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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Chlorophenylboronic Acid supplier in China

Cas:63503-60-6

Min.Order:1 Metric Ton

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

High purity Various Specifications 3-Chlorophenylboronic acid CAS:63503-60-6

Cas:63503-60-6

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product website: http://www.finerchem.com/pro01en/id/826.html Product Name 3-Chlorophenylboronic acid CAS No. 63503-60-6 Appearance

3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:1 Gram

FOB Price: $45.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

3-Chlorophenylboronic acid CAS NO.63503-60-6

Cas:63503-60-6

Min.Order:100 Gram

FOB Price: $2.0

Type:Manufacturers

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

We can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need CMO

3-Chlorophenylboronic acid manufacturer/supplier

Cas:63503-60-6

Min.Order:1 Gram

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Hangzhou Think Chemical Co. Ltd

3-Chlorophenylboronic acid CAS No.:63503-60-6 Name: 3-Chlorophenylboronic acid Molecular Structure Molecular Formula: C6H6BClO2

High purity 3-Chlorophenylboronic acid CAS No.:63503-60-6

Cas:63503-60-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

High purity 3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:100 Gram

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Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 63503-60-6 3-Chlorophenylboronic acid Manufacturer

Cas:63503-60-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Chlorobenzeneboronic acid

Cas:63503-60-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

3-Chlorophenylboronic acid Basic information Product Name: 3-Chlorophenylboronic acid Synonyms: RARECHEM AH PB 0179;M-CHLOROPHENYLBORONIC ACID;AKOS BRN-0010;3-CHLOROPHENYLBORNIC ACID;3-C

63503-60-6 3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Boronicacid, B-(3-chlorophenyl)- CAS 63503-60-6

Cas:63503-60-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 63503-60-6 with best quality

Cas:63503-60-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 3-Chlorophenylboronic acid Synonyms: 3-Chloro benzene boronic acid CAS:63503-60-6 MF: C6H6BClO2 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Syntheses Material Intermediat

3-Chlorophenylboronic acid CAS:63503-60-6

Cas:63503-60-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

High quality 3-chlorophenylboronic acid cas 63503-60-6

Cas:63503-60-6

Min.Order:100 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronicacid, B-(3-chlorophenyl)- 63503-60-6

Cas:63503-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:white powder/ Refer to COA Storage:Refer to COA

3-Chlorophenylboronic acid 63503-60-6 cas door to door

Cas:63503-60-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

3-Chlorophenylboronic acid CAS: 63503-60-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organ

3-Chlorophenylboronic acid CAS: 63503-60-6

Cas:63503-60-6

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronicacid, B-(3-chlorophenyl)-

Cas:63503-60-6

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Boronicacid, B-(3-chlorophenyl)-/ LIDE PHARMA- Factory supply / Best price

Cas:63503-60-6

Min.Order:0

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:63503-60-6

Cas:63503-60-6

Min.Order:0

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Chlorophenylboronicacid

Cas:63503-60-6

Min.Order:0

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:10 Kilogram

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Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Chlorophenylboronic acid

Cas:63503-60-6

Min.Order:0 Metric Ton

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Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Boronicacid, B-(3-chlorophenyl)-

Cas:63503-60-6

Min.Order:0

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Chlorophenylboronic acid(63503-60-6)

Cas:63503-60-6

Min.Order:100 Gram

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Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-Chlorophenylboronic Acid

Cas:63503-60-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3-Chlorobenzeneboronic acid 98%

Cas:63503-60-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 3-Chlorophenylboronic acid Synonyms: B-(3-chlorophenyl)-boronic acid;3-Chlorobenzeneboronic acid 98%;3-Chlorophenylboronic;3-Chlorophenylboornic acid;RARECHEM AH PB 0179;3-CHLOROPHENYLBORNIC ACID;3-CHLOROPHENYLBORONIC ACID;3-CHLOR

3-Chlorophenylboronic acid 63503-60-6 C6H6BClO2

Cas:63503-60-6

Min.Order:1 Gram

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Type:Lab/Research institutions

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Synthetic route

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Trimethyl borate
121-43-7

Trimethyl borate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
97%
Stage #1: 1-bromo-3-chlorobenzene With isopropylmagnesium chloride; lithium chloride; 3-butyl-1-methylimidazolium acetate In tetrahydrofuran at 5 - 10℃; for 3h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at 0℃; for 4h; Inert atmosphere;
Stage #3: With hydrogenchloride In water at 5℃; for 0.5h; Inert atmosphere;
66.43 g
borane
13283-31-3

borane

(3-chlorophenyl)magnesium bromide
36229-42-2

(3-chlorophenyl)magnesium bromide

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran slow addn. of 10 mmol of the Grignard reagent to a stirred soln. of borane in THF (40 mmol); the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;82%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran; hexane Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane Inert atmosphere;
57%
With Trimethyl borate
With Trimethyl borate
C8H10BClO2

C8H10BClO2

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
With sulfuric acid In ethanol; toluene at 0 - 40℃; Solvent; Reagent/catalyst;57%
With water at 98℃; for 2h;14.37 g
(3-chlorophenyl)magnesium bromide
36229-42-2

(3-chlorophenyl)magnesium bromide

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
With boron trifluoride
3-iodochlorobenzene
625-99-0

3-iodochlorobenzene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
(i) (UV-irradiation), BBr3, (ii) aq. NaOH; Multistep reaction;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

borane
13283-31-3

borane

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
With water; magnesium In tetrahydrofuran a 2.0 M soln. of borane (40 mmol) in THF was added to flame dried Mg turnings (12 mmol) at 0°C; slow addn. of the aryl bromide (10 mmol)in THF; stirring at room temp. for 12-16 h; the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Trimethyl borate
121-43-7

Trimethyl borate

A

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

B

(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -78 - -70℃; for 0.5h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at -70℃; for 4h;
Stage #3: With hydrogenchloride In water Overall yield = 24.6 g;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Triisopropyl borate
5419-55-6

Triisopropyl borate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With iodine; magnesium In tetrahydrofuran for 5h; Inert atmosphere; Reflux;
Stage #2: Triisopropyl borate In tetrahydrofuran at -40 - 0℃; Inert atmosphere;
Stage #3: With water at 98℃; for 2h; Inert atmosphere;
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

boric acid tributyl ester
688-74-4

boric acid tributyl ester

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With iodine; magnesium In tetrahydrofuran for 5h; Inert atmosphere; Reflux;
Stage #2: boric acid tributyl ester In tetrahydrofuran at -40 - 0℃; Inert atmosphere;
Stage #3: With water at 98℃; for 2h; Inert atmosphere;
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

ethylene glycol
107-21-1

ethylene glycol

3-chlorophenylboronic acid ethylene glycol ester
402488-97-5

3-chlorophenylboronic acid ethylene glycol ester

Conditions
ConditionsYield
In tetrahydrofuran for 18h; Heating / reflux;100%
In tetrahydrofuran for 18h; Heating / reflux;100%
In toluene for 3h; Heating;
In tetrahydrofuran for 18h; Heating;
In tetrahydrofuran at 20℃; for 8h;
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

7-tert-butoxycarbonyl-2-exo-(3'-bromo-5'-pyridinyl)-7-azabicyclo[2.2.1]heptane

7-tert-butoxycarbonyl-2-exo-(3'-bromo-5'-pyridinyl)-7-azabicyclo[2.2.1]heptane

7-tert-butoxycarbonyl-2-exo-[3-(3-chlorophenyl)-5-pyridinyl]-7-azabicyclo[2.2.1]heptane

7-tert-butoxycarbonyl-2-exo-[3-(3-chlorophenyl)-5-pyridinyl]-7-azabicyclo[2.2.1]heptane

Conditions
ConditionsYield
With sodium carbonate; tris-(o-tolyl)phosphine; palladium diacetate In 1,2-dimethoxyethane; water Suzuki coupling; Heating;100%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

9,10-di(3-chlorophenyl)anthracene
1261083-80-0

9,10-di(3-chlorophenyl)anthracene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 90℃; for 20h; Suzuki coupling; Inert atmosphere;100%
C17H20BrN3O2
1338094-20-4

C17H20BrN3O2

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

2-amino-7''-(3-chlorophenyl)-1-methyl-2',3',5',6'-tetrahydro-3'',4''-dihydro-2''H-dispiro[imidazol-4,1''-naphthalen-3'',4'-pyran]-5(1H)-one
1338092-32-2

2-amino-7''-(3-chlorophenyl)-1-methyl-2',3',5',6'-tetrahydro-3'',4''-dihydro-2''H-dispiro[imidazol-4,1''-naphthalen-3'',4'-pyran]-5(1H)-one

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 95℃;100%
ethyl 5-bromo-4-(3-cyano-4-fluorophenyl)-1,3-thiazole-2-carboxylate
1266520-43-7

ethyl 5-bromo-4-(3-cyano-4-fluorophenyl)-1,3-thiazole-2-carboxylate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

5-(3-chlorophenyl)-4-(3-cyano-4-fluorophenyl)-1,3-thiazole-2-carboxylic acid
1266520-47-1

5-(3-chlorophenyl)-4-(3-cyano-4-fluorophenyl)-1,3-thiazole-2-carboxylic acid

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In 1,2-dimethoxyethane; water at 20℃; for 1h; Reflux;100%
6-chloropyrido[3,2-d]pyrimidin-4-amine

6-chloropyrido[3,2-d]pyrimidin-4-amine

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

6-(3-chlorophenyl)pyrido[3,2-d]pyrimidin-4-amine

6-(3-chlorophenyl)pyrido[3,2-d]pyrimidin-4-amine

Conditions
ConditionsYield
With potassium phosphate; bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) In 1,4-dioxane; water at 100℃; for 1h; Suzuki Coupling;100%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

3‐chloro‐4′‐nitrobiphenyl
952-22-7

3‐chloro‐4′‐nitrobiphenyl

Conditions
ConditionsYield
With 1,1',1'',1'''-benzene-1,2,4,5-tetrayltetrakis(methylene)tetrakis-(piperidin-4-ol); palladium diacetate; potassium carbonate In ethanol; water at 20℃; Suzuki-Miyaura Coupling;100%
With Pd/C; potassium carbonate In ethanol; water at 100℃; for 3h; Suzuki-Miyaura Coupling;98%
With dichloro bis(acetonitrile) palladium(II); C10H11N3S; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 1h; Suzuki Coupling; Schlenk technique; Inert atmosphere;96%
With carbon supported Pd nanoparticles; potassium carbonate at 95℃; for 6h; Suzuki-Miyaura Coupling; Sealed tube;
1-bromo-3-fluoro-5-methoxybenzene
29578-39-0

1-bromo-3-fluoro-5-methoxybenzene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3'-chloro-3-fluoro-5-methoxy-1,1'-biphenyl

3'-chloro-3-fluoro-5-methoxy-1,1'-biphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water at 90℃; for 0.75h; Inert atmosphere;100%
2-bromofluoranthene
26885-42-7

2-bromofluoranthene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C22H13Cl

C22H13Cl

Conditions
ConditionsYield
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); sodium carbonate In water; toluene at 75℃; for 16h; Inert atmosphere;100%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

1-(bromomethyl)-3-fluoro-5-(trifluoromethyl)benzene
239087-09-3

1-(bromomethyl)-3-fluoro-5-(trifluoromethyl)benzene

1-[(3-chlorophenyl)methyl]-3-fluoro-5-(trifluoromethyl)benzene

1-[(3-chlorophenyl)methyl]-3-fluoro-5-(trifluoromethyl)benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In Dimethyl ether; water; N,N-dimethyl-formamide at 100℃; for 3.05h; Inert atmosphere; Microwave irradiation;100%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

(R)-3-(3-Chloro-phenyl)-cyclopentanone

(R)-3-(3-Chloro-phenyl)-cyclopentanone

Conditions
ConditionsYield
With triethylamine; bis(norbornadiene)rhodium(l)tetrafluoroborate; C46H38N2O5P2 In 1,4-dioxane; water at 25℃; for 2h; Product distribution / selectivity;99%
With potassium hydroxide; C46H38N2O5P2; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; water at 50℃; for 16h; Product distribution / selectivity;53%
With potassium hydroxide; (R)-(-)-(3,5-dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine; bis(ethylene)rhodium acetylacetonate In 1,4-dioxane at 50℃; for 6h; Title compound not separated from byproducts;
bromobenzene
108-86-1

bromobenzene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

m-chlorobiphenyl
2051-61-8

m-chlorobiphenyl

Conditions
ConditionsYield
With Pd/C; potassium carbonate In water; N,N-dimethyl-formamide at 40℃; for 5h; Suzuki Coupling;99%
With C24H20Cl2NPPdS; potassium carbonate; palladium In toluene at 100℃; for 1.5h;96%
With sodium carbonate In ethanol; water at 20℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere;96%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

(3R)-3-(3-chlorophenyl)cyclopentanone
583960-72-9

(3R)-3-(3-chlorophenyl)cyclopentanone

Conditions
ConditionsYield
With di(norbornadiene)rhodium(I) tetrafluoroborate; chiral modified linked BINOL derivative; triethylamine In 1,4-dioxane; water at 25℃; for 2h;99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

PCB 11
2050-67-1

PCB 11

Conditions
ConditionsYield
With potassium acetate; silver(l) oxide In methanol at 40℃; for 15h;99%
With dipotassium peroxodisulfate; potassium carbonate In water; acetone for 2h;99%
With p-benzoquinone; (SIPr)Pd(OAc)2(H2O) In methanol at 20℃; for 24h;95%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C5H7O(C6H4Cl)

C5H7O(C6H4Cl)

Conditions
ConditionsYield
With triethylamine; [Rh(ndb)2]BF4; (R)-BINOL-based bidentate phosphoramidite In 1,4-dioxane; water at 25℃; for 2h;99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

4,4-ethylenedioxy-1-oxo-1,4-dihydronaphthalene
6541-89-5

4,4-ethylenedioxy-1-oxo-1,4-dihydronaphthalene

(R)-3-(3-chlorophenyl)-4,4-ethylenedioxy-1-oxo-1,2,3,4-tetrahydronaphthalene

(R)-3-(3-chlorophenyl)-4,4-ethylenedioxy-1-oxo-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; C41H24F12O2P2; potassium hydroxide In water; toluene at 20℃; for 3h; Inert atmosphere; Schlenk technique; enantioselective reaction;99%
With potassium hydroxide; bis(ethylene)rhodium(I) chloride dimer In 1,4-dioxane at 20℃; for 20h;95%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

o-chloro-N-tosylbenzaldimine
135822-90-1

o-chloro-N-tosylbenzaldimine

(S)-N-[(2-chlorophenyl)(3-chlorophenyl)methyl]-4-methylbenzenesulfonamide
1112116-73-0

(S)-N-[(2-chlorophenyl)(3-chlorophenyl)methyl]-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With potassium phosphate tribasic trihydrate; (Pd((C10H6N2C7H4CH2C6H5)2)(H2O)2)(2+)*2CF3SO3(1-)=(Pd((C10H6N2C7H4CH2C6H5)2)(H2O)2)(CF3SO3)2 In tetrahydrofuran at 4 - 20℃; Molecular sieve; optical yield given as %ee; enantioselective reaction;99%
methyl o-formylbenzoate
4122-56-9

methyl o-formylbenzoate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3-(3-chlorophenyl)-3H-isobenzofuran-1-one
4889-71-8

3-(3-chlorophenyl)-3H-isobenzofuran-1-one

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); C27H30N2S(1+)*Cl(1-); cesium fluoride In toluene at 80℃; for 1h; Inert atmosphere;99%
C11H8O3
1202929-10-9

C11H8O3

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C17H13ClO3

C17H13ClO3

Conditions
ConditionsYield
With [Pd(dppp)(H2O)2](2+)(BF4(1-))2 In 1,4-dioxane at 20℃; for 0.166667h; Inert atmosphere; chemoselective reaction;99%
C11H8O3
1202929-10-9

C11H8O3

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C17H13ClO3

C17H13ClO3

Conditions
ConditionsYield
With [Pd(S,S)-bdpp(H2O)2](2+)(BF4(1-))2 In 1,4-dioxane at 20℃; for 0.666667h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
(2-nitroethenyl)benzene
102-96-5

(2-nitroethenyl)benzene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C14H12ClNO2
1245819-50-4

C14H12ClNO2

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; potassium hydrogen bifluoride; C28H22 In water; toluene at 100℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3-monochlorophenol
108-43-0

3-monochlorophenol

Conditions
ConditionsYield
With water In tetrahydrofuran at 100℃; for 12h;99%
With copper(I) oxide; potassium hydroxide In water at 20℃; for 24h; Green chemistry;98%
With copper(II) ferrite; water; sodium hydroxide at 40℃; for 24h; Green chemistry;96%
C21H15F3O5S
1287702-26-4

C21H15F3O5S

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C26H19ClO2
1287702-28-6

C26H19ClO2

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium fluoride; palladium diacetate In tetrahydrofuran at 50℃; for 22h; Suzuki-Miyaura coupling; Inert atmosphere; chemoselective reaction;99%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

(3S)-3-(3-chlorophenyl)cyclopentanone

(3S)-3-(3-chlorophenyl)cyclopentanone

Conditions
ConditionsYield
With C42H46O6Rh2S2; cesium fluoride In 1,4-dioxane at 20℃; Hayashi-Miyaura reaction; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
Stage #1: 3-chlorophenylboronic acid With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); bis(norbornadiene)rhodium(l)tetrafluoroborate In 1,4-dioxane; water for 2h; Inert atmosphere;
Stage #2: cyclopent-2-enone With triethylamine In 1,4-dioxane; water
89.2%
With chlorobis(ethylene)rhodium(I) dimer; potassium phosphate tribasic trihydrate; C19H23NOS In 1,4-dioxane; water at 20℃; for 3h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;62%
Non-3-en-2-on
14309-57-0

Non-3-en-2-on

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

(S)-4-(3-chlorophenyl)nonan-2-one
1346758-83-5

(S)-4-(3-chlorophenyl)nonan-2-one

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (S,S)-1,1'-(1,7,7-trimethylbicyclo[2.2.1]hepta-2,5-diene-2,5-diyl)dinaphthalene; triethylamine In ethanol at 20℃; for 16h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

benzil
134-81-6

benzil

C20H15ClO2

C20H15ClO2

Conditions
ConditionsYield
With bis(ethylene)rhodium(I) chloride dimer; C19H23NOS; potassium hydroxide In 1,4-dioxane; water at 20 - 50℃; for 4h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
di-tert-butyl fumarate
7633-38-7

di-tert-butyl fumarate

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

(S)-di-tert-butyl-2-(3-chlorophenyl)succinate
1378314-39-6

(S)-di-tert-butyl-2-(3-chlorophenyl)succinate

Conditions
ConditionsYield
Stage #1: 3-chlorophenylboronic acid With chlorobis(ethylene)rhodium(I) dimer; (S,S)-1,7,7-trimethyl-2,5-diphenylbicyclo[2.2.1]hepta-2,5-diene; potassium tert-butylate In methanol; dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: di-tert-butyl fumarate In methanol; dichloromethane; isopropyl alcohol at 60℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1-(3'-chlorobiphenyl-4-yl)ethanone
5002-13-1

1-(3'-chlorobiphenyl-4-yl)ethanone

Conditions
ConditionsYield
With Pd/C; potassium carbonate In ethanol; water at 100℃; for 3h; Suzuki-Miyaura Coupling;99%
With C20H38Cl2N4P2Pd; caesium carbonate In N,N-dimethyl-formamide at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;72.3%
With potassium carbonate In ethanol at 70℃; for 4h; Catalytic behavior; Suzuki-Miyaura Coupling; Schlenk technique; Sealed tube;95 %Spectr.
With carbon supported Pd nanoparticles; potassium carbonate at 95℃; for 6h; Suzuki-Miyaura Coupling; Sealed tube;
tetramethylazacalix[1]-arene[3]pyridine
1169706-60-8

tetramethylazacalix[1]-arene[3]pyridine

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C31H28ClN7

C31H28ClN7

Conditions
ConditionsYield
With copper(II) perchlorate hexahydrate; triethylamine In dimethyl sulfoxide at 80℃; for 3.5h;99%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

benzo[e][1,2,3]oxathiazine 2,2-dioxide
71730-46-6

benzo[e][1,2,3]oxathiazine 2,2-dioxide

(S)-4-(3-chlorophenyl)-3,4-dihydrobenzo[e][1,2,3]oxathiazine 2,2-dioxide

(S)-4-(3-chlorophenyl)-3,4-dihydrobenzo[e][1,2,3]oxathiazine 2,2-dioxide

Conditions
ConditionsYield
With silver tetrafluoroborate; C30H38Cl2NPPd In 1,2-dichloro-ethane at 65℃; for 1h; enantioselective reaction;99%
With nickel(II) perchlorate hexahydrate; (S)-2′-(tert-butyl)-7-(diphenylphosphino)-2,3-dihydro-5′H-spiro[indene-1,4′-oxazole] In 2,2,2-trifluoroethanol at 60℃; for 24h; Inert atmosphere; Schlenk technique; enantioselective reaction;97%

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