hydrogenchloride
palladium
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
Stage #1: hydrogenchloride; palladium With aqua regia at 80℃; Stage #2: triphenylphosphine In ethanol at 70℃; Stage #3: In ethanol at 70℃; for 1h; Temperature; Solvent; | 100% |
bis(benzonitrile)palladium(II) dichloride
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In chloroform isolation by filtration; | 95% |
With triphenylphosphine In not given (dry N2); dry and deoxygenated solvents; addn. of 2.2 equiv. of PPh3 to Pd-compd.; filtration; | 95% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With PPh3 In ethanol; water molar ratio borane:Pd:PPh3=1:2:4, 70°C, 2 h (pptn.); filtration, washing (H2O, EtOH, ether); extn. of PdCl2(PPh3)2 (toluene);elem. anal.; | A n/a B 95% |
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; Milling; | 92% |
trans-bis(trifluoromethanesulfonate) bis(triphenylphosphine)palladium trihydrate
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With sodium chloride In water; acetonitrile Pd-compound in CH3CN was treated with aq. NaCl; | 91% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine excess of PPh3; | 90% |
With PPh3; H2O In dimethyl sulfoxide heating a mixt. of PdCl2, PPh3 and water in DMSO under Ar (140°C) yielding a yellow-orange soln., cooling (room temp.), pptn.; filtration, washing (Et2O), drying (vac.); | 90% |
With triphenylphosphine In N,N-dimethyl-formamide Addn. of 2.4 equiv. of PPh3 to DMF soln. of PdCl2 at 140°C.; Cooling, collecting the resultant ppt.; |
tetrakis(triphenylphosphine) palladium(0)
tetrachlorosilane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
mixt. of compds. heated at 60 °C for 14 h, under N2; volatiles collected, residue washed with Et2O; | 89% |
dichloro bis(acetonitrile) palladium(II)
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane Inert atmosphere; Schlenk technique; | 89% |
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzonitrile at 180℃; for 0.333333h; Inert atmosphere; Schlenk technique; | 88% |
In dichloromethane; acetonitrile at 20℃; for 0.166667h; Inert atmosphere; | 82% |
With carbon monoxide In toluene at 125℃; under 7600.51 Torr; for 4h; | 50% |
tetrakis(triphenylphosphine) palladium(0)
chloro-trimethyl-silane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
byproducts: (Me3Si)2, (Me3Si)3O; mixt. of compds. heated at 60 °C for 4 h, under N2; volatiles collected, residue washed with Et2O; elem. anal.; | 80% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 3.5:1) in CH2Cl2, stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.; | A 80% B >99 |
bis(benzonitrile)palladium(II) dichloride
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In acetonitrile under N2, soln. of Pd-complex in CH3CN was added to suspn. of equimolaramt. of Ir-complex in CH3CN, stirred at room temp. for 1 h; ppt. filtered, vac. dried (Pd-product), filtrate evapd. under reduced pressure, filtered, washed with EtOH, vac. dried; elem. anal.; | A 15% B 78% |
tetrakis(triphenylphosphine) palladium(0)
1,2-dichlorotetramethylsilane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene mixt. of educts in benzene stirred at 20°C for 24 h under N2; dild. with pentane, crystals filtered, washed with ether, dried in vac.; elem. anal.; | 75% |
dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane room temp., 22 h; monitored by (1)H NMR; | 74% |
bis(benzonitrile)palladium(II) dichloride
4,4-dimethyl-2-pentyne
A
bis-triphenylphosphine-palladium(II) chloride
B
[(σ,π-CBu(t)=CMeCMe=CBu(t)Cl)PdCl]2
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane N2-atmosphere; addn. of 2 equiv. of pentyne derivative to Pd-complex soln. (ice-water bath), addn. of 1 equiv. PPh3 soln. (pptn.); filtration off of PPh3-complex, evapn. to dryness (0°C, reduced pressure), washing (light petroleum), drying in air; elem. anal.; | A n/a B 72% |
dichloro bis(acetonitrile) palladium(II)
acetonitrile
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane (Ar); Pd complex added to a soln. of Ru complex, stirred for 1 h; stirred at 0°C for 30 min, filtered, concd. (vac.), MeCN added, crystd. at -30°C for 2 d, filtered, washed (cold MeCN), dried (vac.); elem. anal.; | A n/a B 70% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 2.4:1), stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.; | A 68% B >99 |
benzylidene dichloride
tetrakis(triphenylphosphine) palladium(0)
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene byproducts: (E)-stilbene, 1,2-dichloro-1,2-diphenylethane; to soln. of Pd(PPh3)4 in benzene added PhCHCl2 under N2, stirred at room temp. for 5 h; dild. with pentanes, crystals filtered, washed with ether, dried in vac.; GLC anal.; | 64% |
bis(benzonitrile)palladium(II) dichloride
n-Butyl nitrite
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With carbon monoxide; triphenylphosphine In neat (no solvent) stirring (1 h), bubbling of CO; filtn., pptn. on addn. of pentane; elem.anal.; | A 40% B 60% |
((C5H5)Ru(C5H3C(C6H5)NC6H4CH3))2Pd2Cl2
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Ru(C5H3C(C6H5)NC6H4CH3)PdCl(P(C6H5)3)
Conditions | Yield |
---|---|
In benzene room temp.; filtn., pptn. (hexane); elem. anal.; | A n/a B 57% |
tetrakis(triphenylphosphine) palladium(0)
p-methoxyphenylisocyanide
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With HCl In ethanol; toluene CNC6H4OMe in PhMe added dropwise to stirred suspn. of Pd(PPh3)4 in PhMeunder N2, stirred for ca. 1 h, cooled to -70°C, 0.22 M HCl/EtOH in PhMe added dropwise during ca. 2 h, stirred at -70°C for 90 min, allowed to warm to room temp. (3 h); ppt. filtered off, soln. concd., pptd. with Et2O, redissolved in (CH2Cl)2/Et2O, treated with activated charcoal, filtered, concd., pptd. by addn. of Et2O; elem. anal.; | A n/a B 55% |
With HCl In ethanol; toluene 0.26 M ethanolic soln. of HCl added dropwise (30 min) to stirred suspn.of Pd(PPh3)4 in toluene at -70°C under N2, soln. of isocyanide in toluene added dropwise during ca. 10 min, allowed to warm to room temp. (ca. 2 h); concd., Et2O added, sepd. by fractional pptn. from (CH2Cl)2/Et2O; elem.anal.; | A n/a B 16% |
cis-(PPh3)2 bis(azido)palladium(II)
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In chloroform byproducts: N2; Irradiation (UV/VIS); flash photolysis; not isolated; UV/VIS monitoring; | 53% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
[Fe((η(5)-C5H3)C(CH3)=NC6H5)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 52% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
d,l-[Fe((η(5)-C5H3)C(CH3)=NC6H4-4-CH3)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 8% C 46% |
2-(4-nitrophenyl)ethylamine monohydrochloride
palladium diacetate
A
bis-triphenylphosphine-palladium(II) chloride
[Pd(C6H3(CH2)2NH2-2-NO2-5-κ2C,N)Cl(PPh3)]
Conditions | Yield |
---|---|
In acetonitrile Pd(OAc)2 and 4-nitrophenethylamine*HCl in MeCN were refluxed for 16 h, suspn. was filtered through MgSO4, solvent was removed, CH2Cl2 was added,PPh3 was added and stirred for 30 min; soln. was filtered through MgSO4 and concd., ppt. was filtered off, Et2O/n-hexane (1:1) was added to filtrate, ppt. was filtered, washed with n-hexane, and air-dried; elem. anal.; | A 30% B 37% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene complex heated in C6H6 at 75°C for 15 min; (Ar); hexane added at room temp., ppt. filtered off, extd. (CH2Cl2); extract treated with hexane, ppt. reprecipitated (hexane from CH2Cl2, twice), washed (pentane), dried (vac.); elem. anal.; | A n/a B 35% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Ru(C5H3C(CH3)NC6H4CH3)PdCl(P(C6H5)3)
Conditions | Yield |
---|---|
In benzene room temp.; filtn., pptn. (hexane); elem. anal.; | A n/a B 34% |
tetrakis(triphenylphosphine) palladium(0)
(C5H5)Rh(OC6H4(CH3)(CCl3))
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Rh(OC7H4(CH3)Cl)
Conditions | Yield |
---|---|
In benzene byproducts: Ph3P; stirring (20°C, 72 h); concn., chromy. (SiO2, C6H5/EtOH), recry; | A n/a B 34% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
[Pd([(η-(5)-C5H3)C(H)=NCH2C6H5]Fe[(η(5)-C5H4)C(H)=NCH2C6H5])ClPPh3]
[Fe((η(5)-C5H3)CH=NCH2C6H5)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 7% C 32% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With CH3CO2Na*3H2O; triphenylphosphine In methanol stirring equimolar amts. of Na2PdCl4, ferrocene derivative and AcONa inMeOH for 3 h (room temp., protection from light; pptn.), collection (filtration), washing (MeOH), suspending in C6H6, stirring with excess of PPh3 for 30 min; filtration, evapn. of filtrate (reduced pressure), dissoln. in CHCl3, chromy. (SiO2, CHCl3), evapn. (reduced pressure), treatment with hexane (pptn.); elem. anal.; | A n/a B 5% C 15% |
bis-triphenylphosphine-palladium(II) chloride
PdCl[1,3-bis(diphenylthiophosphinoyl)indene(-1H)]
[PdCl[Ind(Ph2PS)2]]PdCl(PPh3)
Conditions | Yield |
---|---|
With polysterene-supported diisopropylethylamine In dichloromethane (under Ar, Schlenk); suspn. of Pd-complexes and polysterene-supported diisopropylethylamine in CH2Cl2 stirred overnight at room temp.; filtered, pentane added, filtered, washed with pentane, dried under vac.; elem. anal.; | 98% |
bis-triphenylphosphine-palladium(II) chloride
acrylic acid methyl ester
methyl cinnamate
Conditions | Yield |
---|---|
With sodium acetate; silver trifluoroacetate In acetonitrile at 60℃; for 24h; Heck Reaction; Schlenk technique; Inert atmosphere; | 98% |
bis-triphenylphosphine-palladium(II) chloride
acetophenone dimethylhydrazone
Conditions | Yield |
---|---|
With NaOCOCH3 In acetonitrile mixt. of freshly distilled hydrazone, Pd(PPh3)2Cl2 and NaOAc in MeCN is heated at 75°C for 48 h under Ar, mixt. is cooled to room temp.; solvent is evapd., chromy. (hexane-EtOAc 4:1); elem. anal.; | 97% |
bis-triphenylphosphine-palladium(II) chloride
triphenylphosphine
lithium bromide
bis(triphenylphosphine)palladium dibromide
Conditions | Yield |
---|---|
In chloroform; isopropyl alcohol at 20℃; for 2h; | 96% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique; | 96% |
bis-triphenylphosphine-palladium(II) chloride
methyl magnesium iodide
9-iodo-m-carborane
9,10-dimethyl-1,7-carborane
Conditions | Yield |
---|---|
In diethyl ether refluxed for 5-15 h under nitrogen; monitored by tlc; decomposed with water;; washed with dilute HCl and with water; dried over Na2SO4; chromd. on silica gel with petroleum ether eluent; distilled in vac.; sublimed in vac. at 30-60°C; recrystd. from pentane; elem. anal.;; | 95% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With H2 In further solvent(s) complex soln. in aniline stirred under H2 at 90°C; aniline removed (vac.), ppt. washed (Et2O and C6H6), C6H6 filtrate concd. (vac.), pptd. (hexane under Ar), washed with hexane and Et2O, dried (vac.), recrystd. (toluene under Ar); elem. anal.; | 95% |
bis-triphenylphosphine-palladium(II) chloride
silver tetrafluoroborate
1-(azidomethyl)-2-isocyanobenzene
trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate
Conditions | Yield |
---|---|
In dichloromethane; acetone byproducts: AgCl; under N2; 1 M soln. of AgBF4 in acetone added to a suspn. of Pd-complex in CH2Cl2 at room temp., stirred for 30 min., AgCl filtered off, filtrate treated with isonitrile, stirred for 2.5 h; Et2O added, ppt. filtered off, dried under vac.; elem. anal.; | 94.3% |
bis-triphenylphosphine-palladium(II) chloride
tetraphenylimidothioxodiphosphinic acid potassium salt
Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)]PF6
Conditions | Yield |
---|---|
In methanol elem. anal.; | 94% |
bis-triphenylphosphine-palladium(II) chloride
Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)]PF6
Conditions | Yield |
---|---|
In methanol elem. anal.; | 94% |
carbon disulfide
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In not given Ru complex was treated with CS2 under basic conditions followed by addn.Pd complex; | 94% |
bis-triphenylphosphine-palladium(II) chloride
C16H17N3O4
Conditions | Yield |
---|---|
With triethylamine In methanol mixt. of Pd complex, OC(C6H4OCH3)NHNCHC5HN(CH2OH)(CH3)(OH) (1 equiv.) and triethylamine stirred and heted at reflux for 3 h; ppt. washed with MeOH, ether, dried in vac., crystd. from CHCl3/MeOH at room temp.; elem. anal.; | 94% |
bis-triphenylphosphine-palladium(II) chloride
5-hexyl-1-ol
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol; (S)-methyl 5-amino-4-(4-bromo-1-oxoisoindolin-2-yl)-5-oxopentanoate With copper(l) iodide; triethylamine In N,N-dimethyl-formamide Inert atmosphere; Stage #2: bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; Sealed tube; | 94% |
bis-triphenylphosphine-palladium(II) chloride
trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide
Conditions | Yield |
---|---|
With CuI; 3,5-bis[(dimethylamino)methyl]phenylacetylene In diethylamine byproducts: (3,5-(Me2NCH2)2C6H3)2C2; (N2); 6 d at room temp.; evapd. (vac.), dissolved in Et2O/Et2NH, filtered, evapd. (vac.), crystd. in pentane; elem. anal.; | 93% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C; | 92.9% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C; elem. anal; | 92.6% |
bis-triphenylphosphine-palladium(II) chloride
{μ-(Ph3P)2PdS2}Fe2(CO)6
Conditions | Yield |
---|---|
In not given | 92% |
bis-triphenylphosphine-palladium(II) chloride
(3-diphenylphosphino)propanethiol
dichlorobis(μ-[(3-diphenylphosphino)propanethiolato]-P,μ-S)dipalladium(II)
Conditions | Yield |
---|---|
In dichloromethane N2-atmosphere; equimolar amts., 30 min; concn. (vac.) hexane addn. crystn. (-24°C, 12 h), collection (filtration), washing (hexane), drying; | 92% |
bis-triphenylphosphine-palladium(II) chloride
N-phenylmethyl-2-pyridinecarbothioamide
Pd(Cl)(κ2-S,N-C6H4CS-N-(4-Bz)(PPh3))
Conditions | Yield |
---|---|
In ethanol at 80℃; for 3h; | 92% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In methanol at 20℃; | 92% |
bis-triphenylphosphine-palladium(II) chloride
silver tetrafluoroborate
{Pd(P(C6H5)3)2(BF4)2}
Conditions | Yield |
---|---|
In nitromethane byproducts: AgCl; stirring mixt. of Pd complex and AgBF4 in CH3NO2 at room temp. for 2 d, under anaerobic conditions;; filtration; removal of solvent in vac.; dissolving in CH2Cl2; evapn. to dryness; repptn. with CH2Cl2/(C2H5)2O/pentane; washing with pentane; drying in vac.; elem. anal.;; | 91% |
bis-triphenylphosphine-palladium(II) chloride
N-methyl N'-cyanoisothiourea sodium salt
Pd(SCNHCNNCH3)2(P(C6H5)3)2
Conditions | Yield |
---|---|
In methanol; water to suspn. of Pd-complex in MeOH was added ligand in MeOH, stirred for 24h at room temp.; filtered, washed with water, dried in vacuo; elem. anal.; | 91% |
bis-triphenylphosphine-palladium(II) chloride
N-(4-methyl-phenyl)-α-thiopicolinamide
[Pd(Cl)(κ2-S,N-C6H4CS=N-(4-MePh)(PPh3)]
Conditions | Yield |
---|---|
In ethanol to soln. ligand in EtOH Pd complex was added and heated under reflux for3 h; react. mixt. was cooled to room temp., ppt. was filtered, washed with EtOH and dried in vacuo; elem. anal.; | 91% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 65℃; for 2h; Inert atmosphere; | 91% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In acetone stoichiometric amts., refluxing (2 h), pptn.; | 90% |
The IUPAC name of Bis(triphenylphosphine)palladium(II) chloride is palladium(2+); triphenylphosphane; dichloride. With the CAS registry number 13965-03-2, it is also named as Dichlorobis(triphenylphosphine)palladium. The product's categories are Metal Compounds; Catalysts-Ligands; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Pd (Palladium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds. It is yellow crystalline powder which is stable under normal temperature and pressure. Additionally, this chemical should be sealed in the container and stored in the dry place.
The other characteristics of this product can be summarized as: (1)ACD/LogP: 5.69; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 5.69; (4)ACD/LogD (pH 7.4): 5.69; (5)ACD/BCF (pH 5.5): 12427.96; (6)ACD/BCF (pH 7.4): 12427.96; (7)ACD/KOC (pH 5.5): 29672.91; (8)ACD/KOC (pH 7.4): 29672.91; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Enthalpy of Vaporization: 58.18 kJ/mol; (13)Vapour Pressure: 4.74E-05 mmHg at 25°C; (14)Rotatable Bond Count: 6; (15)Exact Mass: 700.023462; (16)MonoIsotopic Mass: 700.023462; (17)Heavy Atom Count: 41; (18)Complexity: 202.
Preparation of Bis(triphenylphosphine)palladium(II) chloride: It can be obtained by reaction of palladium(II) chloride with triphenylphosphine.
PdCl2 + 2 PPh3 → PdCl2(PPh3)2
Uses of Bis(triphenylphosphine)palladium(II) chloride: It is used as a catalyst for palladium-catalyzed coupling reactions, e.g. the Suzuki, Kumada, Negishi. It is an intermediate in the preparation of tetrakis(triphenylphosphine)palladium (Pd(PPh3)4):
PdCl2(PPh3)2 + 2 PPh3 + 2.5 N2H4 → Pd(PPh3)4 + 0.5 N2 + 2 N2H5+Cl-
When you are using this chemical, please be cautious about it as the following:
It is not only harmful if swallowed, but also irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable gloves and eye/face protection.
People can use the following data to convert to the molecule structure.
1. Smiles:c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Pd+2].[ClH-].[ClH-]
2. InChI:InChI=1/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
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