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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-methylpropane-2-thiol

Cas:75-66-1

Min.Order:1

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 2-Methyl-2-propanethiol 98% TOP1 supplier in China

Cas:75-66-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

2-Methyl-2-propanethiol Basic information Product Name: 2-Methyl-2-propanethiol Synonyms: 1,1-Dimethylethanethiol;2-Isobutanethiol;2-methyl-2-propanethio;2-methyl-propane-2-thiol;mercapt

2-Methyl-2-propanethiol, 99%

Cas:75-66-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

2-Methyl-2-propanethiol Pesticides intermediates

Cas:75-66-1

Min.Order:1 Kilogram

FOB Price: $35.0 / 50.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:75-66-1

Cas:75-66-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Propanethiol,2-methyl-

Cas:75-66-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:0

Negotiable

Type:Manufacturers

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:liquid with an exceedingly unpleasant smell Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:0

Negotiable

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Fandachem Co.,Ltd

2-Methyl-2-propanethiol(tert-Butyl Mercaptan;2-Propanethiol, 2-methyl-),cas:75-66-1 from fandachem Application:fine chemical Transportation:by air,by sea,by express

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 75-66-1 with competitive price

Cas:75-66-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Propanethiol,2-methyl-

Cas:75-66-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-Methyl-2-propanethiol 75-66-1

Cas:75-66-1

Min.Order:0

Negotiable

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

2-Methyl-2-propanethiol CAS NO.75-66-1 from Jilin Tely with High Purity CAS NO.75-66-1 Application:2-Methyl-2-propanethiol CAS NO.75-66-1 from Jilin Tely with High Purity CAS NO.75-66-1

Hunan Longxianng Runhui Trading Co.,Ltd

2-Methyl-2-propanethiol CAS NO.75-66-1 from Jilin Tely with High Purity CAS NO.75-66-1Appearance:powder Storage:Store at RT. Package:bag Application:Industrial Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(

2-Methyl-2-propanethiol CAS NO.75-66-1 from Jilin Tely with High Purity CAS NO.75-66-1

Cas:75-66-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#75-66-1;CAT#A838479

Cas:75-66-1

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Our company is a professional production leading factory in China in pharmaceutical area of many years,our products have exported to USA, Greece, Spain, UK, Australia and other countries, and we have got very good feedback from our cust

free samples NO.1 factory 2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SuZhou LaiTeou

1, Quality: Our company is a professional production of intermediates and chemicals for many years, our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other country, and we have got very good feedback

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Chemtn Biological Technology Limited

Our company is a professional chemical raw materials manufacturer and exporter for many years in chemical market. There are more than 200 excellent staffs and four factories working for us . Company advantage: 1.Place of Origin in China with Su

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:1 Kilogram

FOB Price: $2200.0 / 2300.0

Type:Lab/Research institutions

inquiry

Beijing Sjar Technology Development Co., Ltd.

Sjar-Tech has set up a R&D team with rich experience and strong technical strength, most of the practitioners have more than ten years' experience and technology in organic synthesis development, especially on the OLED custom syntheis, 2-Br

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:1 Gram

FOB Price: $5.0 / 10.0

Type:Lab/Research institutions

inquiry

hdzhl co., ltd

Product Details Keywords 2-Methyl-2-propanethiol 75-66-1 1,1-Dimethylethanethiol Quick Details ProName:2-Methyl-2-propanethiol CasNo:75-66-1 Molecular Formula:C4H10S

2-Methyl-2-propanethiol CAS NO.75-66-1

Cas:75-66-1

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Profile HeBei Ruishun Trade Co.LTD, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,Seek development by credit

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:500 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

2-Propanethiol,2-methyl-

Cas:75-66-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

AOPHARM

Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of

2-Methyl-2-propanethiol

Cas:75-66-1

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

2-Propanethiol,2-methyl-

Cas:75-66-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

t-butyl bromide
507-19-7

t-butyl bromide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With hydrosulfide exchange resin In acetonitrile at 25℃; for 0.25h;96%
Stage #1: t-butyl bromide With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With sulfur In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;
tertiary butyl chloride
507-20-0

tertiary butyl chloride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With hydrosulfide exchange resin In acetonitrile at 25℃; for 0.25h;95%
With hydrogen sulfide; boron trifluoride
With hydrogen sulfide; tin(IV) chloride
1-chloro-3-phenylpropan-2-one
937-38-2

1-chloro-3-phenylpropan-2-one

t-butyl thionitrite
15459-95-7

t-butyl thionitrite

A

C9H8ClNO2
78946-49-3

C9H8ClNO2

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 95%
B n/a
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

1-chlorohexan-2-one
20261-68-1

1-chlorohexan-2-one

A

C6H10ClNO2
78946-52-8

C6H10ClNO2

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 95%
B n/a
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

1-chloro-3-phenoxyacetone
940-47-6

1-chloro-3-phenoxyacetone

A

C9H8ClNO3
78946-50-6

C9H8ClNO3

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 95%
B n/a
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

1-chloro-3,3-dimethyl-butan-2-one
13547-70-1

1-chloro-3,3-dimethyl-butan-2-one

A

(1Z)-N-hydroxy-3,3-dimethyl-2-oxobutanimidoyl chloride
96759-10-3

(1Z)-N-hydroxy-3,3-dimethyl-2-oxobutanimidoyl chloride

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 85%
B n/a
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

chloroacetone
78-95-5

chloroacetone

A

N-hydroxy-2-oxo-propionimidoyl chloride
17019-27-1

N-hydroxy-2-oxo-propionimidoyl chloride

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 82%
B n/a
tert-butyl alcohol
75-65-0

tert-butyl alcohol

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With polymer supported thiol; trifluoroacetic anhydride In dichloromethane at 20℃; for 0.25h;75%
With hydrogen sulfide at 180℃; under 6251820 Torr;
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

1-bromoacetone
598-31-2

1-bromoacetone

A

(Z)-pyruvohydroximoyl bromide
30822-62-9

(Z)-pyruvohydroximoyl bromide

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 43%
B n/a
methanol
67-56-1

methanol

2-(2-tert-Butylsulfanyl-2-methoxy-ethyl)-benzo[de]isoquinoline-1,3-dione

2-(2-tert-Butylsulfanyl-2-methoxy-ethyl)-benzo[de]isoquinoline-1,3-dione

A

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

B

2-(2,2-dimethoxyethyl)-1H-benzo[d,e]isoquinoline-1,3(2H)-dione
153721-06-3

2-(2,2-dimethoxyethyl)-1H-benzo[d,e]isoquinoline-1,3(2H)-dione

Conditions
ConditionsYield
In dichloromethane Irradiation;A 30%
B 34%
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

1-chloroacetophenone
532-27-4

1-chloroacetophenone

A

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

B

(Z)-N-hydroxy-α-oxobenzeneethanimidoyl chloride
17019-28-2

(Z)-N-hydroxy-α-oxobenzeneethanimidoyl chloride

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A n/a
B 20%
t-butyl thionitrite
15459-95-7

t-butyl thionitrite

α-bromoacetophenone
70-11-1

α-bromoacetophenone

A

C8H6BrNO2
14450-97-6

C8H6BrNO2

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In diethyl ether at 25℃; for 3h;A 10%
B n/a
O,O-di-t-butyl dithiophosphoric acid
92799-96-7

O,O-di-t-butyl dithiophosphoric acid

A

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

B

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 70℃;
Isobutyl bromide
78-77-3

Isobutyl bromide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With sodium hydrogensulfide; ethanol
sulfure de di tert-butyle
107-47-1

sulfure de di tert-butyle

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With iron sulfide; hydrogen sulfide at 190℃; unter Druck;
With hydrogen sulfide; propionic acid anhydride at 190℃; unter Druck;
3-tert-Butyl-2,4,4-trimethyl-pent-2-ene
2437-52-7

3-tert-Butyl-2,4,4-trimethyl-pent-2-ene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With hydrogen sulfide at 200℃; under 36775.4 Torr;
tert-butylmagnesium chloride
677-22-5

tert-butylmagnesium chloride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With diethyl ether; sulfur Zersetzen mit Eiswasser und verd.H2SO4;
S-tert-butyl isothiouronium bromide
53243-22-4

S-tert-butyl isothiouronium bromide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With potassium hydroxide
tert-Butyl iodide
558-17-8

tert-Butyl iodide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With ethanol; zinc sulfide
isobutene
115-11-7

isobutene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With sulfuric acid; hydrogen sulfide
With hydrogen sulfide; benzenesulfonic acid
With phosphoric acid; hydrogen sulfide; pyrographite
thiophene
110-01-0

thiophene

A

thiophene
188290-36-0

thiophene

B

trans-2-Butene
624-64-6

trans-2-Butene

C

Isobutane
75-28-5

Isobutane

D

Dibutyl sulfide
544-40-1

Dibutyl sulfide

E

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

F

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
aluminum oxide; cobalt molybdenum In n-heptane at 290℃; under 21280 Torr; Product distribution; Mechanism; effect of temperature, pressure and contact time;
thiophene
188290-36-0

thiophene

A

thiophene
110-01-0

thiophene

B

trans-2-Butene
624-64-6

trans-2-Butene

C

Isobutane
75-28-5

Isobutane

D

Dibutyl sulfide
544-40-1

Dibutyl sulfide

E

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

F

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
aluminum oxide; cobalt molybdenum In n-heptane at 290℃; under 21280 Torr; Product distribution; Mechanism; effect of temperature, pressure and contact time;
di-tert-butyl disulfide
110-06-5

di-tert-butyl disulfide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With n-butanethiol Equilibrium constant;
t-butyl bromide
507-19-7

t-butyl bromide

Potassium N-<(2-vinyloxy)ethyl>dithiocarbamate
97006-62-7

Potassium N-<(2-vinyloxy)ethyl>dithiocarbamate

A

tert-butyl N-(2-vinyloxyethyl)dithiocarbamate
126560-48-3

tert-butyl N-(2-vinyloxyethyl)dithiocarbamate

B

2-(vinyloxy)ethyl isothiocyanate
59565-09-2

2-(vinyloxy)ethyl isothiocyanate

C

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In ethanol at 60℃; for 1h;A 36 % Spectr.
B n/a
C n/a
S-tert-butyl acetothioacetate
15925-47-0

S-tert-butyl acetothioacetate

A

2-acetoacetic acid
541-50-4

2-acetoacetic acid

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
With water at 23.3 - 49℃; Rate constant; Thermodynamic data; 0.8percent (v/v) acetonitrile, ionic strength 0.1M. ΔH(excit.), ΔS(excit.), study of rate constant at different temperatures.;
With sodium hydroxide at 25℃; Rate constant; ionic strength 0.1M, 0.8percent (v/v) acetonitrile;
di-tert-butyl sulfoxide
2211-92-9

di-tert-butyl sulfoxide

A

2-methyl-2-propanesulfenic acid
4719-19-1

2-methyl-2-propanesulfenic acid

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
at 350℃;
C16H17O2S3(1-)

C16H17O2S3(1-)

A

dibenzo<1,2>dithiin 5,5-dioxide
25331-82-2

dibenzo<1,2>dithiin 5,5-dioxide

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In 1,4-dioxane; water at 25℃; Rate constant; var. pH;
selenium(II) bis(2-methyl-2-propanethiolate)
75272-63-8

selenium(II) bis(2-methyl-2-propanethiolate)

35S-2-methyl-2-propanethiol
58204-98-1

35S-2-methyl-2-propanethiol

A

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

B

C8H18(35)S2Se

C8H18(35)S2Se

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane at 25℃; Rate constant; Kinetics; exchange of 35S labeled thiols with bis(alkylthio) selenides reactions of bis(alkylthio) selenides with various nucleophiles, reactivity and site of nucleophilic attack;
2-methylpropane-2-thiol-d1
32259-07-7

2-methylpropane-2-thiol-d1

2-propanethiol
75-33-2

2-propanethiol

A

isopropylthiol-d
41782-40-5

isopropylthiol-d

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Conditions
ConditionsYield
In Cyclohexane-d12 at 29.9℃; Rate constant; Equilibrium constant; Thermodynamic data; EA (Arrhenius activation energy); ΔH<*> (enthalpy for isotopic exchange); ΔS<*> (entropy for isotopic exchange); various solvents investigated;
sulfure de di tert-butyle
107-47-1

sulfure de di tert-butyle

chlorobenzene
108-90-7

chlorobenzene

A

diphenyl sulfide
139-66-2

diphenyl sulfide

B

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

C

thiophenol
108-98-5

thiophenol

D

benzene
71-43-2

benzene

Conditions
ConditionsYield
at 650℃; Product distribution; Mechanism;
at 650℃; Product distribution; Mechanism; 600 deg C;
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

2-methyl-2-propanethiosulfenyl chloride
6009-05-8

2-methyl-2-propanethiosulfenyl chloride

Conditions
ConditionsYield
With pyridine; sulfur dichloride In diethyl ether at -78℃; for 0.5h;100%
With chlorine In tetrachloromethane
With sulfur dichloride; pentane
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

1,1-dimethylethanesulfenyl chloride
52322-55-1

1,1-dimethylethanesulfenyl chloride

Conditions
ConditionsYield
With pyridine; sulfuryl dichloride In diethyl ether at -78℃; for 0.5h;100%
With methylbutane; chlorine
With hexane; chlorine
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

bis(2-methyl-2-propyl)tetrasulfide
5943-35-1

bis(2-methyl-2-propyl)tetrasulfide

Conditions
ConditionsYield
With disulfur dichloride100%
With disulfur dichloride; benzene
With propylamine; sulfur In dichloromethane
With disulfur dichloride In tetrachloromethane Ambient temperature;
With disulfur dichloride
2-methyl-2-propanethiosulfenyl chloride
6009-05-8

2-methyl-2-propanethiosulfenyl chloride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

di-tert-butyl trisulfide
4253-90-1

di-tert-butyl trisulfide

Conditions
ConditionsYield
With pyridine In diethyl ether for 0.5h;100%
1,1-dimethylethanesulfenyl chloride
52322-55-1

1,1-dimethylethanesulfenyl chloride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

di-tert-butyl disulfide
110-06-5

di-tert-butyl disulfide

Conditions
ConditionsYield
With pyridine In diethyl ether for 0.5h;100%
<(E)-3,3-dimethyl-1-butenyl>mercuric chloride
36525-02-7, 79178-05-5

<(E)-3,3-dimethyl-1-butenyl>mercuric chloride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

(E)-1-tert-Butylsulfanyl-3,3-dimethyl-but-1-ene
75924-71-9

(E)-1-tert-Butylsulfanyl-3,3-dimethyl-but-1-ene

Conditions
ConditionsYield
With sodium hydrogencarbonate In benzene at 35 - 45℃; for 15h; Irradiation;100%
(p-cymene)osmium bis(t-butyloxide)
134654-70-9

(p-cymene)osmium bis(t-butyloxide)

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

A

(p-cymene)osmium bis(t-butylthiolate)
134654-72-1

(p-cymene)osmium bis(t-butylthiolate)

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In benzene-d6 soln. of CymOs(O-t-Bu)2 in C6D6 is degassed, t-BuSH is added at -196°C; (1)H-NMR;A 92%
B 100%
monomethylgallium di-iodide
95050-66-1

monomethylgallium di-iodide

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

diiodomethyl(tert-butylthiol)gallane

diiodomethyl(tert-butylthiol)gallane

Conditions
ConditionsYield
In benzene byproducts: CH4; (under N2); the thiol is introduced into a soln. of MeGaI2 in benzene; the solvent is evapd., the residue is washed, dried; elem. anal.;100%
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

C12H15ClOS
88577-88-2

C12H15ClOS

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 16h;100%
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

1-(1,1-dimethylethyl)sulfanyl-4-nitrobenzene
7205-66-5

1-(1,1-dimethylethyl)sulfanyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium hydroxide In N,N-dimethyl-formamide Inert atmosphere;100%
Stage #1: 2-methylpropan-2-thiol; 4-Fluoronitrobenzene With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃;
Stage #2: With water In N,N-dimethyl-formamide; mineral oil for 0.25h;
91%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 0.5h;
methyl 2-(3-(2-bromomethyl-4-nitrophenoxy)-4-methoxyphenyl)acetate
1313757-49-1

methyl 2-(3-(2-bromomethyl-4-nitrophenoxy)-4-methoxyphenyl)acetate

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

methyl 2-(3-(2-(tert-butylthiomethyl)-4-nitrophenoxy)-4-methoxyphenyl)acetate
1313757-50-4

methyl 2-(3-(2-(tert-butylthiomethyl)-4-nitrophenoxy)-4-methoxyphenyl)acetate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 15℃; for 5h;100%
bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)
114550-41-3

bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

Ru(meso-tetrakis(4-methylphenyl)porphyrin)(t-BuSH)2
1357363-80-4

Ru(meso-tetrakis(4-methylphenyl)porphyrin)(t-BuSH)2

Conditions
ConditionsYield
In benzene at 20℃; for 24h;100%
In benzene-d6 identified by NMR;
4-fluorophenylpyridine
58861-53-3

4-fluorophenylpyridine

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

2-(4-tbutylsulfanylphenyl)pyridine
1580547-38-1

2-(4-tbutylsulfanylphenyl)pyridine

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 120℃; for 24h; Inert atmosphere;100%
8-fluoroquinoline-3-carboxylic acid
71082-53-6

8-fluoroquinoline-3-carboxylic acid

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

8-(tert-butylthio)quinoline-3-carboxylic acid
1414882-17-9

8-(tert-butylthio)quinoline-3-carboxylic acid

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 140℃; for 18h; Inert atmosphere;100%
With sodium hydride In N,N-dimethyl-formamide at 140℃; for 18h; Inert atmosphere;100%
2,6-dichloro-4-phenylpyridine
25297-51-2

2,6-dichloro-4-phenylpyridine

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

2-(tert-butylthio)-6-chloro-4-phenylpyridine

2-(tert-butylthio)-6-chloro-4-phenylpyridine

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 80℃;100%
acetic anhydride
108-24-7

acetic anhydride

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

S-tert-butyl thioacetate
999-90-6

S-tert-butyl thioacetate

Conditions
ConditionsYield
With vanadyl triflate In dichloromethane at 20℃; for 12h;99%
Stage #1: acetic anhydride With molybdenium(VI) dioxodichloride In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-methylpropan-2-thiol In dichloromethane at 20℃; for 18h;
98%
With pyridine
With perchloric acid; acetic acid
With triethylamine
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

di-tert-butyl disulfide
110-06-5

di-tert-butyl disulfide

Conditions
ConditionsYield
With nanophase manganese (VII) oxide coated clay (NM7O coated clay) In toluene at 40℃; for 2h;99%
With potassium permanganate at 20℃; for 8h;99%
With water; dihydrogen peroxide In various solvent(s) at 20℃; for 0.166667h; Oxidation; Dimerization;98%
1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

1,3-bis(tert-butylthio)propan-2-ol
101855-82-7

1,3-bis(tert-butylthio)propan-2-ol

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere;99%
With sodium 1) EtOH, 50 deg C, 30 min, 2) 6 h, reflux; Yield given. Multistep reaction;
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

1-bromo-2-[(tert-butylsulfanyl)methyl]benzene
259136-26-0

1-bromo-2-[(tert-butylsulfanyl)methyl]benzene

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran at 0 - 20℃; for 24h; Substitution;99%
Stage #1: 2-methylpropan-2-thiol With sodium hydride In tetrahydrofuran at 25℃; for 1h; Inert atmosphere;
Stage #2: 1-Bromo-2-bromomethyl-benzene In tetrahydrofuran for 18h; Inert atmosphere; Reflux;
97%
Stage #1: 2-methylpropan-2-thiol With sodium hydride In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;
Stage #2: 1-Bromo-2-bromomethyl-benzene In tetrahydrofuran for 16h; Inert atmosphere; Reflux;
94%
With sodium hydroxide In methanol; water at 20 - 40℃; for 0.5h;
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

1-[(1,1-dimethylethyl)thio]-4-methoxybenzene
7205-64-3

1-[(1,1-dimethylethyl)thio]-4-methoxybenzene

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate In 1,4-dioxane at 100℃; for 18h;99%
2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

2,6-dimethylphenyl 2-methyl-2-propyl sulfide
16463-11-9

2,6-dimethylphenyl 2-methyl-2-propyl sulfide

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate In 1,4-dioxane at 100℃; for 18h;99%
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 110℃; for 4h; Inert atmosphere;92%
Stage #1: 2-Bromo-m-xylene With dichloro[1,3-bis(2,6-di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II); lithium isopropoxide In toluene at 80℃; for 0.5h; Inert atmosphere;
Stage #2: 2-methylpropan-2-thiol With potassium tert-butylate In toluene at 40℃; for 24h; Inert atmosphere;
73%
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