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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 58109-40-3 Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Iodonium Diphenyl Hexafluorophosphate Diphenyliodonium hexafluorophosphate Basic information Product Name: Diphenyliodonium hexafluorophosphate Synonyms: iodonium diphenyl hexafluoroph

Iodonium Diphenyl Hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 58109-40-3 with best quality

Cas:58109-40-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Iodonium Diphenyl Hexafluorophosphate

Cas:58109-40-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Diphenyliodonium hexafluorophosphate 58109-40-3

Cas:58109-40-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Diphenyliodonium hexafluorophosphate CAS:58109-40-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qual

Diphenyliodonium hexafluorophosphate CAS:58109-40-3

Cas:58109-40-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

FOB Price: $130.0 / 190.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Iodonium Diphenyl Hexafluorophosphate

Cas:58109-40-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Diphenyliodonium hexafluorophosphate(DIHP)

Cas:58109-40-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Iodonium Diphenyl Hexafluorophosphate

Cas:58109-40-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Iodonium Diphenyl Hexafluorophosphate CAS No.:58109-40-3 Molecule Formula:C12H10F6IP Molecule Weight:426.08 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING

High Quality Iodonium Diphenyl Hexafluorophosphate on stock

Cas:58109-40-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Diphenyliodonium Hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Greenutra Resource Inc

Diphenyliodonium hexafluorophosphateAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Diphenyliodonium hexafluorophosphate

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Other

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Iodonium Diphenyl Hexafluorophosphate CAS 58109-40-3

Cas:58109-40-3

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

iodobenzene
591-50-4

iodobenzene

benzene
71-43-2

benzene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With hexafluorophosphoric acid; 3-chloro-benzenecarboperoxoic acid
diphenyliodonium 4-nitrophenolate

diphenyliodonium 4-nitrophenolate

A

potassium 4-nitrophenolate
1124-31-8

potassium 4-nitrophenolate

B

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With potassium hexafluorophosphate In acetonitrile at 20℃; Equilibrium constant; Temperature; Inert atmosphere;
diphenyliodonium 4-nitrophenolate

diphenyliodonium 4-nitrophenolate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

A

tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

B

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(allylsulfonyl)benzene
16212-05-8

(allylsulfonyl)benzene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

trans-cinnamyl phenyl sulfone
16212-07-0

trans-cinnamyl phenyl sulfone

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 22h;99%
indole
120-72-9

indole

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-phenyl-indole
948-65-2

2-phenyl-indole

Conditions
ConditionsYield
Stage #1: indole With C64H56N6P2Pd2 In acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate In acetic acid at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
Stage #1: indole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
5-methyl-2-pyridone
1003-68-5

5-methyl-2-pyridone

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Pirfenidone
53179-13-8

Pirfenidone

Conditions
ConditionsYield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.5h; Inert atmosphere;99%
diphenyl sulfide
139-66-2

diphenyl sulfide

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

triphenylsulphonium hexafluorophosphate
57835-99-1

triphenylsulphonium hexafluorophosphate

Conditions
ConditionsYield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; for 0.0333333h; Inert atmosphere; Microwave irradiation;98%
1,2-diacetoxy-3-butene
18085-02-4

1,2-diacetoxy-3-butene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-4-phenylbut-3-ene-1,2-diyl diacetate
119420-99-4

(E)-4-phenylbut-3-ene-1,2-diyl diacetate

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 20h;98%
1-methylindole
603-76-9

1-methylindole

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

1-methyl-2-phenyl-1H-indole
3558-24-5

1-methyl-2-phenyl-1H-indole

Conditions
ConditionsYield
With Pd2[(C6H4)PPh2]2[CF3C(O)CHC(O)CF3]2 In acetic acid at 24.84℃; for 30h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Inert atmosphere; Schlenk technique;98%
Stage #1: 1-methylindole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 10h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
97%
2-(phenylthio)thioxanthone
1195763-38-2

2-(phenylthio)thioxanthone

potassium trifluorotris(pentafluoroethyl)phosphate
123215-04-3

potassium trifluorotris(pentafluoroethyl)phosphate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

Conditions
ConditionsYield
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
98%
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
1-(1H-inden-3-yl)cyclopentan-1-ol

1-(1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;98%
1-(1H-inden-3-yl)cyclopentan-1-ol

1-(1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(1S,2'R)-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

(1S,2'R)-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;98%
dibenzo-18-crown-6
14187-32-7

dibenzo-18-crown-6

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyliodonium hexafluorophosphate-dibenzo-18-crown-6 ether complex

diphenyliodonium hexafluorophosphate-dibenzo-18-crown-6 ether complex

Conditions
ConditionsYield
In ethyl acetate for 0.0833333h; Reflux;97.6%
(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)diphenylsulfonium hexafluorophosphate (V)

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)diphenylsulfonium hexafluorophosphate (V)

Conditions
ConditionsYield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; Inert atmosphere; Microwave irradiation; Darkness;97%
tris(trifluoromethanesulfonyl)methide potassium salt
114395-69-6

tris(trifluoromethanesulfonyl)methide potassium salt

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

C4F9O6S3(1-)*C12H10I(1+)
182505-78-8

C4F9O6S3(1-)*C12H10I(1+)

Conditions
ConditionsYield
In ethyl acetate at 20℃; for 1h;97%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyl sulphone
127-63-9

diphenyl sulphone

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere;96%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

1-(3,4-dihydro-2H-pyran-6-yl)cyclopentan-1-ol
74938-47-9

1-(3,4-dihydro-2H-pyran-6-yl)cyclopentan-1-ol

(5R,10R)-10-phenyl-6-oxaspiro[4.5]decan-1-one

(5R,10R)-10-phenyl-6-oxaspiro[4.5]decan-1-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 36h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;96%
1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;96%
1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(1S,2'R)-5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

(1S,2'R)-5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;96%
(Z)-3-(1-((tert-butyldimethylsilyl)oxy)-5-phenylpent-1-en-1-yl)oxazolidin-2-one
1330660-53-1

(Z)-3-(1-((tert-butyldimethylsilyl)oxy)-5-phenylpent-1-en-1-yl)oxazolidin-2-one

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-3-(2,5-diphenylpentanoyl)oxazolidin-2-one
1330660-76-8

(S)-3-(2,5-diphenylpentanoyl)oxazolidin-2-one

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at -10℃; for 24h; optical yield given as %ee; enantioselective reaction;95%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

benzonitrile
100-47-0

benzonitrile

phenylpropynoic acid ethyl ester
2216-94-6

phenylpropynoic acid ethyl ester

ethyl 2,4-diphenylquinoline-3-carboxylate
17282-90-5

ethyl 2,4-diphenylquinoline-3-carboxylate

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 120℃; Inert atmosphere; Sealed tube; regioselective reaction;95%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

6-phenyl-5-hexyne-1-nitrile
152858-50-9

6-phenyl-5-hexyne-1-nitrile

9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline
10265-82-4

9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 130℃; for 12h; Inert atmosphere; Sealed tube;95%
(Z)-6-(tert-butyldimethylsilyloxy)-6-(2-oxooxazolidin-3-yl)hex-5-enyl benzoate
1330660-55-3

(Z)-6-(tert-butyldimethylsilyloxy)-6-(2-oxooxazolidin-3-yl)hex-5-enyl benzoate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl benzoate
1330660-78-0

(S)-6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl benzoate

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;94%
N-(2-methylbenzoyl)-8-aminoquinoline
1182669-71-1

N-(2-methylbenzoyl)-8-aminoquinoline

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-methyl-N-phenyl-N-(quinolin-8-yl)benzamide

2-methyl-N-phenyl-N-(quinolin-8-yl)benzamide

Conditions
ConditionsYield
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h;94%
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h; Molecular sieve; Schlenk technique;94%
(Z)-benzyl (6-((tert-butyldimethylsilyl)oxy)-6-(2-oxooxazolidin-3-yl)hex-5-en-1-yl)(methyl)carbamate
1330660-56-4

(Z)-benzyl (6-((tert-butyldimethylsilyl)oxy)-6-(2-oxooxazolidin-3-yl)hex-5-en-1-yl)(methyl)carbamate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-benzyl methyl(6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl)carbamate
1330660-79-1

(S)-benzyl methyl(6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl)carbamate

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at 5℃; for 24h; optical yield given as %ee; enantioselective reaction;93%
N-methylisocarbostyril
4594-71-2

N-methylisocarbostyril

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-methyl-8-phenylisoquinolin-1(2H)-one

2-methyl-8-phenylisoquinolin-1(2H)-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In acetic acid at 100℃; for 24h; Mechanism; Reagent/catalyst; Solvent; regiospecific reaction;93%
ethyl 2-acetoxy-3-butenoate
127700-79-2

ethyl 2-acetoxy-3-butenoate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-ethyl 2-acetoxy-4-phenylbut-3-enoate
1151782-13-6

(E)-ethyl 2-acetoxy-4-phenylbut-3-enoate

Conditions
ConditionsYield
With resorcinolbis[(diphenyl)phosphinite] palladium trifluoroacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 19h;92%
3,5-dibromo-2-hydroxypyridine
13472-81-6

3,5-dibromo-2-hydroxypyridine

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

3,5-dibromo-1-phenylpyridin-2(1H)-one
120491-71-6

3,5-dibromo-1-phenylpyridin-2(1H)-one

Conditions
ConditionsYield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.0833333h; Inert atmosphere;92%
5-methyl-2-cyanoaniline
26830-96-6

5-methyl-2-cyanoaniline

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-(4-imino-7-methyl-3-phenyl-3,4-dihydroquinazolin-2-yl)-5-methylaniline

2-(4-imino-7-methyl-3-phenyl-3,4-dihydroquinazolin-2-yl)-5-methylaniline

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;92%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

anthranilic acid nitrile
1885-29-6

anthranilic acid nitrile

(2-(3-phenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

(2-(3-phenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;92%
methyl 3-(3,4-dihydro-2H-pyran-6-yl)-3-hydroxycyclobutane-1-carboxylate

methyl 3-(3,4-dihydro-2H-pyran-6-yl)-3-hydroxycyclobutane-1-carboxylate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;A 92%
B 7%
(Z)-3-(1-(tert-butyldimethylsilyloxy)-6-methoxyhex-1-enyl)oxazolidin-2-one
1330660-49-5

(Z)-3-(1-(tert-butyldimethylsilyloxy)-6-methoxyhex-1-enyl)oxazolidin-2-one

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-3-(6-methoxy-2-phenylhexanoyl)oxazolidin-2-one
1330660-72-4

(S)-3-(6-methoxy-2-phenylhexanoyl)oxazolidin-2-one

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;91%
pyridine N-oxide
694-59-7

pyridine N-oxide

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-(pyridin-1-ium-1-yl)phenolate

2-(pyridin-1-ium-1-yl)phenolate

Conditions
ConditionsYield
Stage #1: pyridine N-oxide; diphenyliodonium hexafluorophosphate In 1,2-dichloro-ethane at 120℃; for 48h; Inert atmosphere; Schlenk technique;
Stage #2: With potassium carbonate In methanol; 1,2-dichloro-ethane at 20℃; for 1h;
91%
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