Synonyms: 3-Chlorobromobenzene 98%;3-Chlorobromobenzene;3-Chlorophenyl bromide;3-chlorophenylbromide;Benzene, 1-bromo-3-chloro-;benzene,1-bromo-3-chloro-;1-bromo-3-chl
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inquiryAppearance:clear colorless to light yellow liquid Storage:room temperature Package:200kg/Drum Application:1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electr
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inquiry3-BROMOCHLOROBENZENE CAS:108-37-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiry3-Chlorobromobenzene CAS: 108-37-2 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure C.The IR spe
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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superior quality Appearance: CLEAR COLOURLESS TO LIGHT YELLOW LIQUID Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Interm
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:108-37-2
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inquiry3-BROMOCHLOROBENZENE Chemical Properties Melting point -21.5 °C Boiling point 196 °C(lit.) density 1.63 g/mL at 25 °C(lit.) refractive index n20/D 1.576(lit.) Fp 177 °F storage temp. Store below +30°C. for
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inquiryConditions | Yield |
---|---|
With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination; | 99% |
4-bromo-2-chloroiodobenzene
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With [Ir(2-phenylpyridine)-2-(4,4’-di-tert-butyl-2,2’-bipyridine)]PF6; N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 1.5h; Irradiation; | 92% |
(3-chlorophenyl)(mesityl)iodonium trifluoromethanesulfonate
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With copper(I) bromide In acetonitrile at 80℃; for 2h; | 92% |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
In dimethyl sulfoxide Ambient temperature; | 90% |
Conditions | Yield |
---|---|
With boron tribromide; dimethyl sulfoxide at 80℃; for 1h; | 90% |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution; | 75% |
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 71% |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; Substitution; | 74% |
3-chlorophenylboronic acid
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In acetonitrile at 81℃; for 8h; | 59% |
Conditions | Yield |
---|---|
With bromine trifluoride; bromine at 0 - 10℃; | A 25% B 5% |
2-(3-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With copper(ll) bromide In methanol Heating; | 24% |
4-Bromo-2-chloro-benzoic Acid
5-bromo-3-chloro-3',5'-dimethyl-[1,1'-biphenyl]-2-carboxylic acid
A
1-bromo-3-chlorobenzene
B
3-bromo-5-chloro-3',5'-dimethyl-1,1'-biphenyl
Conditions | Yield |
---|---|
With silver carbonate In dimethyl sulfoxide at 120℃; for 4h; | A 18% B 5% |
Conditions | Yield |
---|---|
With thallium chloride at 100℃; durch Chlorieren; |
3-chlorobenzenediazonium
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With tetrachloromethane at 270℃; |
Conditions | Yield |
---|---|
With hydrogen bromide; acetic acid at 5 - 10℃; Einleiten von N2O3 und anschliessendes Erhitzen; | |
Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuBr und HBr; | |
Stage #1: 3-chloro-aniline With hydrogen bromide; sodium nitrite In water at 0 - 5℃; Stage #2: With hydrogen bromide; copper(I) bromide In water |
Conditions | Yield |
---|---|
durch sukzessive Chlorierung, Bromierung, Verseifung und Behandlung mit Aethylnitrit; |
Conditions | Yield |
---|---|
Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuCl; |
1-bromo-2,3-dichlorobenzene
A
1-bromo-3-chlorobenzene
B
1,2-dichloro-benzene
Conditions | Yield |
---|---|
With hexane at 25℃; for 4h; Irradiation; relative rate of dehalogenation, other polyhalobenzenes; |
Conditions | Yield |
---|---|
With tetrafluoroboric acid; N,N-dimethyl-formamide; sodium nitrite 1) water, 0 deg C, 2 h, 2) 40 deg C, 30 min; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism; Product distribution; | A 11.6 % Chromat. B 3.2 % Chromat. |
1,3-dibromo-5-chlorobenzene
benzene
A
1-bromo-3-chlorobenzene
B
m-chlorobiphenyl
C
3-bromo-5-chloro-1,1’-biphenyl
Conditions | Yield |
---|---|
at 25℃; for 20h; | A 1.0 % Chromat. B 30.3 % Chromat. C 25.2 % Chromat. D 36.1 % Chromat. |
1,4-dibromo-2-chlorobenzene
benzene
A
1-bromo-3-chlorobenzene
B
4-bromo-1,1'-biphenyl
C
4-bromo-3-chloro-1,1'-biphenyl
D
2-chloro-4-bromobiphenyl
Conditions | Yield |
---|---|
at 25℃; for 20h; | A 2.7 % Chromat. B 8.2 % Chromat. C 4.3 % Chromat. D 17.1 % Chromat. |
Conditions | Yield |
---|---|
With Bromotrichloromethane; cyclohexane In 1,2-dichloro-ethane at 65℃; for 24h; Product distribution; Mechanism; |
Conditions | Yield |
---|---|
at 475℃; |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With bromine; acetic acid |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With hydrogen bromide Behandlung mit CuBr; |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With sodium carbonate |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With tetrachloromethane; bromine |
Conditions | Yield |
---|---|
With bromine at 475℃; |
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3-chlorobenzene With lithium diisopropyl amide In tetrahydrofuran at -78℃; Stage #2: carbon dioxide In tetrahydrofuran at -78 - 20℃; for 2h; | 100% |
With 2,2,6,6-tetramethyl-piperidine; n-butyllithium In tetrahydrofuran; hexane at -75℃; for 2h; | 94% |
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexanes at -78℃; for 2h; Stage #2: carbon dioxide In tetrahydrofuran; hexanes for 0.25h; Stage #3: With hydrogenchloride In tetrahydrofuran; hexanes; water Product distribution / selectivity; | 85% |
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 1.5h; Stage #2: carbon dioxide In tetrahydrofuran; hexane at -78℃; for 0.333333h; Stage #3: With hydrogenchloride; water In tetrahydrofuran; hexane | |
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -75℃; for 4h; Inert atmosphere; Stage #2: carbon dioxide In tetrahydrofuran at -70 - 20℃; for 5.5h; Inert atmosphere; |
1-bromo-3-chlorobenzene
acrylic acid n-butyl ester
3-chloro-trans-cinnamic acid n-butyl ester
Conditions | Yield |
---|---|
With potassium carbonate; bis(dibenzylideneacetone)-palladium(0); 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride In N,N-dimethyl acetamide at 120℃; for 5h; Heck reaction; | 100% |
With tetrabutylammonium acetate; palladium diacetate at 100℃; for 0.5h; Heck reaction; Air atmosphere; Ionic liquid; chemoselective reaction; |
1-bromo-3-chlorobenzene
1-t-Butoxycarbonylpiperazine
tert-butyl 4-(3-chlorophenyl)piperazine-1-carboxylate
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3-chlorobenzene; 1-t-Butoxycarbonylpiperazine With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In xylene at 50℃; Stage #2: With macroporous polymer-supported isocyanate In xylene at 50℃; for 24h; | 100% |
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; | 83% |
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; XPhos In 1,4-dioxane at 95℃; for 2h; Inert atmosphere; | 61.2% |
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; DavePhos | |
With tris-(dibenzylideneacetone)dipalladium(0); potassium tert-butylate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 16h; Inert atmosphere; Heating; | 1.5 g |
Conditions | Yield |
---|---|
With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); tert-butyl XPhos In 1,4-dioxane; water at 100℃; for 1h; | 99% |
Multi-step reaction with 2 steps 1: copper dichloride; potassium carbonate / 20 h / 130 °C / Inert atmosphere; Schlenk technique 2: potassium hydroxide / dimethyl sulfoxide / 3 h / 100 °C / Schlenk technique View Scheme | |
Multi-step reaction with 2 steps 1: fac-tris(2-phenylpyridinato-N,C2')iridium(III); tributyl-amine; water / acetonitrile / 36 h / 25 °C / Schlenk technique; Inert atmosphere; Sealed tube; Irradiation 2: air / 16 h / 25 °C / Inert atmosphere View Scheme | |
With copper(l) iodide; C20H20N4O4; caesium carbonate; Benzaldoxime In dimethyl sulfoxide at 80℃; for 18h; Inert atmosphere; Glovebox; |
Conditions | Yield |
---|---|
With copper(I) bromide In methanol; sodium methylate | 99% |
1-bromo-3-chlorobenzene
di-tert-butyl dicarbonate
3-chlorobenzoic acid tert-butyl ester
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -10℃; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -10℃; Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.; | 99% |
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -10℃; for 1h; Inert atmosphere; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -10℃; for 2h; Inert atmosphere; | 99% |
Stage #1: 1-bromo-3-chlorobenzene With n-hexyllithium In 2-methyltetrahydrofuran; hexane at 0℃; for 0.000194444h; Flow reactor; Stage #2: di-tert-butyl dicarbonate In 2-methyltetrahydrofuran; hexane at 0℃; for 0.00475h; Flow reactor; | 50% |
1-bromo-3-chlorobenzene
carbon monoxide
aniline
3-chloro-N-phenylbenzamide
Conditions | Yield |
---|---|
With palladium diacetate; sodium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 80℃; under 760.051 Torr; for 15h; | 99% |
Conditions | Yield |
---|---|
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; | 99% |
1-bromo-3-chlorobenzene
carbon monoxide
benzylamine
N-benzyl-(3-chloro)benzamide
Conditions | Yield |
---|---|
With triethylamine In toluene at 70℃; under 760.051 Torr; for 7h; Catalytic behavior; | 99% |
Conditions | Yield |
---|---|
Stage #1: 9H-carbazole With methylmagnesium chloride In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 5 - 20℃; for 0.166667h; Inert atmosphere; Stage #2: 1-bromo-3-chlorobenzene With PdCl(π-allyl)(cyclohexyl-(1-methyl-2,2-diphenylcyclopropylphophine)) In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 108 - 112℃; for 2h; Inert atmosphere; | 99% |
Stage #1: 9H-carbazole With methylmagnesium chloride In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 5 - 20℃; for 0.333333h; Inert atmosphere; Stage #2: 1-bromo-3-chlorobenzene With di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene at 110℃; for 1h; | 98.5% |
With bis(di-tert-butyl(2-butenyl)phosphine)dichloropalladium; sodium t-butanolate In o-xylene at 135℃; for 9h; Reagent/catalyst; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction; | A 98% B n/a |
Conditions | Yield |
---|---|
With 3,5-di-tert-butyl-2-hydroxybenzaldehyde; potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 2h; Suzuki-Miyaura Coupling; | 98% |
With (BeDABCO)2Pd2Cl6; potassium carbonate In ethanol at 20℃; for 0.0166667h; Suzuki-Miyaura Coupling; | 97% |
With potassium phosphate; tetraphosphine N,N,N′,N′-tetra(diphenylphosphinomethyl)-pyridine-2,6-diamine; palladium dichloride In o-xylene at 90℃; for 2h; Concentration; Time; Temperature; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 97% |
Conditions | Yield |
---|---|
With copper In water at 100℃; for 12h; Ullmann reaction; | 98% |
Conditions | Yield |
---|---|
With 2C13H19N2(1+)*Cl6Pd2(2+); cesium fluoride In N,N-dimethyl-formamide at 120℃; for 0.0166667h; Stille Cross Coupling; Microwave irradiation; | 98% |
With [Pd{C6H2-(CH2CH2NH2)-(OMe)2-3,4}Br(PPh3)]; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 0.0333333h; Stille coupling; Microwave irradiation; chemoselective reaction; | 92% |
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 0.0666667h; Stille coupling; Microwave irradiation; chemoselective reaction; | 90% |
With dmap; palladium dichloride for 0.333333h; Stille Cross Coupling; Microwave irradiation; | 61% |
Conditions | Yield |
---|---|
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 48h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 2.9-dimethyl-1,10-phenanthroline In 1,4-dioxane at 100℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube; regioselective reaction; | 98% |
styrene
1-bromo-3-chlorobenzene
benzonitrile
6-chloro-2,4-diphenylquinoline
Conditions | Yield |
---|---|
With N-n-butyl-N-methylpiperidine bis(trifluoromethanesulfonyl)imide salt; acetylferrocene; H2SiEt2 at 60℃; for 8h; Reagent/catalyst; | 97.9% |
1-bromo-3-chlorobenzene
ethyl trifluoroacetate,
1-(3-chlorophenyl)-2,2,2-trifluoroethanone
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran at -78 - -50℃; for 1h; Stage #2: ethyl trifluoroacetate, In tetrahydrofuran at -78 - 20℃; Reagent/catalyst; Solvent; Temperature; | 97.3% |
Stage #1: 1-bromo-3-chlorobenzene With magnesium In diethyl ether Inert atmosphere; Stage #2: ethyl trifluoroacetate, In diethyl ether at -78 - -50℃; for 3.5h; Inert atmosphere; |
methanol
1-bromo-3-chlorobenzene
carbon monoxide
methyl 3-chlorobenzoate
Conditions | Yield |
---|---|
With benzophenone; sodium methylate; cobalt(II) acetate at 40℃; under 750.075 Torr; for 15h; Irradiation; | 97% |
With sodium methylate; C2H5OOCCH2Co(CO)4 In diethyl ether at 25 - 35℃; | 78% |
Conditions | Yield |
---|---|
With potassium carbonate In methanol; water at 45℃; for 6h; Catalytic behavior; Heck Reaction; Green chemistry; stereoselective reaction; | 97% |
With CF3O3S(1-)*C52H46NO2P2Pd(1+); potassium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; for 0.1h; Heck cross-coupling reaction; In air; Microwave irradiation; chemoselective reaction; | 96% |
With triethylamine In N,N-dimethyl-formamide for 0.233333h; Sonication; | 95% |
Conditions | Yield |
---|---|
With propyl methanoate; lithium chloride; copper(I) bromide In propan-1-ol at 110℃; for 4h; Sealed tube; | 97% |
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor; Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor; | 97% |
Stage #1: 1-bromo-3-chlorobenzene With isopropylmagnesium chloride; lithium chloride; 3-butyl-1-methylimidazolium acetate In tetrahydrofuran at 5 - 10℃; for 3h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran at 0℃; for 4h; Inert atmosphere; Stage #3: With hydrogenchloride In water at 5℃; for 0.5h; Inert atmosphere; | 66.43 g |
1-bromo-3-chlorobenzene
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water for 20h; Inert atmosphere; Reflux; | 97% |
Conditions | Yield |
---|---|
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; for 5h; Microwave irradiation; chemoselective reaction; | 96% |
With [Pd{C6H2(CH2CH2NH2)-(OMe)2-2,3}(μ-Br)]2; potassium carbonate In 1-methyl-pyrrolidin-2-one at 120℃; for 0.0666667h; Microwave irradiation; | 96% |
With [Pd(C6H4CH2NH2-κ2-CN)PPh3MOBPPY]OTf; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 0.0333333h; Microwave irradiation; chemoselective reaction; | 92% |
1-bromo-3-chlorobenzene
Pentafluorobenzene
3'-chloro-2,3,4,5,6-pentafluoro-1,1'-biphenyl
Conditions | Yield |
---|---|
With di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; potassium carbonate; palladium diacetate In N,N-dimethyl acetamide at 120℃; | 96% |
Conditions | Yield |
---|---|
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; Tri(p-tolyl)phosphine In tetrahydrofuran at 80℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique; | 96% |
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide at 90℃; for 72h; Sonogashira Coupling; | 94% |
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