Add time:08/24/2019 Source:sciencedirect.com
Excess molar volumes at 298.15, 308.15, and 318.15 K of (1-bromobutane + toluene) have been determined using a vibrating-tube digital densimeter. Their isothermal compressibilities at the same temperatures and also at 333.15 K have been measured using a direct-measurement piezometric technique. Excess molar Gibbs free energies at 343.15 K have been calculated from vapour-pressure measurements. The experimental results show that the mixture is essentially ideal with respect to each of the three mentioned quantities.
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