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Shanghai Pinewood Fine Chemical Co., Ltd.

Name: 2-Bromo-4'-chloroacetophenone

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

α-Bromo-4-chloro acetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Bromo-4'-Chloroacetophenone supplier in China

Cas:536-38-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality 4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company

TIANFU-CHEM -4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Bromo-4'-chloroacetophenone CAS 536-38-9

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 536-38-9 with best quality

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Bromo-4'-chloroacetophenone 536-38-9

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Chloro-2'-bromoacetophenone CAS:536-38-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality o

4-Chloro-2'-bromoacetophenone CAS:536-38-9

Cas:536-38-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

low price ,high quality 4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Bromo-4'-Chloroacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply α-Bromo-4-chloroacetophenone

Cas:536-38-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shanghai Send Pharmaceutical Technology Co., Ltd.

Low price and high quality Appearance:White Storage:Preserve In Well-Closed, Light-Resistant and Tight Containers. Store In Cool & Dry Place Package:1g,5g,10g...1kg,5kg...more Application:Pharmaceutical intermediates Transportation:shipping,land,ai

4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Chloro-2'-bromoacetophenone/High quality/Best price

Cas:536-38-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Intermediate 2-Bromo-4'-chloroacetophenone Powder CAS 536-38-9

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.8

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy 4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

4-Chloro-2'-bromoacetophenone Chemical Properties Melting point 93-96 °C(lit.) Boiling point 186°C (rough estimate) density 1.5624 (rough estimate) refractive index 1.5963 (estimate) storage temp. Keep Cold form Cr

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Bromo-4'-chloroacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

4-Chloro-2'-bromoacetophenone

Cas:536-38-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:White to light yellow crystalline powder Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-Chloro-2'-bromoacetophenone cas no. 536-38-9 98%

Cas:536-38-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

4-Chloro-2'-Bromo acetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

α-Bromo-4-chloroacetophenone

Cas:536-38-9

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

para-chloroacetophenone
99-91-2

para-chloroacetophenone

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With pyridinium hydrobromide perbromide; acetic acid at 20℃; for 18h;99%
With bromine In acetic acid98%
With hydrogen bromide; bromine; acetic acid In water at 0 - 20℃;98.67%
1-(bromoethynyl)-4-chlorobenzene
33491-03-1

1-(bromoethynyl)-4-chlorobenzene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With water; copper(II) acetate monohydrate; trifluoroacetic acid at 70℃; for 6h; chemoselective reaction;93%
With water In 1,2-dichloro-ethane at 20℃; for 14h;92%
With tetrafluoroboric acid; water In 2,2,2-trifluoroethanol at 80℃; for 2h;91%
para-chloroacetophenone
99-91-2

para-chloroacetophenone

A

2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With N-Bromosuccinimide; silica gel In methanol for 0.316667h; Reflux; chemoselective reaction;A n/a
B 91%
With trimethylsilyl bromide; potassium nitrate In dichloromethane at 20℃; for 20h;A n/a
B 72%
With N-Bromosuccinimide; trimethylsilyl trifluoromethanesulfonate In acetonitrile at 20℃; for 24h;A n/a
B 89 % Spectr.
With ammonium metavanadate; aluminum tri-bromide; oxygen In acetonitrile at 80℃; for 18h;A 27 %Spectr.
B 70 %Spectr.
With copper(ll) bromide In chloroform; ethyl acetate for 5h; Reflux;
α-bromomethyl-4-chlorostyrene
89220-51-9

α-bromomethyl-4-chlorostyrene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate; C65H77N5O4S2; oxygen In 1,2-dichloro-ethane at 75℃; under 760.051 Torr; for 24h; Green chemistry; chemoselective reaction;91%
1,1-dibromo-1-(4'-chlorophenyl)ethane

1,1-dibromo-1-(4'-chlorophenyl)ethane

A

1-(1-bromovinyl)-4-chlorobenzene
89619-10-3

1-(1-bromovinyl)-4-chlorobenzene

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 90℃; Inert atmosphere;A 91%
B n/a
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; potassium bromide In water at 60℃; for 12h; Green chemistry;90%
With tris(2,2'-bipyridyl)ruthenium dichloride; Bromoform; [bis(acetoxy)iodo]benzene In 1,4-dioxane at 20℃; for 8h; Reagent/catalyst; Irradiation;88%
With hydrogen bromide; oxygen In water; ethyl acetate for 5h; Irradiation;84%
1-(1-bromovinyl)-4-chlorobenzene
89619-10-3

1-(1-bromovinyl)-4-chlorobenzene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate; 2-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)-6-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)pyridine; oxygen In ethylene dibromide at 75℃; under 760.051 Torr; for 16h; Solvent; Green chemistry; chemoselective reaction;89%
<1-(4-Chlor-phenyl)-ethyl>-benzylether
2040-38-2

<1-(4-Chlor-phenyl)-ethyl>-benzylether

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With p-nitrobenzenesulfonamide; hydrogen bromide; oxygen; sodium nitrite In water; acetonitrile at 0 - 60℃; under 760.051 Torr; for 24.5h;88%
1-(4-chlorophenyl)-2-diazoethanone
3282-33-5

1-(4-chlorophenyl)-2-diazoethanone

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With ferric(III) bromide; silica gel In dichloromethane at 20℃; for 0.166667h;85%
4-n-chlorophenylacetylene
873-73-4

4-n-chlorophenylacetylene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With N,N'-ethylenethiourea; 1,3-dibromo-5,5-dimethylhydantoin; water In acetone at 45℃;84%
Stage #1: 4-n-chlorophenylacetylene With methanol; gold(III) chloride; silver(I) triflimide In 1,4-dioxane at 45℃;
Stage #2: With N-Bromosuccinimide In 1,4-dioxane regioselective reaction;
75%
Multi-step reaction with 2 steps
1: dibromamine-T; water / acetone / 0.17 h
2: water; sodium sulfite / acetone; ethyl acetate / 20 °C
View Scheme
C15H14BrClO

C15H14BrClO

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With p-nitrobenzenesulfonamide; hydrogen bromide; oxygen; sodium nitrite In water; acetonitrile at 0 - 60℃; under 760.051 Torr; for 24.5h;84%
2,2,2-tribromo-1-(4-chlorophenyl)ethan-1-one
52119-96-7

2,2,2-tribromo-1-(4-chlorophenyl)ethan-1-one

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With water; hydrogen bromide In tetrahydrofuran at 120℃;83%
1-(p-chlorophenyl)ethyl alcohol
3391-10-4

1-(p-chlorophenyl)ethyl alcohol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With Oxone; ammonium bromide In methanol; water at 20℃; for 24h; Green chemistry;81%
With N-Bromosuccinimide In tetrahydrofuran at 20℃;
C16H17ClO2

C16H17ClO2

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With p-nitrobenzenesulfonamide; hydrogen bromide; oxygen; sodium nitrite In water; acetonitrile at 0 - 50℃; under 760.051 Torr; for 24.5h;80%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

A

2-bromo-1-(4-chlorophenyl)ethanol
6314-52-9

2-bromo-1-(4-chlorophenyl)ethanol

B

1,2-dibromo-1-(4-chlorophenyl)ethane
23135-16-2

1,2-dibromo-1-(4-chlorophenyl)ethane

C

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With sodium bromate; sulfuric acid; sodium bromide In 1,4-dioxane; water at 20℃; for 6.5h;A 12%
B 2%
C 77%
4-chloro(ethylbenzene)
622-98-0

4-chloro(ethylbenzene)

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With hydrogen bromide; oxygen In water; ethyl acetate at 20℃; for 10h; Irradiation;66%
4-chloro(ethylbenzene)
622-98-0

4-chloro(ethylbenzene)

ethyl acetate
141-78-6

ethyl acetate

A

2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With water; hydrogen bromide; oxygen for 7h; Irradiation;A 26%
B 45%
ethanol
64-17-5

ethanol

2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

A

ethyl 2-(4-chlorophenyl)-2-oxoacetate
34966-48-8

ethyl 2-(4-chlorophenyl)-2-oxoacetate

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
for 20h; Inert atmosphere; Irradiation;A 26%
B 22%
4-chloro(ethylbenzene)
622-98-0

4-chloro(ethylbenzene)

ethyl acetate
141-78-6

ethyl acetate

A

ethyl 2-(4-chlorophenyl)-2-oxoacetate
34966-48-8

ethyl 2-(4-chlorophenyl)-2-oxoacetate

B

4-chlorophenylglyoxylic acid
7099-88-9

4-chlorophenylglyoxylic acid

C

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With water; hydrogen bromide; oxygen for 20h; Irradiation;A 64 %Spectr.
B 10%
C 11%
2-bromoacetyl chloride
22118-09-8

2-bromoacetyl chloride

chlorobenzene
108-90-7

chlorobenzene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With aluminium trichloride
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 2h; Friedel-Crafts Acylation;
4-chloro-α-bromoacetophenone methyl hemiacetal
119205-36-6

4-chloro-α-bromoacetophenone methyl hemiacetal

A

methanol
67-56-1

methanol

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With hydrogen cation In water at 25℃; Rate constant;
With water at 25℃; Rate constant;
With hydroxide In water at 25℃; Rate constant;
With acetate In water at 25℃; Rate constant;
2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

A

3,5-bis(4-chlorobenzoyl)-1,2,4-thiadiazole
146692-13-9

3,5-bis(4-chlorobenzoyl)-1,2,4-thiadiazole

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

C

3-(4-chlorobenzoylformamido)-4-(4-chlorophenyl)-1,2,5-thiadiazole
163430-76-0

3-(4-chlorobenzoylformamido)-4-(4-chlorophenyl)-1,2,5-thiadiazole

Conditions
ConditionsYield
With tetrasulphur tetranitride at 115℃; for 10h;A 2 % Turnov.
B 100 mg
C 12 % Turnov.
etheric solution of 1-<4-chloro-phenyl>-ethanone-(1)

etheric solution of 1-<4-chloro-phenyl>-ethanone-(1)

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With aluminium trichloride; bromine
1-(p-chlorophenyl)ethyl alcohol
3391-10-4

1-(p-chlorophenyl)ethyl alcohol

A

2-bromo-1-(4-chlorophenyl)ethanol
6314-52-9

2-bromo-1-(4-chlorophenyl)ethanol

B

para-chloroacetophenone
99-91-2

para-chloroacetophenone

C

1-(1-bromoethyl)-4-chlorobenzene
14804-61-6

1-(1-bromoethyl)-4-chlorobenzene

D

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With para-chloroacetophenone; aluminum tri-tert-butoxide; pyridinium hydrobromide perbromide In toluene at 60℃; for 24h; Title compound not separated from byproducts;
2-bromo-1-(4-chlorophenyl)ethanol
6314-52-9

2-bromo-1-(4-chlorophenyl)ethanol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With dihydrogen peroxide In 1,4-dioxane; water at 25℃; for 10h;
1-(p-chlorophenyl)ethyl alcohol
3391-10-4

1-(p-chlorophenyl)ethyl alcohol

A

para-chloroacetophenone
99-91-2

para-chloroacetophenone

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With sodium bromate; sulfuric acid; sodium bromide In water at 60℃; for 0.166667h; Microwave irradiation;
4-chloro(ethylbenzene)
622-98-0

4-chloro(ethylbenzene)

A

2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

B

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With carbon tetrabromide; hydrogen bromide; oxygen In dichloromethane; water for 10h; Irradiation;A 6 %Spectr.
B 48 %Spectr.
1,2-dibromo-1-(4-chlorophenyl)ethane
23135-16-2

1,2-dibromo-1-(4-chlorophenyl)ethane

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide / water / 24 h / 70 °C
2: iron(III) trifluoromethanesulfonate; 2-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)-6-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)pyridine; oxygen / ethylene dibromide / 16 h / 75 °C / 760.05 Torr / Green chemistry
View Scheme
2,2-dibromo-1-(4-chlorophenyl)ethanone
13651-12-2

2,2-dibromo-1-(4-chlorophenyl)ethanone

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

Conditions
ConditionsYield
With water; sodium sulfite In ethyl acetate; acetone at 20℃;180 mg
thiourea
17356-08-0

thiourea

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

4-(4-chlorophenyl)-2-thiazolamine
2103-99-3

4-(4-chlorophenyl)-2-thiazolamine

Conditions
ConditionsYield
In ethanol at 70℃; for 1h;100%
In ethanol at 70℃; for 1h; Hantzsch Thiazole Synthesis;100%
With sodium fluoride In methanol; water at 20℃; for 0.0166667h; Reagent/catalyst; Solvent;99%
potassium cyanamide salt
29422-34-2

potassium cyanamide salt

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

(4-Amino-2-ethoxy-thiazol-5-yl)-(4-chloro-phenyl)-methanone
86690-08-6

(4-Amino-2-ethoxy-thiazol-5-yl)-(4-chloro-phenyl)-methanone

Conditions
ConditionsYield
With triethylamine In acetone for 2h; Ambient temperature;100%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

((4-chlorophenyl)amino)((2-phenylethyl)amino)methane-1-thione
93360-14-6

((4-chlorophenyl)amino)((2-phenylethyl)amino)methane-1-thione

(4-Chloro-phenyl)-[4-(4-chloro-phenyl)-3-phenethyl-3H-thiazol-(2Z)-ylidene]-amine; hydrobromide

(4-Chloro-phenyl)-[4-(4-chloro-phenyl)-3-phenethyl-3H-thiazol-(2Z)-ylidene]-amine; hydrobromide

Conditions
ConditionsYield
In ethanol for 4h; Heating;100%
2,6-dimethyl-1,5-dihydroxynaphthalene
123979-29-3

2,6-dimethyl-1,5-dihydroxynaphthalene

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2,6-dimethyl-1,5-bis-1-(4-chlorophenyl)-1-oxo-2-ethoxy)naphthalene

2,6-dimethyl-1,5-bis-1-(4-chlorophenyl)-1-oxo-2-ethoxy)naphthalene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;100%
2-Iodophenol
533-58-4

2-Iodophenol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

1-(4-chlorophenyl)-2-(2-iodophenoxy)ethan-1-one

1-(4-chlorophenyl)-2-(2-iodophenoxy)ethan-1-one

Conditions
ConditionsYield
With potassium carbonate In acetone at 80℃; for 4h;100%
With potassium carbonate In acetone Heating;
With potassium carbonate In acetone Heating;
With potassium carbonate In acetone at 60℃;3.39 g
(phenylaminothioyl)ethyl carbamate Wang resin

(phenylaminothioyl)ethyl carbamate Wang resin

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

N-[3-(2-aminoethyl)-4-(4-chlorophenyl)-1,3-thiazol-2(3H)-ylidene]aniline

N-[3-(2-aminoethyl)-4-(4-chlorophenyl)-1,3-thiazol-2(3H)-ylidene]aniline

Conditions
ConditionsYield
Stage #1: (phenylaminothioyl)ethyl carbamate Wang resin; 4-chlorobenzoylmethyl bromide In 1,2-dimethoxyethane at 80℃; for 2h;
Stage #2: With trifluoroacetic acid In dichloromethane for 1.5h;
Stage #3: With aluminum oxide In methanol
100%
4-{[(phenylethylamino)carbothioyl]amino}-phenylethyl carbamate Wang resin

4-{[(phenylethylamino)carbothioyl]amino}-phenylethyl carbamate Wang resin

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

4-(2-aminoethyl)-N-[4-(4-chlorophenyl)-3-phenethyl-1,3-thiazol-2(3H)-ylidene]aniline

4-(2-aminoethyl)-N-[4-(4-chlorophenyl)-3-phenethyl-1,3-thiazol-2(3H)-ylidene]aniline

Conditions
ConditionsYield
Stage #1: 4-{[(phenylethylamino)carbothioyl]amino}-phenylethyl carbamate Wang resin; 4-chlorobenzoylmethyl bromide In DMF (N,N-dimethyl-formamide) at 80℃; for 2h;
Stage #2: With trifluoroacetic acid In dichloromethane at 20℃; for 1.5h;
Stage #3: With aluminum oxide In methanol
100%
(R)-2-thiocarbamoyl-piperidine-1-carboxylic acid tert-butyl ester
1089729-72-5

(R)-2-thiocarbamoyl-piperidine-1-carboxylic acid tert-butyl ester

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

(R)-2-[4-(4-chloro-phenyl)-thiazol-2-yl]-piperidine-1-carboxylic acid tert-butyl ester
1089729-73-6

(R)-2-[4-(4-chloro-phenyl)-thiazol-2-yl]-piperidine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: (R)-2-thiocarbamoyl-piperidine-1-carboxylic acid tert-butyl ester; 4-chlorobenzoylmethyl bromide With sodium hydrogencarbonate In 1,2-dimethoxyethane at 20℃; for 24h;
Stage #2: With pyridine; trifluoroacetic anhydride In 1,2-dimethoxyethane at 0 - 20℃; for 0.5h;
100%
isoquinoline
119-65-3

isoquinoline

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-(2-(4-chlorophenyl)-2-oxoethyl)isoquinolin-2-ium bromide
57269-96-2

2-(2-(4-chlorophenyl)-2-oxoethyl)isoquinolin-2-ium bromide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.333333h;100%
In dichloromethane at 20℃; for 24h;
With cetyltrimethylammonim bromide In water at 20℃; for 0.5h;
2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

C12H15ClOS
88577-88-2

C12H15ClOS

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 16h;100%
tert-butyl 4-carbamothioylpiperidine-1-carboxylate
214834-18-1

tert-butyl 4-carbamothioylpiperidine-1-carboxylate

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

tert-butyl 4-(4-(4-chlorophenyl)thiazol-2-yl)piperidine-1-carboxylate

tert-butyl 4-(4-(4-chlorophenyl)thiazol-2-yl)piperidine-1-carboxylate

Conditions
ConditionsYield
In ethanol at 80℃; for 1h;100%
In N,N-dimethyl-formamide at 20℃; for 2h;
In ethanol Hantzsch Thiazole Synthesis; Reflux;
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

C10H11ClO2S
1157217-46-3

C10H11ClO2S

Conditions
ConditionsYield
at 20℃; for 18h;100%
4-chlorobenzaldehyde thiosemicarbazone
5706-80-9

4-chlorobenzaldehyde thiosemicarbazone

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

1-(4-chlorobenzylidene)-2-[4-(4-chlorophenyl)thiazol-2-yl]hydrazine

1-(4-chlorobenzylidene)-2-[4-(4-chlorophenyl)thiazol-2-yl]hydrazine

Conditions
ConditionsYield
In isopropyl alcohol Reflux;100%
2-(N-t-butoxycarbonylamino)thioacetamide
89226-13-1

2-(N-t-butoxycarbonylamino)thioacetamide

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

[4-(4-chlorophenyl)thiazol-2-yl]methylamine hydrochloride

[4-(4-chlorophenyl)thiazol-2-yl]methylamine hydrochloride

Conditions
ConditionsYield
Stage #1: 2-(N-t-butoxycarbonylamino)thioacetamide; 4-chlorobenzoylmethyl bromide In ethanol at 20℃;
Stage #2: With hydrogenchloride In 1,4-dioxane; ethanol at 20℃; for 2h;
100%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

4-methyl-N-{2-(phenylethynyl)phenyl}benzenesulfonamide
442155-91-1

4-methyl-N-{2-(phenylethynyl)phenyl}benzenesulfonamide

N-(2-(4-chlorophenyl)-2-oxoethyl)-4-methyl-N-(2-(phenylethynyl)phenyl)benzenesulfonamide

N-(2-(4-chlorophenyl)-2-oxoethyl)-4-methyl-N-(2-(phenylethynyl)phenyl)benzenesulfonamide

Conditions
ConditionsYield
Stage #1: 4-methyl-N-{2-(phenylethynyl)phenyl}benzenesulfonamide With potassium carbonate In N,N-dimethyl-formamide at 0℃; for 0.5h;
Stage #2: 4-chlorobenzoylmethyl bromide In N,N-dimethyl-formamide at 20℃;
100%
Stage #1: 4-methyl-N-{2-(phenylethynyl)phenyl}benzenesulfonamide With potassium carbonate In N,N-dimethyl-formamide at 0℃; for 0.5h;
Stage #2: 4-chlorobenzoylmethyl bromide In N,N-dimethyl-formamide at 20℃;
77%
C16H25N3OS

C16H25N3OS

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

(E)-2,6-di-tert-butyl-4-((2-(4-(4-chlorophenyl)thiazol-2-yl)hydrazono)methyl) phenol

(E)-2,6-di-tert-butyl-4-((2-(4-(4-chlorophenyl)thiazol-2-yl)hydrazono)methyl) phenol

Conditions
ConditionsYield
100%
selenosemicarbazide
21198-79-8

selenosemicarbazide

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-imino-5-(4-chlorophenyl)-6H-1,3,4-selenadiazine

2-imino-5-(4-chlorophenyl)-6H-1,3,4-selenadiazine

Conditions
ConditionsYield
Stage #1: selenosemicarbazide; 4-chlorobenzoylmethyl bromide In ethanol at 20℃; Reflux;
Stage #2: With ammonium hydroxide In ethanol pH=8;
100%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

quinidine
56-54-2

quinidine

C28H30ClN2O3(1+)*Br(1-)

C28H30ClN2O3(1+)*Br(1-)

Conditions
ConditionsYield
In tetrahydrofuran Inert atmosphere;100%
(piperidin-4-yl)carbamic acid tert-butyl ester
73874-95-0

(piperidin-4-yl)carbamic acid tert-butyl ester

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

tert-butyl (1-(2-(4-chlorophenyl)-2-oxoethyl)piperidin-4-yl)carbamate

tert-butyl (1-(2-(4-chlorophenyl)-2-oxoethyl)piperidin-4-yl)carbamate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 90℃; Sealed tube;100%
2-aminopyridine
504-29-0

2-aminopyridine

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-(4-chlorophenyl)imidazolo[1,2-a]pyridine
38922-74-6

2-(4-chlorophenyl)imidazolo[1,2-a]pyridine

Conditions
ConditionsYield
In neat (no solvent) at 25 - 30℃; Milling; Green chemistry;99%
Stage #1: 2-aminopyridine; 4-chlorobenzoylmethyl bromide In ethanol for 3h; Reflux;
Stage #2: With sodium hydrogencarbonate In ethanol for 4h; Reflux;
96%
In water; isopropyl alcohol at 75℃; Microwave irradiation; Green chemistry;95%
2-Amino-4-methylpyridine
695-34-1

2-Amino-4-methylpyridine

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-(4-chlorophenyl)-7-methyl-imidazo[1,2-a]pyridine
65964-62-7

2-(4-chlorophenyl)-7-methyl-imidazo[1,2-a]pyridine

Conditions
ConditionsYield
In neat (no solvent) at 25 - 30℃; Milling; Green chemistry;99%
With sodium hydrogencarbonate In ethanol for 20h; Reflux;79%
With ethanol
With sodium carbonate In ethanol for 1h; Reflux;
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

1-(2-bromo-1-chloroethyl)-4-chlorobenzene
109275-35-6

1-(2-bromo-1-chloroethyl)-4-chlorobenzene

Conditions
ConditionsYield
With indium(III) hydroxide; dimethylmonochlorosilane In chloroform at 20℃; for 4h;99%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

3-[1-Dimethylamino-meth-(E)-ylidene]-1,1-diethyl-thiourea

3-[1-Dimethylamino-meth-(E)-ylidene]-1,1-diethyl-thiourea

5-(4'-chlorobenzoyl)-2-N,N-diethylamino-1,3-thiazole

5-(4'-chlorobenzoyl)-2-N,N-diethylamino-1,3-thiazole

Conditions
ConditionsYield
In tetrahydrofuran for 2h; Heating;99%
4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

1-(4-chlorophenyl)-2-[(4-methoxyphenyl)sulfanyl]-1-ethanone

1-(4-chlorophenyl)-2-[(4-methoxyphenyl)sulfanyl]-1-ethanone

Conditions
ConditionsYield
With triethylamine In ethanol at 20℃;99%
With potassium hydroxide In methanol; water at 15℃; for 1h;
papaveraldine
522-57-6

papaveraldine

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

p-chlorophenacylpapaveraldinium bromide

p-chlorophenacylpapaveraldinium bromide

Conditions
ConditionsYield
In acetone for 360h; Heating;99%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

2-methylcyclohexylidene-thiosemicarbazone

2-methylcyclohexylidene-thiosemicarbazone

C16H18ClN3S
1049014-19-8

C16H18ClN3S

Conditions
ConditionsYield
In isopropyl alcohol at 20℃; for 2h;99%
In ethanol at 20℃; Hantzsch reaction;
Stage #1: 4-chlorobenzoylmethyl bromide; 2-methylcyclohexylidene-thiosemicarbazone In methanol for 0.0166667h; Hantzsch Thiazole Synthesis;
Stage #2: In methanol at 90℃; for 0.166667h; Hantzsch Thiazole Synthesis; Microwave irradiation;
4-pentafluorosulfanylbenzoselenoamide
1597437-97-2

4-pentafluorosulfanylbenzoselenoamide

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

4-(4′-chlorophenyl)-2-(4″-pentafluorosulfanylphenyl)-1,3-selenazole
1597437-98-3

4-(4′-chlorophenyl)-2-(4″-pentafluorosulfanylphenyl)-1,3-selenazole

Conditions
ConditionsYield
In ethanol for 2h; Reflux; Inert atmosphere; Schlenk technique;99%
1-methyl-1H-indole-2,3-dione
2058-74-4

1-methyl-1H-indole-2,3-dione

4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

(E)-3’-(4-chlorobenzoyl)-1-methylspiro[indoline-3,2’-oxiran]-2-one

(E)-3’-(4-chlorobenzoyl)-1-methylspiro[indoline-3,2’-oxiran]-2-one

Conditions
ConditionsYield
With potassium carbonate In ethanol at 20℃; Darzens Condensation;99%
4-chlorobenzoylmethyl bromide
536-38-9

4-chlorobenzoylmethyl bromide

saccharin
81-07-2

saccharin

2-[2-(4-chlorophenyl)-2-oxoethyl]-1,2-benzisothiazol-3(2H)-one 1,1-dioxide
41335-62-0

2-[2-(4-chlorophenyl)-2-oxoethyl]-1,2-benzisothiazol-3(2H)-one 1,1-dioxide

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 20℃; for 10h;99%
With triethylamine In N,N-dimethyl-formamide at 20℃; for 9h;
With triethylamine In N,N-dimethyl-formamide

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