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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-(Trifluoromethyl)pyridine Manufacturer/High quality/Best price/In stock

Cas:3796-24-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-(Trifluoromethyl)Pyridine supplier in China

Cas:3796-24-5

Min.Order:1 Metric Ton

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 4-(Trifluoromethyl)pyridine CAS 3796-24-5 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Foo

Factory supply 4-(Trifluoromethyl)pyridine CAS 3796-24-5 with fast delivery

Cas:3796-24-5

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-(Trifluoromethyl)Pyridine

Cas:3796-24-5

Min.Order:1

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Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-(Trifluoromethyl)-pyridine

Cas:3796-24-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU CHEM -- 4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:1 Kilogram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 3796-24-5 with competitive price

Cas:3796-24-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 4-(trifluoromethyl)pyridine Cas number 3796-24-5 Molecular formula C6H4F3N Molecular weight 147.1 Appearance

4-(Trifluoromethyl)pyridine CAS: 3796-24-5

Cas:3796-24-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:1 Gram

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Qingdao Beluga Import and Export Co., LTD

3-trifluoromethylpyridine CAS 3796-24-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

3-trifluoromethylpyridine CAS 3796-24-5

Cas:3796-24-5

Min.Order:1 Gram

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Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biological Technology Co., Ltd. is specialize in the production of chemical raw materials and reagents,located in Shijiazhuang, Hebei Province. In recent decades, under the efforts of all staff, in Shandong, Henan, Guangdong and many othe

4-(Trifluoromethyl)pyridine CAS 3796-24-5

Cas:3796-24-5

Min.Order:1 Kilogram

FOB Price: $20.0 / 40.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-(Trifluoromethyl)Pyridine

Cas:3796-24-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

4-(Trifluoromethyl)pyridineCAS NO.: 3796-24-5Appearance:White powder Storage:stay in dry, cool and well-sealed Package:according to customers' requirements Application:medical research Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by se

4-(Trifluoromethyl)pyridineCAS NO.: 3796-24-5

Cas:3796-24-5

Min.Order:1 Gram

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Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless liquid Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation: as per your request. Po

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:1 Kilogram

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-(Trifluoromethyl)pyridine Manufacturer/High quality/Best price/In stock

Cas:3796-24-5

Min.Order:1 Kilogram

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Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:1 Kilogram

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Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-(Trifluoromethyl)pyridineCAS NO.: 3796-24-5

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

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Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,4-PHENYLENEDIACRYLIC ACID DIETHYL ESTER

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

4-(Trifluoromethyl)Pyridine

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

4-(trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

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Type:Manufacturers

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-(TrifluoroMethyl)pyridine

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

4-(Trifluoromethyl)pyridine CAS No.3796-24-5

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Trading Company

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

4-(Trifluoromethyl)pyridine

Cas:3796-24-5

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

4-(Trifluoromethyl)pyridine cas 3796-24-5Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

4-(Trifluoromethyl)pyridine cas 3796-24-5

Cas:3796-24-5

Min.Order:0

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Type:Other

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Synthetic route

1-oxido-4-(trifluoromethyl)pyridin-1-ium
22253-59-4

1-oxido-4-(trifluoromethyl)pyridin-1-ium

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With phenylsilane; 3-Methyl-1-phenyl-2-phospholene 1-oxide In acetonitrile for 16h; Irradiation; chemoselective reaction;93%
4-iodopyridine
15854-87-2

4-iodopyridine

trifluoromethanesulfonic acid diphenyl(trifluoromethyl)sulfonium salt

trifluoromethanesulfonic acid diphenyl(trifluoromethyl)sulfonium salt

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With copper In N,N-dimethyl-formamide at 60℃; for 11h;91%
pyridine-4-carboxylic acid
55-22-1

pyridine-4-carboxylic acid

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With F6Mo at 170 - 190℃; for 40h;80%
3-hydroxy-3-trifluoromethyl-1,5-pentanedialdehyde
339539-96-7

3-hydroxy-3-trifluoromethyl-1,5-pentanedialdehyde

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With ammonia In methanol for 24h; Heating;70%
With ammonium hydroxide In methanol for 24h; Reflux;70%
2-chloro-4-trifluoromethyl pyridine
81565-18-6

2-chloro-4-trifluoromethyl pyridine

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With propylamine In tetrahydrofuran at 20℃; for 15h; Reagent/catalyst; Solvent; Inert atmosphere; Irradiation; Sealed tube;68%
With triethylamine; Lumogen F Orange 240 In N,N-dimethyl-formamide at 40℃; for 16h; Irradiation;91 %Chromat.
With ZnSe/CdS core/shell QDs; N-ethyl-N,N-diisopropylamine In hexane at 25℃; for 48h; Irradiation; Inert atmosphere;23 %Chromat.
4-iodopyridine
15854-87-2

4-iodopyridine

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With potassium fluoride; copper(l) iodide In 1-methyl-pyrrolidin-2-one; N,N-dimethyl-formamide at 25℃; for 6h;25%
With C13H27CuN2O(1+) In N,N-dimethyl-formamide at 25℃; for 112h;99 %Spectr.
pyridine
110-86-1

pyridine

Bromotrifluoromethane
75-63-8

Bromotrifluoromethane

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

C

2-(trifluoromethyl)pyridine
368-48-9

2-(trifluoromethyl)pyridine

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; sodium dithionite In water at 65℃; under 2250.2 - 3750.3 Torr; for 2h;A 5%
B 1%
C 4%
pyridine
110-86-1

pyridine

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

C

3,5-bis(trifluoromethyl)pyridine
20857-47-0

3,5-bis(trifluoromethyl)pyridine

D

2,6-bis-(trifluoromethyl)pyridine
455-00-5

2,6-bis-(trifluoromethyl)pyridine

E

2-(trifluoromethyl)pyridine
368-48-9

2-(trifluoromethyl)pyridine

Conditions
ConditionsYield
for 96h; Product distribution; Irradiation; The yields, the kind of products depend on the time of the irrad. and/or the temp., and the mol. ratio. Other trifluorometh. agents investigated;
4-hydroxy-4-trifluoromethyl-1,6-heptadiene
36610-32-9

4-hydroxy-4-trifluoromethyl-1,6-heptadiene

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / O3 / CH2Cl2; methanol / 24 h / -78 °C
2: 70 percent / NH3 / methanol / 24 h / Heating
View Scheme
Multi-step reaction with 2 steps
1.1: ozone / dichloromethane; methanol / -78 °C
1.2: 2 h / 20 °C
2.1: ammonium hydroxide / methanol / 24 h / Reflux
View Scheme
pyridine
110-86-1

pyridine

Togni's reagent
887144-97-0

Togni's reagent

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

C

2-(trifluoromethyl)pyridine
368-48-9

2-(trifluoromethyl)pyridine

Conditions
ConditionsYield
In acetonitrile at 80℃; for 96h; Inert atmosphere;A 3 %Spectr.
B 16 %Spectr.
C 17 %Spectr.
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

4-pyridylboronic acid
1692-15-5

4-pyridylboronic acid

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; copper (I) acetate; potassium carbonate In N,N-dimethyl-formamide at 60℃; for 12h; Inert atmosphere; 26 W fluorescent light bulbs;64 %Spectr.
trifluoromethylcopper(I)
77152-08-0

trifluoromethylcopper(I)

4-pyridylboronic acid
1692-15-5

4-pyridylboronic acid

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With oxygen; triethylamine tris(hydrogen fluoride) In N,N-dimethyl-formamide at 25℃; for 4h;67 %Spectr.
trifluoromethylcopper(I)
77152-08-0

trifluoromethylcopper(I)

4-bromopyridine hydrochloride
19524-06-2

4-bromopyridine hydrochloride

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With triethylamine tris(hydrogen fluoride) In N,N-dimethyl-formamide at 23 - 50℃; for 39h; Glovebox; Sealed tube;74 %Spectr.
4-bromopyridin
1120-87-2

4-bromopyridin

(1,10-phenanthroline)(trifluoromethyl)copper (I)

(1,10-phenanthroline)(trifluoromethyl)copper (I)

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 8h; Sealed tube; Inert atmosphere;75 %Spectr.
4-iodopyridine
15854-87-2

4-iodopyridine

trimethylsilyl 2-chloro-2,2-difluoroacetate

trimethylsilyl 2-chloro-2,2-difluoroacetate

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With copper(l) iodide; N,N,N,N,-tetramethylethylenediamine; silver fluoride In N,N-dimethyl-formamide at 100℃; for 2h; Time; Inert atmosphere; Sealed tube;83 %Spectr.
bis(4-(trifluoromethyl)pyridine)iodonium tetrafluoroborate

bis(4-(trifluoromethyl)pyridine)iodonium tetrafluoroborate

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

bis(4-(dimethylamino)pyridine)iodonium tetrafluoroborate

bis(4-(dimethylamino)pyridine)iodonium tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane Kinetics;
pyridine
110-86-1

pyridine

[(Py)2NiF2(CF3)2]

[(Py)2NiF2(CF3)2]

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

C

2-(trifluoromethyl)pyridine
368-48-9

2-(trifluoromethyl)pyridine

[(Py)2Ni(CF3)2]

[(Py)2Ni(CF3)2]

Conditions
ConditionsYield
In neat (no solvent) at 25℃; Schlenk technique; Inert atmosphere; Glovebox;
2-bromo-4-(trifluoromethyl)pyridine
175205-81-9

2-bromo-4-(trifluoromethyl)pyridine

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With ZnSe/CdS core/shell QDs; N-ethyl-N,N-diisopropylamine In hexane at 25℃; for 48h; Irradiation; Inert atmosphere;39 %Chromat.
4-bromopyridin
1120-87-2

4-bromopyridin

dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate

dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With dilithium tetrabromocuprate; 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-2-trisilanol; Ir(2-(2,4-difluorophenyl)-5-fluoropyridine)2(4,4'-di(trifluoromethyl)-2,2'-bipyridyl)PF6; sodium carbonate In acetone at 35℃; Irradiation;
pyridine
110-86-1

pyridine

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

C

2-(trifluoromethyl)pyridine
368-48-9

2-(trifluoromethyl)pyridine

Conditions
ConditionsYield
In acetonitrile at 20℃; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Electrolysis; Overall yield = 82 %Chromat.; regioselective reaction;
(2'-(dicyclohexylphosphino)-2,4,6-triisopropylbiphenyl)Ag(I)(μ-OH)CuIII(CF3)3

(2'-(dicyclohexylphosphino)-2,4,6-triisopropylbiphenyl)Ag(I)(μ-OH)CuIII(CF3)3

4-pyridylboronic acid
1692-15-5

4-pyridylboronic acid

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Conditions
ConditionsYield
With potassium fluoride In N,N-dimethyl-formamide at 100℃; for 6h; Inert atmosphere; Schlenk technique;36 %Spectr.
C37H47BF3FeN5

C37H47BF3FeN5

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

Ph2B(tBuIm)2FeCH2tBu

Ph2B(tBuIm)2FeCH2tBu

Conditions
ConditionsYield
In toluene for 2h; Equilibrium constant; Concentration; Inert atmosphere;
C27H25BF3NO3

C27H25BF3NO3

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

tris(4-methoxyphenyl)borane
28445-29-6

tris(4-methoxyphenyl)borane

Conditions
ConditionsYield
In dichloromethane at 20℃;
C27H25BF3N

C27H25BF3N

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

tri-p-tolylborane
7297-94-1

tri-p-tolylborane

Conditions
ConditionsYield
In dichloromethane at 20℃;
C24H19BF3N

C24H19BF3N

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

triphenylborane
960-71-4

triphenylborane

Conditions
ConditionsYield
In dichloromethane at 20℃;
C24H16BF6N

C24H16BF6N

A

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

B

tris(4-fluorophenyl)borane
47196-74-7

tris(4-fluorophenyl)borane

Conditions
ConditionsYield
In dichloromethane at 20℃;
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

mesitylenesulfonylhydroxylamine
36016-40-7

mesitylenesulfonylhydroxylamine

1-amino-4-trifluoromethylpyridinium 2,4,6-trimethylbenzenesulfonate
1299420-32-8

1-amino-4-trifluoromethylpyridinium 2,4,6-trimethylbenzenesulfonate

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 18h;100%
In dichloromethane at 0 - 20℃; for 21h;
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

[Al(η1-allyl)3(4-dimethylaminopyridine)]
1320213-69-1

[Al(η1-allyl)3(4-dimethylaminopyridine)]

[Al(η1-allyl)2(κ-N-2-allyl-4-trifluoromethyl-1,2-dyhydripyridine-1-yl)(4-dimethylaminopyridine)]
1320213-72-6

[Al(η1-allyl)2(κ-N-2-allyl-4-trifluoromethyl-1,2-dyhydripyridine-1-yl)(4-dimethylaminopyridine)]

Conditions
ConditionsYield
In tetrahydrofuran-d8 under Ar, Schlenk technique; soln. of 4-CF3-pyridine in THF-d8 added to soln. of Al complex in THF-d8, react. for 20 h; evapn. under vac., oil dried under vac. for 2 h; elem. anal.;99%
In tetrahydrofuran under Ar, Schlenk technique; Al complex and 4-CF3-pyridine in THF at room temp.;
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

[Al(η1-allyl)3(triphenylphosphine oxide)]
1320213-61-3

[Al(η1-allyl)3(triphenylphosphine oxide)]

[Al(η1-allyl)2(κ-N-2-allyl-4-trifluoromethyl-1,2-dyhydripyridine-1-yl)(triphenylphosphine oxide)]
1320213-73-7

[Al(η1-allyl)2(κ-N-2-allyl-4-trifluoromethyl-1,2-dyhydripyridine-1-yl)(triphenylphosphine oxide)]

Conditions
ConditionsYield
In tetrahydrofuran under Ar, Schlenk technique; addn. of 4-CF3-pyridine to soln. of Al complex in THF, react. for 18 h; evapn. under vac., oil dried under vac. for 2 h; elem. anal.;99%
bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

bis(η4-1,5-cyclooctadiene)(4-(trifluoromethyl)pyridine)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

bis(η4-1,5-cyclooctadiene)(4-(trifluoromethyl)pyridine)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Conditions
ConditionsYield
In dichloromethane react. of Ir complex with NC5H4CF3 (6-10 equiv.) at 23°C for 1 h,then NaB(C6H3(CF3)2)4 (1.2-1.5 equiv.) added, kept for 12 h;99%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

[(1,3-bis-(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)PdCl(μ-Cl)]2

[(1,3-bis-(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)PdCl(μ-Cl)]2

C33H40Cl2F3N3Pd

C33H40Cl2F3N3Pd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 16h; Inert atmosphere;99%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

[(1,3-dimesitylimidazol-2-ylidene)3[Fe4S4](diethyl ether)][tetrakis[(3,5-trifluoromethyl)phenyl]borate]

[(1,3-dimesitylimidazol-2-ylidene)3[Fe4S4](diethyl ether)][tetrakis[(3,5-trifluoromethyl)phenyl]borate]

[(IMes)3Fe4S4(4-CF3-pyridine)][BArF4]

[(IMes)3Fe4S4(4-CF3-pyridine)][BArF4]

Conditions
ConditionsYield
In diethyl ether; benzene Inert atmosphere; Glovebox; Schlenk technique;99%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

4-Trifluormethyl-piperidin
657-36-3

4-Trifluormethyl-piperidin

Conditions
ConditionsYield
With [Rh(cod)(CI)(CAACMe2)]; hydrogen In hexane at 40℃; for 24h; Molecular sieve; diastereoselective reaction;98%
With hydrogen In tetrahydrofuran at 30℃; under 15001.5 Torr; for 4h; Catalytic behavior; Autoclave; Glovebox;49 %Chromat.
With hydrogen In water; isopropyl alcohol at 120℃; under 37503.8 Torr; for 24h; Autoclave;94 %Chromat.
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

di-μ-bromo(dibromo)bis[1,3-di(propan-2-yl)-1,3-dihydro-2H-benzimidazol-2-ylidene]dipalladium(II)

di-μ-bromo(dibromo)bis[1,3-di(propan-2-yl)-1,3-dihydro-2H-benzimidazol-2-ylidene]dipalladium(II)

trans-dibromido(1,3-diisopropylbenzimidazolin-2-ylidene)(4-trifluoromethylpyridine)palladium(II)

trans-dibromido(1,3-diisopropylbenzimidazolin-2-ylidene)(4-trifluoromethylpyridine)palladium(II)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;98%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethyl)-1,2-dihydropyridine
1360145-63-6

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethyl)-1,2-dihydropyridine

Conditions
ConditionsYield
With [La(η5-C5(CH3)5)H]2 at 25 - 35℃; for 0.4h;96%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; tricyclohexylphosphine In toluene at 50℃; for 24h; Inert atmosphere;92%
With P(C6H11)3; chloro(1,5-cyclooctadiene)rhodium(I) dimer In toluene ligand reacted with pinacolborane in toluene at 50°C for 24 h in presence of (Rh(C8H12)Cl)2 and P(C6H11)3; treated with activated charcoal, filtered under N2, concd. in vacuo;92%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

4-(trifluoromethyl)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide

4-(trifluoromethyl)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide

Conditions
ConditionsYield
In dichloromethane at 22 - 26℃; for 0.75h; Inert atmosphere;95%
tetrafluoroboric acid diethyl ether
67969-82-8

tetrafluoroboric acid diethyl ether

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

BF4(1-)*C6H4F3N*H(1+)

BF4(1-)*C6H4F3N*H(1+)

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃;95%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

1-oxido-4-(trifluoromethyl)pyridin-1-ium
22253-59-4

1-oxido-4-(trifluoromethyl)pyridin-1-ium

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 24h; Inert atmosphere;94%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 16h;86%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 0 - 20℃; for 16.8h;85%
diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

N-methylmaleimide
930-88-1

N-methylmaleimide

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

(3aR*,4R*,9aR*,9bS*)-ethyl-8-(trifluoromethyl)-2-methyl-1,3-dioxo-2,3,3a,4,9a,9b-hexahydro-1H-pyrrolo[3,4-a]indolizine-4-carboxylate

(3aR*,4R*,9aR*,9bS*)-ethyl-8-(trifluoromethyl)-2-methyl-1,3-dioxo-2,3,3a,4,9a,9b-hexahydro-1H-pyrrolo[3,4-a]indolizine-4-carboxylate

Conditions
ConditionsYield
With [Fe(tetraphenylporphyrin)Cl] In toluene at 20℃; for 3h; Inert atmosphere;94%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

methyl iodide
74-88-4

methyl iodide

1-methyl-4-trifluoromethyl-pyridinium chloride

1-methyl-4-trifluoromethyl-pyridinium chloride

Conditions
ConditionsYield
Stage #1: 4-trifluoromethylpyridine; methyl iodide In acetonitrile at 20℃;
Stage #2: With AG(R)21K anion exchange resin chloride form 50-100 mesh Further stages.;
93%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

iodomethane-d3
865-50-9

iodomethane-d3

1-trideuteriomethyl-4-trifluoromethylpyridinium hexafluorophosphate

1-trideuteriomethyl-4-trifluoromethylpyridinium hexafluorophosphate

Conditions
ConditionsYield
Stage #1: 4-trifluoromethylpyridine; iodomethane-d3 at 80℃;
Stage #2: With ammonium hexafluorophosphate In water
92%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

1-benzyl-4-(trifluoromethyl)-1,2,3,6-tetrahydropyridine
866929-69-3

1-benzyl-4-(trifluoromethyl)-1,2,3,6-tetrahydropyridine

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol at 0 - 14℃; for 1.5h;92%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

methyl chloroformate
79-22-1

methyl chloroformate

phenylacetylene
536-74-3

phenylacetylene

methyl 2-(phenylethynyl)-4-(trifluoromethyl)pyridine-1(2H)-carboxylate

methyl 2-(phenylethynyl)-4-(trifluoromethyl)pyridine-1(2H)-carboxylate

Conditions
ConditionsYield
With copper(l) iodide; N-ethyl-N,N-diisopropylamine In dichloromethane at 0 - 20℃; Inert atmosphere;92%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

phenylpropynoic acid methyl ester
4891-38-7

phenylpropynoic acid methyl ester

methyl 2-phenyl-5-(trifluoromethyl)pyrazolo[1,5-a]pyridine-3-carboxylate

methyl 2-phenyl-5-(trifluoromethyl)pyrazolo[1,5-a]pyridine-3-carboxylate

Conditions
ConditionsYield
With perchloric acid; ethyl o-mesitylsulfonylacetohydroxamic acid; potassium carbonate In tetrahydrofuran; 1,4-dioxane; dichloromethane; N,N-dimethyl-formamide at 20℃; for 20h;92%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

benzyl bromide
100-39-0

benzyl bromide

1-benzyl-4-(trifluoromethyl)pyridin-1-ium bromide
1443117-98-3

1-benzyl-4-(trifluoromethyl)pyridin-1-ium bromide

Conditions
ConditionsYield
In acetonitrile at 90℃; for 12h; Inert atmosphere;91%
In acetonitrile at 85℃; for 0.25h; Reflux;
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

methyl iodide
74-88-4

methyl iodide

1-methyl-4-trifluoromethylpyridinium hexafluorophosphate

1-methyl-4-trifluoromethylpyridinium hexafluorophosphate

Conditions
ConditionsYield
Stage #1: 4-trifluoromethylpyridine; methyl iodide at 80℃;
Stage #2: With ammonium hexafluorophosphate In water
90%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

[C2H5NC4H4B(O3SCF3)]
1258790-68-9

[C2H5NC4H4B(O3SCF3)]

C4H4N(C2H5)BNC5H4CF3(1+)*CF3SO3(1-)=(C4H4N(C2H5)BNC5H4CF3)(CF3SO3)

C4H4N(C2H5)BNC5H4CF3(1+)*CF3SO3(1-)=(C4H4N(C2H5)BNC5H4CF3)(CF3SO3)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 4h; Inert atmosphere;90%
In dichloromethane glovebox; soln. of substituted pyridine added to stirred soln. of azaborine, mixt. stirred for 1 h at room temp.; soln. cooled to -20 °C, left at this temp. for 24 h, after crystals pptd. supernatant decanted, solid washed with n-pentane, solvent removed (reduced pressure);90%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

α-bromoacetophenone
70-11-1

α-bromoacetophenone

ethyl acrylate
140-88-5

ethyl acrylate

C19H14F3NO3

C19H14F3NO3

Conditions
ConditionsYield
Stage #1: 4-trifluoromethylpyridine; α-bromoacetophenone In N,N-dimethyl-formamide at 100℃;
Stage #2: ethyl acrylate With sodium acetate; copper(II) acetate monohydrate In N,N-dimethyl-formamide at 100℃; for 16h;
88.9%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

1-dimethylphenylsilyl-4-(trifluoromethyl)-1,4-dihydropyridine

1-dimethylphenylsilyl-4-(trifluoromethyl)-1,4-dihydropyridine

Conditions
ConditionsYield
With C29H38PRuS(1+)*C32H12BF24(1-) In neat (no solvent) at 20℃; for 12h; Inert atmosphere; Glovebox;88%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

2CF3O3S(1-)*C12H8F6N2S(4+)

2CF3O3S(1-)*C12H8F6N2S(4+)

Conditions
ConditionsYield
With sulfur dichloride In dichloromethane at -78℃; Inert atmosphere;87%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

dichlorobis(dimethyl sulfoxide)platinum(II)

dichlorobis(dimethyl sulfoxide)platinum(II)

silver nitrate

silver nitrate

[PtII(4-trifluoromethylpyridine)4](NO3)2

[PtII(4-trifluoromethylpyridine)4](NO3)2

Conditions
ConditionsYield
In methanol for 24h; Reflux;87%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

p-methoxybenzyl chloride
824-94-2

p-methoxybenzyl chloride

1-(4-methoxybenzyl)-4-(trifluoromethyl)pyridin-1-ium chloride

1-(4-methoxybenzyl)-4-(trifluoromethyl)pyridin-1-ium chloride

Conditions
ConditionsYield
In acetonitrile at 80℃;87%
bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(η4-1,5-cyclooctadiene)(tricyclohexylphosphane)[4-(trifluoromethyl)pyridine]iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

(η4-1,5-cyclooctadiene)(tricyclohexylphosphane)[4-(trifluoromethyl)pyridine]iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Conditions
ConditionsYield
In dichloromethane NC5H4CF3 (1 equiv.) added to soln. of Ir complex (0.5 equiv.) at 23°C, kept for 30 min, Cy3P (1 equiv.) added, after 30 min NaB(C6H3(CF3)2)4 (1.02 equiv.) added, kept for 1 h; concd., chromd. (SiO2, CH2CL2);86%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

carbon dioxide
124-38-9

carbon dioxide

4-(trifluoromethyl)nicotinic acid
158063-66-2

4-(trifluoromethyl)nicotinic acid

Conditions
ConditionsYield
With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran at -75℃; for 2h;84%
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