Diphenyliodonium hexafluorophosphate supplier

Name
Diphenyliodonium hexafluorophosphate
EINECS 261-134-5
CAS No. 58109-40-3
Article Data5
CAS DataBase
Density
Solubility
Melting Point 140-144 °C(lit.)
Formula C₁₂H₁₀I^.F₆P
Boiling Point
Molecular Weight 426.08
Flash Point
Transport Information
Appearance
Safety 26-36/37/39-45
Risk Codes 34
Molecular Structure
Hazard Symbols C
Synonyms Iodonium, diphenyl-, hexafluorophosphate(1-);Iodonium Diphenyl Hexafluorophosphate;
PSA 13.59000
LogP 3.19740

Synthetic route

: 591-50-4
iodobenzene

: 71-43-2
benzene

: 58109-40-3
diphenyliodonium hexafluorophosphate

Conditions

Conditions	Yield
With hexafluorophosphoric acid; 3-chloro-benzenecarboperoxoic acid

: diphenyliodonium 4-nitrophenolate

A: 1124-31-8
potassium 4-nitrophenolate

B: 58109-40-3
diphenyliodonium hexafluorophosphate

Conditions

Conditions	Yield
With potassium hexafluorophosphate In acetonitrile at 20℃; Equilibrium constant; Temperature; Inert atmosphere;

: diphenyliodonium 4-nitrophenolate

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

A: 3002-48-0
tetra-n-butylammonium p-nitrophenoxide

B: 58109-40-3
diphenyliodonium hexafluorophosphate

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: 16212-05-8
(allylsulfonyl)benzene

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 16212-07-0
trans-cinnamyl phenyl sulfone

Conditions

Conditions	Yield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 22h;	99%

: 120-72-9
indole

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 948-65-2
2-phenyl-indole

Conditions

Conditions	Yield
Stage #1: indole With C64H56N6P2Pd2 In acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: diphenyliodonium hexafluorophosphate In acetic acid at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;	99%
Stage #1: indole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;	99%

: 1003-68-5
5-methyl-2-pyridone

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 53179-13-8
Pirfenidone

Conditions

Conditions	Yield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.5h; Inert atmosphere;	99%

: 139-66-2
diphenyl sulfide

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 57835-99-1
triphenylsulphonium hexafluorophosphate

Conditions

Conditions	Yield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; for 0.0333333h; Inert atmosphere; Microwave irradiation;	98%

: 18085-02-4
1,2-diacetoxy-3-butene

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 119420-99-4
(E)-4-phenylbut-3-ene-1,2-diyl diacetate

Conditions

Conditions	Yield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 20h;	98%

: 603-76-9
1-methylindole

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 3558-24-5
1-methyl-2-phenyl-1H-indole

Conditions

Conditions	Yield
With Pd2[(C6H4)PPh2]2[CF3C(O)CHC(O)CF3]2 In acetic acid at 24.84℃; for 30h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Inert atmosphere; Schlenk technique;	98%
Stage #1: 1-methylindole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 10h; Reagent/catalyst; Inert atmosphere; Schlenk technique;	97%

: 1195763-38-2
2-(phenylthio)thioxanthone

: 123215-04-3
potassium trifluorotris(pentafluoroethyl)phosphate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

Conditions

Conditions	Yield
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h; Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;	98%
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h; Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h; Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;

...Expand

: 1-(1H-inden-3-yl)cyclopentan-1-ol

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;	98%

: 1-(1H-inden-3-yl)cyclopentan-1-ol

: 58109-40-3
diphenyliodonium hexafluorophosphate

: (1S,2'R)-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;	98%

: 14187-32-7
dibenzo-18-crown-6

: 58109-40-3
diphenyliodonium hexafluorophosphate

: diphenyliodonium hexafluorophosphate-dibenzo-18-crown-6 ether complex

Conditions

Conditions	Yield
In ethyl acetate for 0.0833333h; Reflux;	97.6%

: (E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane

: 58109-40-3
diphenyliodonium hexafluorophosphate

: (E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)diphenylsulfonium hexafluorophosphate (V)

Conditions

Conditions	Yield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; Inert atmosphere; Microwave irradiation; Darkness;	97%

: 114395-69-6
tris(trifluoromethanesulfonyl)methide potassium salt

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 182505-78-8
C4F9O6S3(1-)*C12H10I(1+)

Conditions

Conditions	Yield
In ethyl acetate at 20℃; for 1h;	97%

: 873-55-2
sodium benzenesulfonate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 127-63-9
diphenyl sulphone

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere;	96%

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 74938-47-9
1-(3,4-dihydro-2H-pyran-6-yl)cyclopentan-1-ol

: (5R,10R)-10-phenyl-6-oxaspiro[4.5]decan-1-one

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 36h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;	96%

: 1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;	96%

: 1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

: 58109-40-3
diphenyliodonium hexafluorophosphate

: (1S,2'R)-5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;	96%

: 1330660-53-1
(Z)-3-(1-((tert-butyldimethylsilyl)oxy)-5-phenylpent-1-en-1-yl)oxazolidin-2-one

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1330660-76-8
(S)-3-(2,5-diphenylpentanoyl)oxazolidin-2-one

Conditions

Conditions	Yield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at -10℃; for 24h; optical yield given as %ee; enantioselective reaction;	95%

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 100-47-0
benzonitrile

: 2216-94-6
phenylpropynoic acid ethyl ester

: 17282-90-5
ethyl 2,4-diphenylquinoline-3-carboxylate

Conditions

Conditions	Yield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 120℃; Inert atmosphere; Sealed tube; regioselective reaction;	95%

...Expand

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 152858-50-9
6-phenyl-5-hexyne-1-nitrile

: 10265-82-4
9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline

Conditions

Conditions	Yield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 130℃; for 12h; Inert atmosphere; Sealed tube;	95%

: 1330660-55-3
(Z)-6-(tert-butyldimethylsilyloxy)-6-(2-oxooxazolidin-3-yl)hex-5-enyl benzoate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1330660-78-0
(S)-6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl benzoate

Conditions

Conditions	Yield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;	94%

: 1182669-71-1
N-(2-methylbenzoyl)-8-aminoquinoline

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 2-methyl-N-phenyl-N-(quinolin-8-yl)benzamide

Conditions

Conditions	Yield
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h;	94%
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h; Molecular sieve; Schlenk technique;	94%

: 1330660-56-4
(Z)-benzyl (6-((tert-butyldimethylsilyl)oxy)-6-(2-oxooxazolidin-3-yl)hex-5-en-1-yl)(methyl)carbamate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1330660-79-1
(S)-benzyl methyl(6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl)carbamate

Conditions

Conditions	Yield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at 5℃; for 24h; optical yield given as %ee; enantioselective reaction;	93%

: 4594-71-2
N-methylisocarbostyril

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 2-methyl-8-phenylisoquinolin-1(2H)-one

Conditions

Conditions	Yield
With silver hexafluoroantimonate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In acetic acid at 100℃; for 24h; Mechanism; Reagent/catalyst; Solvent; regiospecific reaction;	93%

: 127700-79-2
ethyl 2-acetoxy-3-butenoate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1151782-13-6
(E)-ethyl 2-acetoxy-4-phenylbut-3-enoate

Conditions

Conditions	Yield
With resorcinolbis[(diphenyl)phosphinite] palladium trifluoroacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 19h;	92%

: 13472-81-6
3,5-dibromo-2-hydroxypyridine

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 120491-71-6
3,5-dibromo-1-phenylpyridin-2(1H)-one

Conditions

Conditions	Yield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.0833333h; Inert atmosphere;	92%

: 26830-96-6
5-methyl-2-cyanoaniline

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 2-(4-imino-7-methyl-3-phenyl-3,4-dihydroquinazolin-2-yl)-5-methylaniline

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;	92%

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1885-29-6
anthranilic acid nitrile

: (2-(3-phenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;	92%

: methyl 3-(3,4-dihydro-2H-pyran-6-yl)-3-hydroxycyclobutane-1-carboxylate

: 58109-40-3
diphenyliodonium hexafluorophosphate

: methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

: methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;	A 92% B 7%

...Expand

: 1330660-49-5
(Z)-3-(1-(tert-butyldimethylsilyloxy)-6-methoxyhex-1-enyl)oxazolidin-2-one

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 1330660-72-4
(S)-3-(6-methoxy-2-phenylhexanoyl)oxazolidin-2-one

Conditions

Conditions	Yield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;	91%

: 694-59-7
pyridine N-oxide

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 2-(pyridin-1-ium-1-yl)phenolate

Conditions

Conditions	Yield
Stage #1: pyridine N-oxide; diphenyliodonium hexafluorophosphate In 1,2-dichloro-ethane at 120℃; for 48h; Inert atmosphere; Schlenk technique; Stage #2: With potassium carbonate In methanol; 1,2-dichloro-ethane at 20℃; for 1h;	91%

Diphenyliodonium hexafluorophosphate Specification

The Diphenyliodonium hexafluorophosphate with the CAS number 58109-40-3 is also called Iodonium Diphenyl Hexafluorophosphate. Its molecular formula is C₁₂H₁₀I^.F₆P. The EINECS registry number is 261-134-5. This chemical belongs to the following product categories: (1)Diphenyliodonium Compounds; (2)Functional Materials; (3)Hypervalent Iodine Compounds; (4)Iodonium Sulfonium & Oxonium Compounds; (5)Photopolymerization Initiators; (6)Synthetic Organic Chemistry; (7)Hypervalent Iodine; (8)Oxidation; (9)Synthetic Reagents; (10)Cationic PhotoinitiatorsMicro/Nanoelectronics; (11)FluoridesSelf Assembly&Contact Printing; (12)Electronic Chemicals; (13)Organic Photoinitiators; (14)Photoacid Generators (PAGs); (15)Photoresists; (16)Polymerization Initiators.

Properties Computed from Structure: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 7; (3)Rotatable Bond Count: 2; (4)Exact Mass: 425.946899; (5)MonoIsotopic Mass: 425.946899; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 20; (8)Formal Charge: 0; (9)Complexity: 179; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.

While using this chemical, you should be very cautious. This chemical can cause burns. Therefore, you should take the following instructions. Firstly, you should wear suitable protective clothing, gloves and eye/face protection. Then in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Finally in case of accident or if you feel unwell, you should seek medical advice immediately (show the label whenever possible).

You can still convert the following datas into molecular structure:
(1)SMILES: F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2
(2)InChI: InChI=1/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1
(3)InChIKey: DSSRLRJACJENEU-UHFFFAOYAG

Product Name

Diphenyliodonium hexafluorophosphate

Synthetic route

Diphenyliodonium hexafluorophosphate Specification

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