Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:578-57-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:578-57-4
Min.Order:1 Metric Ton
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Type:Manufacturers
inquiryChemwill Asia co.,Ltd is one of the leading manufacturer in CHINA. Product quality, process, price and service 2-Bromoanisole CAS 578-57-4 1-Bromo-2-methoxy-benzene IN STOCK o-bromoanisole CAS 578-57-4 578-57-4 CAS 578-57-4 highly quality
Cas:578-57-4
Min.Order:5 Kiloliter
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Type:Manufacturers
inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:578-57-4
Min.Order:1 Metric Ton
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inquiryProduct Description Name 2-Bromoanisole CAS 578-57-4 Assay 99% Appearance C
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
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inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:578-57-4
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:578-57-4
Min.Order:1 Kilogram
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Type:Trading Company
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:578-57-4
Min.Order:10 Kilogram
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Type:Trading Company
inquiryProduct name: 2-Bromoanisole CAS : 578-57-4 Appearance: Light yellow liquid Content: 99% Appearance:Light yellow liquid Storage:Preserve in well-closed, light-resistant and airtight containers. Package:25kg/drum Application: Flavours & Fragrances Int
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:578-57-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryhigh quality 2-Bromoanisole Basic information Product Name: 2-Bromoanisole Synonyms: 1-bromo-2-methoxy-benzen;2-Bromo-1-methoxybenzene;2-Methoxybromobenzene;2-Met
Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:578-57-4
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:578-57-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:578-57-4
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiry1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s
Cas:578-57-4
Min.Order:1 Kilogram
FOB Price: $30.0 / 50.0
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:578-57-4
Min.Order:0
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:578-57-4
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryo-bromoanisoleAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB
Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an
We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:2-Bromoanisole CAS No:578-57-4 Synonym
GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
2-Bromoanisole Chemical Properties Melting point 2 °C (lit.) Boiling point 223 °C (lit.) density 1.502 g/mL at 25 °C (lit.) refractive index n20/D 1.573(lit.) Fp 206 °F storage temp. Store below +30°C. solu
Cas:578-57-4
Min.Order:200 Kilogram
FOB Price: $65.0
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:578-57-4
Min.Order:1 Kilogram
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Type:Trading Company
inquiryLocated in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and
Cas:578-57-4
Min.Order:1 Gram
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Type:Other
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
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Min.Order:1 Gram
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Type:Lab/Research institutions
inquirymethoxybenzene
A
1-bromo-4-methoxy-benzene
B
2-bromoanisole
C
2,4-dibromoanisole
Conditions | Yield |
---|---|
With bromine; tetramethylammonium bromide In liquid sulphur dioxide at -23℃; Rate constant; Product distribution; Thermodynamic data; in H2O at 25 deg C, NaBr, HClO4; ΔH (excit), -ΔS (excit); | A 98.99% B 0.56% C 0.43% |
With (CH3)4Br In liquid sulphur dioxide at -23℃; Kinetics; Thermodynamic data; Product distribution; ΔH(excit.); ΔS(excit.); | A 98.99% B 0.56% C 0.43% |
With (CH3)4Br In liquid sulphur dioxide at -23℃; | A 98.99% B 0.56% C 0.43% |
Conditions | Yield |
---|---|
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent; | 98% |
Stage #1: 2-methoxy-phenylamine With tert.-butylnitrite In dichloromethane; water at 0℃; for 0.166667h; Stage #2: With carbon tetrabromide; dimethylglyoxal In dichloromethane; water at 15 - 35℃; for 16h; | 78% |
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 23h; | 74% |
Conditions | Yield |
---|---|
With Oxone; potassium bromide In methanol at 20℃; for 1h; | A 97% B 2% |
With Oxone; potassium bromide In acetonitrile at 20℃; for 24h; | A 84% B 15% |
With PyHBrCl2 In methanol at 20℃; for 0.0833333h; | A 78% B 18% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h; | 97% |
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube; | 82% |
With 1,10-Phenanthroline; oxygen; potassium bromide; copper(ll) bromide In N,N-dimethyl-formamide at 130℃; for 20h; | 67% |
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sodium methylate In methanol; water; acetonitrile at 23℃; | 94 % Chromat. |
Conditions | Yield |
---|---|
Stage #1: 2-hydroxybromobenzene With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1.16667h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 20℃; for 19h; Inert atmosphere; Reflux; | 97% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2.5h; Inert atmosphere; | 96% |
With potassium hydroxide In CD2Cl2; hexane; acetonitrile | 89% |
Conditions | Yield |
---|---|
With potassium carbonate at 60℃; for 0.3h; Williamson synthesis; | 94% |
With sodium hydroxide | |
With potassium hydroxide | |
With sodium hydroxide for 3h; Heating; | |
With potassium carbonate In acetone Inert atmosphere; |
Conditions | Yield |
---|---|
With potassium phosphate; tetrabuthylammonium tribromide In acetonitrile at 100℃; for 16h; Reagent/catalyst; | 90% |
Conditions | Yield |
---|---|
With sodium carbonate In N,N-dimethyl-formamide at 120℃; for 4h; | 90% |
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0583333h; microwave irradiation; | 84% |
With leucine intercalated Mg-Al layered double hydorxide at 180℃; for 6h; Autoclave; Green chemistry; chemoselective reaction; | 87 %Chromat. |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 25℃; for 3h; Inert atmosphere; Schlenk technique; | 84% |
2-bromoanisole
Conditions | Yield |
---|---|
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h; | 75% |
Conditions | Yield |
---|---|
With boron trifluoride In diethyl ether for 0.0416667h; microwave irradiation; | 74% |
Conditions | Yield |
---|---|
With butyl magnesium bromide; zirconocene dichloride In tetrahydrofuran for 3h; Ambient temperature; | A 72% B 22% |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube; | A 64% B 20% |
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube; | A 12% B 26% |
Conditions | Yield |
---|---|
With potassium phosphate; bromine In acetonitrile at 100℃; for 4h; Reagent/catalyst; | A 26% B 56% |
2-bromoanisole
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 55% |
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution; | 53% |
(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate
2-bromoanisole
Conditions | Yield |
---|---|
With copper(I) bromide In acetonitrile at 80℃; for 2h; | 47% |
2-Methoxybenzoic acid
A
2-bromoanisole
B
2,4-dibromoanisole
C
5-bromo-2-methoxybenzoic acid
Conditions | Yield |
---|---|
With potassium phosphate; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In acetonitrile at 100℃; for 4h; | A 40% B 7% C 32% |
Conditions | Yield |
---|---|
With dibromodifluoromethane; ISOPROPYLAMIDE; copper at 150℃; for 8h; Further byproducts given; | 11% |
diethyl ether
2,4-dibromoanisole
A
1-bromo-4-methoxy-benzene
B
2-bromoanisole
C
methoxybenzene
Conditions | Yield |
---|---|
With potassium hydroxide; methyl iodide | |
With diazomethane; diethyl ether | |
(methylation); |
Conditions | Yield |
---|---|
With potassium hydroxide |
2,6-dibromoanisole
2-bromoanisole
Conditions | Yield |
---|---|
With water; isopropylmagnesium chloride 1) THF, 40 deg C, 3 h; 2) 0 deg C; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With N-chloro-succinimide; sodium bromide In methanol for 0.0833333h; Ambient temperature; Yield given; | |
With N-chloro-succinimide; sodium bromide In methanol for 0.0833333h; Ambient temperature; |
Conditions | Yield |
---|---|
With carbon monoxide at 180℃; |
ethyl bromide
diethyl ether
2,4-dibromoanisole
A
1-bromo-4-methoxy-benzene
B
2-bromoanisole
C
methoxybenzene
O-allyl-2-bromophenol
methyl iodide
A
2-bromoanisole
B
methoxybenzene
Conditions | Yield |
---|---|
Stage #1: O-allyl-2-bromophenol With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; palladium dichloride In N,N-dimethyl-formamide at 20℃; Reduction; Electrochemical reaction; Stage #2: methyl iodide With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 12h; Methylation; |
2-Methoxyphenylboronic acid
A
2-bromoanisole
B
2,4-dibromoanisole
C
5-bromo-2-methoxyphenylboronic acid
Conditions | Yield |
---|---|
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In water; acetonitrile at 40℃; for 4h; | A 45 % Chromat. B 18 % Chromat. C 34 % Chromat. |
2-bromoanisole
2,4-dibromoanisole
Conditions | Yield |
---|---|
With (CH3)4Br In liquid sulphur dioxide at -23℃; Rate constant; | 100% |
With (CH3)4Br In liquid sulphur dioxide at -23℃; | 100% |
With N-Bromosuccinimide; iodine In acetonitrile for 12h; Darkness; | 99% |
With dihydrogen peroxide; ammonium bromide; acetic acid at 20℃; for 12h; | 54% |
With bromine; tetramethylammonium bromide In liquid sulphur dioxide at -23℃; Product distribution; Rate constant; |
Conditions | Yield |
---|---|
With di-tert-butyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water at 50℃; for 24h; Solvent; Temperature; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Glovebox; | 100% |
With di-tert-butyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water at 50℃; Reagent/catalyst; Solvent; Temperature; Suzuki Coupling; Inert atmosphere; Glovebox; | 100% |
With sodium carbonate In water at 100℃; Suzuki-Miyaura reaction; | 99.1% |
Conditions | Yield |
---|---|
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; Reflux; | 100% |
With bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate; palladium dichloride In toluene at 80℃; for 3h; | 97% |
With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate In toluene at 80℃; for 3h; | 94% |
Conditions | Yield |
---|---|
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78 - 22℃; for 20h; Inert atmosphere; | 100% |
Stage #1: 2-bromoanisole With magnesium; lithium chloride In tetrahydrofuran at 50℃; for 0.125h; Flow reactor; Stage #2: benzaldehyde In tetrahydrofuran at 20℃; for 0.333333h; Flow reactor; | 95% |
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere; Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; for 17h; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With caesium carbonate; diisopropyl(2-tert-butyl)phenoxyphosphine; RhCl(PPh3)3 In toluene for 18h; Heating; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura reaction; | 100% |
With Pd/C; potassium carbonate In ethanol; water at 100℃; for 3h; Suzuki-Miyaura Coupling; | 95% |
With cetyltrimethylammonim bromide; sodium hydroxide In water at 25℃; for 1h; Catalytic behavior; Suzuki Coupling; Microwave irradiation; | 94% |
tert-Butyl acrylate
2-bromoanisole
tert-butyl (E)-3-(2-methoxyphenyl)prop-2-enoate
Conditions | Yield |
---|---|
With IMes-Pd(dmba)Cl; potassium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 18h; Heck-Mizoroki reaction; Inert atmosphere; | 100% |
With dichlorobis(1,4-dimesityl-1H-1,2,3-triazol-5-ylidene)palladium(II); sodium acetate In N,N-dimethyl acetamide at 150℃; for 8h; Mizoroki-Heck reaction; Inert atmosphere; optical yield given as %de; | 51% |
With C4H7Cl2Pd(1-)*C27H39N2(1+); potassium carbonate In N,N-dimethyl-formamide at 100℃; for 40h; Heck Reaction; Sealed tube; | 51% |
2-bromoanisole
2-Cyanophenylboronic acid
Conditions | Yield |
---|---|
With sodium tetrachloropalladate(II); 2-(1-(1-phenylethylamino)methyl)pyridine In water; N,N-dimethyl-formamide at 110℃; for 16h; Suzuki-Miyaura coupling; | 100% |
2-bromoanisole
(S,S)-1,2-diphenyl-1,2-diaminoethane
Conditions | Yield |
---|---|
Stage #1: (S,S)-1,2-diphenyl-1,2-diaminoethane With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 20℃; for 1.5h; Inert atmosphere; Schlenk technique; Glovebox; Stage #2: 2-bromoanisole In toluene at 120℃; for 9h; Inert atmosphere; Schlenk technique; Glovebox; | 100% |
2-bromoanisole
cyclohexanecarbaldehyde
cyclohexyl (2-methoxyphenyl)methanol
Conditions | Yield |
---|---|
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran for 6.16667h; Sealed tube; Inert atmosphere; Reflux; Stage #2: cyclohexanecarbaldehyde In tetrahydrofuran at 20℃; Sealed tube; Inert atmosphere; | 100% |
3,7-dimethyl-oct-6-enal
2-bromoanisole
Conditions | Yield |
---|---|
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Stage #2: 3,7-dimethyl-oct-6-enal In tetrahydrofuran at 20℃; for 1.25h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); formaldehyd; caesium carbonate In dimethyl sulfoxide at 80℃; for 12h; | 99% |
With butyl magnesium bromide; zirconocene dichloride for 12h; Ambient temperature; | 98% |
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction; | 98% |
2-bromoanisole
2-methoxyphenyllithium
Conditions | Yield |
---|---|
With n-butyllithium In hexane; pentane at 0 - 20℃; for 1h; Inert atmosphere; | 99% |
With n-butyllithium In hexane; pentane at 0 - 20℃; | 97% |
With n-butyllithium In hexane; pentane at 20℃; in evacuated, closed vessel; |
Conditions | Yield |
---|---|
With lithium perchlorate at 100℃; for 5h; | 99% |
With aluminum (III) chloride In dichloromethane at 20 - 40℃; Friedel-Crafts acylation; Inert atmosphere; | 96% |
With aluminium trichloride In dichloromethane | 68% |
Conditions | Yield |
---|---|
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 110℃; for 2h; Inert atmosphere; | 99% |
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux; | 97% |
With copper(l) iodide; N,N'-dihexyloxalamide; potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; Sealed tube; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry; | 99% |
With dicyclohexyl(2-methoxy-6-methylbiphenyl-2,-yl)phosphine; potassium tert-butylate; palladium diacetate In 1,4-dioxane at 160℃; for 0.25h; Microwave irradiation; Inert atmosphere; | 80% |
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate at 80℃; for 29h; Arylation; | 77% |
Conditions | Yield |
---|---|
With (1-adamantyl)di(tert-butyl) phosphine; triethylamine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 20℃; for 20h; Heck reaction; | 99% |
With C27H21F3N6OPd; tetrabutylammomium bromide; sodium acetate at 140℃; for 12h; Heck reaction; Inert atmosphere; | 89% |
With potassium phosphate In N,N-dimethyl-formamide at 130℃; for 15h; Heck Reaction; | 84% |
Conditions | Yield |
---|---|
With potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; for 0.166667h; Suzuki cross-coupling reaction; | 99% |
With Ph2P(CH2CH2O)22CH3; triethylamine; palladium dichloride In water at 100℃; for 1h; Suzuki coupling; Inert atmosphere; | 98% |
With potassium carbonate; Co0.38Fe0.57LaO3Pd0.05 In isopropyl alcohol at 80℃; for 1h; Suzuki reaction; | 89% |
2-bromoanisole
o-cyanophenylboronic acid-1,3-propylene glycol ester
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate In toluene for 1h; Heating; | 99% |
Conditions | Yield |
---|---|
With (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene)PdCl2(triethylamine); potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 6h; Buchwald-Hartwig Coupling; Sealed tube; | 99% |
With potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 6h; Buchwald-Hartwig Coupling; | 99% |
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 99% |
methanol
2-bromoanisole
carbon monoxide
2-methoxybenzoic acid methyl ester
Conditions | Yield |
---|---|
With dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II); triethylamine at 100℃; under 2585.74 Torr; for 16h; | 99% |
1-phenylmethyl-4-piperidone
2-bromoanisole
1-benzyl-4-(2-methoxyphenyl)piperidin-4-ol
Conditions | Yield |
---|---|
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran Grignard reaction; Inert atmosphere; Reflux; Stage #2: 1-phenylmethyl-4-piperidone In tetrahydrofuran at 20℃; for 3h; Grignard reaction; Inert atmosphere; Cooling with ice; | 99% |
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -70 - 1℃; Stage #2: 1-phenylmethyl-4-piperidone In tetrahydrofuran at 20℃; | 23.1% |
2-bromoanisole
triisopropylsilanethiol
Conditions | Yield |
---|---|
With (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; lithium hexamethyldisilazane In toluene at 110℃; Inert atmosphere; | 99% |
With caesium carbonate; triphenylphosphine; palladium diacetate In toluene at 100℃; for 16h; | 33% |
Conditions | Yield |
---|---|
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 99% |
With potassium tert-butylate; (ϖ-allyl)(diphosphinecyclobutene)palladium at 20℃; for 12h; | 97% |
With potassium phosphate; copper(l) iodide In diethylene glycol at 70℃; for 14h; Sealed tube; | 93% |
2-bromoanisole
Pentafluorobenzene
2,3,4,5,6-pentafluoro-2′-methoxy-1,1′-biphenyl
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium carbonate In Isopropyl acetate at 80℃; for 12h; | 99% |
With potassium phosphate; chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium (II); Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; Glovebox; | 96% |
With potassium phosphate; chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II); Trimethylacetic acid In N,N-dimethyl acetamide at 80℃; for 2 - 4h; | 96% |
Conditions | Yield |
---|---|
With sodium methylate; nickel diacetate In 1,4-dioxane at 110℃; | 99% |
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; trichlorophosphate at 165℃; for 24h; Inert atmosphere; | 67% |
Conditions | Yield |
---|---|
With caesium carbonate; copper(I) oxide In N,N-dimethyl-formamide at 110℃; for 18h; | 99% |
With copper diacetate; sodium hydroxide; 3-(diphenylphosphino)propionic acid In 1,4-dioxane at 120℃; for 36h; Sealed tube; | 51% |
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