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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

tert-Butyl acrylate TOP1 supplier

Cas:1663-39-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless liquid accord Amount% ≥99.5

Top purity Tert-Butyl acrylate with high quality and best price cas:1663-39-4

Cas:1663-39-4

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Tert-Butyl Acrylate supplier in China

Cas:1663-39-4

Min.Order:0 Metric Ton

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Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

Classification: Alcohol CAS No.: 75-65-0 Other Names: TBA MF: C4H10O EINECS No.: 200-889-7 Place of

tba 1663-39-4 tert-Butyl acrylate

Cas:1663-39-4

Min.Order:1 Metric Ton

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply tert-butyl acrylate

Cas:1663-39-4

Min.Order:1

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Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name tert-Butyl acrylate CAS No. 1663-39-4

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:1 Metric Ton

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: tert-Butyl acrylate Synonyms: tert-butylpropenoate;ACRYLIC ACID TERT-BUTYL ESTER;TERTIARY-BUTYL ACRYLATE;TERT-BUTYL ACRYLATE;TBA;T-BUTYL ACRYLATE;2-Propenoic acid, 1,1-dimethylethyl ester;2-Propenoicacid,1,1-dimethylethyl

TBA 1663-39-4 tert-Butyl acrylate

Cas:1663-39-4

Min.Order:1 Metric Ton

FOB Price: $8900.0

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

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Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

supplier in China Appearance:colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:organic synthesis Transportation:BY AIR Port:S

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Siwei Development Group Ltd.

Product name: Tert-Butyl Acrylate CAS No.:1663-39-4 Molecule Formula:C7H12O2 Molecule Weight:128.17 Purity: 99.0% Package: 200kg/drum Description:Colorless liquid Manufacture Standards:Enterprise Standard TESTING I

Best Quality Tert-Butyl Acrylate

Cas:1663-39-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

tert-Butyl acrylateCAS NO.: 1663-39-4

Cas:1663-39-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

tert-Butyl Acrylate

Cas:1663-39-4

Min.Order:0

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Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

tert-butylprop-2-enoate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

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Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Other

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Tert-Butyl Acrylate

Cas:1663-39-4

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 1663-39-4 with best price

Cas:1663-39-4

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Zhejiang Haizhou Pharmaceutical Co., Ltd.

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Propenoic acid,1,1-dimethylethyl ester

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

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Type:Other

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Hubei Langyou International Trading Co., Ltd

tert-butyl acrylate Application:tert-butyl acrylate

tert-butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Other

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Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 5002kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

tert-Butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

1663-39-4

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Tert-Butyl acrylate manufacture

Cas:1663-39-4

Min.Order:0

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Hunan Longxianng Runhui Trading Co.,Ltd

tert-butyl acrylateAppearance:colorless liquid Package:barrel or tank Application:4. Applications tert-Butyl acrylate forms homopolymers and copolymers. Copolymers of tert-butyl acrylate can be prepared with acrylic acid and its salts, amides and es

tert-butyl acrylate

Cas:1663-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

tert-butylprop-2-enoate 1663-39-4

Cas:1663-39-4

Min.Order:0

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Type:Trading Company

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Synthetic route

acrylic acid
79-10-7

acrylic acid

isobutene
115-11-7

isobutene

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With strong acid cation exchange resin; polymerization inhibitor A; polymerization inhibitor B at 10℃; for 13h; Temperature;99.7%
With tempol; 10H-phenothiazine; sulfuric acid
With mesoporous Fe-SBA-15-SO3H at 60℃; for 12h; Autoclave;
tert-butyl prop-2-ynoate
13831-03-3

tert-butyl prop-2-ynoate

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With hydrogen; [Cp2Mo(μ-SH)2Rh(PPh3)2][PF6] In acetone at 20℃; under 760.051 Torr; for 5h; Product distribution; Further Variations:; Catalysts; Reaction partners;99%
β-Propiolactone
57-57-8

β-Propiolactone

potassium tert-butylate
865-47-4

potassium tert-butylate

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.25h;96%
acrylic acid
79-10-7

acrylic acid

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; acetic anhydride at 0 - 60℃; for 5h;66%
With N,N,N,N,N,N-hexamethylphosphoric triamide; Bu3PI2 In diethyl ether for 24h;51%
With nickel(II) polyacrylate; water
acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

methyl 3-methoxypropionate
3852-09-3

methyl 3-methoxypropionate

C

3-tert.-Butoxypropionsaeuremethylester
81048-08-0

3-tert.-Butoxypropionsaeuremethylester

D

3-Methoxy-propionic acid tert-butyl ester
112032-54-9

3-Methoxy-propionic acid tert-butyl ester

E

tert-butyl β-tert-butoxypropionate
21150-74-3

tert-butyl β-tert-butoxypropionate

Conditions
ConditionsYield
With n-butyllithium; bis(acetylacetonate)nickel(II) In benzene at 90℃; for 5h; Product distribution; other time, other temp.;A 33%
B 26%
C 9%
D 32%
E 3%
acryloyl chloride
814-68-6

acryloyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With calcium carbonate at 70℃;
With pyridine
With triethylamine In chloroform at 10℃; for 12h;
2-chloropropionyl chloride
625-36-5

2-chloropropionyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With 2,3-Dimethylaniline at 150℃;
β-Propiolactone
57-57-8

β-Propiolactone

methyl iodide
74-88-4

methyl iodide

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

methyl ester (3-hydroxy) propionic acid
6149-41-3

methyl ester (3-hydroxy) propionic acid

C

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate 1) THF, 20 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
acetylene
74-86-2

acetylene

tert-butyl alcohol
75-65-0

tert-butyl alcohol

carbon monoxide

carbon monoxide

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With hydrogenchloride; tetracarbonyl nickel
acrylic acid
79-10-7

acrylic acid

isobutene
115-11-7

isobutene

polyisobutylene

polyisobutylene

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With sulfuric acid
tert-butyl 3-hydroxy-3-(2-hydroxy-3-methoxyphenyl)-2-methylenenpropanoate
548756-56-5

tert-butyl 3-hydroxy-3-(2-hydroxy-3-methoxyphenyl)-2-methylenenpropanoate

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

3-methoxy-2-hydroxybenzaldehyde
148-53-8

3-methoxy-2-hydroxybenzaldehyde

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform-d1 retro-Baylis-Hillman reaction;
tert-butyl 3-(5-bromo-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate
548756-58-7

tert-butyl 3-(5-bromo-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

5-bromosalicyclaldehyde
1761-61-1

5-bromosalicyclaldehyde

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform-d1 retro-Baylis-Hillman reaction;
tert-butyl 3-(3-ethoxy-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate
548756-57-6

tert-butyl 3-(3-ethoxy-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

3-ethoxysalicylaldehyde
492-88-6

3-ethoxysalicylaldehyde

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform-d1 retro-Baylis-Hillman reaction;
tert-butyl 3-(3,5-dibromo-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate
548756-59-8

tert-butyl 3-(3,5-dibromo-2-hydroxyphenyl)-3-hydroxy-2-methylenenpropanoate

A

3,5-Dibromosalicylaldehyde
90-59-5

3,5-Dibromosalicylaldehyde

B

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In chloroform-d1 retro-Baylis-Hillman reaction;
acrolein
107-02-8

acrolein

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
Stage #1: acrolein With tert-butylhypochlorite In tetrachloromethane at 30℃; for 3.33333h;
Stage #2: tert-butyl alcohol In tetrachloromethane at 50 - 75℃; for 22h;
succinic acid mono-tert-butyl ester
15026-17-2

succinic acid mono-tert-butyl ester

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With 2,2-dimethylpropanoic anhydride; triphenylphosphine; palladium dichloride at 190℃; for 2h; Inert atmosphere;31 %Chromat.
Multi-step reaction with 2 steps
1.1: triethylamine / dichloromethane / 0.17 h / Inert atmosphere
1.2: 20 °C / Inert atmosphere
2.1: palladium dichloride; lithium chloride / 3 h / 155 - 160 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
Multi-step reaction with 2 steps
1: HATU; N-ethyl-N,N-diisopropylamine / dichloromethane / 4 h / 20 °C
2: triphenylphosphine / tetrahydrofuran; water / 20 °C
View Scheme
tert-butyl 4-nitrophenyl succinate

tert-butyl 4-nitrophenyl succinate

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With lithium chloride; palladium dichloride at 155 - 160℃; for 3h; Inert atmosphere; Schlenk technique; Sealed tube;46 %Chromat.
C13H22N10O3

C13H22N10O3

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran; water at 20℃;
C7H14O2

C7H14O2

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With Dess-Martin periodane In dichloromethane at 20℃;
tert-butyl formate
762-75-4

tert-butyl formate

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0 - 20 °C
2: Dess-Martin periodane / dichloromethane / 20 °C
View Scheme
tert-butyl 3-hydroxy-3-(2-hydroxyphenyl)-2-methylenenpropanoate
548756-55-4

tert-butyl 3-hydroxy-3-(2-hydroxyphenyl)-2-methylenenpropanoate

A

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

B

salicylaldehyde
90-02-8

salicylaldehyde

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In [D3]acetonitrile at 20℃; Kinetics; Inert atmosphere;
acrylic acid anhydride
2051-76-5

acrylic acid anhydride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
With 4-methoxy-phenol at 60℃; for 10h;
t-butyl bromide
507-19-7

t-butyl bromide

acrylic acid
79-10-7

acrylic acid

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

Conditions
ConditionsYield
Stage #1: acrylic acid With potassium carbonate In N,N-dimethyl-formamide at 0℃; for 0.75h; Inert atmosphere;
Stage #2: t-butyl bromide In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere;
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

tert-butyl 2,3-dibromopropanoate
138034-79-4, 49855-41-6

tert-butyl 2,3-dibromopropanoate

Conditions
ConditionsYield
With bromine In dichloromethane at 0 - 20℃; for 18h;100%
With bromine In dichloromethane at 5℃; for 2h;90%
With bromine In chloroform for 15h; Ambient temperature;81%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

(E)-t-butyl 4-formylcinnamate
208036-26-4

(E)-t-butyl 4-formylcinnamate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 6h; Heck-Mizoroki reaction;100%
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine Heating;91%
With palladium on silica; triethylamine In N,N-dimethyl-formamide for 0.2h; Heck Reaction; Microwave irradiation; Green chemistry;89%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

2-trifluoromethyl-4-isopropyl-Δ3-oxazolin-5-one
2357-39-3

2-trifluoromethyl-4-isopropyl-Δ3-oxazolin-5-one

tert-butyl 3-[5-oxo-4-(propan-2-yl)-2-(trifluoromethyl)-2,5-dihydro-1,3-oxazol-2-yl]propanoate
87341-14-8

tert-butyl 3-[5-oxo-4-(propan-2-yl)-2-(trifluoromethyl)-2,5-dihydro-1,3-oxazol-2-yl]propanoate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;100%
With triethylamine In dichloromethane 1.) -10 deg C, 2.) 25 deg C, 12 h;80%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

para-bromoacetophenone
99-90-1

para-bromoacetophenone

(E)-tert-butyl 3-(4-acetylphenyl)prop-2-enoate
389091-50-3

(E)-tert-butyl 3-(4-acetylphenyl)prop-2-enoate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 120℃; for 15h; Heck cross-coupling reaction;100%
With 1,3-disubstituted imidazolium bromide; potassium carbonate; 4-methylmorpholine N-oxide; palladium diacetate In 1-methyl-pyrrolidin-2-one at 120℃; for 2h; Heck reaction;99%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 1h; Mizoroki-Heck reaction;99%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

diphenylphosphane
829-85-6

diphenylphosphane

3-Diphenylphosphanyl-propionic acid tert-butyl ester
175407-89-3

3-Diphenylphosphanyl-propionic acid tert-butyl ester

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide In tetrahydrofuran100%
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;81%
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere;81%
iodobenzene
591-50-4

iodobenzene

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

tert-butyl cinnamate
14990-09-1

tert-butyl cinnamate

Conditions
ConditionsYield
With triethylamine; palladium In N,N-dimethyl acetamide at 100℃; for 24h; Heck reaction;100%
With C36H36Cl2N6Pd; triethylamine In methanol at 70℃; for 24h; Reagent/catalyst; Concentration; Heck Reaction;100%
With PdCl2(1-[2-(diphenylphosphanyl)ethyl]-3,5-dimethylpyrazole); tetrabutylammomium bromide; triethylamine In N,N-dimethyl-formamide at 140℃; for 0.16h; Catalytic behavior; Time; Heck Reaction; Inert atmosphere; Schlenk technique;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

4-tolyl iodide
624-31-7

4-tolyl iodide

tert-butyl 4-methylcinnamate
136053-53-7, 125951-00-0

tert-butyl 4-methylcinnamate

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; palladium dichloride at 40℃; for 3h; Heck reaction; Inert atmosphere; neat (no solvent);100%
With triethylamine; palladium In N,N-dimethyl acetamide at 80℃; for 36h; Heck reaction;99%
With poly(N-isopropylacerylamide)-SCS-PdCl; TEA In n-heptane; N,N-dimethyl acetamide; water at 95℃; for 10h; Heck coupling;99%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate
370839-59-1

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate

Conditions
ConditionsYield
With tributyl-amine; [1,2-bis(4-Me-2-pyridylethynyl)benzene]dichloropalladium(II) at 100℃; for 7h; Heck reaction;100%
With {1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}dichloro(pyridine)palladium; caesium carbonate In neat (no solvent) at 100℃; for 12h; Heck Reaction;99%
With C22H24Cl2N4Pd; tetrabutylammomium bromide; triethylamine In methanol at 70℃; for 24h; Reagent/catalyst; Concentration; Heck Reaction;97%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

tert-butyl (E)-3-(4-methoxyphenyl)prop-2-enoate
53484-52-9

tert-butyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 120℃; for 6h; Heck cross-coupling reaction;100%
With tetrabutyl ammonium fluoride; palladium dichloride at 60℃; for 12h; Heck reaction; Inert atmosphere; neat (no solvent);100%
With water; palladium diacetate; caesium carbonate at 140℃; for 4h; Heck reaction; Ionic liquid; Inert atmosphere;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

4-nitrobenzenediazonium tetrafluoroborate
456-27-9

4-nitrobenzenediazonium tetrafluoroborate

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate
370839-59-1

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate

Conditions
ConditionsYield
With 1,6,11-triazacyclopentadeca-3,8,12-triene Pd In ethanol at 20℃; for 2.75h; Heck reaction;100%
With 3-benzyl-1-(2-hydroxy-2-phenylethyl)imidazolium chloride; palladium diacetate In ethanol at 36℃; for 3h; Heck-Matsuda reaction;96%
With dichloro bis(acetonitrile) palladium(II) In water at 0 - 25℃; for 1.5h;96%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

(4-tert-butylphenyl)diazonium tetrafluoroborate
52436-75-6

(4-tert-butylphenyl)diazonium tetrafluoroborate

tert-butyl (E)-4-tert-butylcinnamate

tert-butyl (E)-4-tert-butylcinnamate

Conditions
ConditionsYield
With 1,6,11-triazacyclopentadeca-3,8,12-triene Pd In ethanol at 20℃; for 4h; Heck reaction;100%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

tert-butyl (E)-3-(4-methoxyphenyl)prop-2-enoate
53484-52-9

tert-butyl (E)-3-(4-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With C31H38ClN3Pd; potassium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 18h; Heck-Mizoroki coupling; Inert atmosphere;100%
With IMes-Pd(dmba)Cl; potassium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 18h; Heck-Mizoroki reaction; Inert atmosphere;100%
With 1,3-disubstituted imidazolium bromide; potassium carbonate; palladium diacetate In 1,4-dioxane at 105℃; for 20h; Heck reaction;99%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

propan-1-ol-3-amine
156-87-6

propan-1-ol-3-amine

tert-butyl 3-[(2-tert-butoxycarbonyl-ethyl)-(3-hydroxy-propyl)-amino]-propionate
644968-23-0

tert-butyl 3-[(2-tert-butoxycarbonyl-ethyl)-(3-hydroxy-propyl)-amino]-propionate

Conditions
ConditionsYield
In methanol at 20℃; for 24h; Darkness; Inert atmosphere;100%
In methanol at 20 - 30℃; for 8h;99%
In methanol at 20℃; for 6h;98%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 10500, Mw/Mn = 1.18; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 10500, Mw/Mn = 1.18; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 1h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 20000, Mw/Mn = 1.12; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 20000, Mw/Mn = 1.12; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 1h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 29700, Mw/Mn = 1.09; monomer(s); tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 29700, Mw/Mn = 1.09; monomer(s); tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 47700, Mw/Mn = 1.06; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 47700, Mw/Mn = 1.06; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 58900, Mw/Mn = 1.05; monomer(s): tert-butyl acetate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 58900, Mw/Mn = 1.05; monomer(s): tert-butyl acetate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 83400, Mw/Mn = 1.05; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 83400, Mw/Mn = 1.05; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 250600, Mw/Mn = 1.17; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 250600, Mw/Mn = 1.17; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 3h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Et3Al system, Mn = 170900, Mw/Mn = 1.06; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Et3Al system, Mn = 170900, Mw/Mn = 1.06; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triethylaluminum In toluene at 0℃; for 1h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Et3Al system, Mn = 305900, Mw/Mn = 1.25; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Et3Al system, Mn = 305900, Mw/Mn = 1.25; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triethylaluminum In toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Me3Al system, Mn = 437900, Mw/Mn = 1.61; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/Me3Al system, Mn = 437900, Mw/Mn = 1.61; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; trimethylaluminum In toluene at 0℃; for 2h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 5300, Mw/Mn = 1.26; monomer(s): tert-butyl acrylate

poly-tert-butyl acrylate, obtained by anionic polymerization, initiated with the tBuOK/iBu3Al system, Mn = 5300, Mw/Mn = 1.26; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In toluene at 0℃; for 1h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

3-[Bis-(2-tert-butoxycarbonyl-ethyl)-amino]-propionic acid tert-butyl ester
146743-72-8

3-[Bis-(2-tert-butoxycarbonyl-ethyl)-amino]-propionic acid tert-butyl ester

Conditions
ConditionsYield
With ammonium hydroxide In methanol at 120℃; under 7500.75 Torr; for 3h; Microwave irradiation;100%
With ammonia In methanol at 20℃; for 6h;98%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate
370839-59-1

(E)-tert-butyl 3-(4-nitrophenyl)prop-2-enoate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 80℃; for 4h; Heck cross-coupling reaction;100%
With tetrabutyl ammonium fluoride; palladium dichloride at 40℃; for 3h; Heck reaction; Inert atmosphere; neat (no solvent);100%
With 1,4-diaza-bicyclo[2.2.2]octane; poly(ethylene glycol)-400; potassium carbonate; palladium diacetate In water at 80℃; for 4h; Heck cross-coupling;98%
2-(benzylsulfanyl)-N-(2-bromo-4,6-difluorophenyl)-N-methylacetamide
876061-13-1

2-(benzylsulfanyl)-N-(2-bromo-4,6-difluorophenyl)-N-methylacetamide

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

(E)-tert-butyl 3-(2-(2-(benzylsulfanyl)-N-methylacetamido)-3,5-difluorophenyl)acrylate
876061-15-3

(E)-tert-butyl 3-(2-(2-(benzylsulfanyl)-N-methylacetamido)-3,5-difluorophenyl)acrylate

Conditions
ConditionsYield
With triethylamine; tris-(o-tolyl)phosphine; palladium diacetate In o-xylene at 100℃; for 7h; Heck reaction; microwave irradiation;100%
With triethylamine; tris-(o-tolyl)phosphine; palladium diacetate In o-xylene at 100℃; for 7h; Heck coupling; microwave irradiation;87%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

para-bromoacetophenone
99-90-1

para-bromoacetophenone

3-(4-acetyl-phenyl)-acrylic acid tert-butyl ester

3-(4-acetyl-phenyl)-acrylic acid tert-butyl ester

Conditions
ConditionsYield
With C33H33N2(1+)*Cl(1-); palladium diacetate; potassium carbonate In water; N,N-dimethyl-formamide for 2h; Reagent/catalyst; Heck Reaction; Inert atmosphere; Sealed tube; Heating;100%
With C30H42Cl2N2Pd; potassium carbonate In N,N-dimethyl-formamide at 80℃; for 8h; Catalytic behavior; Reagent/catalyst; Heck Reaction; Inert atmosphere; Schlenk technique;99%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 4h; Heck Reaction;98%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

polymer, Mn 5300, PDI 1.26 by GPC; monomer(s): tert-butyl acrylate

polymer, Mn 5300, PDI 1.26 by GPC; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 1h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

polymer, Mn 1.975E5, PDI 1.40 by GPC; monomer(s): tert-butyl acrylate

polymer, Mn 1.975E5, PDI 1.40 by GPC; monomer(s): tert-butyl acrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0℃; for 2h;100%

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